CN108054259A - A kind of LED chip and preparation method thereof - Google Patents

A kind of LED chip and preparation method thereof Download PDF

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Publication number
CN108054259A
CN108054259A CN201711331483.3A CN201711331483A CN108054259A CN 108054259 A CN108054259 A CN 108054259A CN 201711331483 A CN201711331483 A CN 201711331483A CN 108054259 A CN108054259 A CN 108054259A
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CN
China
Prior art keywords
substrate
led chip
micro
layer
semiconductor layer
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Withdrawn
Application number
CN201711331483.3A
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Chinese (zh)
Inventor
祁月红
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Suzhou Jilin Electronic Technology Co Ltd
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Suzhou Jilin Electronic Technology Co Ltd
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Priority to CN201711331483.3A priority Critical patent/CN108054259A/en
Publication of CN108054259A publication Critical patent/CN108054259A/en
Withdrawn legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/10Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a light reflecting structure, e.g. semiconductor Bragg reflector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0062Processes for devices with an active region comprising only III-V compounds
    • H01L33/0066Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
    • H01L33/007Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound comprising nitride compounds

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Non-Portable Lighting Devices Or Systems Thereof (AREA)

Abstract

Present invention is disclosed a kind of LED chips and preparation method thereof, wherein, the LED chip includes the first substrate and the second substrate and epitaxial layer that are sequentially formed on the first substrate, epitaxial layer includes the first semiconductor layer, luminescent layer and the second semiconductor layer that are sequentially formed on substrate, first substrate and the second substrate are made by transparent material, the one side surface indentation of first substrate and the second substrate attaching is formed with multiple micro-nano structures, and the thickness of the first substrate is more than the thickness of the second substrate.These concave micro-nano structures can reflect the light incided into substrate, return it to the light direction of needs, improve light extraction efficiency, and its manufacture craft is simple, can effectively control the cost of manufacture of LED chip.

Description

A kind of LED chip and preparation method thereof
Technical field
The invention belongs to LED field of luminescent technology, and in particular to a kind of LED chip and preparation method thereof.
Background technology
Conventional incandescent energy consumption is high, short life, in today that global resources are in short supply, forbids giving birth to by national governments gradually Production, substitute products are electronic energy-saving lamps therewith, although electronic energy-saving lamp improves energy-saving effect, but due to the use of many pollutions The heavy metal element of environment, and run counter to the main trend of environmental protection.With LED technology high speed development LED illumination gradually into For the only choosing of novel green illumination.LED principle of luminosity, energy-saving and environmental protection level on all be far superior to traditional lighting production Product.
It is its luminous efficiency to restrict one of bottleneck that LED further develops at present, theoretically uses blue LED excited yellow The luminous efficiency that fluorescent powder obtains white light is that every watt of 300 multithread are bright, but in actual application, the luminous effect of LED chip reality Rate probably only 150 lumens or so, a key factor for restricting LED chip luminous efficiency be exactly from the light that active region is sent without Method escapes inside LED chip.In the prior art, in order to improve the light extraction efficiency of LED chip, usually in the lower section of substrate Reflectance coating or speculum are set or the catoptric arrangement being made of cavity is formed in substrate using the method for laser ablation, In first method, light is needed before by reflectance coating or speculum reflection by multiple contact interfaces, this can cause the pole of light Lossy;And the fabrication process condition of second method is complicated, and the manufacture cost of LED chip can be caused to greatly increase.
The content of the invention
One embodiment of the application provides a kind of LED chip, can improve the light extraction efficiency of LED chip, and manufacture craft Simply, which includes:
First substrate and the second substrate and epitaxial layer being sequentially formed on first substrate, the epitaxial layer include The first semiconductor layer, luminescent layer and the second semiconductor layer being sequentially formed on the substrate, first substrate and the second lining Bottom is made by transparent material, and the one side surface indentation of first substrate and second substrate attaching is formed with multiple micro-nano knots Structure, the thickness of first substrate are more than the thickness of second substrate.
In one embodiment, the micro-nano structure is round bottom shape or back taper.
In one embodiment, first substrate and the second substrate are made by identical material.
In one embodiment, first substrate and the second substrate are connected by Direct Bonding technique.
In one embodiment, the thickness ratio of first substrate and the second substrate is 10:1~8:1.
One embodiment of the application also provides a kind of production method of LED chip, and this method includes:
S1, multiple concave micro-nano structures are formed by etching in a side surface of the first substrate;
S2, the second substrate is connected to a side surface of first substrate with micro-nano structure;
S3, make the first semiconductor layer successively in a side surface of second substrate away from first substrate, shine LED chip is made in layer and the second semiconductor layer.
In one embodiment, step S1 is specifically included, and is protected in the edge of one side surface of the first substrate, and not by The surface of first substrate of protection forms multiple concave micro-nano structures by etching.
In one embodiment, the method is additionally included in form the micro-nano structure after remove one side surface of the first substrate Protection, and by the second substrate by way of Direct Bonding be not etched region on a side surface of first substrate Connection.
Compared with prior art, the technical solution of the application has the advantages that:
By the side surface for setting the first substrate and the second substrate that are connected to each other, the first substrate and the second substrate attaching Recess is formed with multiple micro-nano structures, and the thickness of first substrate is more than the thickness of second substrate, these are concave micro- Micro-nano structure can reflect the light incided into substrate, return it to the light direction of needs, improve light extraction efficiency, system Make simple for process, can effectively control the cost of manufacture of LED chip.
Description of the drawings
Fig. 1 is the structure diagram of LED chip in one embodiment of the application;
Fig. 2 is the structure diagram of LED chip in the another embodiment of the application.
Specific embodiment
The application is described in detail below with reference to specific embodiment shown in the drawings.But these embodiments are simultaneously The application is not limited, structure that those of ordinary skill in the art are made according to these embodiments, method or functionally Conversion is all contained in the protection domain of the application.
Join Fig. 1, introduce the LED chip 100 of one specific embodiment of the application.In the present embodiment, the LED chip 100 include the first substrate 11, the second substrate 12 and epitaxial layer 20.
In the present embodiment, the first substrate 11 and the second substrate 12 are made by transparent material.Epitaxial layer 20 is included successively The first semiconductor layer 21,22 and second semiconductor layer 23 of luminescent layer being formed on the second substrate 12.In one embodiment, the first half Conductor layer 21 is gallium nitride layer, including nitride buffer layer 211, the undoped gallium nitride layer being sequentially formed on substrate 10 212 and doping type gallium nitride layer 213, luminescent layer 22 is multiple quantum well layer, and the second semiconductor layer 23 is doping type gallium nitride layer. Wherein, when the doped gallium nitride layer 213 in the first semiconductor layer 21 is n-type doping, nitridation is adulterated in the second semiconductor layer 23 Gallium layer adulterates for p-type;Conversely, when the doped gallium nitride layer 213 in the first semiconductor layer 21 is adulterated for p-type, the second semiconductor Doped gallium nitride layer is n-type doping in layer 23.
First substrate 11 and the one side surface indentation of the second substrate 12 fitting are formed with multiple micro-nano structures 111, and first The thickness of substrate 11 is more than the thickness of the second substrate 12.These micro-nano structures 111 can reflect the light being incident in substrate Light direction is returned back out, also, due to the thinner thickness of opposite first substrate 11 of the thickness of the second substrate 12, without going past mistake Long reflection path, reduces optical energy loss.
Join Fig. 1 and Fig. 2, in some embodiments, the micro-nano structure 111 can be round bottom shape or back taper.Certainly, In the embodiment of other replacements, which may be arranged as other suitable shapes, embodiment given here It is simply exemplary, and and it is nonrestrictive, others that those skilled in the art make the micro-nano structure 111 are simple to be become Within the form of changing should ought belong to the scope of protection of the present invention.
In one embodiment, 11 and second substrate 12 of the first substrate is made by identical material.
In one embodiment, first substrate 11 is connected with the second substrate 12 by Direct Bonding technique, can so be kept away Exempt to introduce excessive dielectric layer, so as to increase loss when light is propagated in the substrate..
In one embodiment, the thickness ratio of 11 and second substrate 12 of the first substrate is 10:1~8:1.
One embodiment of the invention also provides a kind of production method of LED chip 100, and this method includes:
S1, multiple concave micro-nano structures are formed by etching in a side surface of the first substrate;
S2, the second substrate is connected to a side surface of first substrate with micro-nano structure;
S3, make the first semiconductor layer successively in a side surface of second substrate away from first substrate, shine LED chip is made in layer and the second semiconductor layer.
In one embodiment, step S1 is specifically included, and is protected in the edge of one side surface of the first substrate, and not by The surface of first substrate of protection forms multiple concave micro-nano structures by etching.
In one embodiment, the method is additionally included in form the micro-nano structure after remove one side surface of the first substrate Protection, and by the second substrate by way of Direct Bonding be not etched region on a side surface of first substrate Connection.
The present invention is had the advantages that by the above embodiment:
By setting the first substrate 11 and the second substrate 12 that are connected to each other, the first substrate 11 is bonded with the second substrate 12 One side surface indentation is formed with multiple micro-nano structures, and the thickness of the first substrate 11 is more than the thickness of the second substrate 12, these recess Micro-nano structure the light incided into substrate can be reflected, return it to the light direction of needs, improve light extraction efficiency, Its manufacture craft is simple, can effectively control the cost of manufacture of LED chip.
It should be appreciated that although this specification is described in terms of embodiments, but not each embodiment only includes one A independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should will say For bright book as an entirety, the technical solution in each embodiment may also be suitably combined to form those skilled in the art can With the other embodiment of understanding.
Those listed above it is a series of be described in detail only for the application feasibility embodiment specifically Bright, they are not to limit the protection domain of the application, all equivalent implementations made without departing from the application skill spirit Or change should be included within the protection domain of the application.

Claims (8)

1. a kind of LED chip, which is characterized in that including the first substrate and the second lining being sequentially formed on first substrate Bottom and epitaxial layer, the epitaxial layer includes the first semiconductor layer being sequentially formed on the substrate, luminescent layer and the second half is led Body layer, first substrate and the second substrate are made by transparent material, first substrate and the one of second substrate attaching Side surface recess is formed with multiple micro-nano structures, and the thickness of first substrate is more than the thickness of second substrate.
2. LED chip according to claim 1, which is characterized in that the micro-nano structure is round bottom shape or back taper.
3. LED chip according to claim 1, which is characterized in that first substrate and the second substrate are by identical material It is made.
4. LED chip according to claim 1, which is characterized in that first substrate and the second substrate pass through direct key Close technique connection.
5. LED chip according to claim 1, which is characterized in that the thickness ratio of first substrate and the second substrate is 10:1~8:1.
6. a kind of production method of LED chip, which is characterized in that this method includes:
S1, multiple concave micro-nano structures are formed by etching in a side surface of the first substrate;
S2, the second substrate is connected to a side surface of first substrate with micro-nano structure;
S3, made successively in a side surface of second substrate away from first substrate the first semiconductor layer, luminescent layer and LED chip is made in second semiconductor layer.
7. the production method of LED chip according to claim 6, which is characterized in that step S1 is specifically included, in the first lining The edge of one side surface of bottom is protected, and the surface of unprotected first substrate by etching formed it is multiple recessed Sunken micro-nano structure.
8. the production method of LED chip according to claim 7, which is characterized in that the method is additionally included in form institute State the protection that one side surface of the first substrate is removed after micro-nano structure, and by the second substrate by way of Direct Bonding and institute It states and region connection is not etched on a side surface of the first substrate.
CN201711331483.3A 2017-12-13 2017-12-13 A kind of LED chip and preparation method thereof Withdrawn CN108054259A (en)

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CN201711331483.3A CN108054259A (en) 2017-12-13 2017-12-13 A kind of LED chip and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114038957A (en) * 2021-05-18 2022-02-11 重庆康佳光电技术研究院有限公司 Light-emitting chip epitaxial structure, manufacturing method thereof and light-emitting chip

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101877330A (en) * 2009-04-30 2010-11-03 和椿科技股份有限公司 Sapphire substrate with period structure
CN103022292A (en) * 2012-11-21 2013-04-03 浙江优纬光电科技有限公司 InGaN-based blue light LED (Light Emitting Diode) device and preparation method thereof
CN103078024A (en) * 2013-01-31 2013-05-01 武汉迪源光电科技有限公司 Light-emitting diode (LED) with reflector structure
CN103208568A (en) * 2013-04-01 2013-07-17 厦门市三安光电科技有限公司 Nitride light-emitting diode and manufacturing method
US20150048385A1 (en) * 2013-08-13 2015-02-19 Lextar Electronics Corporation Light emitting diode substrate
CN105264677A (en) * 2013-12-03 2016-01-20 崇高种子公司 Led element

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101877330A (en) * 2009-04-30 2010-11-03 和椿科技股份有限公司 Sapphire substrate with period structure
CN103022292A (en) * 2012-11-21 2013-04-03 浙江优纬光电科技有限公司 InGaN-based blue light LED (Light Emitting Diode) device and preparation method thereof
CN103078024A (en) * 2013-01-31 2013-05-01 武汉迪源光电科技有限公司 Light-emitting diode (LED) with reflector structure
CN103208568A (en) * 2013-04-01 2013-07-17 厦门市三安光电科技有限公司 Nitride light-emitting diode and manufacturing method
US20150048385A1 (en) * 2013-08-13 2015-02-19 Lextar Electronics Corporation Light emitting diode substrate
CN105264677A (en) * 2013-12-03 2016-01-20 崇高种子公司 Led element

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114038957A (en) * 2021-05-18 2022-02-11 重庆康佳光电技术研究院有限公司 Light-emitting chip epitaxial structure, manufacturing method thereof and light-emitting chip

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