CN108059389A - Nano modification lacquer - Google Patents

Nano modification lacquer Download PDF

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Publication number
CN108059389A
CN108059389A CN201711305282.6A CN201711305282A CN108059389A CN 108059389 A CN108059389 A CN 108059389A CN 201711305282 A CN201711305282 A CN 201711305282A CN 108059389 A CN108059389 A CN 108059389A
Authority
CN
China
Prior art keywords
parts
nano
lacquer
mesh
antifoaming agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711305282.6A
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Chinese (zh)
Inventor
朱晓辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinhuasheng Energy Saving Technology Co Ltd
Original Assignee
Xinhuasheng Energy Saving Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinhuasheng Energy Saving Technology Co Ltd filed Critical Xinhuasheng Energy Saving Technology Co Ltd
Priority to CN201711305282.6A priority Critical patent/CN108059389A/en
Publication of CN108059389A publication Critical patent/CN108059389A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses nano modification lacquers, by proportion by weight, include 10 30 parts of the mixture of 100 parts of deionized water, 170 370 parts of pure-acrylic emulsion, 16 20 parts of 1 10 parts of 5 10 parts of 20 50 parts of 600 800 parts of natural colour sand, coalescents, thickener, antifoaming agent, the Ludox of 10 100 mesh, nano silicon dioxide and nano zine oxide.Nano modification lacquer proposed by the invention improves the anti-whiting of coating, jaundice performance, improves the hardness and adhesive force of coating, meanwhile, lacquer difficulty of construction is reduced, improves coating service life.

Description

Nano modification lacquer
Technical field
The present invention relates to building coatings, are specifically nano modification lacquer, are particularly suitable for the application of building inner-outer wall.
Background technology
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using a variety of colors Powder is formulated, applied to the imitative stone effect of external wall, therefore also known as liquid stone.Building after lacquer finishing, tool There is natural real natural colour, give graceful, harmonious, serious aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings. Particularly decorated on curved-surface building object, it is vivid, there is a kind of effect of back to nature.
Compared to traditional architecture coating, lacquer has the characteristics that fire prevention, acid and alkali-resistance, nontoxic, tasteless, can effectively stop Extraneous adverse circumstances corrode building, extend the service life of building;Because such effect, lacquer receives perhaps in recent years The favor of more people.
The quality of existing lacquer is irregular, due to using substantial amounts of solids skeleton such as marble, granite so that Lacquer energy of attachment force difference often has husky phenomenon to occur, be difficult to construct;Lacquer is more demanding to construction environment(20 DEG C with On), delay the duration;Be often accompanied by whitening flavescence, figure layer the problem of feeling like jelly when simultaneously also.
The content of the invention
It is an object of the invention to provide nano modification lacquer, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical solution:
Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 170-370 parts of pure-acrylic emulsion, 10-100 mesh 600-800 parts of natural colour sand, 20-50 parts of coalescents, 5-10 parts of thickener, 1-10 parts of antifoaming agent, 16-20 parts of Ludox, 10-30 parts of the mixture of nano silicon dioxide and nano zine oxide.
Using above-mentioned technical proposal, the lacquer strong adhesive force of formation is matched, can be carried out in 11 DEG C of outdoor temperature or more Construction, while hydrophobic performance is good, ageing-resistant.
The present invention is further improved, and the antifoaming agent uses the mass ratio of NXZ antifoaming agent, antifoaming agent and deionized water For 6-8:100, lacquer bubble-free at this time, no shrinkage cavity is without tangerine peel, and when smearing construction, coating surface is substantially pin-free, it is beautiful and Anti-pollution.
The present invention is further improved, and the natural colour sand by mass percentage, forms and is:10-20 mesh 10%, 20-40 mesh 30%, 40-80 mesh 50%, 80-100 mesh 10%;Coating surface decorative layer is fine and close at this time, and effect is well arranged, and tensile bond strength For 0.96MPa, much larger than the requirement of standard 0.7MPa.
The present invention is further improved, and the Ludox uses model JN-30,18-20 part;It can be formed during film forming firm Si-O keys can improve anti-whiting performance, hardness, adhesive force of paint film etc..
The present invention is further improved, and further includes 2-6 parts of dispersant, is reduced lotion flocculation, is reduced difficulty of construction.
The present invention is further improved, and the mixture of nano silicon dioxide and nano zine oxide takes 30 parts, wherein nano-silica The mass ratio of SiClx and nano zine oxide is 1:1;To long wave blackspot effect rate of ultraviolet shield 88%, to medium wave erythemal effect Rate of ultraviolet shield 85% to the ultraviolet light shortwave shielding rate 70%-80% that sterilizes, improves coating anti-ultraviolet aging and resistant to thermal aging Performance.
Nano modification lacquer proposed by the invention improves the anti-whiting of coating, jaundice performance, improves the hard of coating Degree and adhesive force, meanwhile, lacquer difficulty of construction is reduced, improves coating service life.
Specific embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel all other embodiments obtained without making creative work belong to the model that the present invention protects It encloses.
Embodiment 1:Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 170 parts of pure-acrylic emulsion, 16 parts of 1 part of 5 parts of 20 parts of 800 parts of natural colour sand, coalescents, thickener, antifoaming agent, Ludox, the nano-silica of 10-100 mesh 10 parts of the mixture of SiClx and nano zine oxide.
Embodiment 2:Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 370 parts of pure-acrylic emulsion, 16 parts of 1 part of 5 parts of 20 parts of 600 parts of natural colour sand, coalescents, thickener, antifoaming agent, Ludox, the nano-silica of 10-100 mesh 10 parts of the mixture of SiClx and nano zine oxide.
Embodiment 3:Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 270 parts of pure-acrylic emulsion, 16 parts of 1 part of 5 parts of 20 parts of 700 parts of natural colour sand, coalescents, thickener, antifoaming agent, Ludox, the nano-silica of 10-100 mesh 10 parts of the mixture of SiClx and nano zine oxide.
Embodiment 4:Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 170 parts of pure-acrylic emulsion, 16 parts of 6 parts of 5 parts of 20 parts of 600 parts of natural colour sand, coalescents, thickener, antifoaming agent, Ludox, the nano-silica of 10-100 mesh 10 parts of the mixture of SiClx and nano zine oxide.
Embodiment 5:Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 370 parts of pure-acrylic emulsion, 16 parts of 8 parts of 5 parts of 20 parts of 800 parts of natural colour sand, coalescents, thickener, antifoaming agent, Ludox, the nano-silica of 10-100 mesh 10 parts of the mixture of SiClx and nano zine oxide.
Embodiment 6:Nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 370 parts of pure-acrylic emulsion, 16 parts of 8 parts of 5 parts of 20 parts of 800 parts of natural colour sand, coalescents, thickener, antifoaming agent, Ludox, the nano-silica of 10-100 mesh 6 parts of 10 parts of mixture, the dispersant of SiClx and nano zine oxide.
Preparation process is:It has weighed the raw material needed for embodiment 1-6 respectively in advance, quantitative disengaging is poured into container Water under high speed dispersor 300-400rpm stirrings, is slowly added into the antifoaming agent of 1/2 amount, add rear rotating speed improve to 1000rpm is stirred 8-10 minutes, and then rotating speed is down to 600rpm, average rate addition natural colour sand, and raises speed to 1200rpm, high speed It is 5 minutes scattered, it then adds in coalescents and is stirred for 5 minutes;Rotating speed is adjusted to 500rpm, slowly sequentially add pure-acrylic emulsion, The mixture of nano silicon dioxide and nano zine oxide, coalescents, antifoaming agent, Ludox(Dispersant), in 600- after adding 800rpm is stirred 10 minutes, sequentially adds antifoaming agent, the thickener of 1/2 amount, is continued to stir 10 minutes in 600-800rpm, be gone out Material.
The 6 parts of lacquer samples prepared using above-mentioned technique, state in a reservoir are:Without caking after stirring, it is in Uniform state, after one month without lump, go mouldy, agglomerate and composition variation situation, spray no difficulty.
When the superficial drying time is 2.5 small, and when the sagging blow-through 24 of wind speed of 10m/s is small, flawless;Respectively in clear water And impregnated 7 days in the environment of buck, coating is without playing drum, cracking and flaking off, with not impregnating part comparison, no color change.
The present invention is further improved, and the antifoaming agent uses the mass ratio of NXZ antifoaming agent, antifoaming agent and deionized water For 6-8:100, lacquer bubble-free at this time, no shrinkage cavity is without tangerine peel, and when smearing construction, coating surface is substantially pin-free, it is beautiful and Anti-pollution.
The present invention is further improved, and the natural colour sand by mass percentage, forms and is:10-20 mesh 10%, 20-40 mesh 30%, 40-80 mesh 50%, 80-100 mesh 10%;Coating surface decorative layer is fine and close at this time, and effect is well arranged, and tensile bond strength For 0.96MPa, much larger than the requirement of standard 0.7MPa.
The present invention is further improved, and the Ludox uses model JN-30,18-20 part;It can be formed during film forming firm Si-O keys can improve anti-whiting performance, hardness, adhesive force of paint film etc..
The present invention is further improved, and further includes 2-6 parts of dispersant, is reduced lotion flocculation, is reduced difficulty of construction.
The present invention is further improved, and the mixture of nano silicon dioxide and nano zine oxide takes 30 parts, wherein nano-silica The mass ratio of SiClx and nano zine oxide is 1:1;To long wave blackspot effect rate of ultraviolet shield 88%, to medium wave erythemal effect Rate of ultraviolet shield 85% to the ultraviolet light shortwave shielding rate 70%-80% that sterilizes, improves coating anti-ultraviolet aging and resistant to thermal aging Performance.
Nano modification lacquer proposed by the invention improves the anti-whiting of coating, jaundice performance, improves the hard of coating Degree and adhesive force, meanwhile, lacquer difficulty of construction is reduced, improves coating service life.
The above is only the specific embodiment of the present invention, is made skilled artisans appreciate that or realizing this hair It is bright.A variety of modifications of these embodiments will be apparent to one skilled in the art, it is as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention The embodiments shown herein is not intended to be limited to, and is to fit to and the principles and novel features disclosed herein phase one The most wide scope caused.

Claims (6)

1. nano modification lacquer, by proportion by weight, including 100 parts of deionized water, 170-370 parts of pure-acrylic emulsion, 10-100 600-800 parts of purpose natural colour sand, 20-50 parts of coalescents, 5-10 parts of thickener, 1-10 parts of antifoaming agent, Ludox 16-20 10-30 parts of the mixture of part, nano silicon dioxide and nano zine oxide.
2. nano modification lacquer according to claim 1, it is characterised in that:The antifoaming agent uses NXZ antifoaming agent, The mass ratio of antifoaming agent and deionized water is 6-8:100.
3. nano modification lacquer according to claim 1, it is characterised in that:The natural colour sand presses quality percentage Than forming and being:10-20 mesh 10%, 20-40 mesh 30%, 40-80 mesh 50%, 80-100 mesh 10%.
4. nano modification lacquer according to claim 1, it is characterised in that:The Ludox uses model JN-30, 18-20 parts.
5. nano modification lacquer according to claim 1, it is characterised in that:Further include 2-6 parts of dispersant.
6. nano modification lacquer according to claim 1, it is characterised in that:Nano silicon dioxide and nano zine oxide Mixture takes 30 parts, and the wherein mass ratio of nano silicon dioxide and nano zine oxide is 1:1.
CN201711305282.6A 2017-12-11 2017-12-11 Nano modification lacquer Pending CN108059389A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711305282.6A CN108059389A (en) 2017-12-11 2017-12-11 Nano modification lacquer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711305282.6A CN108059389A (en) 2017-12-11 2017-12-11 Nano modification lacquer

Publications (1)

Publication Number Publication Date
CN108059389A true CN108059389A (en) 2018-05-22

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CN201711305282.6A Pending CN108059389A (en) 2017-12-11 2017-12-11 Nano modification lacquer

Country Status (1)

Country Link
CN (1) CN108059389A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115612319A (en) * 2022-09-08 2023-01-17 河南美饰龙新材料有限公司 Environment-friendly super-weather-resistant self-cleaning contamination-resistant silica paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101117480A (en) * 2006-08-01 2008-02-06 天津市振东涂料有限公司 Manufacture and construction method for nano paint
CN104609772A (en) * 2014-12-26 2015-05-13 三棵树涂料股份有限公司 Really stone paint and preparation method thereof
CN106348648A (en) * 2016-08-25 2017-01-25 阜阳富瑞雪化工科技有限公司 High-adhesion long-service-life natural stone paint
CN107200506A (en) * 2017-06-01 2017-09-26 信阳天意节能技术股份有限公司 A kind of true mineral varnish and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101117480A (en) * 2006-08-01 2008-02-06 天津市振东涂料有限公司 Manufacture and construction method for nano paint
CN104609772A (en) * 2014-12-26 2015-05-13 三棵树涂料股份有限公司 Really stone paint and preparation method thereof
CN106348648A (en) * 2016-08-25 2017-01-25 阜阳富瑞雪化工科技有限公司 High-adhesion long-service-life natural stone paint
CN107200506A (en) * 2017-06-01 2017-09-26 信阳天意节能技术股份有限公司 A kind of true mineral varnish and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115612319A (en) * 2022-09-08 2023-01-17 河南美饰龙新材料有限公司 Environment-friendly super-weather-resistant self-cleaning contamination-resistant silica paint and preparation method thereof

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CB02 Change of applicant information

Address after: 215500 1 1 Jianye Road, Yushan high tech Industrial Park, Changshou City, Suzhou, Jiangsu

Applicant after: XINHUASHENG ENERGY SAVING TECHNOLOGY CO., LTD.

Address before: 215500 Chang Hu Road, Changshou City, Suzhou, Jiangsu Province, No. 2666

Applicant before: XINHUASHENG ENERGY SAVING TECHNOLOGY CO., LTD.

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RJ01 Rejection of invention patent application after publication

Application publication date: 20180522

RJ01 Rejection of invention patent application after publication