CN108929534A - A kind of environmentally protective fibrous composite for building and preparation method thereof - Google Patents

A kind of environmentally protective fibrous composite for building and preparation method thereof Download PDF

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Publication number
CN108929534A
CN108929534A CN201810720068.5A CN201810720068A CN108929534A CN 108929534 A CN108929534 A CN 108929534A CN 201810720068 A CN201810720068 A CN 201810720068A CN 108929534 A CN108929534 A CN 108929534A
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Prior art keywords
parts
building
antioxidant
mixture
environmentally protective
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CN201810720068.5A
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Chinese (zh)
Inventor
程华风
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Hefei Lian Sen Yu Teng New Material Technology Development Co Ltd
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Hefei Lian Sen Yu Teng New Material Technology Development Co Ltd
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Priority to CN201810720068.5A priority Critical patent/CN108929534A/en
Publication of CN108929534A publication Critical patent/CN108929534A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A kind of environmentally protective fibrous composite for building, by weight, including following raw material: 10~20 parts of nylon fiber, 20~30 parts of magnesium calcium carbonate, 10~16 parts of tossa, 10~20 parts of paraffin, 8~16 parts of silicon powder, 10~20 parts of isoprene rubber, 5~10 parts of inorganic filler, 10~20 parts of pearlife, 2~8 parts of fire retardant, 8~16 parts of antioxidant, 6~12 parts of corrosion inhibitor, 6~10 parts of polycarboxylate cement dispersant;The beneficial effects of the invention are as follows the service lifes for extending building, and insulated fire performance is high, while can also play good waterproof effect;Construction material, simple production process, easy to implement and control is at low cost, is conducive to industrialized production and use.

Description

A kind of environmentally protective fibrous composite for building and preparation method thereof
Technical field
The present invention relates to technical field of composite materials, and in particular to a kind of environmentally protective fibrous composite for building and Preparation method.
Background technique
Composite material is that people form material component optimum organization of different nature with advanced material preparation technology New material, the basis material of composite material is divided into metal and nonmetallic two major classes.There are commonly aluminium, magnesium, copper, titaniums for metallic matrix And its alloy.Nonmetal basal body mainly has synthetic resin, rubber, ceramics, graphite, carbon etc.;Reinforcing material mainly have glass fibre, Carbon fiber, boron fibre, aramid fiber, silicon carbide fibre, asbestos fibre, whisker, metal.
However the environment protection architecture art work being known as on the market at present, wherein contain numerous toxic chemical substances, these Toxic chemical substance is constantly evaporated from Building Decoration Material, seriously be polluted indoor air, is affected people Health.
Summary of the invention
The purpose of the present invention is to provide a kind of environmentally protective fibrous composites for building and preparation method thereof, with solution Certainly the problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme:
A kind of environmentally protective fibrous composite for building, by weight, including following raw material: 10~20 parts of nylon fiber, 20~30 parts of magnesium calcium carbonate, 10~16 parts of tossa, 10~20 parts of paraffin, 8~16 parts of silicon powder, 10~20 parts of isoprene rubber, 5~10 parts of inorganic filler, 10~20 parts of pearlife, 2~8 parts of fire retardant, 8~16 parts of antioxidant, 6~12 parts of corrosion inhibitor, poly- carboxylic 6~10 parts of acid salt cement dispersing agent.
As a further technical solution of the present invention is: by weight, including following raw material: 13~17 parts of nylon fiber, 23~27 parts of magnesium calcium carbonate, 12~14 parts of tossa, 13~17 parts of paraffin, 10~14 parts of silicon powder, 13~17 parts of isoprene rubber, 6~9 parts of inorganic filler, 13~17 parts of pearlife, 4~6 parts of fire retardant, 10~14 parts of antioxidant, 8~10 parts of corrosion inhibitor, poly- carboxylic 7~9 parts of acid salt cement dispersing agent.
As the further technical solution of the present invention is: by weight, including following raw material: 15 parts of nylon fiber, carbon 25 parts of sour magnesium calcium, 13 parts of tossa, 15 parts of paraffin, 12 parts of silicon powder, 15 parts of isoprene rubber, 7 parts of inorganic filler, pearlife 15 Part, 10 parts of fire retardant, 12 parts of antioxidant, 9 parts of corrosion inhibitor, 8 parts of polycarboxylate cement dispersant.
It is described anti-as the further technical solution of the present invention is: the fire retardant is magnesium hydroxide or aluminium hydroxide Oxygen agent is antioxidant 1010.
A kind of preparation method of environmentally protective fibrous composite for building, method includes the following steps:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 10~20min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time are 10~20min, obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time is 20~40min, obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, is melted at being 150~200 DEG C in temperature Blending extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) it by pellet made from step (4), after drying, melts and is molded at being 150~200 DEG C in temperature by injection molding machine Matrices of composite material, test package storage is made in type after demoulding.
The beneficial effects of the invention are as follows the service lifes for extending building, and insulated fire performance is high, while can also play Good waterproof effect;Construction material, simple production process, without toxic chemical substance, easy to implement and control, cost It is low, it is conducive to industrialized production and use.
Specific embodiment
In the following, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1:
The environmentally protective fibrous composite for building of the present embodiment includes the weight of following component: 10 parts of nylon fiber, carbon 20 parts of sour magnesium calcium, 10 parts of tossa, 10 parts of paraffin, 8 parts of silicon powder, 10 parts of isoprene rubber, 5 parts of inorganic filler, 10 parts of pearlife, 2 parts of fire retardant, 8 parts of antioxidant, 6 parts of corrosion inhibitor, 6 parts of polycarboxylate cement dispersant.
The above environmentally protective fibrous composite for building specific the preparation method is as follows:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 10min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time 10min obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time 20min obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, melt blending at being 150 DEG C in temperature Extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) by pellet made from step (4), after drying, injection molding is melted at being 150 DEG C in temperature by injection molding machine, is taken off Matrices of composite material, test package storage are made after mould.
Embodiment 2:
The environmentally protective fibrous composite for building of the present embodiment includes the weight of following component: 20 parts of nylon fiber, carbon 30 parts of sour magnesium calcium, 16 parts of tossa, 20 parts of paraffin, 16 parts of silicon powder, 20 parts of isoprene rubber, 10 parts of inorganic filler, pearlife 20 Part, 8 parts of fire retardant, 16 parts of antioxidant, 12 parts of corrosion inhibitor, 10 parts of polycarboxylate cement dispersant.
The above environmentally protective fibrous composite for building specific the preparation method is as follows:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 20min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time 20min obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time 40min obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, melt blending at being 200 DEG C in temperature Extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) by pellet made from step (4), after drying, injection molding is melted at being 200 DEG C in temperature by injection molding machine, is taken off Matrices of composite material, test package storage are made after mould.
Embodiment 3:
The environmentally protective fibrous composite for building of the present embodiment includes the weight of following component: 13 parts of nylon fiber, carbon 23 parts of sour magnesium calcium, 12 parts of tossa, 13 parts of paraffin, 10 parts of silicon powder, 13 parts of isoprene rubber, 6 parts of inorganic filler, pearlife 13 Part, 4 parts of fire retardant, 10 parts of antioxidant, 8 parts of corrosion inhibitor, 7 parts of polycarboxylate cement dispersant.
The above environmentally protective fibrous composite for building specific the preparation method is as follows:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 12min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time 12min obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time 25min obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, melt blending at being 160 DEG C in temperature Extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) by pellet made from step (4), after drying, injection molding is melted at being 160 DEG C in temperature by injection molding machine, is taken off Matrices of composite material, test package storage are made after mould.
Embodiment 4:
The environmentally protective fibrous composite for building of the present embodiment includes the weight of following component: 17 parts of nylon fiber, carbon 27 parts of sour magnesium calcium, 14 parts of tossa, 17 parts of paraffin, 14 parts of silicon powder, 17 parts of isoprene rubber, 9 parts of inorganic filler, pearlife 17 Part, 6 parts of fire retardant, 14 parts of antioxidant, 10 parts of corrosion inhibitor, 9 parts of polycarboxylate cement dispersant.
The above environmentally protective fibrous composite for building specific the preparation method is as follows:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 18min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time 18min obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time 35min obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, melt blending at being 190 DEG C in temperature Extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) by pellet made from step (4), after drying, injection molding is melted at being 190 DEG C in temperature by injection molding machine, is taken off Matrices of composite material, test package storage are made after mould.
Embodiment 5:
The environmentally protective fibrous composite for building of the present embodiment includes the weight of following component: 15 parts of nylon fiber, carbon 25 parts of sour magnesium calcium, 13 parts of tossa, 15 parts of paraffin, 12 parts of silicon powder, 15 parts of isoprene rubber, 7 parts of inorganic filler, pearlife 15 Part, 10 parts of fire retardant, 12 parts of antioxidant, 9 parts of corrosion inhibitor, 8 parts of polycarboxylate cement dispersant.
The above environmentally protective fibrous composite for building specific the preparation method is as follows:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 15min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time 15min obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time 30min obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, melt blending at being 175 DEG C in temperature Extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) by pellet made from step (4), after drying, injection molding is melted at being 175 DEG C in temperature by injection molding machine, is taken off Matrices of composite material, test package storage are made after mould.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (5)

1. a kind of environmentally protective fibrous composite for building, which is characterized in that by weight, including following raw material: nylon 10~20 parts of fiber, 20~30 parts of magnesium calcium carbonate, 10~16 parts of tossa, 10~20 parts of paraffin, 8~16 parts of silicon powder, isoamyl 10~20 parts of rubber, 5~10 parts of inorganic filler, 10~20 parts of pearlife, 2~8 parts of fire retardant, 8~16 parts of antioxidant, corrosion inhibitor 6~12 parts, 6~10 parts of polycarboxylate cement dispersant.
2. the environmentally protective fibrous composite for building of one kind according to claim 1, which is characterized in that with weight Meter, including following raw material: 13~17 parts of nylon fiber, 23~27 parts of magnesium calcium carbonate, 12~14 parts of tossa, paraffin 13~17 Part, 10~14 parts of silicon powder, 13~17 parts of isoprene rubber, 6~9 parts of inorganic filler, 13~17 parts of pearlife, 4~6 parts of fire retardant, 10~14 parts of antioxidant, 8~10 parts of corrosion inhibitor, 7~9 parts of polycarboxylate cement dispersant.
3. the environmentally protective fibrous composite for building of one kind according to claim 1, which is characterized in that with weight Meter, including following raw material: 15 parts of nylon fiber, 25 parts of magnesium calcium carbonate, 13 parts of tossa, 15 parts of paraffin, 12 parts of silicon powder, isoamyl 15 parts of rubber, 7 parts of inorganic filler, 15 parts of pearlife, 10 parts of fire retardant, 12 parts of antioxidant, 9 parts of corrosion inhibitor, polycarboxylate cement 8 parts of dispersing agent.
4. the environmentally protective fibrous composite for building of one kind according to claim 1, which is characterized in that described fire-retardant Agent is magnesium hydroxide or aluminium hydroxide, and the antioxidant is antioxidant 1010.
5. a kind of preparation method of environmentally protective fibrous composite for building according to claim 1, feature exist In, method includes the following steps:
(1) nylon fiber, magnesium calcium carbonate, tossa, paraffin, silicon powder are put into blender and are stirred, mixing time is 10~20min obtains the first mixture;
(2) the first mixture made from isoprene rubber, inorganic filler, pearlife and step (1) is put into grinder and is ground Mill, milling time are 10~20min, obtain the second mixture;
(3) the second mixture made from fire retardant, antioxidant, corrosion inhibitor, polycarboxylate cement dispersant and step (2) is put Enter in blender and stir, mixing time is 20~40min, obtains third mixture;
(4) third mixture made from step (3) is added in double screw extruder, is melted at being 150~200 DEG C in temperature Blending extrusion molding, through pelleter pelletizing at pellet after cooling;
(5) it by pellet made from step (4), after drying, melts and is molded at being 150~200 DEG C in temperature by injection molding machine Matrices of composite material, test package storage is made in type after demoulding.
CN201810720068.5A 2018-07-03 2018-07-03 A kind of environmentally protective fibrous composite for building and preparation method thereof Pending CN108929534A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001234492A (en) * 2000-02-25 2001-08-31 Ide Shigyo Kk Sheet material for multi-purpose use
CN107721350A (en) * 2017-10-30 2018-02-23 安徽嘉中金属材料有限公司 A kind of composite architectural materials of high-performance heat-insulating and fire-proof and preparation method thereof
CN108046660A (en) * 2017-11-02 2018-05-18 安徽嘉中金属材料有限公司 A kind of environmentally protective composite building material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001234492A (en) * 2000-02-25 2001-08-31 Ide Shigyo Kk Sheet material for multi-purpose use
CN107721350A (en) * 2017-10-30 2018-02-23 安徽嘉中金属材料有限公司 A kind of composite architectural materials of high-performance heat-insulating and fire-proof and preparation method thereof
CN108046660A (en) * 2017-11-02 2018-05-18 安徽嘉中金属材料有限公司 A kind of environmentally protective composite building material and preparation method thereof

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Application publication date: 20181204

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