CN108093724A - A kind of method using the swollen pearl improvement soil of high-titanium blast furnace slag - Google Patents

A kind of method using the swollen pearl improvement soil of high-titanium blast furnace slag Download PDF

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Publication number
CN108093724A
CN108093724A CN201711364501.8A CN201711364501A CN108093724A CN 108093724 A CN108093724 A CN 108093724A CN 201711364501 A CN201711364501 A CN 201711364501A CN 108093724 A CN108093724 A CN 108093724A
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China
Prior art keywords
blast furnace
furnace slag
pearl
titanium blast
slag
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Pending
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CN201711364501.8A
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Chinese (zh)
Inventor
鲜中菊
杨志远
邓梅艳
蓝静
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PANZHIHUA HUANYE METALLURGY REFUSE DEVELOPMENT Co Ltd
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PANZHIHUA HUANYE METALLURGY REFUSE DEVELOPMENT Co Ltd
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Priority to CN201711364501.8A priority Critical patent/CN108093724A/en
Publication of CN108093724A publication Critical patent/CN108093724A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/02Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/02Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
    • C09K17/04Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only applied in a physical form other than a solution or a grout, e.g. as granules or gases
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Environmental Sciences (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Road Paving Structures (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)

Abstract

The invention discloses a kind of methods using the swollen pearl improvement soil of high-titanium blast furnace slag, belong to soil remediation field.The technical problem to be solved in the present invention is to provide a kind of methods using trade waste high-titanium blast furnace slag improvement soil.A kind of method using the swollen pearl improvement soil of high-titanium blast furnace slag, including:The swollen pearl of high-titanium blast furnace slag is evenly laid out in upper soll layer, it is ploughed, the swollen pearl of high-titanium blast furnace slag is made to be uniformly mixed with soil, you can.The method of the present invention improves soil using the swollen pearl of high-titanium blast furnace slag, after adding in swollen pearl, energy moisture-locking, inhibit moisture evaporation, ensure plant growth moisture content requirement, improve ground temperature, reduce salinity and accumulated in earth's surface, plant growth situation can be effectively improved, the soil improvement especially suitable for hillside fields and non-solid water.

Description

A kind of method using the swollen pearl improvement soil of high-titanium blast furnace slag
Technical field
The invention belongs to soil remediation fields, and in particular to a kind of side using the swollen pearl improvement soil of high-titanium blast furnace slag Method.
Background technology
Soil improvement is to improve the physics of soil, chemistry and biological property, it is made to be more suitable for plant growth, effectively Ground improves soil moisture content, increases topsoil ground temperature, shifts to an earlier date Crop growing stage, and soil moisture increases, while can also improve soil knot Structure coordinates the relation between the soil water, fertilizer, air and heat and biology, prevents erosion, and enhances anti-seepage of channels ability, inhibits soil Secondary salinization improves the utilization of sandy bare land.
High-titanium blast furnace slag is when climbing steel ordinary blast to smelt vanadium titano-magnetite, and the melted gangue of generation is natural in air A kind of fine and close slag with some strength that cooling or water cooling are formed.With ordinary blast slag ratio, titanium dioxide in steel climbing high slag Titanium (TiO2) content is up to 20%~24% (since high-titanium blast furnace slag titaniferous amount is high, also referred to as high-titanium dry slag), calcium oxide Content is relatively low, i.e. the grain slag of raw material production belongs to non-active material, and therefore, climb steel has more than 5,500 ten thousand tons of high titania type height so far Clinker is not utilized, it takes up an area thousands of mus, and it is annual also increased with 3,000,000 tons of bed drain purge, climb steel and be faced with and nowhere arrange The situation of slag.Can high-titanium blast furnace slag be integrated into utilizing, and not only influence and climb steel, the sustainable development of Panzhihua social economy Exhibition, and to saving natural resources, reduce engineering cost, protection Upper Yangtze River ecological environment etc. and be respectively provided with important meaning.
Utilization for high-titanium dry slag, there are two types of different technology paths, have both carried titanium and have utilized and do not propose titanium utilization. It is utilized for carrying titanium, although realizing the most dreamboat of high-titanium dry slag value, due to current limitation of the technology, utilizes cost It is high, the consumption of blast furnace slag is also extremely limited, still remaining most slags after titanium is carried, therefore to solve to climb steel slag at present Bulk deposition, land occupation, the realistic problem for polluting environment, the task of top priority must also walk not carrying the way that titanium utilizes high-titanium dry slag Footpath.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of soil is improved using trade waste high-titanium blast furnace slag Method
There is provided a kind of swollen using high-titanium blast furnace slag for technical solution used by the present invention solves above-mentioned technical problem The method that pearl improves soil, this method comprise the following steps:
The swollen pearl of high-titanium blast furnace slag is evenly laid out in upper soll layer, it is ploughed, makes the swollen pearl of high-titanium blast furnace slag and soil Earth is uniformly mixed, you can.
Wherein, in the method described above using the swollen pearl improvement soil of high-titanium blast furnace slag, the high-titanium blast furnace slag The dosage of swollen pearl is 500~1500Kg/ mus.
Wherein, in the method described above using the swollen pearl improvement soil of high-titanium blast furnace slag, the high-titanium blast furnace slag Granularity Wei≤3mm of swollen pearl.
Wherein, in the method described above using the swollen pearl improvement soil of high-titanium blast furnace slag, the high-titanium blast furnace slag Swollen pearl is prepared by following methods:
High titania type blast furnace cinder is poured into slag runner, swollen pearl slot is flowed to, then flows on the roller of rotation, rotating cylinder leaf Piece crushes slag, then casts in the air, sprays water to the slag pearl of aerial sports, slag pearl forms spherical shape, falls into swollen Zhu Chi, carries out Screening, obtains the swollen pearl of high-titanium blast furnace slag of granularity Wei≤3mm.
Wherein, in the method described above using the swollen pearl improvement soil of high-titanium blast furnace slag, the high titania type blast furnace melts The temperature of slag is not less than 1000 DEG C.
Wherein, in the method described above using the swollen pearl improvement soil of high-titanium blast furnace slag, the high titania type blast furnace melts The iron content of slag is no more than 1%.
The beneficial effects of the invention are as follows:
The method of the present invention improves soil using the swollen pearl of high-titanium blast furnace slag, after adding in swollen pearl, energy moisture-locking, and suppression Moisture evaporation processed, it is ensured that the requirement of plant growth moisture content improves ground temperature, reduces salinity and is accumulated in earth's surface, can be effectively improved plant Growing state, the soil improvement especially suitable for hillside fields and non-solid water;The method of the present invention efficiently utilizes high-titanium blast furnace slag industry Discarded object improves the utilization rate of high-titanium blast furnace slag, is worthy of popularization.
Specific embodiment
Specifically, a kind of method using the swollen pearl improvement soil of high-titanium blast furnace slag, this method comprises the following steps:
The swollen pearl of high-titanium blast furnace slag is evenly laid out in upper soll layer, it is ploughed, makes the swollen pearl of high-titanium blast furnace slag and soil Earth is uniformly mixed, you can.
The method of the present invention improves soil using the swollen pearl of high-titanium blast furnace slag, after adding in swollen pearl, energy moisture-locking, and suppression Moisture evaporation processed, it is ensured that the requirement of plant growth moisture content improves ground temperature, reduces salinity and is accumulated in earth's surface, can be effectively improved plant Growing state, the soil improvement especially suitable for hillside fields and non-solid water.High-titanium blast furnace slag is as a kind of trade waste, by it When being prepared as swollen pearl for soil improvement, to improve the utilization rate of high-titanium blast furnace slag, while ensure reclamation result, this hair The dosage of the bright swollen pearl of middle high-titanium blast furnace slag is 500~1500Kg/ mus, and controls its granularity Wei≤3mm.
In the method for the present invention, the swollen pearl of high-titanium blast furnace slag is prepared by following methods:
The present invention by smelt iron out temperature for 1000 DEG C and more than high titania type blast furnace cinder transport to cinder field with slag ladle, incline Slag runner is poured into, swollen pearl slot is then reached, then flows on the roller of rotation, rotating cylinder blade crushes big stock slag, then Cast aerial, the slag pearl thrown is cooked oblique upper paraboloiding movement in the air, while roller lower part is sprayed water to the slag pearl of movement, and slag pearl meets water Fast speed is cooled into spherical shape, falls into swollen Zhu Chi, forms the swollen ball of size fractionated, is sieved the height for≤3mm to get granularity The swollen pearl of titanium blast furnace slag;High titania type blast furnace cinder cannot have solidifying body, otherwise can influence slag fluidity, and drum blade rotation is difficult Solidifying body to be crushed, it is unfavorable for swollen pearl and is formed.
In addition, cannot have too many iron in high titania type blast furnace cinder, i.e., the iron content in slag is no more than 1%;If high titania type Iron content is excessively high in blast furnace cinder, is unfavorable for slag and crushes, and also influences the application of swollen pearl;Slag pearl has to during projectile Injection water, will make slag rapidly cool to form swollen pearl, and water can use common domestic water.
The present invention is described in further detail below by embodiment, but is not therefore limited the scope of the present invention Among the embodiment described scope.
Embodiment 1
The swollen pearl of the present embodiment high-titanium blast furnace slag is prepared by following methods:
The high titania type blast furnace cinder that 1060 DEG C of iron content is 0.75% is transported into cinder field with slag ladle, pours into slag runner, so After reach swollen pearl slot, flow on the roller of rotation, rotating cylinder blade crushes big stock slag, then casts to aerial, is thrown Slag pearl do oblique upper paraboloiding movement in the air, while roller lower part is sprayed water to the slag pearl of movement, and slag pearl meets water fast speed and is cooled into Spherical shape falls into swollen Zhu Chi, obtains the swollen ball of high-titanium blast furnace slag, is sieved, and obtains the swollen pearl of the high-titanium blast furnace slag of degree≤3mm.
Utilize the swollen pearl improvement soil of above-mentioned high-titanium blast furnace slag:
The swollen pearl of the high-titanium blast furnace slag of Li Du≤3mm is evenly laid out in hillside fields and the upper soll layer of non-solid water, it is ploughed It turns over, the swollen pearl of high-titanium blast furnace slag is made to be uniformly mixed with soil, you can;Soil applies the swollen pearl 1000Kg of high-titanium blast furnace slag per acre;
Grown on soil mango after improvement, by one month it has been observed that mango grows fine.
Embodiment 2
The swollen pearl of the present embodiment high-titanium blast furnace slag is prepared by following methods:
The high titania type blast furnace cinder that 1150 DEG C of iron content is 0.65% is transported into cinder field with slag ladle, pours into slag runner, so After reach swollen pearl slot, flow on the roller of rotation, rotating cylinder blade crushes big stock slag, then casts to aerial, is thrown Slag pearl do oblique upper paraboloiding movement in the air, while roller lower part is sprayed water to the slag pearl of movement, and slag pearl meets water fast speed and is cooled into Spherical shape falls into swollen Zhu Chi, obtains the swollen ball of high-titanium blast furnace slag, is sieved, and obtains the swollen pearl of the high-titanium blast furnace slag of degree≤3mm.
Utilize the swollen pearl improvement soil of above-mentioned high-titanium blast furnace slag:
The swollen pearl of the high-titanium blast furnace slag of Li Du≤3mm is evenly laid out in hillside fields and the upper soll layer of non-solid water, it is ploughed It turns over, the swollen pearl of high-titanium blast furnace slag is made to be uniformly mixed with soil, you can;Soil applies the swollen pearl 800Kg of high-titanium blast furnace slag per acre;
Grown on soil mango after improvement, by one month it has been observed that mango grows fine.
Comparative example 1
Soil is improved except not applying high-titanium blast furnace slag swollen pearl, other conditions are identical with embodiment 1,2, pass through One month it has been observed that the growing way of mango is poor.

Claims (6)

1. utilize the method for the swollen pearl improvement soil of high-titanium blast furnace slag, it is characterised in that:Comprise the following steps:
The swollen pearl of high-titanium blast furnace slag is evenly laid out in upper soll layer, it is ploughed, the swollen pearl of high-titanium blast furnace slag is made to be mixed with soil It closes uniform, you can.
2. the method according to claim 1 using the swollen pearl improvement soil of high-titanium blast furnace slag, it is characterised in that:The height The dosage of the swollen pearl of titanium blast furnace slag is 500~1500Kg/ mus.
3. the method according to claim 1 using the swollen pearl improvement soil of high-titanium blast furnace slag, it is characterised in that:The height Granularity Wei≤3mm of the swollen pearl of titanium blast furnace slag.
4. the method according to claim 3 using the swollen pearl improvement soil of high-titanium blast furnace slag, it is characterised in that:The height The swollen pearl of titanium blast furnace slag is prepared by following methods:
High titania type blast furnace cinder is poured into slag runner, swollen pearl slot is flowed to, then flows on the roller of rotation, rotating cylinder blade will Slag crushes, and then casts in the air, sprays water to the slag pearl of aerial sports, slag pearl forms spherical shape, falls into swollen Zhu Chi, sieved Point, obtain the swollen pearl of high-titanium blast furnace slag of granularity Wei≤3mm.
5. the method according to claim 4 using the swollen pearl improvement soil of high-titanium blast furnace slag, it is characterised in that:The height The temperature of titanium-type blast furnace cinder is not less than 1000 DEG C.
6. the method according to claim 4 using the swollen pearl improvement soil of high-titanium blast furnace slag, it is characterised in that:The height The iron content of titanium-type blast furnace cinder is no more than 1%.
CN201711364501.8A 2017-12-18 2017-12-18 A kind of method using the swollen pearl improvement soil of high-titanium blast furnace slag Pending CN108093724A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102241536A (en) * 2011-03-31 2011-11-16 张兴华 Method for producing long-acting compound fertilizer by utilizing waste resources
CN103724101A (en) * 2013-11-29 2014-04-16 苏州负碳谷材料科技有限公司 Caustic slag carrier for a slow release compound fertilizer and preparation method of caustic slag carrier
CN104387207A (en) * 2014-11-03 2015-03-04 贵州省化工研究院 Fertilizer prepared from yellow phosphorus furnace slag and specially applied to kiwi fruits and preparation method of fertilizer
CN105340407A (en) * 2015-09-21 2016-02-24 史汉祥 Improved treatment method for saline-alkali soil
CN106833675A (en) * 2017-04-08 2017-06-13 新疆天物生态科技股份有限公司 A kind of method that use cinder prepares saline-alkali soil conditioner

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102241536A (en) * 2011-03-31 2011-11-16 张兴华 Method for producing long-acting compound fertilizer by utilizing waste resources
CN103724101A (en) * 2013-11-29 2014-04-16 苏州负碳谷材料科技有限公司 Caustic slag carrier for a slow release compound fertilizer and preparation method of caustic slag carrier
CN104387207A (en) * 2014-11-03 2015-03-04 贵州省化工研究院 Fertilizer prepared from yellow phosphorus furnace slag and specially applied to kiwi fruits and preparation method of fertilizer
CN105340407A (en) * 2015-09-21 2016-02-24 史汉祥 Improved treatment method for saline-alkali soil
CN106833675A (en) * 2017-04-08 2017-06-13 新疆天物生态科技股份有限公司 A kind of method that use cinder prepares saline-alkali soil conditioner

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