CN108117266A - A kind of wear-resisting acid corrosion-resistant glass - Google Patents
A kind of wear-resisting acid corrosion-resistant glass Download PDFInfo
- Publication number
- CN108117266A CN108117266A CN201711488005.3A CN201711488005A CN108117266A CN 108117266 A CN108117266 A CN 108117266A CN 201711488005 A CN201711488005 A CN 201711488005A CN 108117266 A CN108117266 A CN 108117266A
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- CN
- China
- Prior art keywords
- wear
- acid corrosion
- resistant glass
- glass
- resisting acid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/004—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of particles or flakes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
Abstract
The invention discloses a kind of wear-resisting acid corrosion-resistant glass, are related to glassmaking art, are made of following component：Silica 95, glass microballoon 13, silicon nitride 39, nano-ceramic particle 1.2, talcum powder 46,1.5 aluminum sulfate 0.6 of zinc borate, cerium chloride 0.01, Melamine are attapulgite modified 6 12, sodium tetraborate decahydrate 0.5, triisobutyl aluminium 0.8, sodium tripolyphosphate 0.3, calcining sericite in powder 46；A kind of wear-resisting acid corrosion-resistant glass prepared by the present invention not only with good acid corrosion-resistant performance, while also has good wear-resisting and heat resistance.
Description
Technical field
The invention belongs to glassmaking arts, and in particular to a kind of wear-resisting acid corrosion-resistant glass.
Background technology
Glass can be divided into oxide glass and nonoxide glass by its main component, and zirconium dioxide has excellent heat surely
Qualitative and chemical stability, have high-melting-point, higher boiling, thermal conductivity factor is small, hardness is big, wearability is good, under room temperature for insulator,
The characteristics of high refractive index, but existing glass acid corrosion-resistant performance is poor, can not meet the needs of market.
The content of the invention
The purpose of the present invention is being directed to the problem of existing, a kind of wear-resisting acid corrosion-resistant glass is provided.
The present invention is achieved by the following technical solutions：
A kind of wear-resisting acid corrosion-resistant glass, is made by weight of following component：Silica 95, glass microballoon 1-3, nitridation
Silicon 3-9, nano-ceramic particle 1.2, talcum powder 4-6,1.5 aluminum sulfate 0.6 of zinc borate, cerium chloride 0.01, Melamine are modified recessed
Convex stick soil 6-12, sodium tetraborate decahydrate 0.5, triisobutyl aluminium 0.8, sodium tripolyphosphate 0.3, calcining sericite in powder 4-6.
Further, the attapulgite modified preparation method of the Melamine is：
Attapulgite and mass fraction are pressed into 50g for 6.5% sodium radio-phosphate,P-32 solution：After the ratio uniform mixing of 350mL, ground
Mill, grinding rotating speed are 3500r/min, are then filtered, and impregnate 10min using deionized water, then drying to constant weight, crosses 500
Mesh sieve, then the attapulgite after drying and melamine are pressed 30:1 mass ratio uniformly mixes, and then quickly heats up to 430 again
DEG C, with 100r/min rotating speeds stir 35min, then cooled to room temperature to get.
Further, the rate of heat addition for quickly heating up to 430 DEG C is 10 DEG C/s.
Further, the nano-ceramic particle granularity is 120nm.
Further, the glass microballoon and silicon nitride weight part ratio are 1:3.
Further, the calcining sericite in powder preparation method is：Sericite in powder is calcined into 45min at 880 DEG C, then
After being cooled to 50 DEG C, the mass fraction for being added to 5 times of its quality is to be impregnated in 1.5% neopelex solution
Then 30min is filtered, drying to constant weight.
The present invention has the following advantages compared with prior art：A kind of wear-resisting acid corrosion-resistant glass prepared by the present invention, not only
With good acid corrosion-resistant performance, while also there is good wear-resisting and heat resistance, and with good transparency, have
Good surface property after the use of long period, remains to keep color constant, is not in yellowing phenomenon, the present invention
By using the attapulgite modified synergistic effect with calcining sericite in powder of Melamine, it can effectively improve the wear-resisting of glass
With acid corrosion-resistant performance so that glass works under external environment for a long time can still keep higher transparency.
Specific embodiment
Embodiment 1
A kind of wear-resisting acid corrosion-resistant glass, is made by weight of following component：Silica 95, glass microballoon 1, silicon nitride
3rd, nano-ceramic particle 1.2, talcum powder 4-6,1.5 aluminum sulfate 0.6 of zinc borate, cerium chloride 0.01, Melamine modified attapulgite
Soil 6, sodium tetraborate decahydrate 0.5, triisobutyl aluminium 0.8, sodium tripolyphosphate 0.3, calcining sericite in powder 4.
Further, the attapulgite modified preparation method of the Melamine is：
Attapulgite and mass fraction are pressed into 50g for 6.5% sodium radio-phosphate,P-32 solution：After the ratio uniform mixing of 350mL, ground
Mill, grinding rotating speed are 3500r/min, are then filtered, and impregnate 10min using deionized water, then drying to constant weight, crosses 500
Mesh sieve, then the attapulgite after drying and melamine are pressed 30:1 mass ratio uniformly mixes, and then quickly heats up to 430 again
DEG C, with 100r/min rotating speeds stir 35min, then cooled to room temperature to get.
Further, the rate of heat addition for quickly heating up to 430 DEG C is 10 DEG C/s.
Further, the nano-ceramic particle granularity is 120nm.
Further, the glass microballoon and silicon nitride weight part ratio are 1:3.
Further, the calcining sericite in powder preparation method is：Sericite in powder is calcined into 45min at 880 DEG C, then
After being cooled to 50 DEG C, the mass fraction for being added to 5 times of its quality is to be impregnated in 1.5% neopelex solution
Then 30min is filtered, drying to constant weight.
Embodiment 2
A kind of wear-resisting acid corrosion-resistant glass, is made by weight of following component：Silica 95, glass microballoon 2, silicon nitride
6th, nano-ceramic particle 1.2, talcum powder 5,1.5 aluminum sulfate 0.6 of zinc borate, cerium chloride 0.01, Melamine are attapulgite modified
10th, sodium tetraborate decahydrate 0.5, triisobutyl aluminium 0.8, sodium tripolyphosphate 0.3, calcining sericite in powder 5.
Further, the attapulgite modified preparation method of the Melamine is：
Attapulgite and mass fraction are pressed into 50g for 6.5% sodium radio-phosphate,P-32 solution：After the ratio uniform mixing of 350mL, ground
Mill, grinding rotating speed are 3500r/min, are then filtered, and impregnate 10min using deionized water, then drying to constant weight, crosses 500
Mesh sieve, then the attapulgite after drying and melamine are pressed 30:1 mass ratio uniformly mixes, and then quickly heats up to 430 again
DEG C, with 100r/min rotating speeds stir 35min, then cooled to room temperature to get.
Further, the rate of heat addition for quickly heating up to 430 DEG C is 10 DEG C/s.
Further, the nano-ceramic particle granularity is 120nm.
Further, the glass microballoon and silicon nitride weight part ratio are 1:3.
Further, the calcining sericite in powder preparation method is：Sericite in powder is calcined into 45min at 880 DEG C, then
After being cooled to 50 DEG C, the mass fraction for being added to 5 times of its quality is to be impregnated in 1.5% neopelex solution
Then 30min is filtered, drying to constant weight.
Embodiment 3
A kind of wear-resisting acid corrosion-resistant glass, is made by weight of following component：Silica 95, glass microballoon 3, silicon nitride
9th, nano-ceramic particle 1.2, talcum powder 4-6,1.5 aluminum sulfate 0.6 of zinc borate, cerium chloride 0.01, Melamine modified attapulgite
Soil 12, sodium tetraborate decahydrate 0.5, triisobutyl aluminium 0.8, sodium tripolyphosphate 0.3, calcining sericite in powder 6.
Further, the attapulgite modified preparation method of the Melamine is：
Attapulgite and mass fraction are pressed into 50g for 6.5% sodium radio-phosphate,P-32 solution：After the ratio uniform mixing of 350mL, ground
Mill, grinding rotating speed are 3500r/min, are then filtered, and impregnate 10min using deionized water, then drying to constant weight, crosses 500
Mesh sieve, then the attapulgite after drying and melamine are pressed 30:1 mass ratio uniformly mixes, and then quickly heats up to 430 again
DEG C, with 100r/min rotating speeds stir 35min, then cooled to room temperature to get.
Further, the rate of heat addition for quickly heating up to 430 DEG C is 10 DEG C/s.
Further, the nano-ceramic particle granularity is 120nm.
Further, the glass microballoon and silicon nitride weight part ratio are 1:3.
Further, the calcining sericite in powder preparation method is：Sericite in powder is calcined into 45min at 880 DEG C, then
After being cooled to 50 DEG C, the mass fraction for being added to 5 times of its quality is to be impregnated in 1.5% neopelex solution
Then 30min is filtered, drying to constant weight.
Comparative example 1：With embodiment 1 differ only in by Melamine it is attapulgite modified replace with common concave-convex stick soil.
The performance test results that abrasion-resistance glass is made are as shown in table 1：
Table 1
| Refractive index % | Vickers hardness | |
| Embodiment 1 | 1.89 | 786 |
| Embodiment 2 | 1.88 | 782 |
| Embodiment 3 | 1.87 | 781 |
| Comparative example 1 | 1.35 | 556 |
As can be seen from Table 1, the glass that prepared by the present invention has good hardness and refractive index.
Claims (6)
1. a kind of wear-resisting acid corrosion-resistant glass, which is characterized in that be made by weight of following component：Silica 95, glass
Glass microballon 1-3, silicon nitride 3-9, nano-ceramic particle 1.2, talcum powder 4-6,1.5 aluminum sulfate 0.6 of zinc borate, cerium chloride 0.01,
The attapulgite modified 6-12 of Melamine, sodium tetraborate decahydrate 0.5, triisobutyl aluminium 0.8, sodium tripolyphosphate 0.3, calcining thin,tough silk cloud
Female powder 4-6.
A kind of 2. wear-resisting acid corrosion-resistant glass as described in claim 1, which is characterized in that the Melamine modified attapulgite
Native preparation method is：
Attapulgite and mass fraction are pressed into 50g for 6.5% sodium radio-phosphate,P-32 solution：After the ratio uniform mixing of 350mL, ground
Mill, grinding rotating speed are 3500r/min, are then filtered, and impregnate 10min using deionized water, then drying to constant weight, crosses 500
Mesh sieve, then the attapulgite after drying and melamine are pressed 30:1 mass ratio uniformly mixes, and then quickly heats up to 430 again
DEG C, with 100r/min rotating speeds stir 35min, then cooled to room temperature to get.
3. a kind of wear-resisting acid corrosion-resistant glass as claimed in claim 2, which is characterized in that described to quickly heat up to 430 DEG C
The rate of heat addition is 10 DEG C/s.
4. a kind of wear-resisting acid corrosion-resistant glass as described in claim 1, which is characterized in that the nano-ceramic particle granularity is
120nm。
5. a kind of wear-resisting acid corrosion-resistant glass as described in claim 1, which is characterized in that the glass microballoon and silicon nitride weight
Amount part is compared for 1:3.
A kind of 6. wear-resisting acid corrosion-resistant glass as described in claim 1, which is characterized in that the calcining sericite in powder preparation side
Method is：Sericite in powder is calcined into 45min at 880 DEG C, after being subsequently cooled to 50 DEG C, is added to the mass fraction of 5 times of its quality
To impregnate 30min in 1.5% neopelex solution, then filter, drying to constant weight.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711488005.3A CN108117266A (en) | 2017-12-30 | 2017-12-30 | A kind of wear-resisting acid corrosion-resistant glass |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711488005.3A CN108117266A (en) | 2017-12-30 | 2017-12-30 | A kind of wear-resisting acid corrosion-resistant glass |
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| CN108117266A true CN108117266A (en) | 2018-06-05 |
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Application publication date: 20180605 |
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