CN108054273A - A kind of field effect transistor tubular type Magnetic Sensor, its preparation method and application method - Google Patents

A kind of field effect transistor tubular type Magnetic Sensor, its preparation method and application method Download PDF

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Publication number
CN108054273A
CN108054273A CN201711456098.1A CN201711456098A CN108054273A CN 108054273 A CN108054273 A CN 108054273A CN 201711456098 A CN201711456098 A CN 201711456098A CN 108054273 A CN108054273 A CN 108054273A
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effect transistor
magnetic sensor
field
tubular type
semiconductor
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CN108054273B (en
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巫远招
刘宜伟
李润伟
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Ningbo Institute of Material Technology and Engineering of CAS
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • H10N35/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • H10N35/80Constructional details

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Hall/Mr Elements (AREA)
  • Measuring Magnetic Variables (AREA)
  • Investigating Or Analyzing Materials By The Use Of Magnetic Means (AREA)

Abstract

The present invention provides a kind of field effect transistor tubular type Magnetic Sensors, have field-effect transistor structure, including semiconductor base, source electrode, drain electrode and grid;Wherein, semiconductor base is made of basal layer and the semiconductor layer positioned at the substrate surface, and is electrically insulated between basal layer and semiconductor layer, and basal layer has magnetostrictive effect, and semiconductor layer has piezoelectric effect;During working condition, the electric signal of field-effect transistor changes when external magnetic field acts on basal layer, and the detection in magnetic field is realized by testing the electric signal.The magnetic sensor arrangement is simple, and due to the signal amplification for combining field-effect transistor, can realize highly sensitive detection of magnetic field.

Description

A kind of field effect transistor tubular type Magnetic Sensor, its preparation method and application method
Technical field
The present invention relates to detection of magnetic field technologies, and in particular to a kind of field effect transistor tubular type Magnetic Sensor, its preparation method With application method.
Background technology
Magnetic Sensor is an important component in sensor, be magnetics signal be for conversion into electric signal etc. other The sensor of the information output of required form.By the development in a nearly century, Magnetic Sensor is in each of human society life Aspect, which plays, increasingly carrys out important role, and the annual whole world has billions of Magnetic Sensors to come into operation.With Magnetic Sensor becomes better and approaching perfection day by day, and all trades and professions propose it increasingly higher demands, especially requires its detection accuracy more next It is higher, while require it more and more wider using range, application field is further widened, to meet the needs of practical application.Therefore, With high detection accuracy simultaneously with it is wide the use of range is one of new developing direction of Magnetic Sensor, also increasingly receive The extensive concern of researcher.
At present, relatively conventional Magnetic Sensor mainly has following a few classes:Hall (Hall) sensor, fluxgate and electric current sense Answer Magnetic Sensor, magnetoelectricity resistance type sensor etc..From the point of view of current present Research, the detection accuracy and amount of Magnetic Sensor at room temperature Journey is typically to attend to one thing and lose sight of another.Therefore, prepare and meet the magnetic field sensor that high detection accuracy can realize wide detection range again It is still a major challenge, it is one of direction made great efforts at present to seek new Magnetic Sensor.
The content of the invention
For the above-mentioned state of the art, the present invention provides a kind of Magnetic Sensor, has field-effect transistor structure, including partly leading The body substrate and source electrode being electrically connected with semiconductor base, drain electrode and grid;Wherein, semiconductor base is by basal layer and position It forms in the semiconductor layer of the substrate surface, and is electrically insulated between basal layer and semiconductor layer, basal layer is stretched with mangneto Contracting effect, semiconductor layer have piezoelectric effect.
During working condition, external magnetic field acts on basal layer, and due to magnetostriction materials, there is magnetoelectricities with piezoelectric material Coupling effect, magnetostriction materials generate stress or strain transfer to semiconductor layer, and the piezoelectric material of semiconductor layer is due to piezoelectricity Effect and generate charge, so as to change the concentration of carrier in fieldistor channel, cause the electricity of field-effect transistor Signal changes, and the detection of the external magnetic field is realized by testing the electric signal.
The semiconductor base is the semiconductor base in field-effect transistor.
The basal layer has magnetostrictive effect, i.e. base layer material is magnetostriction materials, and species is unlimited;Make To be preferred, the base layer material has big magnetostriction coefficient, to improve detectivity;As further preferred, The base layer material, which uses, has high saturation field, the magnetostriction materials of big magnetostriction coefficient and forced magnetostriction system The big amorphous soft magnetic material of number is compound, to realize the detection of magnetic field of wide-range simultaneously.Described there is high saturation field, big mangneto to stretch The magnetostriction materials of contracting coefficient include but unlimited iron gallium (FeGa) or terbium dysprosium ferrum (TeDyFe) etc.;The pressure mangneto is stretched The big amorphous soft magnetic material of contracting coefficient includes but not limited to iron silicon boron (FeSiB) or ferro-cobalt silicon (CoFeSi) etc..
It is flexible magnetostriction materials as further preferred, described base layer material, such as flexible nickel foil etc., it is described Semiconductor layer be the film layer of the low thickness on the flexibility magnetostriction materials, the source electrode, drain electrode and grid are low The thin-film material of thickness, thus base layer material such as can be stretched, reversed, folded at the deformations, so as to meet it is flexible should With the needs in field, such as applied to wearable device etc..
The semiconductor layer has piezoelectric effect, i.e. and the semi-conducting material is piezoelectric material, and species is unlimited, Including zinc oxide, gallium nitride etc..
It is electrically insulated between the basal layer and semiconductor layer, as a kind of realization method, in basal layer and semiconductor layer Between insulating layer, such as aluminum oxide film layer etc. are set.
The source electrode is the source electrode in field-effect transistor, and material is unlimited, including metal material etc.;As excellent Choosing, the source electrode is using golden (Au) thin-film material or titanium (Ti) thin-film material.
The drain electrode is the drain electrode in field-effect transistor, and material is unlimited, including metal material etc.;As excellent Choosing, the drain electrode is using golden (Au) thin-film material or titanium (Ti) thin-film material.
The electric signal of the field-effect transistor includes but not limited to the source and drain electrode current of field-effect transistor, raceway groove electricity Transport factor etc..
The present invention also provides a kind of methods for preparing above-mentioned field effect transistor tubular type Magnetic Sensor, include the following steps:
(1) preparation of the semiconductor base of field-effect transistor
On the base layer using the method growth semi-conducting material of magnetron sputtering;
(2) prepared by the source electrode of field-effect transistor
Source electrode is prepared by micro fabrication on a semiconductor substrate, preferably, preparing source using ultraviolet photolithographic method Then pole figure case prepares source electrode using magnetically controlled sputter method in the source electrode patterned surfaces;As further preferred, prepare source electrode it Short annealing heat treatment is carried out afterwards, and Ohmic contact is formed to further ensure that;
(3) prepared by the drain electrode of field-effect transistor
It is prepared and drained by micro fabrication on a semiconductor substrate, leaked preferably, being prepared using ultraviolet photolithographic method Then pole figure case is prepared on the drain pattern surface using magnetically controlled sputter method and drained;As further preferred, drain electrode is prepared Short annealing heat treatment is carried out afterwards, and Ohmic contact is formed to further ensure that;
(4) prepared by the grid of field-effect transistor
Grid is prepared by micro fabrication on a semiconductor substrate, preferably, preparing grid using ultraviolet photolithographic method Then pole figure case grows grid material using pulse laser, chemical spin coating or magnetically controlled sputter method;As further preferred, It prepares grid and carries out short annealing heat treatment afterwards, Schottky contacts are formed to further ensure that;
The application method of the field effect transistor tubular type Magnetic Sensor of the present invention includes the following steps:
(1) fixed externally-applied magnetic field is applied to the basal layer of Magnetic Sensor, tests field-effect transistor in the Magnetic Sensor Electric signal under certain testing situations, such as output characteristic curve, transfer characteristic curve etc. change the size of externally-applied magnetic field, Obtain a series of reference electrical signals under a certain fixed externally-applied magnetic field;
(2) keep identical with the test condition in step (1), test the actual electricity of field-effect transistor in the Magnetic Sensor Signal the actual electric signal is compared with the reference electrical signal obtained in step (1), same reference electrical signal institute The magnetic field value that corresponding externally-applied magnetic field as actually measures.
In conclusion the present invention forms a kind of new Magnetic Sensor using field-effect transistor structure, pass through transistor Semiconductor base is designed as the basal layer that the semiconductor layer being made of piezoelectric material and magnetostriction materials form by structure design Composition, external magnetic field acts on basal layer during working condition, and due to magnetostrictive effect, it generates mechanical movement and acts on half Conductor layer so that the carrier concentration in fieldistor channel changes under the effect of piezoelectricity effectiveness, causes field effect transistor The electric signal parameter of pipe changes, and the detection in magnetic field is realized by testing the electric signal.In addition, the Magnetic Sensor combines field-effect The signal amplification of transistor realizes highly sensitive detection of magnetic field, especially when using with high saturation field, big mangneto The material of coefficient of dilatation and the big amorphous soft magnetic material of forced magnetostriction coefficient it is compound as base layer material when, can be made Not only there is high detection accuracy, and can realize the wide magnetic field sensor for detecting range, detectable external magnetic field scope from Tesla (nT) is received to tesla (T) magnitude, is had a good application prospect in magnetic sensor technologies field.Also, work as base Primer is flexible magnetostriction materials, and semiconductor layer is the film layer of the low thickness on the flexibility magnetostriction materials, source When pole, drain electrode and grid are the thin-film material of low thickness, the deformations such as which can be stretched, reversed, folded, So as to meeting the needs in flexible application field, such as applied to wearable device etc..
Description of the drawings
Fig. 1 is the structure diagram of flexible Magnetic Sensor in the embodiment of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawings with embodiment, the present invention is furture elucidated.It is to be understood that these embodiments are merely to illustrate this hair It is bright rather than limit the scope of the invention.
Reference numeral in Fig. 1 is:Source electrode 1, grid 2, drain electrode 3, semiconductor layer 4, basal layer 5.
Embodiment 1:
In the present embodiment, the structure of Magnetic Sensor is as shown in Figure 1.The Magnetic Sensor has field-effect transistor structure, by Semiconductor base, source electrode 1, drain electrode 3 and grid 2 are formed.Source electrode 1, drain electrode 3 are located at grid 2 on semiconductor base;Wherein, Semiconductor base is made of the basal layer 5 to insulate with the semiconductor layer 4 on basal layer 5, and basal layer 5 is stretched with mangneto Contracting effect, semiconductor layer 4 have piezoelectric effect.
Basal layer 5 is the aluminum oxide film structure that the flexible nickel foil that thickness is 5 μm~50 μm is 10nm~1000nm with thickness Into aluminum oxide film is for the nickel foil that insulate.Semiconductor layer 4 is the zinc-oxide film that thickness is 10nm~500nm nanometers.Source electrode 1 be thickness be 2nm~100nm gold thin film, drain electrode 3 be titanium film that thickness is 2nm~100nm, grid 4 is that thickness is 2nm The gold thin film of~100nm.
The preparation method of above-mentioned Magnetic Sensor includes the following steps:
(1) preparation of flexible base layer
Using atomic layer deposition or magnetically controlled sputter method 5 μm~50 μm flexible nickel foil surface growth 10nm~ 1000nm aluminum oxide films.
(2) preparation of semiconductor layer
10nm~500nm zinc-oxide films are grown on above-mentioned flexible base layer table surface using the method for magnetron sputtering.
(3) prepared by the source electrode of field-effect transistor
After step (1) and (2), semiconductor base is obtained, is prepared on the semiconductor base using ultraviolet photolithographic method Length is 5 μm~500 μm, and width is 5 μm~500 μm of rectangle pattern, then using magnetically controlled sputter method in the rectangle Golden (Au) films of patterned surfaces growth 2nm~100nm, the heat treatment of short annealing afterwards form Ohmic contact.
(4) prepared by the drain electrode of field-effect transistor
Ultraviolet photolithographic method is used to prepare length as 5 μm~500 μm on a semiconductor substrate, width is 5 μm~500 μm Then rectangle pattern grows 2nm~100nm titaniums (Ti) film using magnetically controlled sputter method in the rectangle patterned surfaces, it Short annealing is heat-treated afterwards, forms Ohmic contact.
(5) prepared by the grid of field-effect transistor
Ultraviolet photolithographic method is used to prepare length as 5 μm~50 μm on a semiconductor substrate, width is 5 μm~50 μm of length Square-shaped gate pattern, then using golden (Au) films of magnetically controlled sputter method 2nm~100nm, the heat treatment of short annealing afterwards is formed Schottky contacts.
The Magnetic Sensor is tested as follows:
(1) when not applying externally-applied magnetic field, which is tested using semiconductor parameter instrument under certain testing situations and is passed The output characteristic curve of field-effect transistor in sensor;
(2) fixed externally-applied magnetic field is applied to the basal layer of the semiconductor magnetic sensor, using identical with step (1) Semiconductor parameter instrument, and field-effect crystalline substance in the semiconductor magnetic sensor is tested under the test condition identical with step (1) The reference output characteristic curve of body pipe;It was found that when applying externally-applied magnetic field, the output of the field-effect transistor of the Magnetic Sensor is special Linearity curve changes;
Change the size of externally-applied magnetic field, obtain a series of reference output characteristic curves under a certain fixed externally-applied magnetic field.
In practical applications, the reality output characteristic curve of the field-effect transistor in the semiconductor magnetic sensor is tested, Specific test condition is identical with the test condition described in step (1), obtains actual output characteristic curve;By the defeated of the reality Go out characteristic curve and compare with the output characteristic curve obtained in step (2), corresponding to same output characteristic curve The magnetic field value that externally-applied magnetic field as actually measures.
Embodiment 2:
In the present embodiment, the structure and the structure of the Magnetic Sensor in embodiment 1 of Magnetic Sensor are essentially identical, different It is:Source electrode 1 be thickness be 2nm~100nm titanium film, drain electrode 3 be gold thin film that thickness is 2nm~100nm, basal layer 5 is Thickness is the magnetostriction materials FeSiB films of 2nm~500nm, and semiconductor layer 4 is the gallium nitride that thickness is 2nm~500nm (GaN) film.
The preparation method of the Magnetic Sensor and the preparation method in embodiment 1 are essentially identical, except that:Step (3) In, use magnetically controlled sputter method on the rectangle source electrode pattern growth thickness for 2~100nm titanium film;In step (4), Use magnetically controlled sputter method in the rectangle drain pattern growth thickness for 2~100nm gold thin film;In step (2), use Magnetically controlled sputter method prepares gallium nitride (GaN) film that thickness is 2~500nm in substrate surface.
The semiconductor magnetic sensor is tested as follows:
(1) when not applying externally-applied magnetic field, which is tested using semiconductor parameter instrument under certain testing situations and is passed The transfer characteristic curve of field-effect transistor in sensor;
(2) fixed externally-applied magnetic field is applied to the basal layer of the semiconductor magnetic sensor, using identical with step (1) Semiconductor parameter instrument, and field-effect crystalline substance in the semiconductor magnetic sensor is tested under the test condition identical with step (1) Reference transfer characteristic curve of body pipe etc.;It was found that when applying externally-applied magnetic field, the transfer of the field-effect transistor of the Magnetic Sensor Characteristic curve changes;
Change the size of externally-applied magnetic field, obtain a series of reference transfer characteristic curves under a certain fixed externally-applied magnetic field.
In practical applications, the actual transfer characteristic curve of the field-effect transistor in the semiconductor magnetic sensor is tested, Specific test condition is identical with the test condition described in step (1), obtains actual transfer characteristic curve;By turning for the reality It moves characteristic curve to compare with the transfer characteristic curve obtained in step (2), corresponding to same transfer characteristic curve The magnetic field value that externally-applied magnetic field as actually measures.
Technical scheme and advantageous effect is described in detail in embodiment described above, it should be understood that The foregoing is merely specific embodiments of the present invention, are not intended to limit the invention, all to be done in the spirit of the present invention Any modification and improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of field effect transistor tubular type Magnetic Sensor, it is characterized in that:It is including semiconductor base and mutually electric with semiconductor base Source electrode, drain electrode and the grid of connection;Wherein, semiconductor base is by basal layer and the semiconductor layer group positioned at the substrate surface Into, and be electrically insulated between basal layer and semiconductor layer, basal layer has magnetostrictive effect, and semiconductor layer is imitated with piezoelectricity It should;
During working condition, external magnetic field acts on basal layer, and the electric signal of field-effect transistor changes, by testing the electricity Signal realizes the detection in magnetic field.
2. field effect transistor tubular type Magnetic Sensor as described in claim 1, it is characterized in that:The base layer material is One or more kinds of composite materials in FeGa, TeDyFe, iron silicon boron FeSiB, CoFeSi.
3. field effect transistor tubular type Magnetic Sensor as described in claim 1, it is characterized in that:The semiconductor layer material is oxygen Change zinc, lead zirconate titanate or polyvinylidene fluoride.
4. field effect transistor tubular type Magnetic Sensor as described in claim 1, it is characterized in that:The source electrode is in aluminium, gold, titanium One or several kinds;
Preferably, the drain electrode is the one or several kinds in aluminium, gold, titanium;
Preferably, the grid is the one or several kinds in aluminium, gold, titanium.
5. field effect transistor tubular type Magnetic Sensor as described in claim 1, it is characterized in that:The semiconductor base is micro-nano Size;
Preferably, the thickness of the semiconductor base is 1 micron~50 microns.
6. field effect transistor tubular type Magnetic Sensor as claimed in claim 5, it is characterized in that:Source electrode, drain electrode and the grid It is micro-or nano size;
Preferably, the length and width of the source electrode, drain electrode and grid is 1 micron~200 microns, thickness is nanoscale.
7. field effect transistor tubular type Magnetic Sensor as described in claim 1, it is characterized in that:The base layer material is flexibility Magnetostriction materials.
8. field effect transistor tubular type Magnetic Sensor as described in claim 1, it is characterized in that:The electric signal includes source-drain electrode Electric current and/or channel electron mobility.
9. the preparation method of the field effect transistor tubular type Magnetic Sensor as described in any claim in claim 1 to 8, special Sign is:Include the following steps:
On the base layer using the method growth semi-conducting material of magnetron sputtering;
Source electrode pattern is prepared using ultraviolet photolithographic method on a semiconductor substrate, then using magnetically controlled sputter method in the source electrode figure Case surface prepares source electrode;Preferably, short annealing heat treatment is carried out after preparing source electrode;
Drain pattern is prepared using ultraviolet photolithographic method on a semiconductor substrate, then using magnetically controlled sputter method in the drain electrode figure Case surface prepares drain electrode;Preferably, carry out short annealing heat treatment after preparing drain electrode;
Gate pattern is prepared using ultraviolet photolithographic method on a semiconductor substrate, then using pulse laser method, chemical spin coating Method or magnetically controlled sputter method prepare grid;Preferably, short annealing heat treatment is carried out after preparing grid.
10. the application method of the field effect transistor tubular type Magnetic Sensor as described in any claim in claim 1 to 8, It is characterized in:Include the following steps:
(1) fixed externally-applied magnetic field is applied to the basal layer of Magnetic Sensor, tests in the Magnetic Sensor field-effect transistor one Determine the electric signal under test condition, change the size of externally-applied magnetic field, obtain a series of references under a certain fixed externally-applied magnetic field Electric signal;
(2) keep identical with the test condition in step (1), test the actual telecommunications of field-effect transistor in the Magnetic Sensor Number, which is compared with the reference electrical signal obtained in step (1), same reference electrical signal institute is right The magnetic field value that the externally-applied magnetic field answered as actually measures.
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CN109920844A (en) * 2019-03-26 2019-06-21 电子科技大学 A kind of insulated-gate type piezoelectricity field effect transistor
CN110729396A (en) * 2019-09-25 2020-01-24 郑州轻工业学院 Magnetoelectric film sensor with self-amplification capability

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