CN108046781A - High-strength ceramsite sand preparation process - Google Patents

High-strength ceramsite sand preparation process Download PDF

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CN108046781A
CN108046781A CN201711496288.6A CN201711496288A CN108046781A CN 108046781 A CN108046781 A CN 108046781A CN 201711496288 A CN201711496288 A CN 201711496288A CN 108046781 A CN108046781 A CN 108046781A
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parts
stirring
kiln
sieve nest
water
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CN108046781B (en
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赵武营
许松林
李经三
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Henan Xiangsheng Ceramsite Co Ltd
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Henan Xiangsheng Ceramsite Co Ltd
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/3215Barium oxides or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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    • C04B2235/48Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
    • C04B2235/483Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes

Abstract

The present invention discloses a kind of high-strength ceramsite sand preparation process, following ingredient is chosen by weight first to be dried and crush, 90 parts of bauxite raw material, 28 parts of barite, 0.3 1.0 parts of alum, 36 parts of iron oxide, 13 parts of manganese ore mountain flour, 0.2 0.5 parts of zircon sand, 14 parts of barium monoxide wear into mixing after fine powder crosses the choosing of 300 mesh sieves and form PRIMARY STIRRING material respectively.Then uniform coarse grain is quickly formed on sieve is rocked, then is taken out after coarse grain is immersed in dipping liquid pool, continues stirring stirring and round shaped grain semi-finished product idiosome is made.Then it is fired.Each components compatibility of selected raw material of the present invention is reasonable, the manganese ore mountain flour wherein used contributes to ceramsite sand blank under rotary kiln hot conditions, contained Al2O3 and SiO2 in blank is promoted to react, other each ingredients are catalyzed, so as to form more mullite phases and part corundum phase, and then realize the purpose for the compressive resistance for improving ceramsite propping agent.

Description

High-strength ceramsite sand preparation process
Technical field
The present invention relates to ceramsite sand fabricating technology fields, and in particular to a kind of high intensity high efficiency prepares ceramsite sand Technique.
Background technology
Haydite is a kind of artificial lightweight aggregate, and shell is hard, and inside has micro- porous ceramic shot-like particle, it has good guarantor Warm thermal insulation, has excellent fire-resistance, and there is the glaze layer that one layer of water proof protects gas on surface, and water absorption rate is low, and impervious shock resistance is good, anti-freezing property and Endurance quality is good, has excellent physics, chemistry and hydraulic characteristic(s).The shortcomings that in order to improve above-mentioned air entrained concrete, some factories Family adds haydite into air entrained concrete, not only increases the skeleton structure of concrete, and can effectively keep aerating and mix The advantage of soil is coagulated, its common quality defect is overcome, gives full play of high-strength characteristic, reduce the consumption of the energy.But due to haydite It is a kind of hollow aglite, in whipping process, since the ratio of slurry is great, haydite easily floats, and causes to be unevenly distributed It is even, product defects is formed, on the other hand, since the self-strength of haydite aggregate is relatively low, breakage is also easy to produce in whipping process, this is not Itself water absorption rate of haydite is increased only, and also reduces product heat-insulating property.
In the preparation process of current existing haydite, mainly with clay, shale, flyash, colliery overburden, loess, dirt Mud etc. is made of primary raw material.Due to excavating clay, shale, loess, sludge etc., soil erosion can be caused, environmental pollution destroys Therefore the ecological balance, is not suitable for promoting and applying.On the other hand, the remaining industrial waste of chemical enterprise and slag, such as aluminium manufacturer give up Slag or sulfuric acid waste Aluminum slag and gangue and flyash etc., it is impossible to be effectively addressed and resource recycling.
The content of the invention
The present invention is of high cost for raw material in existing ceramsite preparation process, the problems such as being easily destroyed environment, and providing one kind can To provide the ceramsite preparation process of haydite intensity.
In order to solve the above technical problems, it adopts the following technical scheme that:A kind of high-strength ceramsite sand preparation process, including as follows Step.
(1)It is prepared by raw material:It chooses following ingredient by weight to be dried and crush, 90 parts of bauxite raw material, weight is brilliant 2-8 parts of stone, 0.3-1.0 parts of alum, 3-6 parts of iron oxide, 1-3 parts of manganese ore mountain flour, 0.2-0.5 parts of zircon sand, 1-4 parts of barium monoxide, Mixing after fine powder crosses the choosing of 300 mesh sieves is worn into respectively forms PRIMARY STIRRING material.
(2)PRIMARY STIRRING material using 5% water is atomized, and adds 0.2~0.5% water-soluble binder, on sieve is rocked Uniform coarse grain is quickly formed, subject to 200 mesh of granularity;The sieve that rocks includes pedestal and sieve nest and driving mechanism:Pedestal passes through Driving rotating mechanism is equipped with rotating turret, sets bearing in the one side on rotating turret top, bearing upper end is hinged on sieve nest bottom; The other end on rotating turret top is fixed with vertical guide sleeve, in the guide sleeve matching be set with push-pull rod, push-pull rod it is upper End is hinged on sieve nest bottom;Oscillating motor is also equipped on the adjustable shelf, bias is installed in the shaft of the oscillating motor Axis turntable, the eccentric position on the eccentric shaft turntable are fixed with eccentric shaft, and the lower end of the push-pull rod is hinged with a swing rod, The lower end of swing rod is hinged on eccentric shaft.
(3)First prepare weight percent for 0.1%~methyl silanol sodium solution O.5%, then add in weight percent For 10%~30% portland cement, maceration extract is configured to.
(4)By step(2)Coarse grain be immersed in dipping liquid pool in is kept for 1~2 second after take out, by after dipping coarse grain add in make While secondary stirring is carried out in grain machine, and continues to add PRIMARY STIRRING material, lasting supplement addition clay powder common 10-20 parts and zinc Powder is 2-5 parts common, is atomized using 5% water, and adds 0.1~0.5% water-soluble binder, is stirred continuously until that granularity increases to 10 The secondary semi-finished product of~30 mesh.
(5)Stop adding powder and stop atomized water and water-soluble binder supplement, be continuously added into 1-2 parts of zinc powder and stir 30 minutes After stop zincification, continue stirring stirring 3~5 it is small when, round shaped grain semi-finished product idiosome is made.
(6)It is sent after 8-30 mesh screens to rotary kiln firing after taking out semi-finished product idiosome.
(7)It fires:After semi-finished product idiosome is entered kiln, first 300~500 are heated to 20~30 DEG C/min in kiln hood position DEG C, it keeps carrying out decarbonizing process in 10~30 minutes;Temperature of kiln head is promoted again is heated to 1300-1400 DEG C with 10~20 DEG C/min, 300-350 DEG C of kiln end temperature, heat preservation carry out process of guaranteeing the quality in 90 minutes or more.
(8)Cool down kiln discharge.
Further, the PRIMARY STIRRING material chooses following ingredient and is dried and crushes by weight, bauxite life 90 parts of material, 4-6 parts of barite, 0.5-0.8 parts of alum, 3-5 parts of iron oxide, 2-3 parts of manganese ore mountain flour, 0.3-0.5 parts of zircon sand, oxygen Change 2-4 parts of barium.
Strainer is horizontally arranged on the inside of the sieve nest, the region on the upside of strainer is that qualified blank screens room, is located at Region on the downside of strainer is particle collecting chamber, and the one side for screening room and collecting chamber is respectively arranged with blank floss hole and particle row Put mouth.
The sieve nest is mounted on the eccentric position of adjustable shelf, i.e. the axial direction of sieve nest and the axial rotary of adjustable shelf is misaligned.
Advantageous effect:Each components compatibility of selected raw material of the present invention is reasonable, wherein the manganese ore mountain flour used contributes to ceramsite sand Blank promotes contained Al2O3 and SiO2 in blank to react, other each ingredients is urged under rotary kiln hot conditions Change, so as to form more mullite phases and part corundum phase, and then realize the compressive resistance for improving ceramsite propping agent Purpose.
The present invention saves nucleation time, improves granulating effect using sieve is rocked first by small part elder generation fast nucleation in raw material Rate.The wherein used sieve that rocks can keep in sieve nest sub-material and small core also to have to pitch and shake in the process of rotation The effect of rolling can make sieve nest periphery have a side position to be less than there are one always all after being combined by turning effort and the effect of rocking The region on side, and low level and high-order alternate process can all occur in the periphery of sieve nest, so as to be especially advantageous for the mistake of initial stage granulating Journey.
In sintering procedure, repeatedly different degrees of burning process is taken respectively, improves sintering strength and performance.So as to this Invention improves density, intensity and the hydrophobicity of haydite, and pellet surface is smooth, and effect is very good.
Description of the drawings
Fig. 1 is to rocking sieve structure schematic diagram involved in the present invention.
Figure label:1 is pedestal, and 2 be driving rotating mechanism, and 3 be rotating turret, and 4 be oscillating motor, and 5 be eccentric shaft turntable, 6 be swing rod, and 7 be push-pull rod, and 8 be guide sleeve, and 9 be sieve nest, and 10 be strainer, and 11 be particle collecting chamber, and 12 be blank floss hole, 13 It is bearing for particle floss hole, 14.
Specific embodiment
Embodiment 1:A kind of high-strength ceramsite sand preparation process, includes the following steps:
(1)It is prepared by raw material:It chooses following ingredient by weight to be dried and crush, 90 parts of bauxite raw material, barite 2-8 Part, 0.3-1.0 parts of alum, 3-6 parts of iron oxide, 1-3 parts of manganese ore mountain flour, 0.2-0.5 parts of zircon sand, 1-4 parts of barium monoxide are ground respectively It crosses after the choosing of 300 mesh sieves to be mixed into fine powder and forms PRIMARY STIRRING material.
(2)PRIMARY STIRRING material using 5% water is atomized, and adds 0.2~0.5% water-soluble binder, on sieve is rocked Uniform coarse grain is quickly formed, subject to 200 mesh of granularity.
The sieve that rocks includes pedestal and sieve nest and driving mechanism, and shown in Figure 1, pedestal is by driving whirler Structure is equipped with rotating turret, sets bearing in the one side on rotating turret top, bearing upper end is hinged on sieve nest bottom;On rotating turret top The other end be fixed with vertical guide sleeve, in the guide sleeve matching be set with push-pull rod, the upper end of push-pull rod is hinged on sieve Body bottom;Oscillating motor is also equipped on the adjustable shelf, eccentric shaft turntable is installed, at this in the shaft of the oscillating motor Eccentric position on eccentric shaft turntable is fixed with eccentric shaft, and the lower end of the push-pull rod is hinged with a swing rod, the lower end of swing rod It is hinged on eccentric shaft.
(3)First prepare weight percent for 0.1%~methyl silanol sodium solution O.5%, then add in weight percent For 10%~30% portland cement, maceration extract is configured to.
(4)By step(2)Coarse grain be immersed in dipping liquid pool in is kept for 1~2 second after take out, by after dipping coarse grain add in make While secondary stirring is carried out in grain machine, and continues to add PRIMARY STIRRING material, lasting supplement addition clay powder common 10-20 parts and zinc Powder is 2-5 parts common, is atomized using 5% water, and adds 0.1~0.5% water-soluble binder, is stirred continuously until that granularity increases to 10 The secondary semi-finished product of~30 mesh.
(5)Stop adding powder and stop atomized water and water-soluble binder supplement, be continuously added into 1-2 parts of zinc powder and stir 30 minutes After stop zincification, continue stirring stirring 3~5 it is small when, round shaped grain semi-finished product idiosome is made.
(6)It is sent after 8-30 mesh screens to rotary kiln firing after taking out semi-finished product idiosome.
(7)It fires:After semi-finished product idiosome is entered kiln, first 300~500 are heated to 20~30 DEG C/min in kiln hood position DEG C, it keeps carrying out decarbonizing process in 10~30 minutes;Temperature of kiln head is promoted again is heated to 1300-1400 DEG C with 10~20 DEG C/min, 300-350 DEG C of kiln end temperature, heat preservation carry out process of guaranteeing the quality in 90 minutes or more.
(8)Cool down kiln discharge.
Embodiment 2:On the basis of embodiment 1, the PRIMARY STIRRING material that is related to is chosen following ingredient and is done by weight It is dry and broken, 90 parts of bauxite raw material, 4-6 parts of barite, 0.5-0.8 parts of alum, 3-5 parts of iron oxide, 2-3 parts of manganese ore mountain flour, 0.3-0.5 parts of zircon sand, 2-4 parts of barium monoxide.
Embodiment 3:On the basis of embodiment 1, strainer is horizontally arranged on the inside of sieve nest, the region on the upside of strainer is Qualified blank screens room, and the region on the downside of strainer is particle collecting chamber, and the one side for screening room and collecting chamber is respectively arranged with Blank floss hole and particle floss hole.
Embodiment 4:On the basis of embodiment 1, the sieve nest be mounted on adjustable shelf eccentric position, i.e., the axial direction of sieve nest and The axial rotary of adjustable shelf is misaligned.At this point, overturning amplitude can be significantly improved.

Claims (4)

1. a kind of high-strength ceramsite sand preparation process, which is characterized in that include the following steps:
(1)It is prepared by raw material:It chooses following ingredient by weight to be dried and crush, 90 parts of bauxite raw material, barite 2-8 Part, 0.3-1.0 parts of alum, 3-6 parts of iron oxide, 1-3 parts of manganese ore mountain flour, 0.2-0.5 parts of zircon sand, 1-4 parts of barium monoxide are ground respectively It crosses after the choosing of 300 mesh sieves to be mixed into fine powder and forms PRIMARY STIRRING material;
(2)PRIMARY STIRRING material using 5% water is atomized, and adds 0.2~0.5% water-soluble binder, it is quick on sieve is rocked Uniform coarse grain is formed, subject to 200 mesh of granularity;The sieve that rocks includes pedestal and sieve nest and driving mechanism:Pedestal passes through driving Rotating mechanism is equipped with rotating turret, sets bearing in the one side on rotating turret top, bearing upper end is hinged on sieve nest bottom;It is rotating The other end on frame top is fixed with vertical guide sleeve, is matched in the guide sleeve and is set with push-pull rod, the upper end hinge of push-pull rod It is connected on sieve nest bottom;Oscillating motor is also equipped on the adjustable shelf, eccentric shaft in the shaft of the oscillating motor is installed and is turned Disk, the eccentric position on the eccentric shaft turntable are fixed with eccentric shaft, and the lower end of the push-pull rod is hinged with a swing rod, swing rod Lower end be hinged on eccentric shaft;
(3)First prepare weight percent for 0.1%~methyl silanol sodium solution O.5%, then adding in weight percent is 10%~30% portland cement, is configured to maceration extract;
(4)By step(2)Coarse grain be immersed in dipping liquid pool in is kept for 1~2 second after take out, by after dipping coarse grain addition granulator It is middle to carry out secondary stirring, and while continue to add PRIMARY STIRRING material, lasting common 10-20 parts of supplement addition clay powder is total to zinc powder It 2-5 parts, is atomized using 5% water, and adds 0.1~0.5% water-soluble binder, be stirred continuously until that granularity increases to 10~30 Purpose secondary semi-finished product;
(5)Stop adding powder and stop atomized water and water-soluble binder supplement, stop after being continuously added into the stirring 30 minutes of 1-2 parts of zinc powder Only zincification, continue stirring stirring 3~5 it is small when, round shaped grain semi-finished product idiosome is made;
(6)It is sent after 8-30 mesh screens to rotary kiln firing after taking out semi-finished product idiosome;
(7)It fires:After semi-finished product idiosome is entered kiln, 300~500 DEG C first are heated to 20~30 DEG C/min in kiln hood position, is protected It holds 10~30 minutes and carries out decarbonizing process;Temperature of kiln head is promoted again is heated to 1300-1400 DEG C with 10~20 DEG C/min, kiln tail 300-350 DEG C of temperature, heat preservation carry out process of guaranteeing the quality in 90 minutes or more;
(8)Cool down kiln discharge.
2. high-strength ceramsite sand preparation process according to claim 1, which is characterized in that PRIMARY STIRRING material is by weight It chooses following ingredient to be dried and crush, 90 parts of bauxite raw material, 4-6 parts of barite, 0.5-0.8 parts of alum, iron oxide 3-5 Part, 2-3 parts of manganese ore mountain flour, 0.3-0.5 parts of zircon sand, 2-4 parts of barium monoxide.
3. high-strength ceramsite sand preparation process according to claim 1, which is characterized in that laterally set on the inside of the sieve nest Strainer is equipped with, the region on the upside of strainer is that qualified blank screens room, and the region on the downside of strainer is particle collecting chamber, is sieved Room and the one side of collecting chamber is selected to be respectively arranged with blank floss hole and particle floss hole.
4. high-strength ceramsite sand preparation process according to claim 1, which is characterized in that the sieve nest is mounted on adjustable shelf Eccentric position, i.e. the axial direction of sieve nest and the axial rotary of adjustable shelf be misaligned.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109293371A (en) * 2018-09-30 2019-02-01 柳晶(长春)环保科技有限公司 A kind of technique preparing haydite using building waste
CN110093149A (en) * 2019-06-03 2019-08-06 太原理工大学 A kind of preparation method of gangue Quito hole ceramsite propping agent
CN113564356A (en) * 2021-07-28 2021-10-29 河南建杰实业有限公司 Adhesive for zinc-containing dedusting ash pellets of rotary hearth furnace and preparation method thereof
CN114273224A (en) * 2021-12-27 2022-04-05 程建中 Wet soft viscidity granule material letter sorting equipment

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