CN108085986A - A kind of fiber antioxidant and preparation method thereof - Google Patents
A kind of fiber antioxidant and preparation method thereof Download PDFInfo
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- CN108085986A CN108085986A CN201810085615.7A CN201810085615A CN108085986A CN 108085986 A CN108085986 A CN 108085986A CN 201810085615 A CN201810085615 A CN 201810085615A CN 108085986 A CN108085986 A CN 108085986A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of fiber antioxidant, include the composition of following parts by weight：Emulsifier 0.1 10, surfactant 0.1 20, alcohols 10 50, benzyl hydroxylamine 0.5 15, water 10 89.7.The antioxidant is at low cost, good to the antioxidant effect of white and light fibres fabric, can meet European Union's relevant criterion, have no toxic and side effect to human body.The preparation method of the fiber antioxidant is also disclosed, is comprised the following steps：(1) add in reaction kettle, be stirred by the group component of emulsifier, surfactant；(2) benzyl hydroxylamine and alcohols of group component are added in, heating is stirred to react, and reacts to material to add in water during transparency liquid；(3) water of surplus is added in after cooling down, stirring is got product.The preparation method is simple to operation, industrialization easy to implement.
Description
Technical field
The present invention relates to fibre care agent technical fields, and in particular to a kind of fiber antioxidant and its preparation side
Method.
Background technology
The fabrics such as wite textiles and dyed textiles are favored by consumers, but for needing by high-temperature process
If the white crossed such as thermal finalization, high-temperature high-pressure film process and light fibres fabric without resistance to high temperature oxidation yellowing-resistant arrange,
Easily turn yellow quickly, not only appearance damage, also influence service life, so as to influence the final performance of fabric.So for need to be into
The white and light fibres fabric of row high-temperature process (such as thermal finalization, high-temperature high-pressure film process) must carry out resistance to high temperature oxidation, anti-yellowing
Change is handled.And existing resistance to high temperature oxidation, anti-yellowing agent formulation cost are higher, most of businessman uses imported product, domestic city
There is Spain, Britain's shell, the U.S., some Belgian productions in field except there is the antioxidant BHT of sale Bayer A.G
Product.The most people of food-grade BHT of the wherein antioxidant BHT of Bayer A.G and Yang Ying groups of Germany use.Antioxidant BHT is
Common phenol antiager is one of latency for causing textile phenol Huang phenomenon；So as to which packaged textile be caused to have
Yellowing may occur during transporting and storing.Therefore there are many brands that its product packaging bags has been forbidden to contain BHT
Class substance, aldehydes matter have been forbidden using, while such antioxidant is generally also served only for relatively low now to human hazard
At a temperature of handle the elastomer calico of some xanthochromias of resistance to phenol, to the anti-oxidant Huang of nylon elastic fiber calico of high-temperature process
Change effect is bad, and existing market is more using ADH antioxidant, and ADH is formaldehyde adsorbent, in production process or storage, fortune
Formaldehyde adsorption is easy to during defeated etc., so that containing formaldehyde inside textile, so human health is affected
Or hidden danger, ADH itself is also containing certain toxicity, so people have slowly eliminated ADH as resistance to high temperature oxidation agent now.It can
See, existing market is using in the product of more resistance to high temperature oxidation agent xanthochromia agent or containing not environmentally substance or ADH is contained, all
Environmental requirement is not met.It is very high for the cost of the imported product of meet the requirement of environmental protection, such product domestic at present can reach into
The horizontal quantity of resistance to high temperature oxidation yellowing-resistant effect of mouth product is few.At home and abroad all there is prospect in market to such product very much, therefore
It is necessary to provide a kind of new fiber resistance to high temperature oxidation anti-yellowing agent.
The content of the invention
It is an object of the present invention to provide a kind of fiber (including fibers such as nylon, nylon elastics) resistance to high temperature oxidation,
Anti-yellowing agent.The resistance to high temperature oxidation, anti-yellowing agent are of low cost, harmless, can reach the antioxygen of similar imported product
Change effect.
Another object of the present invention is to provide above-mentioned fiber resistance to high temperature oxidation, the preparation method of anti-yellowing agent.This method letter
It is single, easy to operate, industrialization easy to implement.
First purpose to realize the present invention, using following technical scheme：
A kind of fiber antioxidant is formed including following parts by weight：
Further, the fiber antioxidant is formed including following parts by weight：2-10 parts of emulsifier, surface are lived
5-15 parts of agent of property, 20-50 parts of alcohols, 5-15.0 parts of benzyl hydroxylamine, 10.0-45 parts of water.
Further, the fiber antioxidant is formed including following parts by weight：10 parts of emulsifier, surface-active
15 parts of agent, 45 parts of alcohols, 5 parts of benzyl hydroxylamine, 25 parts of water.
Further, the fiber antioxidant be colourless transparent liquid, solid content 20-60%, pH value (1%
Aqueous solution) it is 7.0 ± 1.0, room temperature is soluble easily in water.
Further, for fatty alcohol ethers, (AEO3-50, isomerous tridecanol polyoxyethylene ether class, oleyl alcohol gather the emulsifier
Ethylene oxide ethers (OE), castor oil polyoxyethylene ether class (EL), sorbitan fatty esters (Span), polyoxyethylene sorbitol
At least one of acid anhydride stearic acid esters (TWeen), glycerin monostearate.
Further, the surfactant includes arbitrary in anion, nonionic or zwitterionic surfactant
It is a kind of.
Further, the alcohols is fatty alcohol and its derivative.
The second purpose to realize the present invention, using following technical scheme：
A kind of preparation method of above-mentioned fiber antioxidant, comprises the following steps：
(1) add in reaction kettle, be stirred by the group component of emulsifier, surfactant；
(2) benzyl hydroxylamine and alcohols of group component are added in, heating is stirred to react, and reacts to material to add during transparency liquid
Enter part water；
(3) water of surplus is added in after cooling down, stirring is got product.
Further, speed of agitator is 50-100rpm/min, mixing time 10-30min in the step (1).
Preferably, speed of agitator is 100rpm/min, mixing time 30min.
Further, reaction temperature is 40-45 DEG C in the step (2), reaction time 2-4h.
Preferably, the reaction time is 3h.
Preferably, 50% of total water weight in group component is added in the step (2).
Further, 25-35 DEG C is cooled in the step (3).
The invention has the advantages that：
(1) present invention can reduce the cost of 10-15% compared with the similar product of market；
(2) antioxidant of the invention, antioxidant effect is good, for high-temperature process to be carried out (such as thermal finalization, high temperature press mold
Processing) white and after light fibres fabric handled by antioxidant of the present invention, non yellowing keeps original whiteness and bright-coloured
Degree.Meet the requirement of 100 standards of European Union OeKo-TEX Standard and the requirement of REACH standards, keep fabric by 200 degree high
Original whiteness and vividness, excellent effect are still maintained after temperature processing.Antioxidant effect has met or exceeded imported product
Effect.Resistance to high temperature oxidation, the yellowing-resistant effect of imported from America similar product can be reached.
(3) this product without ADH, without formaldehyde, without heavy metal ion, without allergy, without teratogenesis, without mutagenesis, without cause
Cancer acts on, and has no toxic and side effect to human body.
Description of the drawings
Fig. 1-4 is to the anti-oxidant xanthochromia colour table contrast test effect diagram of nylon fiber using different antioxidants.
Specific embodiment
With reference to specific embodiment, the technical solution that the present invention will be described in detail.
Embodiment one
A kind of fiber antioxidant, including following parts by weight of component：
A kind of preparation method of above-mentioned fiber antioxidant, comprises the following steps：
(1) by 20 parts of 10 parts of AEO7, AES addition reaction kettles, 30min is stirred with 100rpm/min；
(2) 20 parts of 5 parts of benzyl hydroxylamine and ethyl alcohol are added in, 43 DEG C is heated to, is stirred to react 3h, it is transparent liquid to react to material
22.5 parts of water are added in during body；
(3) 28 DEG C are cooled to, adds in remaining water, stirring is got product.
Embodiment two
A kind of fiber antioxidant, including following parts by weight of component：
A kind of preparation method of above-mentioned fiber antioxidant, comprises the following steps：
(1) by 10 parts of EL-406 parts, MES addition reaction kettles, 30min is stirred with rotating speed 100rpm/min；
(2) 30 parts of 10 parts of benzyl hydroxylamine and isopropanol are added in, 43 DEG C is heated to, is stirred to react 3h, reacts to material and is
22 parts of water are added in during prescribed liquid；
(3) 28 DEG C are cooled to, adds in remaining water, stirring is got product.
Embodiment three
A kind of fiber antioxidant, including following parts by weight of component：
A kind of preparation method of above-mentioned fiber antioxidant, comprises the following steps：
(1) press in 5 parts of 40 2 parts of castor oil polyoxyethylene ether, dodecyl benzene sulfonic acid addition reaction kettles, with rotating speed
100rpm/min is stirred 30min；
(2) 50 parts of 15 parts of benzyl hydroxylamine and octadecyl alcolol are added in, 43 DEG C is heated to, is stirred to react 3h, reacts to material and is
5 parts of water are added in during prescribed liquid；
(3) 28 DEG C are cooled to, adds in remaining water, stirring is got product.
By 180 to 220 DEG C of high temperature, treated that anti-oxidant xanthochromia is protected primarily directed to white fiber fabric by the present invention
Effect is not occurred substantially using the white fabrics that preparation resulting product is handled in the embodiment of the present invention after high-temperature process
Flavescence, and white fiber fabric by antioxidant handle, by 180-200 DEG C heat treatment tens seconds or several seconds will
Turn yellow at once.
Single benzyl hydroxylamine is antioxidant, but its is not soluble in water, it is impossible to is directly used in white fiber fabric, this hair
It is bright to be dissolved into the smaller dispersion of water-soluble molecular particle size by carrying out emulsification to it, it can so be inhaled more completely by fiber
Receive, so as to use minimum raw material reach it is most effective to the greatest extent anti-oxidant, yellowing-resistant protective effect so that it can
With extensive utilization into textile industry, therefore the antioxidant of this programme compounding is more scientific, and environmental protection reduces cost.
Resistance to high temperature oxidation agent test and comparison is made to white nylon elastic fiber cloth using different antioxidants：
1st, processing operation method：
1. weighing four parts of 6000ml of water simultaneously is separately added into four rotating cage type wash water cylinders, in A, B, C, D cylinder, then at No. A
Antioxidant 120g (20g/L) of the present invention is slowly added in cylinder, then domestic pharmaceutical industry product antioxidant is slowly added in B cylinders
120g (20g/L), then import quality product 120g (20g/L) is slowly added in C cylinders, then four pieces of nylon elastics of clip respectively
Fiber calico about 400g) put into respectively machine in A, B, C, D cylinder rotate 5min after, discharge water taking-ups after cold water 10min, pass through
Cross laboratory mangle squeeze it is spare after superfluous water.
It is fixed that 2. tetra- pieces of calicos of AB C D above are carried out 5 seconds heat in 220 degrees Celsius of heat setting machine is reached in advance simultaneously
Type processing, then removes calico and is compared.
1 antioxidant dosage of table
2nd, conclusion：It tests shown in effect as Figure of description 1-4, it is more first than domestic using yellowing-resistant effect after this antioxidant
30-50%, or raising 5% more identical than import quality product antioxidant effect are improved into product.
Above example is only the section Example of the present invention, but can not be used as limitation of the present invention, any to be based on
Present inventive concept, the modification and variation made, each falls within protection scope of the present invention, and specific protection domain is with claim
Subject to secretary carries.
Claims (10)
1. a kind of fiber antioxidant, which is characterized in that formed including following parts by weight：
2. fiber antioxidant according to claim 1, which is characterized in that formed including following parts by weight：Emulsifier
2-10 parts, 5-15 parts of surfactant, 20-50 parts of alcohols, 5-15.0 parts of benzyl hydroxylamine, 10.0-45 parts of water.
3. fiber antioxidant according to claim 1, which is characterized in that formed including following parts by weight：Emulsifier
10 parts, 15 parts of surfactant, 45 parts of alcohols, 5 parts of benzyl hydroxylamine, 25 parts of water.
4. according to the fiber antioxidant described in claim 1-3 any one, which is characterized in that the emulsifier is fatty alcohol
Ethers, castor oil polyoxyethylene ether class, sorbitan fatty esters, polyoxyethylene sorbitol acid anhydride stearic acid esters, single tristearin
At least one of acid glyceride.
5. a kind of any one of the claim 1-3 fiber antioxidant, which is characterized in that the surfactant include it is cloudy from
Any one in son, nonionic or zwitterionic surfactant.
6. any one of a kind of claim 1-3 fiber antioxidant, which is characterized in that the alcohols is fatty alcohol and its spreads out
Biology.
7. the preparation method of the fiber antioxidant according to claim 1-6 any one, which is characterized in that including following
Step：
(1) add in reaction kettle, be stirred by the group component of emulsifier, surfactant；
(2) add in group component benzyl hydroxylamine and alcohols, heating, be stirred to react, react to material be transparency liquid when addition portion
Divide water；
(3) water of surplus is added in after cooling down, stirring is got product.
8. the preparation method of fiber antioxidant according to claim 7,
It is characterized in that, speed of agitator is 50-100rpm/min, mixing time 10-30min in the step (1).
9. the preparation method of fiber antioxidant according to claim 7, which is characterized in that reaction in the step (2)
Temperature is 40-45 DEG C, reaction time 2-4h.
10. the preparation method of fiber antioxidant according to claim 7, which is characterized in that cooling in the step (3)
To 25-35 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810085615.7A CN108085986B (en) | 2018-01-29 | 2018-01-29 | Fiber antioxidant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810085615.7A CN108085986B (en) | 2018-01-29 | 2018-01-29 | Fiber antioxidant and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108085986A true CN108085986A (en) | 2018-05-29 |
| CN108085986B CN108085986B (en) | 2020-05-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810085615.7A Active CN108085986B (en) | 2018-01-29 | 2018-01-29 | Fiber antioxidant and preparation method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114133662A (en) * | 2021-12-02 | 2022-03-04 | 江苏东方电缆材料有限公司 | Basalt fiber reinforced polypropylene-based composite material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194892A (en) * | 2013-04-24 | 2013-07-10 | 广州市番禺区协运来化工用品有限公司 | Anti-yellowing agent |
| CN103556459A (en) * | 2013-10-28 | 2014-02-05 | 四川大学 | Composite heat-yellow discolouration resistant finishing agent of chinlon, spandex and blended fabric of two |
-
2018
- 2018-01-29 CN CN201810085615.7A patent/CN108085986B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194892A (en) * | 2013-04-24 | 2013-07-10 | 广州市番禺区协运来化工用品有限公司 | Anti-yellowing agent |
| CN103556459A (en) * | 2013-10-28 | 2014-02-05 | 四川大学 | Composite heat-yellow discolouration resistant finishing agent of chinlon, spandex and blended fabric of two |
Non-Patent Citations (2)
| Title |
|---|
| 中国化学工业年鉴编辑部: "《中国化学工业年鉴 2009 第二十五卷 上卷 行业篇》", 31 December 2009, 中国化工信息中心出版 * |
| 黄枢: "《有机合成试剂制备手册》", 31 August 1988, 四川大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114133662A (en) * | 2021-12-02 | 2022-03-04 | 江苏东方电缆材料有限公司 | Basalt fiber reinforced polypropylene-based composite material |
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| CN108085986B (en) | 2020-05-19 |
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