CN108060423A - The Quick Response Code braider stain cleaning agent and preparation method thereof that derusts - Google Patents
The Quick Response Code braider stain cleaning agent and preparation method thereof that derusts Download PDFInfo
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- CN108060423A CN108060423A CN201711345553.0A CN201711345553A CN108060423A CN 108060423 A CN108060423 A CN 108060423A CN 201711345553 A CN201711345553 A CN 201711345553A CN 108060423 A CN108060423 A CN 108060423A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
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Abstract
The invention discloses a kind of Quick Response Code braider preparation method for the stain cleaning agent that derusts, preparation method includes：1) water, phosphoric acid and glycolic are placed under conditions of temperature is 40 60 DEG C and mixed, mixed liquor M1 is made；2) graphite is placed in acid solution after impregnating, is placed under conditions of temperature is 200 300 DEG C and is roasted, powder M2 is made；3) mixed liquor M1, powder M2 and sodium pyrophosphate are mixed, mixed liquor M3 is made；4) under conditions of temperature is 60 80 DEG C, octyl phenol polyoxyethylene ether and triethanolamine mixing is added in into mixed liquor M3, the Quick Response Code braider stain cleaning agent that derusts is made.The present invention mixes water, phosphoric acid and glycolic, graphite is placed in acid solution again and is impregnated, roasting, above-mentioned mixed liquor, powder and sodium pyrophosphate are mixed again, by said mixture and octyl phenol polyoxyethylene ether and triethanolamine so that there is good derusting effect by cleaning agent made from above-mentioned material and method.
Description
Technical field
The present invention relates to cleaning agent Material Fields, and in particular, to Quick Response Code braider stain cleaning agent and its system of derusting
Preparation Method.
Background technology
With the continuous progress of science and technology, Quick Response Code is convenient to use performance with it to be subject to increasingly to use to be extensive, and
Quick Response Code is subjected to braiding preparation so that it more adapts to the use under most of environment, and will not sensitive paper matter Quick Response Code
Equally, cause it that cannot make moist.And with the use of Quick Response Code braider, situations such as inevitably getting rusty,
It is taken to so as to cause rusty stain on the Quick Response Code of braiding, the quality of product is caused to go wrong.
Therefore it provides a kind of can effectively derust, the Quick Response Code braider for greatly improving its performance is cleaned with stain of derusting
The problem of agent and preparation method thereof is urgent need to resolve of the present invention.
The content of the invention
For the above-mentioned prior art, it is an object of the invention to overcome with Quick Response Code braider to make in the prior art
With situations such as inevitably getting rusty, being taken to so as to cause rusty stain on the Quick Response Code of braiding, cause the quality of product
Go wrong, so provide it is a kind of can effectively derust, the Quick Response Code braider for greatly improving its performance is cleaned with stain of derusting
Agent and preparation method thereof.
To achieve these goals, the present invention provides a kind of Quick Response Code braider preparation sides for the stain cleaning agent that derusts
Method, wherein, the preparation method includes：
1) water, phosphoric acid and glycolic are placed under conditions of temperature is 40-60 DEG C and mixed, mixed liquor M1 is made；
2) graphite is placed in acid solution after impregnating, is placed under conditions of temperature is 200-300 DEG C and is roasted, powder is made
M2；
3) mixed liquor M1, powder M2 and sodium pyrophosphate are mixed, mixed liquor M3 is made；
4) under conditions of temperature is 60-80 DEG C, octyl phenol polyoxyethylene ether and triethanolamine are added in into mixed liquor M3
The Quick Response Code braider stain cleaning agent that derusts is made in mixing.
The present invention also provides a kind of Quick Response Code braider according to made from preparation method described above is clear with stain of derusting
Lotion.
Through the above technical solutions, the present invention mixes water, phosphoric acid and glycolic, then graphite is placed in acid solution and is impregnated,
It is then roasted, obtains powder, then above-mentioned mixed liquor, powder and sodium pyrophosphate are mixed, further, by above-mentioned mixing
Object and octyl phenol polyoxyethylene ether and triethanolamine, so that having by cleaning agent made from above-mentioned material and method good
Derusting effect.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
The specific embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The endpoint of disclosed scope and any value are not limited to the accurate scope or value herein, these scopes or
Value should be understood to comprising the value close to these scopes or value.For numberical range, between the endpoint value of each scope, respectively
It between the endpoint value of a scope and individual point value and can be individually combined with each other between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
The present invention provides a kind of Quick Response Code braider preparation method for the stain cleaning agent that derusts, wherein, the preparation side
Method includes：
1) water, phosphoric acid and glycolic are placed under conditions of temperature is 40-60 DEG C and mixed, mixed liquor M1 is made；
2) graphite is placed in acid solution after impregnating, is placed under conditions of temperature is 200-300 DEG C and is roasted, powder is made
M2；
3) mixed liquor M1, powder M2 and sodium pyrophosphate are mixed, mixed liquor M3 is made；
4) under conditions of temperature is 60-80 DEG C, octyl phenol polyoxyethylene ether and triethanolamine are added in into mixed liquor M3
The Quick Response Code braider stain cleaning agent that derusts is made in mixing.
The present invention mixes water, phosphoric acid and glycolic, then graphite is placed in acid solution and is impregnated, and is then roasted, obtained
Powder, then above-mentioned mixed liquor, powder and sodium pyrophosphate are mixed, further, by said mixture and octyl phenol polyoxy second
Alkene ether and triethanolamine, so that there is good derusting effect by cleaning agent made from above-mentioned material and method.
In a kind of preferred embodiment of the present invention, in step 1), compared with the water of 10 parts by weight, the phosphorus
The dosage of acid is 20-40 parts by weight, and the dosage of the glycolic is 1-3 parts by weight.
In a kind of embodiment being more highly preferred to, acid solution described in step 2) is selected from the aqueous solution of hydrochloric acid, and the hydrochloric acid
Aqueous solution in hydrochloric acid content be 10-30 weight %.
In further preferred embodiment, in step 2), the calcination temperature of roasting process is 3-6h.
In another preferred embodiment of the present invention, in step 3), compared with the mixed liquor of 100 parts by weight
The dosage of M1, the powder M2 are 10-20 parts by weight, and the dosage of the sodium pyrophosphate is 5-10 parts by weight.
It is described compared with the mixed liquor M3 of 100 parts by weight in step 4) in a kind of embodiment being more highly preferred to
The dosage of octyl phenol polyoxyethylene ether is 0.5-2 parts by weight, and the dosage of the triethanolamine is 3-10 parts by weight.
The present invention also provides a kind of Quick Response Code braider according to made from preparation method described above is clear with stain of derusting
Lotion.
The present invention will be described in detail by way of examples below.
Embodiment 1
1) water of 10 parts by weight, 20 parts by weight of phosphoric acid and 1 parts by weight of ethanol acid are placed under conditions of temperature is 40 DEG C and mixed
It closes, mixed liquor M1 is made；
2) after graphite to be placed in the content of hydrochloric acid to be impregnated in the aqueous solution of the hydrochloric acid of 10 weight %, temperature is placed in as 200
3h is roasted under conditions of DEG C, powder M2 is made；
3) the mixed liquor M1 of 100 parts by weight, 10 parts by weight of powder M2 and 5 parts by weight sodium pyrophosphates are mixed, mixing is made
Liquid M3；
4) under conditions of temperature is 60 DEG C, 0.5 parts by weight octyl phenol polyoxy is added in into the mixed liquor M3 of 100 parts by weight
Vinethene and the mixing of 3 parts by weight triethanolamines, are made the Quick Response Code braider stain cleaning agent A1 that derusts.
Embodiment 2
1) water of 10 parts by weight, 40 parts by weight of phosphoric acid and 3 parts by weight of ethanol acid are placed under conditions of temperature is 60 DEG C and mixed
It closes, mixed liquor M1 is made；
2) after graphite to be placed in the content of hydrochloric acid to be impregnated in the aqueous solution of the hydrochloric acid of 30 weight %, temperature is placed in as 300
6h is roasted under conditions of DEG C, powder M2 is made；
3) the mixed liquor M1 of 100 parts by weight, 20 parts by weight of powder M2 and 10 parts by weight sodium pyrophosphates are mixed, mixing is made
Liquid M3；
4) under conditions of temperature is 80 DEG C, 2 parts by weight octyl phenol polyoxy second are added in into the mixed liquor M3 of 100 parts by weight
Alkene ether and the mixing of 10 parts by weight triethanolamines, are made the Quick Response Code braider stain cleaning agent A2 that derusts.
Embodiment 3
1) water of 10 parts by weight, 30 parts by weight of phosphoric acid and 2 parts by weight of ethanol acid are placed under conditions of temperature is 50 DEG C and mixed
It closes, mixed liquor M1 is made；
2) after graphite to be placed in the content of hydrochloric acid to be impregnated in the aqueous solution of the hydrochloric acid of 20 weight %, temperature is placed in as 260
5h is roasted under conditions of DEG C, powder M2 is made；
3) the mixed liquor M1 of 100 parts by weight, 15 parts by weight of powder M2 and 8 parts by weight sodium pyrophosphates are mixed, mixing is made
Liquid M3；
4) under conditions of temperature is 70 DEG C, 1 parts by weight octyl phenol polyoxy second is added in into the mixed liquor M3 of 100 parts by weight
Alkene ether and the mixing of 7 parts by weight triethanolamines, are made the Quick Response Code braider stain cleaning agent A3 that derusts.
Embodiment 4
It is prepared by the preparation method according to embodiment 1, unlike, the dosage of the phosphoric acid is 10 parts by weight, described
The dosage of glycolic is 0.5 parts by weight, and the Quick Response Code braider stain cleaning agent A4 that derusts is made.
Embodiment 5
It is prepared by the preparation method according to embodiment 2, unlike, the dosage of the powder M2 is 5 parts by weight, described
The dosage of sodium pyrophosphate is 2 parts by weight, and the Quick Response Code braider stain cleaning agent A5 that derusts is made.
Embodiment 6
It is prepared by the preparation method according to embodiment 3, unlike, the dosage of the octyl phenol polyoxyethylene ether is
0.1 parts by weight, the dosage of the triethanolamine is 1 parts by weight, and the Quick Response Code braider stain cleaning agent A6 that derusts is made.
Comparative example 1
It is prepared by the preparation method according to embodiment 1, unlike, without step 2), directly powder M2 is used
Graphite substitutes, and cleaning agent D1 is made.
Comparative example 2
It is prepared by the preparation method according to embodiment 2, unlike, it is added without glycolic and octylphenol polyethylene ethylene oxide
Cleaning agent D2 is made in ether.
Test case
By above-mentioned A1-A6, D1 and D2 each with water according to 1:5 ratio mixing, is made cleaning solution, and surface is had rusty stain
Metal derby be placed in above-mentioned cleaning solution carry out oscillation cleaning after, observe its surface rusty stain situation, obtained result such as 1 institute of table
Show.
Table 1
| Number | Surface rusty stain situation |
| A1 | Substantially it is rustless |
| A2 | Substantially it is rustless |
| A3 | Substantially it is rustless |
| A4 | Slight rust staining |
| A5 | Substantially it is rustless |
| A6 | Slight rust staining |
| D1 | Apparent rust staining |
| D2 | Apparent rust staining |
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail, within the scope of the technical concept of the present invention, a variety of simple variants can be carried out to technical scheme, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that the specific technical features described in the above specific embodiments, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (7)
1. a kind of Quick Response Code braider preparation method for the stain cleaning agent that derusts, which is characterized in that the preparation method includes：
1) water, phosphoric acid and glycolic are placed under conditions of temperature is 40-60 DEG C and mixed, mixed liquor M1 is made；
2) graphite is placed in acid solution after impregnating, is placed under conditions of temperature is 200-300 DEG C and is roasted, powder M2 is made；
3) mixed liquor M1, powder M2 and sodium pyrophosphate are mixed, mixed liquor M3 is made；
4) under conditions of temperature is 60-80 DEG C, octyl phenol polyoxyethylene ether and triethanolamine mixing are added in into mixed liquor M3,
The Quick Response Code braider stain cleaning agent that derusts is made.
2. preparation method according to claim 1, wherein, in step 1), compared with the water of 10 parts by weight, the phosphorus
The dosage of acid is 20-40 parts by weight, and the dosage of the glycolic is 1-3 parts by weight.
3. preparation method according to claim 1 or 2, wherein, acid solution described in step 2) is selected from the aqueous solution of hydrochloric acid, and
The content of hydrochloric acid is 10-30 weight % in the aqueous solution of the hydrochloric acid.
4. preparation method according to claim 1 or 2, wherein, in step 2), the calcination temperature of roasting process is 3-6h.
5. preparation method according to claim 1 or 2, wherein, in step 3), compared with the mixing of 100 parts by weight
The dosage of liquid M1, the powder M2 are 10-20 parts by weight, and the dosage of the sodium pyrophosphate is 5-10 parts by weight.
6. preparation method according to claim 1 or 2, wherein, in step 4), compared with the mixing of 100 parts by weight
Liquid M3, the dosage of the octyl phenol polyoxyethylene ether is 0.5-2 parts by weight, and the dosage of the triethanolamine is 3-10 parts by weight.
7. Quick Response Code braider made from the preparation method in a kind of 1-6 according to claim described in any one is clear with stain of derusting
Lotion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711345553.0A CN108060423A (en) | 2017-12-15 | 2017-12-15 | The Quick Response Code braider stain cleaning agent and preparation method thereof that derusts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711345553.0A CN108060423A (en) | 2017-12-15 | 2017-12-15 | The Quick Response Code braider stain cleaning agent and preparation method thereof that derusts |
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| Publication Number | Publication Date |
|---|---|
| CN108060423A true CN108060423A (en) | 2018-05-22 |
Family
ID=62138986
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| Application Number | Title | Priority Date | Filing Date |
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| CN201711345553.0A Pending CN108060423A (en) | 2017-12-15 | 2017-12-15 | The Quick Response Code braider stain cleaning agent and preparation method thereof that derusts |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103069050A (en) * | 2010-08-20 | 2013-04-24 | 3M创新有限公司 | Rust removing composition |
| CN103422099A (en) * | 2012-05-22 | 2013-12-04 | 苏州一方金属表面处理科技有限公司 | A cleaning agent for stainless steel and iron member composite boards and a preparation method of the cleaning agent |
| CN103590054A (en) * | 2012-08-14 | 2014-02-19 | 苏州一方金属表面处理科技有限公司 | Cleaning passivator for galvanized metal part |
| CN103911625A (en) * | 2014-04-25 | 2014-07-09 | 湖南大学 | Neutral oil removal rust remover and preparation method thereof |
| CN104846384A (en) * | 2015-04-30 | 2015-08-19 | 青岛东昌瑞纺织品有限公司 | Equipment interior cleaning agent |
-
2017
- 2017-12-15 CN CN201711345553.0A patent/CN108060423A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103069050A (en) * | 2010-08-20 | 2013-04-24 | 3M创新有限公司 | Rust removing composition |
| CN103422099A (en) * | 2012-05-22 | 2013-12-04 | 苏州一方金属表面处理科技有限公司 | A cleaning agent for stainless steel and iron member composite boards and a preparation method of the cleaning agent |
| CN103590054A (en) * | 2012-08-14 | 2014-02-19 | 苏州一方金属表面处理科技有限公司 | Cleaning passivator for galvanized metal part |
| CN103911625A (en) * | 2014-04-25 | 2014-07-09 | 湖南大学 | Neutral oil removal rust remover and preparation method thereof |
| CN104846384A (en) * | 2015-04-30 | 2015-08-19 | 青岛东昌瑞纺织品有限公司 | Equipment interior cleaning agent |
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Application publication date: 20180522 |