CN108660759A - A kind of antibacterial crease-resistant antistatic shirt fabric - Google Patents
A kind of antibacterial crease-resistant antistatic shirt fabric Download PDFInfo
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- CN108660759A CN108660759A CN201810409832.7A CN201810409832A CN108660759A CN 108660759 A CN108660759 A CN 108660759A CN 201810409832 A CN201810409832 A CN 201810409832A CN 108660759 A CN108660759 A CN 108660759A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1807—C7-(meth)acrylate, e.g. heptyl (meth)acrylate or benzyl (meth)acrylate
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Abstract
The present invention relates to a kind of antibacterial crease-resistant antistatic shirt fabrics, which is characterized in that warp thread is modified anti-wrinkle cotton fibre, weft yarn is hydrophilic antimicrobial type polyester fiber, and preparation method is：(1) it is spinned as warp thread, by weft yarn of hydrophilic antimicrobial type polyester fiber using being modified anti-wrinkle cotton fibre；(2) warp thread cheese yarn dyeing：Including metal, cage is filled, enters cylinder, pre-treatment is dyed, and is post-processed, and is dehydrated, drying, tight cylinder；(3) it weaves：Including warping, sizing is gaited, woven fabric；(4) anti-crease finishing：It is put into crease-resistant liquid and pads 10 15min of processing, 60 75 DEG C of dryings after taking-up obtain antibacterial crease-resistant antistatic shirt fabric.The present invention can kill 98% or more Escherichia coli, staphylococcus aureus, and it is small that there is fabulous anti-wrinkle effect and washing to shrink.
Description
Technical field
The present invention relates to a kind of antibacterial crease-resistant antistatic shirt fabrics, belong to fabric technical field.
Background technology
With the development of science and technology the development of society, the textile industry in China have obtained quick development, the thing followed is
The fast development of textile fabric, common fabric can no longer meet the market demand of diversification.Shirt a great variety is people
Clothes are commonly used in daily life.And the object of this daily indispensability have the shortcomings that it is apparent.Shirt as the clothing worn next to the skin,
Not only need ventilative comfortable, good water absorption, such shirt generally uses cotton fabric, but traditional shirt fabric function compared with
To be single, static electricity resistance, wrinkle resistance are poor.
Patent 201710736279.3 discloses a kind of creasing anti-bacterial shirt fabric and its makes finishing technique, the fabric packet
Outer layer, middle level and internal layer are included, the described fabric includes mainly following component according to mass ratio：Cotton fiber 40%-60%, milk
Azelon 10%-20%, bamboo charcoal fiber 10%-20%, polyester fiber 5%-10% and ptt fiber 5%-10%, it is described outer
Layer is using bamboo charcoal fiber and polyester fiber is blended forms, and the middle level is using cotton fiber and ptt fiber is blended forms, the internal layer
It forms using milk protein fiber and cotton fiber are blended, is interweaved using outer layer weft yarn and middle level warp thread wherein between outer layer and middle level
It becames one, is became one using internal layer weft yarn and middle level warp thread intertexture between middle level and internal layer.Shirt face described in the invention
Material is not only comfortable to absorb water, good permeability, and improves its crease-resistant and fungistatic effect, safety comfortable and easy to wear.But the invention by
It is relative complex in the expensive raw material prices such as milk protein fiber, technique, limit its extensive use.
Invention content
The shortcomings that overcome the prior art and deficiency, the present invention provide a kind of antibacterial crease-resistant antistatic shirt fabric.
The present invention uses following technical scheme：A kind of antibacterial crease-resistant antistatic shirt fabric, which is characterized in that warp thread is to change
Property anti-wrinkle cotton fibre, weft yarn be hydrophilic antimicrobial type polyester fiber, through close 512/10 centimetres, 510/10 centimetres of filling density.
The preparation method of the modification anti-wrinkle cotton fibre is：It is 80-100Pa, aura in argon plasma gas pressure
Under the conditions of discharge power is 10-20W, low-voltage plasma processing is carried out to cotton fiber, processing time 10-15min is obtained at plasma
The cotton fiber of reason；It is 2 by mass ratio:8-3:7 XLA fibers, the cotton fiber blend spinning of plasma treatment obtain modified crease-resistant
Cotton fiber.
The preparation method of the hydrophilic antimicrobial type polyester fiber, in terms of mass fraction, steps are as follows：By 25-30 parts of second
Glycol, 130-140 part dimethyl terephthalate (DMT), 5-10 parts of cationic chitosans, 2-5 parts of carboxymethyl cyclodextrin sodium, 0.5-1 parts
Polycondensation catalyst is added in reaction kettle, stirring to pulp under room temperature, and 80-85 DEG C of progress esterification is warming up to after mashing,
3-4h, adds stabilizer, stops heating after heat preservation the reaction was continued 3-4h, obtains chitin modified polyester liquid；Chitosan is changed
Property polyester liquid slowly to heating crystalline in crystallization kettle, crystallization temperature be 160-165 DEG C polyester crystal, then by polyester crystal
In 170-185 DEG C of drying, then hydrophilic antimicrobial type polyester fiber is obtained after cooling slice, wire drawing weaving.
The XLA fibers are Dow Chemical's product.
The cationic chitosan is quaternary chitosan, number-average molecular weight 8000-12000；The carboxymethyl
The molecular weight of cyclodextrin sodium is 800-1500.
The polycondensation catalyst is at least one of antimony glycol, germanium dioxide, antimony oxide.
The stabilizer is at least one of magnesium stearate, zinc stearate, aluminum stearate.
A kind of antibacterial crease-resistant antistatic shirt fabric, preparation method are：(1) using be modified anti-wrinkle cotton fibre as warp thread, with
Hydrophilic antimicrobial type polyester fiber spins for weft yarn；(2) warp thread cheese yarn dyeing：Including metal, cage is filled, enters cylinder, pre-treatment is dyed,
Post-processing is dehydrated, drying, tight cylinder；(3) it weaves：Including warping, sizing is gaited, woven fabric；(4) anti-crease finishing：It is put into crease-resistant liquid
In pad processing 10-15min, 60-75 DEG C of drying after taking-up obtain antibacterial crease-resistant antistatic shirt fabric.
It is calculated in mass percent, the ingredient of the crease-resistant liquid is：5%-10% cation acrylics lotion, 2%-4%
Sodium hypophosphite, 1%-1.5% malic acid, 1%-1.5% tartaric acid, remaining is water.
The cation acrylic lotion, the preparation method in terms of mass fraction are：By 0.4-0.8 parts of ammonium persulfates,
5-10 parts of cationic monomers are dissolved in 30 parts of water, and it is 1. spare to obtain solution；4-8 parts of methyl acrylates, 4-8 are added in a kettle
Part hydroxy-ethyl acrylate, 15-25 parts of tert-butyl acrylates, 2-6 parts of styrene, 0.5-1.5 parts of dodecyl trimethyl ammonium chloride,
50-60 parts of deionized waters stand 1h after high-speed stirred emulsification uniformly, remove bubble and upper foam, and then heating systems are extremely
65-75 DEG C, solution is then added dropwise dropwise 1. into reaction kettle, rear insulation reaction 2-4h is added dropwise in 4-6h, stops heating, cooling
After discharge to get cation acrylic lotion.
The cationic monomer is dimethyl diallyl ammonium chloride, acrylamide ethyl-trimethyl salmiac, methyl
At least one of acrylamide ethyl-trimethyl salmiac.
Compared with the existing technology, the present invention has the following advantages：
1, the raw material of the shirt fabric are simple, are easy to get, and are most common cotton fiber and polyester fiber；
2, the modification anti-wrinkle cotton fibre resists through glow discharge process then with elastic preferable XLA fiber blends
Wrinkle performance, comfort property (comfort especially after absorbing sweat) are improved；
3, the treatment mechanism of the crease-resistant liquid include organic acid arrange and cation acrylic emulsion resin dip finishing,
Wherein cation acrylic lotion assigns shirt fabric preferably elasticity and anti-wrinkle effect；
4, the hydrophilic antimicrobial type polyester fiber due to using cationic chitosan, carboxymethyl cyclodextrin sodium be modified,
Hydrophilic effect is good, improves the antistatic property of shirt fabric.
Specific implementation mode
The antibacterial crease-resistant antistatic shirt fabric of one kind of the present invention is further described with reference to embodiment.It can be with
Understand, specific embodiment described herein is used only for explaining related invention, rather than the restriction to the invention.
Embodiment 1
A kind of constituent of crease-resistant liquid A is：10% cation acrylic lotion, 4% sodium hypophosphite, 1% malic acid,
1% tartaric acid, remaining is water.
Cation acrylic lotion described in the present embodiment, the preparation method in terms of mass fraction are：
0.4 part of ammonium persulfate, 5 parts of acrylamide ethyl-trimethyl salmiacs are dissolved in 30 parts of water, it is 1. standby to obtain solution
With；8 parts of methyl acrylates, 8 parts of hydroxy-ethyl acrylates, 15 parts of tert-butyl acrylates, 2 parts of styrene, 1.5 are added in a kettle
Part dodecyl trimethyl ammonium chloride, 60 parts of deionized waters stand 1h after high-speed stirred emulsification uniformly, remove bubble and upper layer
Foam, then heating systems solution is then added dropwise dropwise 1. into reaction kettle to 65 DEG C, rear insulation reaction 4h is added dropwise in 4h,
Stop heating, discharges to get cation acrylic lotion after cooling.
Embodiment 2
A kind of constituent of crease-resistant liquid B is：5% cation acrylic lotion, 2% sodium hypophosphite, 1.5% apple
Acid, 1.5% tartaric acid, remaining is water.
Cation acrylic lotion described in the present embodiment, the preparation method in terms of mass fraction are：
0.8 part of ammonium persulfate, 10 parts of dimethyl diallyl ammonium chlorides are dissolved in 30 parts of water, it is 1. spare to obtain solution；
In a kettle be added 4 parts of methyl acrylates, 4 parts of hydroxy-ethyl acrylates, 25 parts of tert-butyl acrylates, 6 parts of styrene, 0.5 part
Dodecyl trimethyl ammonium chloride, 50 parts of deionized waters stand 1h after high-speed stirred emulsification uniformly, remove bubble and upper layer bubble
Foam, then heating systems solution is then added dropwise dropwise 1. into reaction kettle to 75 DEG C, rear insulation reaction 2h is added dropwise in 6h, stops
It only heats, discharges to get cation acrylic lotion after cooling.
Embodiment 3
A kind of constituent of crease-resistant liquid C is：8% cation acrylic lotion, 2.5% sodium hypophosphite, 1.2% apple
Acid, 1.1% tartaric acid, remaining is water.
Cation acrylic lotion described in the present embodiment, the preparation method in terms of mass fraction are：
0.6 part of ammonium persulfate, 8 parts of Methacrylamide ethyl-trimethyl salmiacs are dissolved in 30 parts of water, solution is obtained
1. spare；7 parts of methyl acrylates, 5 parts of hydroxy-ethyl acrylates, 18 parts of tert-butyl acrylates, 3.5 parts of benzene second are added in a kettle
Alkene, 0.6 part of dodecyl trimethyl ammonium chloride, 54 parts of deionized waters stand 1h after high-speed stirred emulsification uniformly, remove bubble
And upper foam, then heating systems solution is then added dropwise dropwise 1. into reaction kettle to 70 DEG C, 5h keeps the temperature anti-after being added dropwise
3h is answered, stops heating, discharges to get cation acrylic lotion after cooling.
Embodiment 4
A kind of preparation method of modified anti-wrinkle cotton fibre H is：It is 80Pa, glow discharge work(in argon plasma gas pressure
Under the conditions of rate is 20W, low-voltage plasma processing is carried out to cotton fiber, processing time 10min obtains the cotton fiber of plasma treatment；
It is 3 by mass ratio:7 XLA fibers, the cotton fiber blend spinning of plasma treatment obtain modified anti-wrinkle cotton fibre H.
Embodiment 5
A kind of preparation method of modified anti-wrinkle cotton fibre J is：It is 100Pa, glow discharge in argon plasma gas pressure
Under the conditions of power is 10W, low-voltage plasma processing is carried out to cotton fiber, processing time 15min obtains the cotton fibre of plasma treatment
Dimension；It is 2 by mass ratio:8 XLA fibers, the cotton fiber blend spinning of plasma treatment obtain modified anti-wrinkle cotton fibre J.
Embodiment 6
A kind of preparation method of modified anti-wrinkle cotton fibre K is：It is 90Pa, glow discharge work(in argon plasma gas pressure
Under the conditions of rate is 15W, low-voltage plasma processing is carried out to cotton fiber, processing time 12min obtains the cotton fiber of plasma treatment；
It is 3 by mass ratio:8 XLA fibers, the cotton fiber blend spinning of plasma treatment obtain modified anti-wrinkle cotton fibre K.
Embodiment 7
A kind of preparation method of hydrophilic antimicrobial type polyester fiber M, in terms of mass fraction, steps are as follows：By 28 parts of ethylene glycol,
134 parts of dimethyl terephthalate (DMT)s, 7 parts of cationic chitosans, 3 parts of carboxymethyl cyclodextrin sodium, 0.6 part of condensed ethandiol antimony are added to
In reaction kettle, stirring to pulp under room temperature is warming up to 83 DEG C of progress esterifications after mashing, 3.5h adds zinc stearate,
Stop heating after heat preservation the reaction was continued 3.5h, obtains chitin modified polyester liquid；By chitin modified polyester liquid slowly to knot
Heating crystalline in brilliant kettle, crystallization temperature is 162 DEG C and obtains polyester crystal, then by polyester crystal in 175 DEG C of dryings, then through cooling
Hydrophilic antimicrobial type polyester fiber M is obtained after slice, wire drawing weaving.
Embodiment 8
A kind of preparation method of hydrophilic antimicrobial type polyester fiber N, in terms of mass fraction, steps are as follows：By 25 parts of ethylene glycol,
130 parts of dimethyl terephthalate (DMT)s, 5 parts of cationic chitosans, 5 parts of carboxymethyl cyclodextrin sodium, 0.5 part of antimony oxide are added to
In reaction kettle, stirring to pulp under room temperature is warming up to 80 DEG C of progress esterifications after mashing, 4h adds aluminum stearate, protects
Stop heating after temperature the reaction was continued 3h, obtains chitin modified polyester liquid；By chitin modified polyester liquid slowly to crystallization kettle
Middle heating crystalline, crystallization temperature is 160 DEG C and obtains polyester crystal, then by polyester crystal in 170 DEG C of dryings, is then cut through cooling
Hydrophilic antimicrobial type polyester fiber N is obtained after piece, wire drawing weaving.
Embodiment 9
A kind of preparation method of hydrophilic antimicrobial type polyester fiber P, in terms of mass fraction, steps are as follows：By 30 parts of ethylene glycol,
140 parts of dimethyl terephthalate (DMT)s, 10 parts of cationic chitosans, 2 parts of carboxymethyl cyclodextrin sodium, 1 part of germanium dioxide are added to instead
It answers in kettle, stirring to pulp under room temperature, 85 DEG C of progress esterifications is warming up to after mashing, 3h adds zinc stearate, keeps the temperature
Stop heating after the reaction was continued 4h, obtains chitin modified polyester liquid；By chitin modified polyester liquid slowly in crystallization kettle
Heating crystalline, crystallization temperature is 165 DEG C and obtains polyester crystal, then by polyester crystal in 185 DEG C of dryings, be then sliced through cooling,
Hydrophilic antimicrobial type polyester fiber P is obtained after wire drawing weaving.
Embodiment 10
A kind of antibacterial crease-resistant antistatic shirt fabric X, which is characterized in that warp thread is modified anti-wrinkle cotton fibre, weft yarn is parent
Water antibacterial polyester fiber, through close 512/10 centimetres, 510/10 centimetres of filling density；Preparation method is：(1) crease-resistant with modification
Cotton fiber H is warp thread, spins by weft yarn of hydrophilic antimicrobial type polyester fiber M；(2) warp thread cheese yarn dyeing：Including metal, cage is filled,
Enter cylinder, pre-treatment is dyed, and is post-processed, and is dehydrated, drying, tight cylinder；(3) it weaves：Including warping, sizing is gaited, woven fabric；(4) resist
Wrinkle arranges：It is put into crease-resistant liquid A and pads processing 10min, 75 DEG C of dryings after taking-up obtain antibacterial crease-resistant antistatic shirt fabric.
Embodiment 11
A kind of antibacterial crease-resistant antistatic shirt fabric Y, which is characterized in that warp thread is modified anti-wrinkle cotton fibre, weft yarn is parent
Water antibacterial polyester fiber, through close 512/10 centimetres, 510/10 centimetres of filling density；Preparation method is：(1) crease-resistant with modification
Cotton fiber J is warp thread, spins by weft yarn of hydrophilic antimicrobial type polyester fiber N；(2) warp thread cheese yarn dyeing：Including metal, cage is filled,
Enter cylinder, pre-treatment is dyed, and is post-processed, and is dehydrated, drying, tight cylinder；(3) it weaves：Including warping, sizing is gaited, woven fabric；(4) resist
Wrinkle arranges：It is put into crease-resistant liquid B and pads processing 15min, 60 DEG C of dryings after taking-up obtain antibacterial crease-resistant antistatic shirt fabric Y.
Embodiment 12
A kind of antibacterial crease-resistant antistatic shirt fabric Z, which is characterized in that warp thread is modified anti-wrinkle cotton fibre, weft yarn is parent
Water antibacterial polyester fiber, through close 512/10 centimetres, 510/10 centimetres of filling density；Preparation method is：(1) crease-resistant with modification
Cotton fiber K is warp thread, spins by weft yarn of hydrophilic antimicrobial type polyester fiber P；(2) warp thread cheese yarn dyeing：Including metal, cage is filled,
Enter cylinder, pre-treatment is dyed, and is post-processed, and is dehydrated, drying, tight cylinder；(3) it weaves：Including warping, sizing is gaited, woven fabric；(4) resist
Wrinkle arranges：It is put into crease-resistant liquid C and pads processing 13min, 68 DEG C of dryings after taking-up obtain antibacterial crease-resistant antistatic shirt fabric Z.
Anti-microbial property test：According to GB/T20944.3-2008《The evaluation Part III of antibacterial textile performance：Concussion
Method》The anti-microbial property of testing example 10-12 and commercial antimicrobial shirt fabric (comparative example)；Sterilizing methods：High pressure steam sterilization；
Shake liquid 0.03mol/L phosphate buffers；24 ± 1 DEG C of Contact Temperature；Time of contact 18h；Test strain：It is Escherichia coli, golden yellow
Color staphylococcus, strain initial concentration 2.5 × 104CFU/mL；Detection data such as table 1.
Table 1：The anti-microbial property of embodiment
| Embodiment 10 | Embodiment 11 | Embodiment 12 | Comparative example | |
| To Escherichia coli antibiotic rate | 99.5% | 99.8% | 99.9% | 96.2% |
| To staphylococcus aureus | 98.3% | 98.9% | 99.2% | 90.6% |
As can be seen from Table 1, the anti-microbial property of antibacterial crease-resistant antistatic shirt fabric of the present invention protrudes, and can kill
98% or more Escherichia coli, staphylococcus aureus, and anti-microbial property is better than commercial antimicrobial shirt fabric.
Resistance to color, water-fast crease-resistant detection：According to GB1841-2010《National general safety technical code for textile products》B classes,
GB/T2660-2008《Shirt》, U.S. textile examination criteria AATCC66-2003 embodiment 10-12 is detected, testing number
According to such as the following table 2.
Table 2：Resistance to color, water-fast crease-resistant testing result table
The color fastness to washing of antibacterial crease-resistant antistatic shirt fabric of the present invention, resistance to water colour jail as can be seen from Table 2
Spend compound GB 1841-2010 requirement, washing size changing rate is relatively low, anti-folding recovery angle is more than 350 °, illustrates the present invention with pole
Good anti-wrinkle effect and washing is shunk small.
Antistatic property：According to GB/T 12703.2-2009《The evaluation of textile antistatic property》To embodiment 10-12 and
The surface resistivity of commercially available antistatic blended shirt fabric, according to FZ/T 01042-1996《Textile material antistatic property electrostatic pressure
The measurement of half-life period》Measure electrostatic pressure and half-life period, test data such as table 3:
Table 3：The antistatic property of embodiment
| Embodiment 10 | Embodiment 11 | Embodiment 12 | Comparative example | |
| Surface resistivity | 0.104Ω.cm | 0.112Ω.cm | 0.131Ω.cm | 0.654Ω.cm |
| Electrostatic pressure | 35V | 41V | 53V | 386V |
| Half-life period | 0.26s | 0.28s | 0.32s | 1.85s |
The antistatic property of antibacterial crease-resistant antistatic shirt fabric of the present invention is far superior to city as can be seen from Table 3
Sell commercially available antistatic blended shirt fabric.
Claims (10)
1. a kind of antibacterial crease-resistant antistatic shirt fabric, which is characterized in that warp thread is modified anti-wrinkle cotton fibre, weft yarn is hydrophilic anti-
Bacterial type polyester fiber.
2. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 1, which is characterized in that the modification is crease-resistant
The preparation method of cotton fiber is：Under the conditions of argon plasma gas pressure is 80-100Pa, glow discharge power is 10-20W,
Low-voltage plasma processing is carried out to cotton fiber, processing time 10-15min obtains the cotton fiber of plasma treatment；It is 2 by mass ratio:
8-3:7 XLA fibers, the cotton fiber blend spinning of plasma treatment obtain modified anti-wrinkle cotton fibre.
3. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 1, which is characterized in that the hydrophilic antimicrobial
The preparation method of type polyester fiber, in terms of mass fraction, steps are as follows：By 25-30 parts of ethylene glycol, 130-140 parts of terephthaldehydes
Dimethyl phthalate, 5-10 part cationic chitosan, 2-5 parts of carboxymethyl cyclodextrin sodium, 0.5-1 parts of polycondensation catalysts are added to reaction kettle
In, stirring to pulp under room temperature is warming up to 80-85 DEG C of progress esterification 3-4h, adds stabilizer after mashing, heat preservation after
Stop heating after continuous reaction 3-4h, obtains chitin modified polyester liquid；Chitin modified polyester liquid is slowly added to crystallization
Heating crystalline in kettle, crystallization temperature are 160-165 DEG C, obtain polyester crystal；Then by polyester crystal in 170-185 DEG C of drying, then
Hydrophilic antimicrobial type polyester fiber is obtained after cooling slice, wire drawing weaving.
4. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 3, which is characterized in that the cationic shell
Glycan is quaternary chitosan, number-average molecular weight 8000-12000；The molecular weight of the carboxymethyl cyclodextrin sodium is 800-
1500。
5. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 3, which is characterized in that the polycondensation catalysis
Agent is at least one of antimony glycol, germanium dioxide, antimony oxide.
6. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 3, which is characterized in that the stabilizer is
At least one of magnesium stearate, zinc stearate, aluminum stearate.
7. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 1, which is characterized in that preparation method is：
(1) it is spinned as warp thread, by weft yarn of hydrophilic antimicrobial type polyester fiber using being modified anti-wrinkle cotton fibre；(2) warp thread cheese yarn dyeing：Including
Metal fills cage, enters cylinder, and pre-treatment is dyed, and is post-processed, and is dehydrated, drying, tight cylinder；(3) it weaves：Including warping, sizing is gaited,
Woven fabric；(4) anti-crease finishing：It is put into crease-resistant liquid and pads processing 10-15min, 60-75 DEG C of drying after taking-up obtains antibacterial crease-resistant
Antistatic shirt fabric.
8. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 7, which is characterized in that with mass percent
Meter, the ingredient of the crease-resistant liquid are：5%-10% cation acrylics lotion, 2%-4% sodium hypophosphites, 1%-1.5%
Malic acid, 1%-1.5% tartaric acid, remaining is water.
9. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 8, which is characterized in that the cation third
Olefin(e) acid lotion, in terms of mass fraction, preparation method is：
0.4-0.8 parts of ammonium persulfates, 5-10 parts of cationic monomers are dissolved in 30 parts of water, it is 1. spare to obtain solution；In reaction kettle
4-8 parts of methyl acrylates of middle addition, 4-8 parts of hydroxy-ethyl acrylates, 15-25 parts of tert-butyl acrylates, 2-6 parts of styrene, 0.5-
1.5 parts of dodecyl trimethyl ammonium chloride, 50-60 parts of deionized waters stand 1h after high-speed stirred emulsification uniformly, remove bubble
And upper foam, reaction system is then heated to 65-75 DEG C, and solution is then added dropwise dropwise 1. into reaction kettle；4-6h is dripped
Insulation reaction 2-4h after finishing stops heating, and discharging is to get cation acrylic lotion after cooling.
10. the antibacterial crease-resistant antistatic shirt fabric of one kind according to claim 9, which is characterized in that the cation
Monomer is dimethyl diallyl ammonium chloride, acrylamide ethyl-trimethyl salmiac, Methacrylamide ethyl-trimethyl chlorine
Change at least one of ammonium.
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| CN113089151B (en) * | 2021-04-07 | 2022-06-17 | 罗莱生活科技股份有限公司 | Three-dimensional antibacterial yarn containing cotton fibers, preparation method of three-dimensional antibacterial yarn and towel product |
| CN114960197A (en) * | 2022-06-27 | 2022-08-30 | 徐微 | Anti-pilling elastic fabric and preparation method thereof |
| CN115652470A (en) * | 2022-11-07 | 2023-01-31 | 浙江恒百华化纤有限公司 | Polyester DTY fiber and preparation process thereof |
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