CN108070383A - A kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof - Google Patents

A kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof Download PDF

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Publication number
CN108070383A
CN108070383A CN201711409309.6A CN201711409309A CN108070383A CN 108070383 A CN108070383 A CN 108070383A CN 201711409309 A CN201711409309 A CN 201711409309A CN 108070383 A CN108070383 A CN 108070383A
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CN
China
Prior art keywords
foam
pressure balance
soil pressure
sodium sulfate
persistent form
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711409309.6A
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Chinese (zh)
Inventor
周忠太
崔素彬
李保莉
齐瑞琴
宋尚珍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinxiang Hengxing Technology Co Ltd
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Xinxiang Hengxing Technology Co Ltd
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Filing date
Publication date
Application filed by Xinxiang Hengxing Technology Co Ltd filed Critical Xinxiang Hengxing Technology Co Ltd
Priority to CN201711409309.6A priority Critical patent/CN108070383A/en
Publication of CN108070383A publication Critical patent/CN108070383A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2103/00Civil engineering use

Abstract

The invention discloses a kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof, belong to Shield Construction Technique field.Technical scheme main points are:A kind of foam stabilizing persistent form Soil pressure balance shield foam agent is that the raw material matched by following weight percent is prepared:Lauryl sodium sulfate 12%~15%;Sodium sulfate of polyethenoxy ether of fatty alcohol 3%~6%;Lauryl alcohol 0.1%~0.3%;Hexene ethylene glycol 2%~4%;Cocoamidopropyl betaine 3%~5%;NH3·H2O 1%~1.8%;Surplus is water.The invention further particularly discloses the preparation methods of the foam stabilizing persistent form Soil pressure balance shield foam agent.Foam stabilizing persistent form Soil pressure balance shield foam agent produced by the present invention is improveing soil, prevents gush etc., shows excellent performance, effectively increases driving speed and reduce construction cost.

Description

A kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof
Technical field
The invention belongs to Shield Construction Technique fields, and in particular to a kind of foam stabilizing persistent form Soil pressure balance shield foam agent and Its preparation method.
Background technology
The development of transportation plays the role of China's expanding economy very important.Instantly subway, high ferro and most The 4000km/h driving three-step-march plans closely proposed, all illustrate pursuit of the people to speed, also embody fireballing important Property.
The subway vehicles indispensable as modern metropolitan cities are only popularized now in a line city, it is following with The city expansion and the increase of the density of population in two wires and three line cities, subway must be as the standard configuration in city.
Product currently on the market, quality generally existing problem are used inferior materials and turned out substandard goods serious, with the thickening of no substantial role Agent is adulterated, and is not drawn attention to the danger of shield-tunneling construction, it is therefore necessary to the development of shield technique is followed, into one Step research and development debugging improves, and adapts to complex working condition and the update of equipment instantly.
The content of the invention
The technical problem to be solved by the present invention is to provide a kind of foam stabilizing persistent form Soil pressure balance shield foam agent and its preparations Method solve thes problems, such as that existing foaming agent foam bubbles are generally bigger than normal, is tested by improvement, obtains with suitable thin The foam of degree, and further extend the foam stabilizing time.
The present invention adopts the following technical scheme that a kind of foam stabilizing persistent form earth pressure balanced shield, EPBS steeps to solve above-mentioned technical problem Foam agent, it is characterised in that be that the raw material matched by following weight percent is prepared:
Lauryl sodium sulfate 12%~15%;
Sodium sulfate of polyethenoxy ether of fatty alcohol 3%~6%;
Lauryl alcohol 0.1%~0.3%;
Hexene ethylene glycol 2%~4%;
Cocoamidopropyl betaine 3%~5%;
NH3·H2O 1%~1.8%;
Surplus is water.
Further preferably, the foam stabilizing persistent form Soil pressure balance shield foam agent is the original matched by following weight percent What material was prepared:
Lauryl sodium sulfate 12%;
Sodium sulfate of polyethenoxy ether of fatty alcohol 4%;
Lauryl alcohol 0.1%;
Hexene ethylene glycol 3.2%;
Cocoamidopropyl betaine 4.3%;
NH3·H2O 1%;
Surplus is water.
Further preferably, the water mineral and the mass concentration of salt are less than 0.05%.
The preparation method of foam stabilizing persistent form Soil pressure balance shield foam agent of the present invention, it is characterised in that specific steps For:By water, lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, lauryl alcohol, hexene ethylene glycol, cocamidopropyl propyl amide Glycine betaine and NH3·H2The aqueous solution of O is sequentially added in the reaction kettle with stirring, is squeezed into air compressor machine into reaction kettle 1h is stirred at room temperature in the air pressure of 0.8MPa, and slow pressure release is up to foam stabilizing persistent form Soil pressure balance shield foam agent.
Foam stabilizing persistent form Soil pressure balance shield foam agent produced by the present invention is improveing soil, prevents gush etc., table Reveal excellent performance, effectively increase driving speed and reduce construction cost.
Specific embodiment
The above of the present invention is described in further details by the following examples, but this should not be interpreted as to this The scope for inventing above-mentioned theme is only limitted to following embodiment, and all technologies realized based on the above of the present invention belong to this hair Bright scope.
Embodiment 1
By 75.4Kg water, 12Kg lauryl sodium sulfate, 4Kg sodium sulfate of polyethenoxy ether of fatty alcohol, 0.1Kg lauryl alcohols, 3.2Kg Hexene ethylene glycol, 4.3Kg Cocoamidopropyl betaines and contain 1Kg NH3·H2The aqueous solution of O is sequentially added with stirring In reaction kettle, the air pressure of 0.8MPa is squeezed into reaction kettle with air compressor machine, 1h is stirred at room temperature, slow pressure release is up to foam stabilizing Persistent form Soil pressure balance shield foam agent.
Embodiment 2
By 73.1Kg water, 12Kg lauryl sodium sulfate, 6Kg sodium sulfate of polyethenoxy ether of fatty alcohol, 0.1Kg lauryl alcohols, 4Kg oneself Allyl diglycol, 3Kg Cocoamidopropyl betaines and contain 1.8Kg NH3·H2The aqueous solution of O is sequentially added with the anti-of stirring It answers in kettle, squeezes into the air pressure of 0.8MPa into reaction kettle with air compressor machine, 1h is stirred at room temperature, slow pressure release is held up to foam stabilizing Long type Soil pressure balance shield foam agent.
Embodiment 3
By 73.7Kg water, 15Kg lauryl sodium sulfate, 3Kg sodium sulfate of polyethenoxy ether of fatty alcohol, 0.3Kg lauryl alcohols, 2Kg oneself Allyl diglycol, 5Kg Cocoamidopropyl betaines and contain 1.0Kg NH3·H2The aqueous solution of O is sequentially added with the anti-of stirring It answers in kettle, squeezes into the air pressure of 0.8MPa into reaction kettle with air compressor machine, 1h is stirred at room temperature, slow pressure release is held up to foam stabilizing Long type Soil pressure balance shield foam agent.
The requirement of foam stabilizing persistent form Soil pressure balance shield foam agent made from Examples 1 to 3:
1st, in use, being made into water 2%~10% dilution with reference to soil layer situation;
2nd, the actual value of injection rate need to specifically be adjusted with reference to the water content of soil layer.
Foam stabilizing persistent form Soil pressure balance shield foam agent made from embodiment 1 and the performance comparison of similar sample in the market:
The basic principle of the present invention, main feature and advantage has been shown and described above, is not departing from spirit and scope of the invention On the premise of, the present invention also has various changes and modifications, these changes and improvements both fall within the scope of claimed invention.

Claims (4)

1. a kind of foam stabilizing persistent form Soil pressure balance shield foam agent, it is characterised in that be the raw material system matched by following weight percent For what is formed:
Lauryl sodium sulfate 12%~15%;
Sodium sulfate of polyethenoxy ether of fatty alcohol 3%~6%;
Lauryl alcohol 0.1%~0.3%;
Hexene ethylene glycol 2%~4%;
Cocoamidopropyl betaine 3%~5%;
NH3·H2O 1%~1.8%;
Surplus is water.
2. foam stabilizing persistent form Soil pressure balance shield foam agent according to claim 1, it is characterised in that be by following weight What the raw material of per distribution ratio was prepared:
Lauryl sodium sulfate 12%;
Sodium sulfate of polyethenoxy ether of fatty alcohol 4%;
Lauryl alcohol 0.1%;
Hexene ethylene glycol 3.2%;
Cocoamidopropyl betaine 4.3%;
NH3·H2O 1%;
Surplus is water.
3. foam stabilizing persistent form Soil pressure balance shield foam agent according to claim 1 or 2, it is characterised in that:In the water The mass concentration of minerals and salt is less than 0.05%.
4. a kind of preparation method of the foam stabilizing persistent form Soil pressure balance shield foam agent in claim 1-3 described in any one, It is characterized in that it concretely comprises the following steps:By water, lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, lauryl alcohol, hexene second Glycol, Cocoamidopropyl betaine and NH3·H2The aqueous solution of O sequentially add with stirring reaction kettle in, with air compressor machine to The air pressure of 0.8MPa is squeezed into reaction kettle, 1h is stirred at room temperature, slow pressure release is up to foam stabilizing persistent form earth pressure balanced shield, EPBS Foaming agent.
CN201711409309.6A 2017-12-22 2017-12-22 A kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof Pending CN108070383A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711409309.6A CN108070383A (en) 2017-12-22 2017-12-22 A kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711409309.6A CN108070383A (en) 2017-12-22 2017-12-22 A kind of foam stabilizing persistent form Soil pressure balance shield foam agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108070383A true CN108070383A (en) 2018-05-25

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102359925A (en) * 2011-07-14 2012-02-22 北京工业大学 Complete earth pressure balance shield construction soil mass improvement test method
CN103864334A (en) * 2014-02-12 2014-06-18 东莞市明洁隧道建设材料有限公司 Environment-friendly foaming agent for earth pressure balance shield tunneling machine
CN103964726A (en) * 2013-01-24 2014-08-06 北京交通大学 Foaming agent for earth pressure balance shield
CN104840402A (en) * 2015-05-28 2015-08-19 福建农林大学 Foam disinfectant hand sanitizer as well as preparation method and application thereof
CN104946263A (en) * 2015-04-02 2015-09-30 厦门诺恩斯科技有限公司 Earth pressure balance shield foaming agent
CN105198269A (en) * 2015-09-01 2015-12-30 北京铁五院工程机械有限公司 Foaming agent for low temperature-resistant soil pressure balance shield, and preparation method and application of foaming agent
CN105969368A (en) * 2016-05-16 2016-09-28 四川恒泽建材有限公司 Foaming agent for shield tunnelling machine and preparation method of foaming agent
CN106433679A (en) * 2016-10-10 2017-02-22 中昊(大连)化工研究设计院有限公司 Acid-resistant shield foaming agent
CN106635027A (en) * 2016-11-17 2017-05-10 纳拓润滑技术(上海)有限公司 Foaming agent for shielding and preparation method thereof
CN106929023A (en) * 2017-02-17 2017-07-07 山东大学 The stable foam agent and preparation method and application of bad ground shield-tunneling construction
CN107033916A (en) * 2017-04-21 2017-08-11 中国建筑材料科学研究总院 A kind of Soil pressure balance shield foam agent and preparation method thereof

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102359925A (en) * 2011-07-14 2012-02-22 北京工业大学 Complete earth pressure balance shield construction soil mass improvement test method
CN103964726A (en) * 2013-01-24 2014-08-06 北京交通大学 Foaming agent for earth pressure balance shield
CN103864334A (en) * 2014-02-12 2014-06-18 东莞市明洁隧道建设材料有限公司 Environment-friendly foaming agent for earth pressure balance shield tunneling machine
CN104946263A (en) * 2015-04-02 2015-09-30 厦门诺恩斯科技有限公司 Earth pressure balance shield foaming agent
CN104840402A (en) * 2015-05-28 2015-08-19 福建农林大学 Foam disinfectant hand sanitizer as well as preparation method and application thereof
CN105198269A (en) * 2015-09-01 2015-12-30 北京铁五院工程机械有限公司 Foaming agent for low temperature-resistant soil pressure balance shield, and preparation method and application of foaming agent
CN105969368A (en) * 2016-05-16 2016-09-28 四川恒泽建材有限公司 Foaming agent for shield tunnelling machine and preparation method of foaming agent
CN106433679A (en) * 2016-10-10 2017-02-22 中昊(大连)化工研究设计院有限公司 Acid-resistant shield foaming agent
CN106635027A (en) * 2016-11-17 2017-05-10 纳拓润滑技术(上海)有限公司 Foaming agent for shielding and preparation method thereof
CN106929023A (en) * 2017-02-17 2017-07-07 山东大学 The stable foam agent and preparation method and application of bad ground shield-tunneling construction
CN107033916A (en) * 2017-04-21 2017-08-11 中国建筑材料科学研究总院 A kind of Soil pressure balance shield foam agent and preparation method thereof

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Application publication date: 20180525

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