CN108046660A - A kind of environmentally protective composite building material and preparation method thereof - Google Patents
A kind of environmentally protective composite building material and preparation method thereof Download PDFInfo
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- CN108046660A CN108046660A CN201711061750.XA CN201711061750A CN108046660A CN 108046660 A CN108046660 A CN 108046660A CN 201711061750 A CN201711061750 A CN 201711061750A CN 108046660 A CN108046660 A CN 108046660A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of environmentally protective composite building material and preparation method thereof, including being prepared by the raw material of following parts by weight：5 10 parts of 20 35 parts of waste ceramic material, 20 30 parts of magnesium calcium carbonate, 15 30 parts of paraffin, 10 20 parts of isoprene rubber, 8 15 parts of inorganic filler, 20 35 parts of calcium silicate powder, 11 22 parts of pearlife, 10 12 parts of chlorosulfonated polyethylene, 10 15 parts of ethylenediamine tetra-acetic acid, 26 parts of fire retardant, 8 15 parts of antioxidant and polycarboxylate cement dispersant.The present invention is made composite building material and is improved the shock resistance of product, anti-cracking performance using effective proportioning of the raw materials such as waste ceramic material, magnesium calcium carbonate, paraffin, isoprene rubber, inorganic filler, calcium silicate powder, pearlife.Building and ornament materials and preparation method of the present invention have the characteristics that resistance to cracking, easily impact resistance, transport and low-maintenance cost；Possesses the features such as preparation process is simple, high yield rate, material repeat utilization, environmentally protective, energy-saving consumption-reducing.
Description
Technical field
The present invention relates to composite material manufacture technology fields, and in particular to a kind of environmentally protective composite building material and its
Preparation method.
Background technology
As market has gradually built up the extensive approval to light building material, the continuous improvement of light building material quality and function and
It improves, the usage amount of following light building material will be substantially improved.Light building material will be to environmentally friendly, energy saving, green, compound, common
Mixed technology, the direction of multifunction are developed, and constantly meet the market demand.
At present, domestic construction industry develop rapidly, presently, there are construction material made of building template, exist using week
Phase is short, best product also can only use 7-8 times, and after product use can not recycling, cause environmental pollution.Mesh simultaneously
The manufacturing of preceding architectural intermediate water mud needs to consume substantial amounts of mine resources, and brings larger environmental pollution, so finding
The research and development of more preferable cement replacement receive extensive attention.Have disclosed at present report containing flyash
In building latex material, the effect that cement is replaced with flyash is not really achieved.
With the continuous improvement of people's living standards, requirement of the people for indoor decoration is higher and higher, at present, on the market
The environment protection architecture art work being known as, wherein containing numerous toxic chemical substances, these toxic chemical substances constantly from
It is evaporated in Building Decoration Material, seriously polluted indoor air, affect the health of people.
Therefore, to solve the above problems, providing a kind of new technical solution.
The content of the invention
To solve the above problems, the present invention provides a kind of environmentally protective composite building materials and preparation method thereof.
To achieve the above object, the technical solution taken of the present invention is：
A kind of environmentally protective composite building material and preparation method thereof, including being prepared by the raw material of following parts by weight：It is useless
Abandon 20-35 parts of ceramic material, 20-30 parts of magnesium calcium carbonate, 15-30 parts of paraffin, 10-20 parts of isoprene rubber, 8-15 parts of inorganic filler, silicon
Sour calcium powder 20-35 parts, 11-22 parts of pearlife, 10-12 parts of chlorosulfonated polyethylene, 10-15 parts of ethylenediamine tetra-acetic acid, fire retardant 2-6
5-10 parts of part, 8-15 parts of antioxidant and polycarboxylate cement dispersant.
Further, a kind of environmentally protective composite building material, including being prepared by the raw material of following parts by weight：It is useless
Abandon 21-33 parts of ceramic material, 21-33 parts of magnesium calcium carbonate, 16-29 parts of paraffin, 11-19 parts of isoprene rubber, 9-14 parts of inorganic filler, silicon
Sour calcium powder 21-34 parts, 12-21 parts of pearlife, 11-12 parts of chlorosulfonated polyethylene, 11-14 parts of ethylenediamine tetra-acetic acid, fire retardant 3-5
6-9 parts of part, 9-14 parts of antioxidant and polycarboxylate cement dispersant.
Further, a kind of environmentally protective composite building material, is prepared by the raw material of following parts by weight：Discarded pottery
25 parts of porcelain, 28 parts of magnesium calcium carbonate, 18 parts of paraffin, 17 parts of isoprene rubber, 13 parts of inorganic filler, 26 parts of calcium silicate powder, pearlife
12 parts, 11 parts of chlorosulfonated polyethylene, 14 parts of ethylenediamine tetra-acetic acid, 4 parts of fire retardant, 11 parts of antioxidant and polycarboxylate cement disperse
6 parts of agent.
Further, the fire retardant is antimony oxide, magnesium hydroxide or aluminium hydroxide, and the antioxidant is antioxidant
At least one of 1010 and antioxidant 1076.
Further, the inorganic filler is polyester fiber, blast-furnace cinder, soil, methyl methacrylate and bentonite
One or more of.
Further, a kind of preparation method of environmentally protective composite building material, includes the following steps：
S1：By 20-35 parts of waste ceramic material, 15-30 parts of paraffin, 10-20 parts of isoprene rubber, 8-15 parts of inorganic filler, calcium silicates
20-35 parts of powder, 11-22 parts of pearlife, 10-15 parts of ethylenediamine tetra-acetic acid are separately added into grinder and are ground, and cross 110-130 mesh
It is mixed after sieve, obtains mixed powder；
S2：Step S1 is obtained mixed powder to add in homogenizer, sequentially adds 20-30 parts of magnesium calcium carbonate, chlorosulfonation is gathered
5-10 parts of 10-12 parts of ethylene, 2-6 parts of fire retardant, 8-15 parts of antioxidant and polycarboxylate cement dispersant are 30-50 DEG C in temperature
Under continue stir 1-2h, be down to room temperature, obtain mixed material；
S3：The obtained mixed materials of step S2 are added in double screw extruder, the melt blending in the case where temperature is 150-200 DEG C
Extrusion molding, through pelleter pelletizing into pellet after cooling；
S4：The pellet that step S3 is obtained after drying, injection molding is melted by injection molding machine in the case where temperature is 150-200 DEG C,
Matrices of composite material, test package storage are made after the demoulding.
A kind of environmentally protective composite building material, is prepared by the raw material of following parts by weight：25 parts of waste ceramic material,
28 parts of magnesium calcium carbonate, 18 parts of paraffin, 17 parts of isoprene rubber, 13 parts of inorganic filler, 26 parts of calcium silicate powder, 12 parts of pearlife, chlorine sulphur
Change 6 parts of 11 parts of polyethylene, 14 parts of ethylenediamine tetra-acetic acid, 4 parts of fire retardant, 11 parts of antioxidant and polycarboxylate cement dispersant.
The present invention using waste ceramic material, magnesium calcium carbonate, paraffin, isoprene rubber, inorganic filler, calcium silicate powder, pearlife,
Effective proportioning of the raw materials such as chlorosulfonated polyethylene；Composite building material is made and improves the shock resistance of product, anti-cracking performance.
Compared with prior art, the building and ornament materials introduced of the present invention and preparation method have resistance to cracking, impact resistance, easily transport and low
The features such as maintenance cost；Possess that preparation process is simple, high yield rate, material repeat the spies such as utilization, environmentally protective, energy-saving consumption-reducing
Point.
Blast-furnace cinder of the present invention, exciting agent improve the performance of inorganic coagulation material, and extend building uses the longevity
Life, insulated fire performance is high, while can also play good waterproof effect；Construction material, simple production process are easy to implement
It is at low cost with control, beneficial to industrialized production and use.
Specific embodiment
In order to which objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight：20-35 parts of waste ceramic material, magnesium calcium carbonate 20-30
Part, 15-30 parts of paraffin, 10-20 parts of isoprene rubber, 8-15 parts of inorganic filler, 20-35 parts of calcium silicate powder, 11-22 parts of pearlife,
10-12 parts of chlorosulfonated polyethylene, 10-15 parts of ethylenediamine tetra-acetic acid, 2-6 parts of fire retardant, 8-15 parts of antioxidant and polycarboxylate
5-10 parts of cement dispersant.
A kind of environmentally protective composite building material, including being prepared by the raw material of following parts by weight：Waste ceramic material
21-33 parts, 21-33 parts of magnesium calcium carbonate, 16-29 parts of paraffin, 11-19 parts of isoprene rubber, 9-14 parts of inorganic filler, calcium silicate powder
21-34 parts, it is 12-21 parts of pearlife, 11-12 parts of chlorosulfonated polyethylene, 11-14 parts of ethylenediamine tetra-acetic acid, 3-5 parts of fire retardant, anti-
6-9 parts of 9-14 parts of oxygen agent and polycarboxylate cement dispersant.
A kind of environmentally protective composite building material, is prepared by the raw material of following parts by weight：25 parts of waste ceramic material,
28 parts of magnesium calcium carbonate, 18 parts of paraffin, 17 parts of isoprene rubber, 13 parts of inorganic filler, 26 parts of calcium silicate powder, 12 parts of pearlife, chlorine sulphur
Change 6 parts of 11 parts of polyethylene, 14 parts of ethylenediamine tetra-acetic acid, 4 parts of fire retardant, 11 parts of antioxidant and polycarboxylate cement dispersant.
The fire retardant is antimony oxide, magnesium hydroxide or aluminium hydroxide, the antioxidant for antioxidant 1010 and
At least one of antioxidant 1076.
The inorganic filler be polyester fiber, blast-furnace cinder, soil, methyl methacrylate and bentonite in one kind or
It is several.
A kind of preparation method of environmentally protective composite building material, includes the following steps：
S1：By 20-35 parts of waste ceramic material, 15-30 parts of paraffin, 10-20 parts of isoprene rubber, 8-15 parts of inorganic filler, calcium silicates
20-35 parts of powder, 11-22 parts of pearlife, 10-15 parts of ethylenediamine tetra-acetic acid are separately added into grinder and are ground, and cross 110-130 mesh
It is mixed after sieve, obtains mixed powder；
S2：Step S1 is obtained mixed powder to add in homogenizer, sequentially adds 20-30 parts of magnesium calcium carbonate, chlorosulfonation is gathered
5-10 parts of 10-12 parts of ethylene, 2-6 parts of fire retardant, 8-15 parts of antioxidant and polycarboxylate cement dispersant are 30-50 DEG C in temperature
Under continue stir 1-2h, be down to room temperature, obtain mixed material；
S3：The obtained mixed materials of step S2 are added in double screw extruder, the melt blending in the case where temperature is 150-200 DEG C
Extrusion molding, through pelleter pelletizing into pellet after cooling；
S4：The pellet that step S3 is obtained after drying, injection molding is melted by injection molding machine in the case where temperature is 150-200 DEG C,
Matrices of composite material, test package storage are made after the demoulding.
Embodiment 1：
A kind of preparation method of environmentally protective composite building material, includes the following steps：
S1：By 25 parts of waste ceramic material, 18 parts of paraffin, 17 parts of isoprene rubber, 13 parts of inorganic filler, 26 parts of calcium silicate powder, pearly-lustre
12 parts of sand, 10 parts of ethylenediamine tetra-acetic acid are separately added into grinder and are ground, and cross mixing after 100 mesh sieves, obtain mixed powder；
S2：Step S1 is obtained mixed powder to add in homogenizer, sequentially adds 28 parts of magnesium calcium carbonate, chlorosulfonated polyethylene
6 parts of 11 parts, 14 parts of ethylenediamine tetra-acetic acid, 4 parts of fire retardant, 11 parts of antioxidant and polycarboxylate cement dispersant are 30- in temperature
Continue to stir 1-2h at 50 DEG C, be down to room temperature, obtain mixed material；
S3：The obtained mixed materials of step S2 are added in double screw extruder, in the case where temperature is 190 DEG C, melt blending squeezes out
Shaping, through pelleter pelletizing into pellet after cooling；
S4：The pellet that step S3 is obtained after drying, melts injection molding in the case where temperature is 190 DEG C by injection molding machine, demoulds
Matrices of composite material, test package storage are made afterwards.
Embodiment 2：
S1：By 35 parts of waste ceramic material, 30 parts of paraffin, 20 parts of isoprene rubber, 15 parts of inorganic filler, 35 parts of calcium silicate powder, pearly-lustre
22 parts of sand, 15 parts of ethylenediamine tetra-acetic acid are separately added into grinder and are ground, and cross mixing after 120 mesh sieves, obtain mixed powder；
S2：Step S1 is obtained mixed powder to add in homogenizer, sequentially adds 30 parts of magnesium calcium carbonate, chlorosulfonated polyethylene
10 parts of 12 parts, 6 parts of fire retardant, 15 parts of antioxidant and polycarboxylate cement dispersant continue to stir 2h, drop in the case where temperature is 50 DEG C
To room temperature, mixed material is obtained；
S3：The mixed material that step S2 is obtained, is added in double screw extruder, and in the case where temperature is 200 DEG C, melt blending squeezes
Go out shaping, through pelleter pelletizing into pellet after cooling；
S4：The pellet that step S3 is obtained after drying, melts injection molding in the case where temperature is 200 DEG C by injection molding machine, demoulds
Matrices of composite material, test package storage are made afterwards.
Embodiment 3：
S1：By 20 parts of waste ceramic material, 15 parts of paraffin, 10 parts of isoprene rubber, 8 parts of inorganic filler, 20 parts of calcium silicate powder, pearlife
11 parts, 10 parts of ethylenediamine tetra-acetic acid be separately added into grinder and be ground, cross 100 mesh sieves after mix, obtain mixed powder；
S2：Step S1 is obtained mixed powder to add in homogenizer, sequentially adds 20 parts of magnesium calcium carbonate, chlorosulfonated polyethylene
5 parts of 10 parts, 2 parts of fire retardant, 8 parts of antioxidant and polycarboxylate cement dispersant continue to stir 1h in the case where temperature is 30 DEG C, are down to
Room temperature obtains mixed material；
S3：The mixed material that step S2 is obtained, is added in double screw extruder, and in the case where temperature is 180 DEG C, melt blending squeezes
Go out shaping, through pelleter pelletizing into pellet after cooling；
S4：The pellet that step S3 is obtained after drying, melts injection molding in the case where temperature is 150 DEG C by injection molding machine, demoulds
Matrices of composite material, test package storage are made afterwards.
The present invention using waste ceramic material, magnesium calcium carbonate, paraffin, isoprene rubber, inorganic filler, calcium silicate powder, pearlife,
Effective proportioning of the raw materials such as chlorosulfonated polyethylene is made composite building material and improves the shock resistance of product, anti-cracking performance.
Compared with prior art, the building and ornament materials introduced of the present invention and preparation method have resistance to cracking, impact resistance, easily transport and low
The features such as maintenance cost；Possess that preparation process is simple, high yield rate, material repeat the spies such as utilization, environmentally protective, energy-saving consumption-reducing
Point.
Component of the present invention is convenient source, compared with existing products in markets, has the advantage of cost, uses
Low thermal conductivity raw material has reached light weight, intensity height, the low technique effect of unit weight；With green environmental protection, not only make use of
Obsolete material, while the product produced can secondary recovery；Cheap, simple production process is suitble to large-scale production.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, several improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (6)
1. a kind of environmentally protective composite building material, which is characterized in that including being prepared by the raw material of following parts by weight：It is useless
Abandon 20-35 parts of ceramic material, 20-30 parts of magnesium calcium carbonate, 15-30 parts of paraffin, 10-20 parts of isoprene rubber, 8-15 parts of inorganic filler, silicon
Sour calcium powder 20-35 parts, 11-22 parts of pearlife, 10-12 parts of chlorosulfonated polyethylene, 10-15 parts of ethylenediamine tetra-acetic acid, fire retardant 2-6
5-10 parts of part, 8-15 parts of antioxidant and polycarboxylate cement dispersant.
2. a kind of environmentally protective composite building material, which is characterized in that including being prepared by the raw material of following parts by weight：It is useless
Abandon 21-33 parts of ceramic material, 21-33 parts of magnesium calcium carbonate, 16-29 parts of paraffin, 11-19 parts of isoprene rubber, 9-14 parts of inorganic filler, silicon
Sour calcium powder 21-34 parts, 12-21 parts of pearlife, 11-12 parts of chlorosulfonated polyethylene, 11-14 parts of ethylenediamine tetra-acetic acid, fire retardant 3-5
6-9 parts of part, 9-14 parts of antioxidant and polycarboxylate cement dispersant.
3. a kind of environmentally protective composite building material according to claim 1, which is characterized in that by following parts by weight
Raw material is prepared：25 parts of waste ceramic material, 28 parts of magnesium calcium carbonate, 18 parts of paraffin, 17 parts of isoprene rubber, 13 parts of inorganic filler,
26 parts of calcium silicate powder, 12 parts of pearlife, 11 parts of chlorosulfonated polyethylene, 14 parts of ethylenediamine tetra-acetic acid, 4 parts of fire retardant, antioxidant 11
6 parts of part and polycarboxylate cement dispersant.
4. a kind of environmentally protective composite building material according to claim 1, which is characterized in that the fire retardant is three
Two antimony, magnesium hydroxide or aluminium hydroxide are aoxidized, the antioxidant is at least one in antioxidant 1010 and antioxidant 1076
Kind.
5. a kind of environmentally protective composite building material according to claim 1, which is characterized in that the inorganic filler is
One or more of polyester fiber, blast-furnace cinder, soil, methyl methacrylate and bentonite.
6. a kind of preparation method of environmentally protective composite building material according to claim 1, which is characterized in that including
Following steps：
S1：By 20-35 parts of waste ceramic material, 15-30 parts of paraffin, 10-20 parts of isoprene rubber, 8-15 parts of inorganic filler, calcium silicates
20-35 parts of powder, 11-22 parts of pearlife, 10-15 parts of ethylenediamine tetra-acetic acid are separately added into grinder and are ground, and cross 110-130 mesh
It is mixed after sieve, obtains mixed powder；
S2：Step S1 is obtained mixed powder to add in homogenizer, sequentially adds 20-30 parts of magnesium calcium carbonate, chlorosulfonation is gathered
5-10 parts of 10-12 parts of ethylene, 2-6 parts of fire retardant, 8-15 parts of antioxidant and polycarboxylate cement dispersant are 30-50 DEG C in temperature
Under continue stir 1-2h, be down to room temperature, obtain mixed material；
S3：The obtained mixed materials of step S2 are added in double screw extruder, the melt blending in the case where temperature is 150-200 DEG C
Extrusion molding, through pelleter pelletizing into pellet after cooling；
S4：The pellet that step S3 is obtained after drying, injection molding is melted by injection molding machine in the case where temperature is 150-200 DEG C,
Matrices of composite material, test package storage are made after the demoulding.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711061750.XA CN108046660A (en) | 2017-11-02 | 2017-11-02 | A kind of environmentally protective composite building material and preparation method thereof |
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| CN201711061750.XA CN108046660A (en) | 2017-11-02 | 2017-11-02 | A kind of environmentally protective composite building material and preparation method thereof |
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| CN108046660A true CN108046660A (en) | 2018-05-18 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929534A (en) * | 2018-07-03 | 2018-12-04 | 合肥连森裕腾新材料科技开发有限公司 | A kind of environmentally protective fibrous composite for building and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589577A (en) * | 2016-10-28 | 2017-04-26 | 芜湖浩权建筑工程有限公司 | High-performance environment-friendly building composite material and preparation method thereof |
-
2017
- 2017-11-02 CN CN201711061750.XA patent/CN108046660A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589577A (en) * | 2016-10-28 | 2017-04-26 | 芜湖浩权建筑工程有限公司 | High-performance environment-friendly building composite material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929534A (en) * | 2018-07-03 | 2018-12-04 | 合肥连森裕腾新材料科技开发有限公司 | A kind of environmentally protective fibrous composite for building and preparation method thereof |
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Application publication date: 20180518 |