CN106359375A - Phosphate wetting dispersant, and preparation method and application thereof - Google Patents
Phosphate wetting dispersant, and preparation method and application thereof Download PDFInfo
- Publication number
- CN106359375A CN106359375A CN201610738395.4A CN201610738395A CN106359375A CN 106359375 A CN106359375 A CN 106359375A CN 201610738395 A CN201610738395 A CN 201610738395A CN 106359375 A CN106359375 A CN 106359375A
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- CN
- China
- Prior art keywords
- agent
- acid ester
- suspending agent
- phosphoric acid
- wetting dispersing
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The invention relates to a phosphate wetting dispersant, and a preparation method and application thereof. The phosphate wetting dispersant comprises 5 to 20 percent of a wetting agent, 50 to 80 percent of a dispersant, 5 to 25 percent of a pH regulator and 1 to 10 percent of an anti-freezing agent. The preparation method comprises the following steps: throwing the dispersant and the pH regulator into a reaction kettle for reacting for 30 minutes at 60 DEG C, then, throwing the wetting agent, the anti-freezing agent and the like into the reaction kettle, continuing stirring for 10 minutes, and discharging when a product is transparent and uniform. The phosphate wetting dispersant provided by the invention is stable in quality, high in phosphate content, high in wetting dispersibility, low in foamability, good in flowing property and wide in application range, and can be applied to most suspending agents.
Description
Technical field
The present invention relates to field of pesticide preparation and in particular to a kind of phosphoric acid ester wetting dispersing agent and preparation method thereof and should
With.
Background technology
In aqueous suspension agent preparation, main auxiliary agent is wetting agent and dispersant.What wherein wetting agent was commonly used has: alkyl sulfide
Hydrochlorate, alkylnaphthalene sulfonate, fatty alcohol-polyoxyethylene ether, alkylamide taurate, dialkyl group succinic acid sulfonate, alkyl phenol
Polyoxyethylene ether, PULLRONIC F68 block type polyethers etc..What dispersant was commonly used has: alkylsulfonate, fatty alcohol polyoxy
Ethylene ether sulfonate, naphthalene sulfonate, lignosulfonates, alkylphenol polyoxyethylene phosphate ester salt, alkylphenol polyoxyethylene
Alkylamine salt, polycarboxylate, alkyl phosphate triethanolamine salt etc..
This year deepens to the attention of environmental protection with people, and the ratio of water base agent type is listed in and is continuously increased, auxiliary agent species
Constantly increase, have two outstanding problems often to perplex production schedule personnel at present, one auxiliary agent total amount increases, and highly versatile
Auxiliary agent is again few, certainly will shine into the increase that person skilled screens auxiliary agent workload, and it is two due to the aqueous suspension agent sand milling time relatively
Long, easily accumulate substantial amounts of foam in process of producing product, these foams are difficult to eliminate, and will result in the false cream of sand milling slurry
Change, make troubles to production.
Phosphate ester surfactant is a kind of function admirable, widely used surfactant.It has excellent profit
The characteristic such as moist, detergency, lyotropy, emulsibility, antistatic behaviour, inhibition be antirust, easily biological-degradable, zest ratio is relatively low, rises
Bubble property is low, and especially heat stability, alkaline-resisting and electrolyte-resistant, antistatic behaviour are superior to general anion surfactant, extensively should
For fields such as chemical fibre, weaving, plastics, papermaking, leather and household chemicalss.
The phosphoric acid ester wetting dispersing agent major part using both at home and abroad at present contains low, poor fluidity admittedly, and quality is unstable, holds
Easily it is layered, go bad and wait impact to use.
In sum, prior art also has larger defect.
Content of the invention
In view of this it is necessary to for above-mentioned problem, provide a kind of phosphoric acid ester wetting dispersing agent and preparation method thereof
And application, this phosphoric acid ester wetting dispersing agent steady quality, large arch dam phosphate ester, foaming characteristic are low.
The present invention employs the following technical solutions:
A kind of phosphoric acid ester wetting dispersing agent, component includes wetting agent: 5-20%, dispersant: 50-80%, ph regulator:
5-25%, antifreezing agent: 1-10%.
Further, described component preferably includes wetting agent: 10-15%, dispersant: 65-75%, ph regulator: 10-
15%th, antifreezing agent: 5-8%.
Further, described wetting agent is PULLRONIC F68 block type polyethers, oxirane and high fatty alcohol
Condensation substance, amber acid ester sodium sulfonate, lauric acid diethanolamine, Polyethylene Glycol series, one or more of alcohol ether phosphate.
Further, described dispersant is alkylphenol-polyethenoxy phosphate ester, APG, aliphatic alcohol polyethenoxy phosphorus
Acid esters, tristyrylphenol polyoxyethylene ether phosphate ester, LOMAR PWA EINECS 246-676-2 and its formaldehyde condensation products, alkyl phosphate triethanolamine salt
One or more of.
Further, described ph regulator is sodium alkoxide, sodium hydroxide, potassium hydroxide, ammonia, triethanolamine, triethylamine, boron
One of acid, hydrochloric acid.
Further, described antifreezing agent is one of methanol, ethylene glycol, glycerol, calcium chloride, sodium chloride or two kinds.
Further, the preparation method of described phosphoric acid ester wetting dispersing agent, comprising: first dispersant and ph regulator are thrown
Enter in reactor and react 30min at 60 DEG C, then by wetting agent, antifreezing agent etc. puts into and continues stirring in reactor reactor
10min product is transparent homogeneous to get final product discharging.
Further, described phosphoric acid ester wetting dispersing agent, for preparing Tolfenpyrad suspending agent, thiophanate-methyl hangs
Floating agent, difenoconazole suspending agent, Bifenazate suspending agent, spiral shell worm ethyl ester suspending agent, pyrimethanil, indoxacarb suspend
Agent, MTI-446 suspending agent, hexaconazole suspending agent, carbendazim suspending agent, imidacloprid suspension seed-coating agent, emamectin benzoate+efficient chlorine fluorine cyanogen
Chrysanthemum ester suspending agent, acetamiprid suspending agent and pesticide seed coating.
The beneficial effect that the present invention reaches:
The present invention provides phosphoric acid ester wetting dispersing agent, has extraordinary wettability, especially in the water of difficult moistening, high-load
Show substantially in suspending agent, it may have dispersant property well, most of aqueous suspension agent this auxiliary agent alone just can reach joins
Fang Yaoqiu.
The present invention provides phosphoric acid ester wetting dispersing agent, large arch dam phosphate ester, stable in properties, can improve pesticide well and hang
The suspensibility of floating agent, and in aqueous suspension agent, sand grinding process foam number is little, especially in the bubble aqueous suspension agent of very difficult elimination
Performance is more meaningful.
The present invention provides phosphoric acid ester wetting dispersing agent, and in aqueous suspension agent, application broad spectrum activity very greatly aqueous suspension agent is first
Select auxiliary agent, and viscosity is little, good fluidity, it is convenient to shift in production and use.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with claim and specifically
Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only in order to explain
The present invention, is not intended to limit the present invention.
Embodiment one
Preparation total amount is the phosphoric acid ester wetting dispersing agent of the present invention of 1000g
Component and proportioning:
Lauric acid diethyl amide 10%, diethanolamine 5%, triethanolamine 15%, aliphatic alcohol polyethenoxy phosphate ester
65%, ethylene glycol 5%
Preparation method:
By the aliphatic alcohol polyethenoxy phosphate ester of 650g, 50g diethanolamine, 150g triethanolamine stirring reaction at 60 DEG C
30min, then adding 100g lauric acid diethyl amide, 50g ethylene glycol continues stirring 10min, and material to be mixed is full and uniform
After assuming transparence, that is, compound and obtain assistant composition.
Embodiment two
Preparation total amount is the phosphoric acid ester wetting dispersing agent of the present invention of 1000g
Component and proportioning:
Lauric acid diethyl amide 10%, triethanolamine 18%, tristyrylphenol polyoxyethylene ether phosphate ester 67%,
Ethylene glycol 5%
Preparation method:
By the tristyrylphenol polyoxyethylene ether phosphate ester of 670g, 180g triethanolamine stirring reaction at 60 DEG C
30min, is adding 100g lauric acid diethyl amide, 50g ethylene glycol continues stirring 10min, and material to be mixed is full and uniform to be in
After existing transparence, that is, compound and obtain assistant composition.
Embodiment three
Preparation total amount is the phosphoric acid ester wetting dispersing agent of the present invention of 1000g
Component and proportioning:
Lauric acid diethanolamine 6%, PEG400 4%, triethanolamine 20%, triphenyl vinyl phenol polyoxyethylene
Ether phosphate 65%, ethylene glycol 5%
Preparation method:
By the tristyrylphenol polyoxyethylene ether phosphate ester of 650g, 200g triethanolamine stirring reaction at 60 DEG C
30min, is adding 60g lauric acid diethyl amide, 40g PEG400,50g ethylene glycol continues stirring 10min, to be mixed
Material is full and uniform assume transparence after, that is, compound obtain assistant composition.
The wetting dispersing agent of embodiment two gained is applied in 30% Tolfenpyrad sc formula, consumption 5-6%.Sand milling mistake
In 30% Tolfenpyrad sc in journey, sand milling terminates substantially do not have bubble in rear sand milling cylinder, with the application of this type common wetting dispersing agent
In 30% Tolfenpyrad sc, sand milling terminates there is numerous air-bubble in rear sand milling cylinder, and the defoamer consumption bubble doubling does not have yet
Disappear and.30% prepared Tolfenpyrad sc heat storage 14 days at 54 DEG C, cold storage 7 days, freeze-thaw cycle three times at -18 DEG C at -5 DEG C
Experiment, product stability is not changed in.
The wetting dispersing agent of embodiment three gained is applied in 50% thiophanate-methyl suspending agent formula, consumption 4-5%.
Product is stable, and mobility is preferable, modest viscosity, and other control sample mobility are very poor, and viscosity is larger.Under the same conditions,
Increase the thickening agent of equivalent, the 50% thiophanate-methyl suspending agent viscosity made with this wetting dispersing agent is in 900cp, similar
50% thiophanate-methyl suspending agent viscosity that the common wetting dispersing agent of type is made is in 1300cp.
Alone for the wetting dispersing agent of embodiment one gained or one auxiliary agent of collocation are applied to 40% difenoconazole suspending
Agent, 40% Bifenazate suspending agent, 30% spiral shell worm ethyl ester suspending agent, 50% pyrimethanil, 50% thiophanate-methyl suspend
Agent, 30% indoxacarb suspending agent, 20% MTI-446 suspending agent, 40% hexaconazole suspending agent, 50% carbendazim suspending agent, 600g/l
Imidacloprid suspension seed-coating agent, 3% emamectin benzoate+7% gamma cyhalothrin suspending agent, 30% Tolfenpyrad suspending agent, 20% pyridine
In the formula such as worm amidine suspending agent, consumption 3-4%, such as: by the phosphate ester wetting dispersing agent of 3% embodiment one, 3% carboxylate of arranging in pairs or groups
Dispersant is for can be made into 20% qualified acetamiprid suspending agent in product in 20% acetamiprid suspending agent.The system of above-mentioned gained
Agent is stable, and wetting and dispersing is good, and low lamination is no tied in heat storage, meets national standard.
The present invention provides phosphoric acid ester wetting dispersing agent as can be seen here is a wide spectrum, the wetting and dispersing of stable in properties
Agent, can be used for multiple compounds, and particularly high-load in the big suspending agent of some difficulty, and fusing point is low, big outstanding of water solublity
In floating agent.
Embodiment described above only have expressed the several embodiments of the present invention, and its description is more concrete and detailed, but simultaneously
Therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, some deformation can also be made and improve, these broadly fall into the guarantor of the present invention
Shield scope.Therefore, the protection domain of patent of the present invention should be defined by claims.
Claims (8)
1. a kind of phosphoric acid ester wetting dispersing agent, component includes wetting agent: 5-20%, dispersant: 50-80%, ph regulator: 5-
25%th, antifreezing agent: 1-10%.
2. phosphoric acid ester wetting dispersing agent according to claim 1 is it is characterised in that described component preferably includes moistening
Agent: 10-15%, dispersant: 65-75%, ph regulator: 10-15%, antifreezing agent: 5-8%.
3. phosphoric acid ester wetting dispersing agent according to claim 1 it is characterised in that described wetting agent be polyoxyethylene-
The condensation substance of oxypropylene block type polyethers, oxirane and high fatty alcohol, amber acid ester sodium sulfonate, lauric acid diethanol
One or more of amine, Polyethylene Glycol series, alcohol ether phosphate.
4. phosphoric acid ester wetting dispersing agent according to claim 1 is it is characterised in that described dispersant is alkyl phenol polyoxy
Ethylene phosphate ester, APG, aliphatic alcohol polyethenoxy phosphate ester, tristyrylphenol polyoxyethylene ether phosphate ester, naphthalene
One or more of sulfonic acid and its formaldehyde condensation products, alkyl phosphate triethanolamine salt.
5. phosphoric acid ester wetting dispersing agent according to claim 1 is it is characterised in that described ph regulator is sodium alkoxide, hydrogen
One of sodium oxide, potassium hydroxide, ammonia, triethanolamine, triethylamine, boric acid, hydrochloric acid.
6. phosphoric acid ester wetting dispersing agent according to claim 1 is it is characterised in that described antifreezing agent is methanol, second two
One of alcohol, glycerol, calcium chloride, sodium chloride or two kinds.
7. the preparation method of the phosphoric acid ester wetting dispersing agent described in claim 1 is it is characterised in that include: first by dispersant
And ph regulator puts in reactor and reacts 30min at 60 DEG C, then by wetting agent, antifreezing agent etc. puts into reactor reactor
The middle stirring 10min that continues is to homogeneous transparent.
8. the phosphoric acid ester wetting dispersing agent described in claim 1 is it is characterised in that preparing Tolfenpyrad suspending agent, methyl
Thiophanate suspending agent, difenoconazole suspending agent, Bifenazate suspending agent, spiral shell worm ethyl ester suspending agent, pyrimethanil, indenes worm
Prestige suspending agent, MTI-446 suspending agent, hexaconazole suspending agent, carbendazim suspending agent, imidacloprid suspension seed-coating agent, emamectin benzoate+efficiently
Application in lambda-cyhalothrin suspending agent, acetamiprid suspending agent and pesticide seed coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610738395.4A CN106359375B (en) | 2016-08-26 | 2016-08-26 | Phosphate wetting dispersant, preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610738395.4A CN106359375B (en) | 2016-08-26 | 2016-08-26 | Phosphate wetting dispersant, preparation method and application thereof |
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| CN106359375A true CN106359375A (en) | 2017-02-01 |
| CN106359375B CN106359375B (en) | 2020-04-14 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102137A (en) * | 2017-12-26 | 2018-06-01 | 广东生益科技股份有限公司 | Nano pulp composition, its preparation method and include its resin combination |
| CN109371674A (en) * | 2018-09-11 | 2019-02-22 | 杭州传化精细化工有限公司 | A kind of preparation method of textile antistatic agent |
| CN109699653A (en) * | 2019-01-31 | 2019-05-03 | 上海师范大学 | Epoxiconazole aqueous suspension agent and preparation method thereof |
| CN110250187A (en) * | 2019-06-24 | 2019-09-20 | 江苏凯元科技有限公司 | A kind of pyrimethanil aqueous suspension agent and its preparation process |
| CN115863643A (en) * | 2022-12-10 | 2023-03-28 | 安徽皓飞新材料有限公司 | Dispersing and softening agent for lithium ion battery anode slurry and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101715761A (en) * | 2009-11-04 | 2010-06-02 | 深圳诺普信农化股份有限公司 | Cyanogens traniliprole suspending agent and preparation method thereof |
| CN102939981A (en) * | 2011-12-05 | 2013-02-27 | 江西正邦生物化工股份有限公司 | Chlorfluazuron-containing pesticide suspending agent and preparation method thereof |
| CN103636612A (en) * | 2013-12-20 | 2014-03-19 | 李视辉 | Cyantraniliprole and chlorfenapyr suspending agent and preparation method thereof |
| CN103783058A (en) * | 2011-12-05 | 2014-05-14 | 江西正邦生物化工股份有限公司 | Pesticide suspending agent containing chlorfluazuron and butene-fipronil and preparation method of pesticide suspending agent |
| CN103798271A (en) * | 2011-12-05 | 2014-05-21 | 江西正邦生物化工股份有限公司 | Pesticide suspension concentrate containing chlorfluazuron and acetamiprid and preparation method of pesticide suspension concentrate |
| CN105076145A (en) * | 2015-08-20 | 2015-11-25 | 广东中迅农科股份有限公司 | Microcapsule suspending agent containing azoxystrobin and preparation method thereof |
-
2016
- 2016-08-26 CN CN201610738395.4A patent/CN106359375B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101715761A (en) * | 2009-11-04 | 2010-06-02 | 深圳诺普信农化股份有限公司 | Cyanogens traniliprole suspending agent and preparation method thereof |
| CN102939981A (en) * | 2011-12-05 | 2013-02-27 | 江西正邦生物化工股份有限公司 | Chlorfluazuron-containing pesticide suspending agent and preparation method thereof |
| CN103783058A (en) * | 2011-12-05 | 2014-05-14 | 江西正邦生物化工股份有限公司 | Pesticide suspending agent containing chlorfluazuron and butene-fipronil and preparation method of pesticide suspending agent |
| CN103798271A (en) * | 2011-12-05 | 2014-05-21 | 江西正邦生物化工股份有限公司 | Pesticide suspension concentrate containing chlorfluazuron and acetamiprid and preparation method of pesticide suspension concentrate |
| CN103636612A (en) * | 2013-12-20 | 2014-03-19 | 李视辉 | Cyantraniliprole and chlorfenapyr suspending agent and preparation method thereof |
| CN105076145A (en) * | 2015-08-20 | 2015-11-25 | 广东中迅农科股份有限公司 | Microcapsule suspending agent containing azoxystrobin and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102137A (en) * | 2017-12-26 | 2018-06-01 | 广东生益科技股份有限公司 | Nano pulp composition, its preparation method and include its resin combination |
| CN108102137B (en) * | 2017-12-26 | 2020-11-17 | 广东生益科技股份有限公司 | Nanopal composition, method of preparing the same, and resin composition comprising the same |
| CN109371674A (en) * | 2018-09-11 | 2019-02-22 | 杭州传化精细化工有限公司 | A kind of preparation method of textile antistatic agent |
| CN109699653A (en) * | 2019-01-31 | 2019-05-03 | 上海师范大学 | Epoxiconazole aqueous suspension agent and preparation method thereof |
| CN110250187A (en) * | 2019-06-24 | 2019-09-20 | 江苏凯元科技有限公司 | A kind of pyrimethanil aqueous suspension agent and its preparation process |
| CN115863643A (en) * | 2022-12-10 | 2023-03-28 | 安徽皓飞新材料有限公司 | Dispersing and softening agent for lithium ion battery anode slurry and application thereof |
| CN115863643B (en) * | 2022-12-10 | 2023-08-18 | 安徽皓飞新材料有限公司 | Dispersing softening agent for lithium ion battery anode slurry and application thereof |
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| Publication number | Publication date |
|---|---|
| CN106359375B (en) | 2020-04-14 |
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