CN108126293A - A kind of compound protein fire foam - Google Patents
A kind of compound protein fire foam Download PDFInfo
- Publication number
- CN108126293A CN108126293A CN201711279093.6A CN201711279093A CN108126293A CN 108126293 A CN108126293 A CN 108126293A CN 201711279093 A CN201711279093 A CN 201711279093A CN 108126293 A CN108126293 A CN 108126293A
- Authority
- CN
- China
- Prior art keywords
- parts
- protein
- nano
- water
- compound protein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
- A62D1/0078—Foams containing proteins or protein derivatives
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Cosmetics (AREA)
- Materials For Medical Uses (AREA)
Abstract
The invention discloses a kind of compound protein fire foams, belong to technical field of fire safety.The compound protein foam that the present invention the develops extinguishing chemical that goes out is made of protein hydrolysate, antifreezing agent, stabilizer, preservative and water, wherein protein hydrolysate is by after animal protein and water ultrasonic disperse, after being mixed with small molecule liquid glucose, constant temperature is stirred to react, after pre-cooled again, vacuum freeze drying, and heating stirring hydrolyzes to obtain under acid condition, and stabilizer is then made of polyallylamine, nano-powder, sodium sulfite and carbomer, antifreezing agent is small molecule alcohol substance, and nano-powder is then nano-oxide.Compound protein fire foam prepared by technical solution of the present invention has the characteristics that excellent extinguishing property, while its stability is significantly improved compared to conventional foam extinguishing chemical.
Description
Technical field
The invention discloses a kind of compound protein fire foams, belong to technical field of fire safety.
Background technology
For protein foam extinguishing agent since thermal stability is good, analysis liquid is slower, the long period can seal pasta, be widely used in
In the combustible liquid fires not soluble in water such as various petroleum-type products, grease, be current China's output is maximum, application range most
One of wide extinguishing chemical.Its main component is the biochemical substances such as protein, carbohydrate, it is easy to degrade and environment will not be caused forever
Long contact scar has the higher value of environmental protection.Protein foam extinguishing agent is divided into animal protein type and vegetable protein type, mesh by raw material
Preceding domestic production is based on animal protein type.Its protein is to be formed with objects such as animal hair, hoof, angles through acid or basic hydrolysis, water
Environmental pollution is heavier in solution preocess, and can generate in fire extinguishing procedure largely containing mercaptan, thioether, hydrosulfuric acid foul gas,
Pollute air.When vegetable protein fire foam had both overcome the production of animal protein foam extinguishing chemical and dirt to air during fire extinguishing
Dye, and without chemical to the corrosion of place related substances and the pollution of environment of putting out a fire, thus by International Environmental Protection tissue institute
It praises highly.Albumen, fluoroprotein foam extinguishing agent base-material be mainly animal protein, the sulfur-containing compound in hydrolysate is hydrolyzed
Inorganic sulfide compound and sulfur-bearing residue are generated, is easily generated after leading to eggwhite type foam extinguishing agent storage for a period of time unpleasant
" stench " taste is not easy to be received.In addition to this, eggwhite type foam extinguishing chemical also pollutes big, foam in the prevalence of production technology
Stability is poor with mobility, and extinguishing effect is poor, and resistance to resume combustion is bad, and unstable product quality and Storage period are shorter etc.
Problem restricts the application of eggwhite type foam extinguishing chemical product.
Therefore, the shortcomings that how improving traditional protein fire foam foam stability difference and bad extinguishing property, to obtain
The protein foam extinguishing agent of more high combination property is taken, is that it is promoted and applies, meets industrial production demand urgent problem to be solved.
Invention content
The present invention solves the technical problem of：For traditional protein fire foam foam stability difference and fire extinguishing property
Can be bad the shortcomings that, provide a kind of compound protein fire foam.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of compound protein fire foam, is made of the raw material of following parts by weight：
80~100 parts of protein hydrolysate
8~10 parts of antifreezing agent
20~30 parts of stabilizer
3~5 parts of preservative
20~30 parts of water
The protein hydrolysate preparation process is：
（1）It is 1 in mass ratio by animal protein and water：80~1：Ultrasonic disperse after 90 mixing, obtains dispersion liquid, and gained is disperseed
Liquid is 1 by volume with small molecule liquid glucose：1~3：1 mixing, constant temperature are stirred to react 4~8h, obtain reaction mixture；
（2）After gained reaction mixture precooling, vacuum freeze drying obtains modified animal albumen；
（3）It is 1 in mass ratio by modified animal albumen and water：40~1：50 are stirred, and with careless acid for adjusting pH to 2.0~
2.2, heating stirring hydrolyzes 4~6h, obtains protein hydrolysate；
The stabilizer is made of the raw material of following parts by weight：30~40 parts of polyallylamines, 10~15 parts of nano-powders, 8
~10 parts of sodium sulfites, 8~10 parts of carbomers.
The antifreezing agent is any one in hexylene glycol, glycerine or ethylene glycol.
The preservative is that phenol, sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 is configured.
Step（1）The animal protein is any one in collagen or feather keratin.
Step（1）The small molecule liquid glucose configuration process is：It is 1 in mass ratio：10~1：20 are scattered in small molecular sugar
In deionized water, small molecule liquid glucose is obtained；The small molecular sugar is any one in sucrose, glucose or lactose.
The nano-powder is nano silicon dioxide, nano zine oxide, nano aluminium oxide, nano magnesia or nano-silica
Change any one in titanium.
The carbomer is carbomer 910, any one in carbomer 934 or Acritamer 940.
The beneficial effects of the invention are as follows：
（1）Technical solution of the present invention passes through in animal protein surface grafting glycosyl, on the one hand, the space bit provided using glycosyl
The interface film thickness that resistance can be such that graft product is formed in gas-water interface increases, so as to improve the foam stability after product use,
On the other hand, by being aided with carbomer, the addition of carbomer can form hydrogen bond with glycosyl, so as to formed on interface film compared with
Strong mucous gels reticular structure, in addition, because containing more acid groups, therefore adsorbable addition in carbomer molecular structure
Nano oxide powder, and after the film thickness increase of interface, it is beneficial to the absorption of carbomer mucous gels reticular structure and more receives
Rice oxide powder so as to make nano oxide powder close-packed arrays at interfacial film, generates hydrodynamics flowing in liquid film
Larger resistance so as to slow down the drain of liquid film, and due to the dense arrangement of nano oxide powder, reduces connecing for gas and water
Contacting surface is accumulated, and interfacial film is made to keep higher mechanical strength, so as to which product stability be made further to be promoted；
（2）Technical solution of the present invention is by adding a small amount of polyallylamine, in preparation process, by high-speed stirred can make air with
Micro-bubble form is scattered in system, and polyallylamine can gradually absorb the carbon dioxide in air, and make in carbon dioxide
It is crosslinked under, makes to form cross-linked network inside system, so as to further promote product stability, and polyallylamine absorbs two
, can be by carbon dioxide storage in system, in use after carbonoxide, heated rear decomposable asymmetric choice net discharges carbon dioxide again,
So as to further improve product extinguishing property.
Specific embodiment
It is 1 in mass ratio：10~1：Small molecular sugar with deionized water is mixed and is poured into beaker by 20, with glass bar stirring point
10~15min is dissipated, obtains small molecule liquid glucose；It is 1 in mass ratio by animal protein and water：80~1：After 90 mixing, in supersonic frequency
For 45~55kHz, under the conditions of temperature is 45~55 DEG C, 45~60min of ultrasonic disperse obtains dispersion liquid, and by gained dispersion liquid with
Small molecule liquid glucose is 1 by volume：1~1：Reactor is poured into 3 mixing, is 75~90 DEG C in temperature, rotating speed is 500~600r/
Under the conditions of min, constant temperature is stirred to react 4~8h, reaction mixture is obtained, and gained reaction mixture is transferred in refrigerator, in temperature
Under the conditions of -28~-30 DEG C, 8~12h is pre-chilled, then the reaction mixture after precooling is transferred to vacuum freeze drier, in temperature
It it is -50 DEG C, under the conditions of pressure is 20~30Pa, vacuum freeze drying 12~for 24 hours, discharging obtains modified animal albumen, then by gained
Modified animal albumen is 1 in mass ratio with water：40~1：Hydrolysis kettle is poured into 50 mixing, and is 20% oxalic acid solution with mass fraction
PH to 2.0~2.2 is adjusted, to the end of pH is adjusted, is 95~100 DEG C in temperature, under the conditions of rotating speed is 600~800r/min, adds
Thermal agitation hydrolyzes 4~6h, obtains protein hydrolysate；It counts in parts by weight, takes 80~100 parts of protein hydrolysate successively, 8~10 parts antifreeze
Agent, 20~30 parts of stabilizers, 3~5 portions of preservatives, 20~30 parts of water first add in protein hydrolysate in batch mixer, adjust batch mixer
Under stirring, stabilizer is added in into batch mixer, is stirred 40~60min to 800~1200r/min for speed of agitator
Afterwards, antifreezing agent, preservative and water are sequentially added, continues to mix 3~5h with 1600~2000r/min rotating speeds high-speed stirred, go out
Material, it is filling to get compound protein fire foam.The stabilizer is made of the raw material of following parts by weight：30~40 parts
Polyallylamine, 10~15 parts of nano-powders, 8~10 parts of sodium sulfites, 8~10 parts of carbomers.The antifreezing agent is hexylene glycol, third
Any one in triol or ethylene glycol.The preservative is that phenol, sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 matches
It puts.The animal protein is any one in collagen or feather keratin.The small molecular sugar is sucrose, grape
Sugar or lactose in any one.The nano-powder is nano silicon dioxide, nano zine oxide, nano aluminium oxide, nano oxygen
Change any one in magnesium or nano-titanium dioxide.The carbomer is carbomer 910, in carbomer 934 or Acritamer 940
Any one.
Example 1
It is 1 in mass ratio：Small molecular sugar with deionized water is mixed and is poured into beaker by 20, is dispersed with stirring 15min with glass bar, is obtained
Small molecule liquid glucose；It is 1 in mass ratio by animal protein and water：It is 55kHz in supersonic frequency, temperature is 55 DEG C of items after 90 mixing
Under part, ultrasonic disperse 60min obtains dispersion liquid, and is 1 by volume by gained dispersion liquid and small molecule liquid glucose：3 mixing are poured into anti-
Device is answered, is 90 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 8h, obtains reaction mixture, and gained is anti-
Mixture is answered to be transferred in refrigerator, under the conditions of temperature is -30 DEG C, 12h is pre-chilled, then the reaction mixture after precooling is transferred to vacuum
Freeze drier is -50 DEG C in temperature, and under the conditions of pressure is 30Pa, for 24 hours, discharging obtains modified animal egg to vacuum freeze drying
In vain, then by gained modified animal albumen and water it is 1 in mass ratio：Hydrolysis kettle is poured into 50 mixing, and is 20% oxalic acid with mass fraction
Solution adjusts pH to 2.2, is 100 DEG C in temperature, under the conditions of rotating speed is 800r/min, heating stirring hydrolyzes to the end of pH is adjusted
6h obtains protein hydrolysate；It counts in parts by weight, takes 100 parts of protein hydrolysate, 10 parts of antifreezing agents, 30 parts of stabilizers, 5 parts of anti-corrosions successively
Agent, 30 parts of water first add in protein hydrolysate in batch mixer, batch mixer speed of agitator are adjusted to 1200r/min, in stirring
Under, stabilizer is added in into batch mixer, after being stirred 60min, sequentially adds antifreezing agent, preservative and water, continue with
2000r/min rotating speeds high-speed stirred mixes 5h, and discharging is filling to get compound protein fire foam.The stabilizer be by with
The raw material composition of lower parts by weight：40 parts of polyallylamines, 15 parts of nano-powders, 10 parts of sodium sulfites, 10 parts of carbomers.It is described anti-
Jelly agent is hexylene glycol.The preservative is that phenol, sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 is configured.It is described
Animal protein is collagen.The small molecular sugar is sucrose.The nano-powder is nano silicon dioxide.The carbomer is
Carbomer 910.
Example 2
It is 1 in mass ratio by animal protein and water：After 90 mixing, it is 55kHz in supersonic frequency, under the conditions of temperature is 55 DEG C, surpasses
Sound disperse 60min, obtain dispersion liquid to get reaction mixture, and by gained reaction mixture be transferred in refrigerator, in temperature be -30
Under the conditions of DEG C, 12h is pre-chilled, then the reaction mixture after precooling is transferred to vacuum freeze drier, in temperature be -50 DEG C, pressure
Under the conditions of 30Pa, for 24 hours, discharging obtains modified animal albumen, then gained modified animal albumen and water is pressed matter vacuum freeze drying
Amount is than being 1：Hydrolysis kettle is poured into 50 mixing, and adjusts pH to 2.2 for 20% oxalic acid solution with mass fraction, to the end of pH is adjusted, in
Temperature is 100 DEG C, and under the conditions of rotating speed is 800r/min, heating stirring hydrolysis 6h obtains protein hydrolysate；It counts in parts by weight, successively
Take 100 parts of protein hydrolysate, 10 parts of antifreezing agents, 30 parts of stabilizers, 5 portions of preservatives, protein hydrolysate first adds in batch mixer by 30 parts of water
In, batch mixer speed of agitator is adjusted to 1200r/min, and under stirring, stabilizer is added in into batch mixer, is stirred
After 60min, antifreezing agent, preservative and water are sequentially added, continues to mix 5h with 2000r/min rotating speeds high-speed stirred, discharge, fill
Dress is to get compound protein fire foam.The stabilizer is made of the raw material of following parts by weight：40 parts of polyallylamines,
15 parts of nano-powders, 10 parts of sodium sulfites, 10 parts of carbomers.The antifreezing agent is hexylene glycol.The preservative is phenol, benzene first
Sour sodium and potassium sorbate are 1 in mass ratio：2：1 is configured.The animal protein is collagen.The small molecular sugar is sugarcane
Sugar.The nano-powder is nano silicon dioxide.The carbomer is carbomer 910.
Example 3
It is 1 in mass ratio：Small molecular sugar with deionized water is mixed and is poured into beaker by 20, is dispersed with stirring 15min with glass bar, is obtained
Small molecule liquid glucose；It is 1 in mass ratio by animal protein and water：It is 55kHz in supersonic frequency, temperature is 55 DEG C of items after 90 mixing
Under part, ultrasonic disperse 60min obtains dispersion liquid, and is 1 by volume by gained dispersion liquid and small molecule liquid glucose：3 mixing are poured into anti-
Device is answered, is 90 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 8h, obtains reaction mixture, and gained is anti-
Mixture is answered to be transferred in refrigerator, under the conditions of temperature is -30 DEG C, 12h is pre-chilled, then the reaction mixture after precooling is transferred to vacuum
Freeze drier is -50 DEG C in temperature, and under the conditions of pressure is 30Pa, for 24 hours, discharging obtains modified animal egg to vacuum freeze drying
In vain, then by gained modified animal albumen and water it is 1 in mass ratio：Hydrolysis kettle is poured into 50 mixing, and is 20% oxalic acid with mass fraction
Solution adjusts pH to 2.2, is 100 DEG C in temperature, under the conditions of rotating speed is 800r/min, heating stirring hydrolyzes to the end of pH is adjusted
6h obtains protein hydrolysate；It counts in parts by weight, takes 100 parts of protein hydrolysate, 10 parts of antifreezing agents, 30 parts of stabilizers, 5 parts of anti-corrosions successively
Agent, 30 parts of water first add in protein hydrolysate in batch mixer, batch mixer speed of agitator are adjusted to 1200r/min, in stirring
Under, stabilizer is added in into batch mixer, after being stirred 60min, sequentially adds antifreezing agent, preservative and water, continue with
2000r/min rotating speeds high-speed stirred mixes 5h, and discharging is filling to get compound protein fire foam.The stabilizer be by with
The raw material composition of lower parts by weight：40 parts of polyallylamines, 15 parts of nano-powders, 10 parts of sodium sulfites.The antifreezing agent for oneself two
Alcohol.The preservative is that phenol, sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 is configured.The animal protein is
Collagen.The small molecular sugar is sucrose.The nano-powder is nano silicon dioxide.
Example 4
It is 1 in mass ratio：Small molecular sugar with deionized water is mixed and is poured into beaker by 20, is dispersed with stirring 15min with glass bar, is obtained
Small molecule liquid glucose；It is 1 in mass ratio by animal protein and water：It is 55kHz in supersonic frequency, temperature is 55 DEG C of items after 90 mixing
Under part, ultrasonic disperse 60min obtains dispersion liquid, and is 1 by volume by gained dispersion liquid and small molecule liquid glucose：3 mixing are poured into anti-
Device is answered, is 90 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 8h, obtains reaction mixture, and gained is anti-
Mixture is answered to be transferred in refrigerator, under the conditions of temperature is -30 DEG C, 12h is pre-chilled, then the reaction mixture after precooling is transferred to vacuum
Freeze drier is -50 DEG C in temperature, and under the conditions of pressure is 30Pa, for 24 hours, discharging obtains modified animal egg to vacuum freeze drying
In vain, then by gained modified animal albumen and water it is 1 in mass ratio：Hydrolysis kettle is poured into 50 mixing, and is 20% oxalic acid with mass fraction
Solution adjusts pH to 2.2, is 100 DEG C in temperature, under the conditions of rotating speed is 800r/min, heating stirring hydrolyzes to the end of pH is adjusted
6h obtains protein hydrolysate；It counts in parts by weight, takes 100 parts of protein hydrolysate, 10 parts of antifreezing agents, 30 parts of stabilizers, 5 parts of anti-corrosions successively
Agent, 30 parts of water first add in protein hydrolysate in batch mixer, batch mixer speed of agitator are adjusted to 1200r/min, in stirring
Under, stabilizer is added in into batch mixer, after being stirred 60min, sequentially adds antifreezing agent, preservative and water, continue with
2000r/min rotating speeds high-speed stirred mixes 5h, and discharging is filling to get compound protein fire foam.The stabilizer be by with
The raw material composition of lower parts by weight：40 parts of polyallylamines, 10 parts of sodium sulfites, 10 parts of carbomers.The antifreezing agent is hexylene glycol.
The preservative is that phenol, sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 is configured.The animal protein is collagen
Albumen.The small molecular sugar is sucrose.The carbomer is carbomer 910.
Example 5
It is 1 in mass ratio：Small molecular sugar with deionized water is mixed and is poured into beaker by 20, is dispersed with stirring 15min with glass bar, is obtained
Small molecule liquid glucose；It is 1 in mass ratio by animal protein and water：It is 55kHz in supersonic frequency, temperature is 55 DEG C of items after 90 mixing
Under part, ultrasonic disperse 60min obtains dispersion liquid, and is 1 by volume by gained dispersion liquid and small molecule liquid glucose：3 mixing are poured into anti-
Device is answered, is 90 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 8h, obtains reaction mixture, and gained is anti-
Mixture is answered to be transferred in refrigerator, under the conditions of temperature is -30 DEG C, 12h is pre-chilled, then the reaction mixture after precooling is transferred to vacuum
Freeze drier is -50 DEG C in temperature, and under the conditions of pressure is 30Pa, for 24 hours, discharging obtains modified animal egg to vacuum freeze drying
In vain, then by gained modified animal albumen and water it is 1 in mass ratio：Hydrolysis kettle is poured into 50 mixing, and is 20% oxalic acid with mass fraction
Solution adjusts pH to 2.2, is 100 DEG C in temperature, under the conditions of rotating speed is 800r/min, heating stirring hydrolyzes to the end of pH is adjusted
6h obtains protein hydrolysate；It counts in parts by weight, takes 100 parts of protein hydrolysate, 10 parts of antifreezing agents, 30 parts of stabilizers, 5 parts of anti-corrosions successively
Agent, 30 parts of water first add in protein hydrolysate in batch mixer, batch mixer speed of agitator are adjusted to 1200r/min, in stirring
Under, stabilizer is added in into batch mixer, after being stirred 60min, sequentially adds antifreezing agent, preservative and water, continue with
2000r/min rotating speeds high-speed stirred mixes 5h, and discharging is filling to get compound protein fire foam.The stabilizer be by with
The raw material composition of lower parts by weight：15 parts of nano-powders, 10 parts of sodium sulfites, 10 parts of carbomers.The antifreezing agent is hexylene glycol.
The preservative is that phenol, sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 is configured.The animal protein is collagen
Albumen.The small molecular sugar is sucrose.The nano-powder is nano silicon dioxide.The carbomer is carbomer 910.
Comparative example：The protein foam extinguishing agent of Shandong fire-fighting equipment Co., Ltd production.
The compound protein fire foam of 1 to 5 gained of example and comparative example product are subjected to performance detection, specific detection side
Method is as follows：
1. foam stability：Using 2152 type Roche foam meters, 25% drainage time of foam, the extinguishing chemical of drainage time length are measured
Stability is good；
2. extinguishing property：Test specimen extinguishing property is detected according to GB 15308.
Specific testing result is as shown in table 1：
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Comparative example |
| 25% drainage time/s | 39 | 33 | 29 | 27 | 24 | 11 |
| Attack time/s | 40 | 69 | 83 | 91 | 93 | 273 |
| Fire resistanttime/min | 25.3 | 20.2 | 19.8 | 17.5 | 16.3 | 11.4 |
By 1 testing result of table it is found that compound protein fire foam prepared by technical solution of the present invention has excellent fire extinguishing
The characteristics of energy, while its stability is significantly improved compared to conventional foam extinguishing chemical, is had in the development of extinguishing chemical industry wide
Wealthy prospect.
Claims (7)
1. a kind of compound protein fire foam, it is characterised in that：It is made of the raw material of following parts by weight：
80~100 parts of protein hydrolysate
8~10 parts of antifreezing agent
20~30 parts of stabilizer
3~5 parts of preservative
20~30 parts of water
The protein hydrolysate preparation process is：
（1）It is 1 in mass ratio by animal protein and water：80~1：Ultrasonic disperse after 90 mixing, obtains dispersion liquid, and gained is disperseed
Liquid is 1 by volume with small molecule liquid glucose：1~3：1 mixing, constant temperature are stirred to react 4~8h, obtain reaction mixture；
（2）After gained reaction mixture precooling, vacuum freeze drying obtains modified animal albumen；
（3）It is 1 in mass ratio by modified animal albumen and water：40~1：50 are stirred, and with careless acid for adjusting pH to 2.0~
2.2, heating stirring hydrolyzes 4~6h, obtains protein hydrolysate；
The stabilizer is made of the raw material of following parts by weight：30~40 parts of polyallylamines, 10~15 parts of nano-powders, 8
~10 parts of sodium sulfites, 8~10 parts of carbomers.
2. a kind of compound protein fire foam according to claim 1, it is characterised in that：The antifreezing agent for oneself two
Any one in alcohol, glycerine or ethylene glycol.
3. a kind of compound protein fire foam according to claim 1, it is characterised in that：The preservative for phenol,
Sodium benzoate and potassium sorbate are 1 in mass ratio：2：1 is configured.
4. a kind of compound protein fire foam according to claim 1, it is characterised in that：Step（1）The animal egg
Any one white in collagen or feather keratin.
5. a kind of compound protein fire foam according to claim 1, it is characterised in that：Step（1）The small molecule
Liquid glucose configuration process is：It is 1 in mass ratio：10~1：20 are scattered in small molecular sugar in deionized water, obtain small molecule liquid glucose；Institute
Small molecular sugar is stated as any one in sucrose, glucose or lactose.
6. a kind of compound protein fire foam according to claim 1, it is characterised in that：The nano-powder is nanometer
Any one in silica, nano zine oxide, nano aluminium oxide, nano magnesia or nano-titanium dioxide.
7. a kind of compound protein fire foam according to claim 1, it is characterised in that：The carbomer is carbomer
910, any one in carbomer 934 or Acritamer 940.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711279093.6A CN108126293A (en) | 2017-12-06 | 2017-12-06 | A kind of compound protein fire foam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711279093.6A CN108126293A (en) | 2017-12-06 | 2017-12-06 | A kind of compound protein fire foam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108126293A true CN108126293A (en) | 2018-06-08 |
Family
ID=62389089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711279093.6A Pending CN108126293A (en) | 2017-12-06 | 2017-12-06 | A kind of compound protein fire foam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108126293A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108992828A (en) * | 2018-07-05 | 2018-12-14 | 何治伟 | A kind of macromolecule hydrogel extinguishing chemical |
| CN110604898A (en) * | 2019-09-18 | 2019-12-24 | 浙江华消科技有限公司 | Fire extinguishing agent and application thereof |
| CN112439156A (en) * | 2020-11-18 | 2021-03-05 | 安徽理工大学 | Foam fire prevention and extinguishing material and preparation method and application thereof |
| CN112604225A (en) * | 2020-12-30 | 2021-04-06 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of graphene composite fumed silica foam extinguishing agent and product thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60259279A (en) * | 1984-06-04 | 1985-12-21 | 株式会社 初田製作所 | Water film forming capacity protein fire extinguishing agent |
| CN101491723A (en) * | 2009-03-05 | 2009-07-29 | 宁波能林消防器材有限公司 | Protein foam fire extinguisher production method using hoof and horn grain |
| CN101745194A (en) * | 2009-12-29 | 2010-06-23 | 天津市裕川置业集团有限公司 | Sludge microorganism protein foam extinguishing agent and preparation method thereof |
| CN104815411A (en) * | 2015-04-03 | 2015-08-05 | 滨州学院 | Novel foam fire extinguishing agent |
| CN104958860A (en) * | 2015-07-15 | 2015-10-07 | 安徽天元消防科技有限公司 | Vegetable protein foam extinguishing agent |
| CN106925181A (en) * | 2017-02-14 | 2017-07-07 | 榆林学院 | A kind of hair protein foaming agent and preparation method thereof |
| FR3061025A1 (en) * | 2016-12-23 | 2018-06-29 | Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic | NOVEL SURFACE MIXTURE, NOVEL COMPOSITION COMPRISING THE SAME AND USE THEREOF IN EMULSIONS FOR COMBATTING FIRES |
-
2017
- 2017-12-06 CN CN201711279093.6A patent/CN108126293A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60259279A (en) * | 1984-06-04 | 1985-12-21 | 株式会社 初田製作所 | Water film forming capacity protein fire extinguishing agent |
| CN101491723A (en) * | 2009-03-05 | 2009-07-29 | 宁波能林消防器材有限公司 | Protein foam fire extinguisher production method using hoof and horn grain |
| CN101745194A (en) * | 2009-12-29 | 2010-06-23 | 天津市裕川置业集团有限公司 | Sludge microorganism protein foam extinguishing agent and preparation method thereof |
| CN104815411A (en) * | 2015-04-03 | 2015-08-05 | 滨州学院 | Novel foam fire extinguishing agent |
| CN104958860A (en) * | 2015-07-15 | 2015-10-07 | 安徽天元消防科技有限公司 | Vegetable protein foam extinguishing agent |
| FR3061025A1 (en) * | 2016-12-23 | 2018-06-29 | Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic | NOVEL SURFACE MIXTURE, NOVEL COMPOSITION COMPRISING THE SAME AND USE THEREOF IN EMULSIONS FOR COMBATTING FIRES |
| CN106925181A (en) * | 2017-02-14 | 2017-07-07 | 榆林学院 | A kind of hair protein foaming agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 李灿鹏等: "《蛋品科学与技术》", 30 April 2013, 中国质检出版社 * |
| 胡振铎: "《短平快致富技术200例3》", 31 October 1997, 四川科学技术出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108992828A (en) * | 2018-07-05 | 2018-12-14 | 何治伟 | A kind of macromolecule hydrogel extinguishing chemical |
| CN110604898A (en) * | 2019-09-18 | 2019-12-24 | 浙江华消科技有限公司 | Fire extinguishing agent and application thereof |
| CN112439156A (en) * | 2020-11-18 | 2021-03-05 | 安徽理工大学 | Foam fire prevention and extinguishing material and preparation method and application thereof |
| CN112604225A (en) * | 2020-12-30 | 2021-04-06 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of graphene composite fumed silica foam extinguishing agent and product thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108126293A (en) | A kind of compound protein fire foam | |
| CN103553420B (en) | A kind of lignin-base foam concrete foamer and preparation method thereof and application | |
| CN110016323B (en) | Self-repairing gel-based phase change material and preparation method thereof | |
| CN106867463A (en) | A kind of graphene oxide composite aquogel based phase-change material and its preparation method and application | |
| CN109517212A (en) | Preparation method of cellulose-graphene oxide-chitosan ternary composite aerogel | |
| CN108992830A (en) | A kind of high-adhesiveness hydrogel extinguishing chemical and preparation method thereof | |
| CN103160269A (en) | Water base guanidine gum fracturing fluid and preparation method thereof | |
| CN101974193B (en) | Method for preparing low-leaching-rate water-swellable rubbers | |
| CN107899173A (en) | A kind of alcohol foam extinguishing chemical of continuous-stable | |
| CN104356975A (en) | Preparation method of modified starch adhesive | |
| CN108837366A (en) | A kind of preparation method of non-fusibility aqueous film-forming foam extinguishing agent | |
| CN107778767A (en) | A kind of preparation method of lignin phenol formaldehyde resin foamed material | |
| CN107446523A (en) | A kind of glued board adhesive | |
| Jaktorn et al. | Production of thermal insulator from water hyacinth fiber and natural rubber latex | |
| CN101284882B (en) | Process for depriving acetyl of kanjak glucomannosan | |
| CN102533275A (en) | Natural gum adhesive for ecological restoration and application thereof | |
| CN113896450B (en) | Powder foaming agent for preparing cement-based foam material and preparation method thereof | |
| CN104725804A (en) | Polylactic acid-fir powder-bamboo fiber composite material and preparation method thereof | |
| CN107903738A (en) | A kind of corrosion-resistant waterproof material and preparation method thereof | |
| CN106625947A (en) | Composite modifying agent added with oxide graphene modified emulsion for fast growing wood | |
| CN103012978A (en) | Rubber mixture | |
| Tako et al. | Calcium Induced Association Characteristics of Alginates | |
| CN102127232A (en) | Graft modification method for lignosulfonate | |
| CN104262658A (en) | Preparation method for degradable polysaccharide-based hemicellulose composite biomembrane | |
| CN106517984B (en) | A kind of building decoration fire proofing material and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180608 |
|
| RJ01 | Rejection of invention patent application after publication |