CN105907202A - Composite heat insulation paint and preparation method thereof - Google Patents
Composite heat insulation paint and preparation method thereof Download PDFInfo
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- CN105907202A CN105907202A CN201610295237.6A CN201610295237A CN105907202A CN 105907202 A CN105907202 A CN 105907202A CN 201610295237 A CN201610295237 A CN 201610295237A CN 105907202 A CN105907202 A CN 105907202A
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- insulation coating
- heat insulation
- compound heat
- preparation
- propylgallate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Catalysts (AREA)
Abstract
The invention provides composite heat insulation paint and a preparation method thereof. The composite heat insulation paint is prepared from the following ingredients including nanosilicon dioxide, nanometer titanium dioxide, bismuth oxychloride, liquid paraffin, calcium stearate, erucyl amide, nano-silver, aqueous acrylic resin, ammonium dihydrogen phosphate, propylgallate, resveratrol, sodium dodecyl benzene sulfonate, sodium benzoate, calcium propionate, isopropanol and water. The composite heat insulation paint is prepared from the following steps of (1) performing mixing and grinding on the nanometer titanium dioxide and the bismuth oxychloride; (2) putting the materials into a muffle furnace to be roasted; (3) mixing and stirring propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol; (4) mixing all ingredients, and performing high-speed dispersion by a high-speed homogeneous machine to obtain the composite heat insulation paint. The composite heat insulation paint provided by the invention has the advantages that the reflectivity on the infrared light is high; heat energy can be well insulated; a good heat insulation effect is achieved; meanwhile, a good bacteriostasis effect is achieved.
Description
Technical field
The present invention relates to paint field, be specifically related to a kind of compound heat-insulation coating and preparation method thereof.
Background technology
Along with the swift and violent growth of China's economic society, the made rapid progress of science and technology, people are more and more higher to the requirement of environment and material.Wherein, people there has also been the biggest raising for the requirement of the living environment of oneself, and because material heat absorption causes the too high problem being exactly one of them people and urgently wanting to solve of house facade temperature.Therefore, research and develop the insulating moulding coating that a kind of effect is good, have very important meaning to solving this problem.Insulating moulding coating is a kind of new function type coating that Recent study is the most popular, it is applied to surface of wall and can reduce interior of building temperature, thus reaching to reduce the purpose of energy resource consumption, it can be divided mainly into Radiation Heat-insulated Paint, isolation-type insulating moulding coating and reflection type thermal insulation coating etc..The shortcoming of Radiation Heat-insulated Paint is that the sintering process of the selection of base material and material is complex;Although isolation-type insulating moulding coating has that thermal conductivity is low, dielectric constant is little and the advantage such as corrosion-resistant, but have the most water-fast, adhesive force is little and the not shortcoming such as temperature tolerance;And reflection type thermal insulation coating is a kind of newer technology, have that good heat-insulation effect, technique is simple, an advantage such as light weight and persistency length, be worth studying further.
Summary of the invention
Solve the technical problem that:It is an object of the invention to provide a kind of compound heat-insulation coating, higher near infrared reflectance, the extraordinary obstruct heat energy of energy, there is good effect of heat insulation, meanwhile, there is good fungistatic effect.
Technical scheme:A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 1-2 part, nano titanium oxide 2-4 part, bismuth oxychloride 1-3 part, liquid paraffin 0.2-0.4 part, calcium stearate 0.1-0.3 part, erucyl amide 0.1-0.2 part, nanometer silver 0.1-0.2 part, water-borne acrylic resin 20-35 part, ammonium dihydrogen phosphate 0.1-0.2 part, propylgallate 0.2-0.5 part, resveratrol 0.1-0.3 part, dodecylbenzene sodium sulfonate 1-2 part, sodium benzoate 0.1-0.3 part, calcium propionate 0.1-0.2 part, isopropanol 4-8 part, water 40-60 part.
Further preferred, described a kind of compound heat-insulation coating, it is prepared from weight portion by following component: nano silicon 1.1-1.6 part, nano titanium oxide 2.5-3.5 part, bismuth oxychloride 1.5-2.5 part, liquid paraffin 0.25-0.35 part, calcium stearate 0.15-0.25 part, erucyl amide 0.11-0.16 part, nanometer silver 0.11-0.16 part, water-borne acrylic resin 25-30 part, ammonium dihydrogen phosphate 0.11-0.17 part, propylgallate 0.3-0.4 part, resveratrol 0.15-0.25 part, dodecylbenzene sodium sulfonate 1.3-1.8 part, sodium benzoate 0.15-0.25 part, calcium propionate 0.11-0.16 part, isopropanol 5-7 part, water 45-55 part.
The preparation method of above-mentioned compound heat-insulation coating comprises the following steps:
(1) will mix by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 100-120 minute;
(2) put in Muffle furnace, roasting 2-2.5 hour at temperature 600-650 DEG C;
(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 20-40 minute under rotating speed 60-90r/min with magnetic stirrer;
(4) all components is mixed, by high speed homogenizer high speed dispersion 5-10 minute and get final product under rotating speed 1000-1200r/min.
It is further preferred that milling time is 105-115 minute in step (1).
It is further preferred that temperature is 630 DEG C in step (2), roasting time is 2 hours.
It is further preferred that step (3) medium speed is 70-80r/min, the time is 25-35 minute.
It is further preferred that step (4) medium speed is 1050-1150 r/min, jitter time is 7.5 minutes.
Beneficial effect:The compound heat-insulation coating of the present invention is up to 83.7% near infrared reflectance, can extraordinary obstruct heat energy, there is good effect of heat insulation, meanwhile, the suppression ratio of escherichia coli and staphylococcus aureus reached 100%, there is good fungistatic effect.
Detailed description of the invention
Embodiment 1
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 1.1 parts, nano titanium oxide 2.5 parts, bismuth oxychloride 1.5 parts, liquid paraffin 0.25 part, calcium stearate 0.15 part, erucyl amide 0.11 part, nanometer silver 0.11 part, water-borne acrylic resin 25 parts, ammonium dihydrogen phosphate 0.11 part, propylgallate 0.3 part, resveratrol 0.15 part, dodecylbenzene sodium sulfonate 1.3 parts, sodium benzoate 0.15 part, calcium propionate 0.11 part, isopropanol 5 parts, 45 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 105 minutes;(2) put in Muffle furnace, roasting 2 hours at temperature 630 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 25 minutes under rotating speed 70r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 7.5 minutes and get final product under rotating speed 1050r/min.
Embodiment 2
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 1.6 parts, nano titanium oxide 3.5 parts, bismuth oxychloride 2.5 parts, liquid paraffin 0.35 part, calcium stearate 0.25 part, erucyl amide 0.16 part, nanometer silver 0.16 part, water-borne acrylic resin 30 parts, ammonium dihydrogen phosphate 0.17 part, propylgallate 0.4 part, resveratrol 0.25 part, dodecylbenzene sodium sulfonate 1.8 parts, sodium benzoate 0.25 part, calcium propionate 0.16 part, isopropanol 7 parts, 55 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 115 minutes;(2) put in Muffle furnace, roasting 2 hours at temperature 630 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 35 minutes under rotating speed 80r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 7.5 minutes and get final product under rotating speed 1150r/min.
Embodiment 3
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 1 part, nano titanium oxide 2 parts, bismuth oxychloride 1 part, liquid paraffin 0.2 part, calcium stearate 0.1 part, erucyl amide 0.1 part, nanometer silver 0.1 part, water-borne acrylic resin 20 parts, ammonium dihydrogen phosphate 0.1 part, propylgallate 0.2 part, resveratrol 0.1 part, dodecylbenzene sodium sulfonate 1 part, sodium benzoate 0.1 part, calcium propionate 0.1 part, isopropanol 4 parts, 40 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 100 minutes;(2) put in Muffle furnace, roasting 2 hours at temperature 600 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 20 minutes under rotating speed 60r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 5 minutes and get final product under rotating speed 1000r/min.
Embodiment 4
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 1.5 parts, nano titanium oxide 3 parts, bismuth oxychloride 2 parts, liquid paraffin 0.3 part, calcium stearate 0.15 part, erucyl amide 0.15 part, nanometer silver 0.15 part, water-borne acrylic resin 27 parts, ammonium dihydrogen phosphate 0.15 part, propylgallate 0.35 part, resveratrol 0.2 part, dodecylbenzene sodium sulfonate 1.5 parts, sodium benzoate 0.2 part, calcium propionate 0.15 part, isopropanol 6 parts, 50 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 110 minutes;(2) put in Muffle furnace, roasting 2 hours at temperature 625 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 30 minutes under rotating speed 75r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 7.5 minutes and get final product under rotating speed 1100r/min.
Embodiment 5
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 2 parts, nano titanium oxide 4 parts, bismuth oxychloride 3 parts, liquid paraffin 0.4 part, calcium stearate 0.3 part, erucyl amide 0.2 part, nanometer silver 0.2 part, water-borne acrylic resin 35 parts, ammonium dihydrogen phosphate 0.2 part, propylgallate 0.5 part, resveratrol 0.3 part, dodecylbenzene sodium sulfonate 2 parts, sodium benzoate 0.3 part, calcium propionate 0.2 part, isopropanol 8 parts, 60 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 120 minutes;(2) put in Muffle furnace, roasting 2.5 hours at temperature 650 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 40 minutes under rotating speed 90r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 10 minutes and get final product under rotating speed 1200r/min.
Comparative example 1
The present embodiment is not contain liquid paraffin and erucyl amide with the difference of embodiment 5.Specifically:
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 2 parts, nano titanium oxide 4 parts, bismuth oxychloride 3 parts, calcium stearate 0.3 part, nanometer silver 0.2 part, water-borne acrylic resin 35 parts, ammonium dihydrogen phosphate 0.2 part, propylgallate 0.5 part, resveratrol 0.3 part, dodecylbenzene sodium sulfonate 2 parts, sodium benzoate 0.3 part, calcium propionate 0.2 part, isopropanol 8 parts, 60 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 120 minutes;(2) put in Muffle furnace, roasting 2.5 hours at temperature 650 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 40 minutes under rotating speed 90r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 10 minutes and get final product under rotating speed 1200r/min.Comparative example 2
The present embodiment is not contain nanometer silver and ammonium dihydrogen phosphate with the difference of embodiment 5.Specifically:
A kind of compound heat-insulation coating, is prepared from weight portion by following component: nano silicon 2 parts, nano titanium oxide 4 parts, bismuth oxychloride 3 parts, liquid paraffin 0.4 part, calcium stearate 0.3 part, erucyl amide 0.2 part, nanometer silver 0.2 part, water-borne acrylic resin 35 parts, propylgallate 0.5 part, resveratrol 0.3 part, dodecylbenzene sodium sulfonate 2 parts, sodium benzoate 0.3 part, calcium propionate 0.2 part, isopropanol 8 parts, 60 parts of water.
The preparation method of above-mentioned compound heat-insulation coating is: (1) will be mixed by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 120 minutes;(2) put in Muffle furnace, roasting 2.5 hours at temperature 650 DEG C;(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 40 minutes under rotating speed 90r/min with magnetic stirrer;(4) all components is mixed, by high speed homogenizer high speed dispersion 10 minutes and get final product under rotating speed 1200r/min.
The performance indications of material of the present invention are as follows, it may be seen that the present invention is up to 83.7% near infrared reflectance, and the extraordinary obstruct heat energy of energy, there is good effect of heat insulation, meanwhile, the suppression ratio of escherichia coli and staphylococcus aureus is reached 100%, there is good fungistatic effect.
The performance indications of table 1 compound heat-insulation coating
Claims (7)
1. a compound heat-insulation coating, it is characterized in that: be prepared from weight portion by following component: nano silicon 1-2 part, nano titanium oxide 2-4 part, bismuth oxychloride 1-3 part, liquid paraffin 0.2-0.4 part, calcium stearate 0.1-0.3 part, erucyl amide 0.1-0.2 part, nanometer silver 0.1-0.2 part, water-borne acrylic resin 20-35 part, ammonium dihydrogen phosphate 0.1-0.2 part, propylgallate 0.2-0.5 part, resveratrol 0.1-0.3 part, dodecylbenzene sodium sulfonate 1-2 part, sodium benzoate 0.1-0.3 part, calcium propionate 0.1-0.2 part, isopropanol 4-8 part, water 40-60 part.
nullA kind of compound heat-insulation coating the most according to claim 1,It is characterized in that: be prepared from weight portion by following component: nano silicon 1.1-1.6 part、Nano titanium oxide 2.5-3.5 part、Bismuth oxychloride 1.5-2.5 part、Liquid paraffin 0.25-0.35 part、Calcium stearate 0.15-0.25 part、Erucyl amide 0.11-0.16 part、Nanometer silver 0.11-0.16 part、Water-borne acrylic resin 25-30 part、Ammonium dihydrogen phosphate 0.11-0.17 part、Propylgallate 0.3-0.4 part、Resveratrol 0.15-0.25 part、Dodecylbenzene sodium sulfonate 1.3-1.8 part、Sodium benzoate 0.15-0.25 part、Calcium propionate 0.11-0.16 part、Isopropanol 5-7 part、Water 45-55 part.
3. the preparation method of a kind of compound heat-insulation coating described in any one of claim 1 to 2, it is characterised in that: comprise the following steps:
(1) will mix by nano titanium oxide and bismuth oxychloride, be placed in mortar grinding 100-120 minute;
(2) put in Muffle furnace, roasting 2-2.5 hour at temperature 600-650 DEG C;
(3) propylgallate, liquid paraffin, calcium stearate, erucyl amide, resveratrol and isopropanol are mixed, stir 20-40 minute under rotating speed 60-90r/min with magnetic stirrer;
(4) all components is mixed, by high speed homogenizer high speed dispersion 5-10 minute and get final product under rotating speed 1000-1200r/min.
The preparation method of a kind of compound heat-insulation coating the most according to claim 3, it is characterised in that: in described step (1), milling time is 105-115 minute.
The preparation method of a kind of compound heat-insulation coating the most according to claim 3, it is characterised in that: in described step (2), temperature is 630 DEG C, and roasting time is 2 hours.
The preparation method of a kind of compound heat-insulation coating the most according to claim 3, it is characterised in that: described step (3) medium speed is 70-80r/min, and the time is 25-35 minute.
The preparation method of a kind of compound heat-insulation coating the most according to claim 3, it is characterised in that: described step (4) medium speed is 1050-1150 r/min, and jitter time is 7.5 minutes.
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CN201610295237.6A CN105907202A (en) | 2016-05-06 | 2016-05-06 | Composite heat insulation paint and preparation method thereof |
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CN201610295237.6A CN105907202A (en) | 2016-05-06 | 2016-05-06 | Composite heat insulation paint and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107383573A (en) * | 2017-07-13 | 2017-11-24 | 北京华腾新材料股份有限公司 | One kind contains near infrared absorption and reflection composite pigment multifunctional transparent heat insulating coat and polyolefin coextruded film and preparation |
CN109852175A (en) * | 2018-12-19 | 2019-06-07 | 南京红枫环保材料有限公司 | A kind of reflective insulation exterior wall paint and preparation method thereof |
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CN101831224A (en) * | 2010-04-02 | 2010-09-15 | 中国建筑科学研究院深圳分院 | Nano-rare earth heat-insulated transparent coating and preparation method thereof |
CN102618134A (en) * | 2012-04-10 | 2012-08-01 | 江苏思力玻璃科技有限公司 | Water-based glass heat insulation paint |
CN102702886A (en) * | 2012-05-09 | 2012-10-03 | 佛山市福泉新材料科技发展有限公司 | Nano-insulation reflective paint |
CN103555102A (en) * | 2013-10-14 | 2014-02-05 | 苏州富莱希涂料有限公司 | Reflective thermal-insulation exterior wall coating |
-
2016
- 2016-05-06 CN CN201610295237.6A patent/CN105907202A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101831224A (en) * | 2010-04-02 | 2010-09-15 | 中国建筑科学研究院深圳分院 | Nano-rare earth heat-insulated transparent coating and preparation method thereof |
CN102618134A (en) * | 2012-04-10 | 2012-08-01 | 江苏思力玻璃科技有限公司 | Water-based glass heat insulation paint |
CN102702886A (en) * | 2012-05-09 | 2012-10-03 | 佛山市福泉新材料科技发展有限公司 | Nano-insulation reflective paint |
CN103555102A (en) * | 2013-10-14 | 2014-02-05 | 苏州富莱希涂料有限公司 | Reflective thermal-insulation exterior wall coating |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107383573A (en) * | 2017-07-13 | 2017-11-24 | 北京华腾新材料股份有限公司 | One kind contains near infrared absorption and reflection composite pigment multifunctional transparent heat insulating coat and polyolefin coextruded film and preparation |
CN107383573B (en) * | 2017-07-13 | 2020-01-24 | 北京华腾新材料股份有限公司 | Multifunctional transparent heat-insulating coating containing near-infrared absorption and reflection composite pigment, polyolefin co-extruded film and preparation |
CN109852175A (en) * | 2018-12-19 | 2019-06-07 | 南京红枫环保材料有限公司 | A kind of reflective insulation exterior wall paint and preparation method thereof |
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Application publication date: 20160831 |