CN108042966A - A kind of fire-extinguishing chemical - Google Patents
A kind of fire-extinguishing chemical Download PDFInfo
- Publication number
- CN108042966A CN108042966A CN201711167897.7A CN201711167897A CN108042966A CN 108042966 A CN108042966 A CN 108042966A CN 201711167897 A CN201711167897 A CN 201711167897A CN 108042966 A CN108042966 A CN 108042966A
- Authority
- CN
- China
- Prior art keywords
- parts
- fire
- sodium
- compounding
- extinguishing chemical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
A kind of fire-extinguishing chemical is made in parts by weight of following raw material：38 parts of fluorinated alkyl glycine betaine, 10 20 parts of fatty alcohol ether succinic acid sodium salt, 15 25 parts of dodecanamide propyl decil lactone, 0.5 2.5 parts of organosilicon quaternary ammonium salt, 5 15 parts of empgen BB, 40 55 parts of the compounding of ethylene glycol and glycerine, butyl compounds 5 20 parts with n-butanol, 5 10 parts of urea, 0.03 0.08 parts of xanthans, 0.5 1 parts of sodium alginate, sodium ethylene diamine tetracetate or 2 10 parts of ethylenediamine tetra-acetic acid or sodium citrate, 0.1 1 parts of triethanolamine, 40 50 parts of water.The beneficial effects of the invention are as follows：Any poisonous and harmful substance is not generated in production and use; in the experiment of the skin contacts such as hand, face; skin is reacted without any discomfort; experiment of gargling is proved to human body mucosal tissue without the extremely low corrosivity of any damage; residue after holding vessel, fire fighting device and item to be protected are put out a fire is not damaged to be highly susceptible to clearing up; it can voluntarily degrade, be particularly applicable to protect oil, chemical product.
Description
Technical field
The present invention relates to fire-fighting fire extinguishing fields, and in particular to a kind of fire-extinguishing chemical.
Background technology
What fire foam can put out a fire to save life and property flammable flammable liquid has efficient fire-extinguishing chemical, it is mainly in liquid surface generation cohesion
Floatation of foam layer plays asphyxia and cooling effect.Fire foam is divided into chemical foam, air foam, fluoroprotein foam, MJPZ
Foam and water-resistant foam etc., it is applied widely.
Fire foam is medicament miscible with water, being put out a fire by mechanism or chemical reaction generation foam.Bubble
Foam extinguishing agent is generally made of foaming agent, foam stabiliser, visbreaking agent, antifreeze, cosolvent, preservative and water.It is mainly used for
It puts out a fire to save life and property water-insoluble flammable liquid and general solid fire.Special fire foam can also put out water-soluble burnable liquid fire
Calamity.
Extinguishing chemical on the market possesses higher corrosivity at present, shortens the physical life of fire-fighting equipment indirectly, puts out a fire
While to fire extinguishing object generate corrosivity, human body contacts extinguishing chemical accidentally can also have a negative impact.
The content of the invention
In view of this, it is an object of the invention to provide one kind：Low toxicity, low-corrosiveness, degradable fire-extinguishing chemical.
To achieve these goals, the technical solution adopted by the present invention one is：A kind of fire-extinguishing chemical, in parts by weight by
Following raw material is made：3-8 parts of fluorinated alkyl glycine betaine, 10-20 parts of fatty alcohol ether succinic acid sodium salt, dodecanamide propyl dimethylamine
15-25 parts of second lactone, 0.5-2.5 parts of organosilicon quaternary ammonium salt, 5-15 parts of empgen BB, the compounding of ethylene glycol and glycerine
40-55 parts, butyl and 5-20 parts of n-butanol compounding, 5-10 parts of urea, 0.03-0.08 parts of xanthans, sodium alginate
0.5-1 parts, sodium ethylene diamine tetracetate or ethylenediamine tetra-acetic acid or 2-10 parts of sodium citrate, 0.1-1 parts of triethanolamine, water 40-50
Part.
Further, it is made in parts by weight of following raw material：7.8 parts of fluorinated alkyl glycine betaine, fatty alcohol ether succinic acid
18 parts of sodium salt, 24.8 parts of dodecanamide propyl decil lactone, 2 parts of organosilicon quaternary ammonium salt, 14 parts of empgen BB, second
40.2 parts of the compounding of glycol and glycerine, butyl and 5.6 parts of n-butanol compounding, 5.6 parts of urea, xanthans 0.03
Part, 0.5 part of sodium alginate, 2.1 parts of sodium ethylene diamine tetracetate, 0.2 part of triethanolamine, 41 parts of water.
Further, it is made in parts by weight of following raw material：5.4 parts of fluorinated alkyl glycine betaine, fatty alcohol ether succinic acid
15 parts of sodium salt, 20.2 parts of dodecanamide propyl decil lactone, 1.5 parts of organosilicon quaternary ammonium salt, 10 parts of empgen BB,
50 parts of the compounding of ethylene glycol and glycerine, butyl and 12 parts of n-butanol compounding, 7 parts of urea, 0.05 part of xanthans, sea
0.75 part of mosanom, 6 parts of ethylenediamine tetra-acetic acid, 0.5 part of triethanolamine, 45 parts of water.
Further, it is made in parts by weight of following raw material：3.1 parts of fluorinated alkyl glycine betaine, fatty alcohol ether succinic acid
10.2 parts of sodium salt, 15.3 parts of dodecanamide propyl decil lactone, 0.51 part of organosilicon quaternary ammonium salt, empgen BB
5.2 parts, 55 parts of the compounding of ethylene glycol and glycerine, butyl and n-butanol compound 19.5 parts, 9.5 parts of urea, xanthan
0.08 part of glue, 1 part of sodium alginate, 9.9 parts of sodium citrate, 1 part of triethanolamine, 49 parts of water.
The key ideas of above-mentioned technical proposal one is：Selected extinguishing chemical synthesis material is less toxic or nontoxic, without corruption
The natural extract of corrosion or the compound good to skin low irritant, biological degradability, while select ethylene glycol and glycerine
Compounding as antifreeze, not only ensured the anti-freezing property of extinguishing chemical, but also reduced the corrosivity of extinguishing chemical.
The advantageous effect of above-mentioned technical proposal one is：Any poisonous and harmful substance, hand, face etc. are not generated in production and use
In skin contact experiment, skin is reacted without any discomfort, and experiment of gargling proves extremely low without any damage to human body mucosal tissue
Corrosivity does not damage residue after holding vessel, fire fighting device and item to be protected are put out a fire and is highly susceptible to clearing up, can voluntarily degrade,
It is particularly applicable to protect oil, chemical product.
To achieve these goals, the technical solution adopted by the present invention two is：A kind of preparation method of fire-extinguishing chemical, bag
Include following steps：
Step 1: weigh fluorinated alkyl glycine betaine, fatty alcohol ether succinic acid sodium salt, dodecanamide propyl dimethylamine by above-mentioned weight
Second lactone, empgen BB, urea, xanthans, sodium alginate, sodium ethylene diamine tetracetate or ethylenediamine tetra-acetic acid or lemon
Sour sodium, stirs evenly in mixer, and mixer rotating speed is 2200-2400 revs/min；
Step 2: compounding, butyl and n-butanol that ethylene glycol or ethylene glycol and glycerine are weighed by above-mentioned weight are answered
Match somebody with somebody, triethanolamine, water, add in reaction kettle and stir evenly, then mixture made from addition step 1 is stirred well to completely
Fire-extinguishing chemical is made in dissolving.
The key ideas of above-mentioned technical proposal two is：After above-mentioned solid feed is sufficiently mixed stirring, it is then added to
It is uniformly mixed in liquid material through fully merging, reaction speed is fast, and production efficiency is high.
The advantageous effect of above-mentioned technical proposal two is：Do not generate any poisonous and harmful substance in production process, easy to operate,
Safety, production is efficient, and finished product yields is high.
Specific embodiment
With reference to specific embodiment, that the present invention is described further is as follows：
Embodiment one：
Step 1: weigh 7.8 parts of fluorinated alkyl glycine betaine, 18 parts of fatty alcohol ether succinic acid sodium salt, dodecanamide propyl dimethylamine
24.8 parts of second lactone, 2 parts of organosilicon quaternary ammonium salt, 14 parts of empgen BB, 5.6 parts of urea, 0.03 part of xanthans, alginic acid
0.5 part of sodium, 2.1 parts of sodium ethylene diamine tetracetate, stir evenly in mixer, and mixer rotating speed is 2400 revs/min；
Step 2: weigh 40.2 parts of compounding, butyl or n-butanol or the two compounding 5.6 of ethylene glycol and glycerine
Part, 0.2 part of triethanolamine, 41 parts of water are added in reaction kettle and stirred evenly, and then mixture made from addition step 1 fully stirs
It mixes to being completely dissolved obtained fire-extinguishing chemical.
Apply example two：
Step 1: weigh 5.4 parts of fluorinated alkyl glycine betaine, 15 parts of fatty alcohol ether succinic acid sodium salt, dodecanamide propyl dimethylamine
20.2 parts of second lactone, 1.5 parts of organosilicon quaternary ammonium salt, 10 parts of empgen BB, 7 parts of urea, 0.05 part of xanthans, alginic acid
0.75 part of sodium, 6 parts of ethylenediamine tetra-acetic acid, stir evenly in mixer, and mixer rotating speed is 2300 revs/min；
Step 2: weighing 50 parts of the compounding of ethylene glycol and glycerine, butyl and n-butanol compounds 12 parts, triethanolamine
0.5 part, 45 parts of water are added in reaction kettle and stirred evenly, and then mixture made from addition step 1 is stirred well to completely molten
Fire-extinguishing chemical is made in solution.
Apply example three：
Step 1: weigh 3.1 parts of fluorinated alkyl glycine betaine, 10.2 parts of fatty alcohol ether succinic acid sodium salt, dodecanamide propyl diformazan
15.3 parts of amine second lactone, 0.51 part of organosilicon quaternary ammonium salt, 5.2 parts of empgen BB, 9.5 parts of urea, 0.08 part of xanthans,
1 part of sodium alginate, 9.9 parts of sodium citrate, stir evenly in mixer, and mixer rotating speed is 2200 revs/min；
Step 2: weighing 55 parts of the compounding of ethylene glycol and glycerine, butyl and n-butanol compounds 19.5 parts, three ethyl alcohol
1 part of amine, 49 parts of water are added in reaction kettle and stirred evenly, and then mixture made from addition step 1 is stirred well to completely molten
Fire-extinguishing chemical is made in solution.
The fire-extinguishing chemical product characteristic of the present invention is as follows obtained by above-described embodiment 1-3：
| Skin irritation | Solidification point DEG C | Coefficient of foaming | PH value | Degradation time h | |
| Embodiment 1 | Subexcite | -38 | 7.8 | 7.2 | 30 |
| Embodiment 2 | It is nonirritant | -42 | 7.2 | 7.3 | 29 |
| Embodiment 3 | It is nonirritant | -45 | 6.6 | 7.1 | 28 |
The present invention is described by above-mentioned related embodiment, however above-described embodiment is only the example for implementing the present invention.
It must be noted that the embodiment disclosed is not limiting as the scope of the present invention.On the contrary, be included in claim spirit and
The modification of scope and impartial setting are included in the scope of the present invention.
Claims (5)
1. a kind of fire-extinguishing chemical, which is characterized in that be made in parts by weight of following raw material：3-8 parts of fluorinated alkyl glycine betaine,
10-20 parts of fatty alcohol ether succinic acid sodium salt, 15-25 parts of dodecanamide propyl decil lactone, organosilicon quaternary ammonium salt 0.5-2.5
Part, 40-55 parts of the compounding of 5-15 parts of empgen BB, ethylene glycol and glycerine, butyl and n-butanol compound
5-20 parts, 5-10 parts of urea, 0.03-0.08 parts of xanthans, 0.5-1 parts of sodium alginate, sodium ethylene diamine tetracetate or ethylenediamine tetraacetic
Acetic acid or 2-10 parts of sodium citrate, 0.1-1 parts of triethanolamine, 40-50 parts of water.
2. a kind of fire-extinguishing chemical according to claim 1, which is characterized in that be made in parts by weight of following raw material：
7.8 parts of fluorinated alkyl glycine betaine, 18 parts of fatty alcohol ether succinic acid sodium salt, have 24.8 parts of dodecanamide propyl decil lactone
2 parts of machine silicon quaternary ammonium salt, 14 parts of empgen BB, 40.2 parts of the compounding of ethylene glycol and glycerine, butyl with just
5.6 parts of butanol compounding, 5.6 parts of urea, 0.03 part of xanthans, 0.5 part of sodium alginate, 2.1 parts of sodium ethylene diamine tetracetate, three ethyl alcohol
0.2 part of amine, 41 parts of water.
3. a kind of fire-extinguishing chemical according to claim 1, which is characterized in that be made in parts by weight of following raw material：
5.4 parts of fluorinated alkyl glycine betaine, 15 parts of fatty alcohol ether succinic acid sodium salt, have 20.2 parts of dodecanamide propyl decil lactone
1.5 parts of machine silicon quaternary ammonium salt, 10 parts of empgen BB, 50 parts of the compounding of ethylene glycol and glycerine, butyl with just
12 parts of butanol compounding, 7 parts of urea, 0.05 part of xanthans, 0.75 part of sodium alginate, 6 parts of ethylenediamine tetra-acetic acid, triethanolamine 0.5
Part, 45 parts of water.
4. a kind of fire-extinguishing chemical according to claim 1, which is characterized in that be made in parts by weight of following raw material：
3.1 parts of fluorinated alkyl glycine betaine, 10.2 parts of fatty alcohol ether succinic acid sodium salt, 15.3 parts of dodecanamide propyl decil lactone,
0.51 part of organosilicon quaternary ammonium salt, 5.2 parts of empgen BB, 55 parts of compounding, the butyl of ethylene glycol and glycerine
With 19.5 parts of n-butanol compounding, 9.5 parts of urea, 0.08 part of xanthans, 1 part of sodium alginate, 9.9 parts of sodium citrate, triethanolamine 1
Part, 49 parts of water.
A kind of 5. preparation method of fire-extinguishing chemical according to claim 1-4 any claims, which is characterized in that bag
Include following steps：
Step 1: weigh fluorinated alkyl glycine betaine, fatty alcohol ether succinic acid sodium salt, dodecanamide propyl dimethylamine by above-mentioned weight
Second lactone, empgen BB, urea, xanthans, sodium alginate, sodium ethylene diamine tetracetate or ethylenediamine tetra-acetic acid or lemon
Sour sodium, stirs evenly in mixer, and mixer rotating speed is 2200-2400 revs/min；
Step 2: compounding, butyl and n-butanol that ethylene glycol or ethylene glycol and glycerine are weighed by above-mentioned weight are answered
Match somebody with somebody, triethanolamine, water, add in reaction kettle and stir evenly, then mixture made from addition step 1 is stirred well to completely
Fire-extinguishing chemical is made in dissolving.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711167897.7A CN108042966A (en) | 2017-11-21 | 2017-11-21 | A kind of fire-extinguishing chemical |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711167897.7A CN108042966A (en) | 2017-11-21 | 2017-11-21 | A kind of fire-extinguishing chemical |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108042966A true CN108042966A (en) | 2018-05-18 |
Family
ID=62120220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711167897.7A Pending CN108042966A (en) | 2017-11-21 | 2017-11-21 | A kind of fire-extinguishing chemical |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108042966A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023235454A1 (en) * | 2022-06-02 | 2023-12-07 | Tyco Fire Products Lp | High speed wetting agents for thermal control of li-ion hazards |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1413749A (en) * | 2002-12-04 | 2003-04-30 | 中国石油化工股份有限公司 | Foam extingusher with covering function |
| WO2007030982A1 (en) * | 2005-09-15 | 2007-03-22 | Onid Technology (Shanghai) Corporation | Highly active (hydr) oxide aqueous sol-gel fire extinguishing agent and the application thereof |
| CN102886114A (en) * | 2012-11-07 | 2013-01-23 | 公安部天津消防研究所 | General A-type foam extinguishing agent easy to degrade |
| CN105363164A (en) * | 2015-11-24 | 2016-03-02 | 中国民用航空飞行学院 | Hazardous chemical substance fire-fighting foam fire extinguishing agent formula and preparation method of hazardous chemical substance fire-fighting foam fire extinguishing agent |
-
2017
- 2017-11-21 CN CN201711167897.7A patent/CN108042966A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1413749A (en) * | 2002-12-04 | 2003-04-30 | 中国石油化工股份有限公司 | Foam extingusher with covering function |
| WO2007030982A1 (en) * | 2005-09-15 | 2007-03-22 | Onid Technology (Shanghai) Corporation | Highly active (hydr) oxide aqueous sol-gel fire extinguishing agent and the application thereof |
| CN102886114A (en) * | 2012-11-07 | 2013-01-23 | 公安部天津消防研究所 | General A-type foam extinguishing agent easy to degrade |
| CN105363164A (en) * | 2015-11-24 | 2016-03-02 | 中国民用航空飞行学院 | Hazardous chemical substance fire-fighting foam fire extinguishing agent formula and preparation method of hazardous chemical substance fire-fighting foam fire extinguishing agent |
Non-Patent Citations (1)
| Title |
|---|
| 杨亮等: "《灭火剂与其标准化》", 31 January 2015, 科学技术文献出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023235454A1 (en) * | 2022-06-02 | 2023-12-07 | Tyco Fire Products Lp | High speed wetting agents for thermal control of li-ion hazards |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106075792B (en) | A kind of efficient and environment-friendly type fire foam and preparation method thereof | |
| WO2005057588A2 (en) | Granulated decontamination formulations | |
| CN108530691A (en) | A kind of degradable biological polysaccharide lotion mulch and preparation method thereof | |
| CN113088260A (en) | Efficient environment-friendly degradable dust suppressant with quick sterilization effect and preparation method thereof | |
| EP4337343A1 (en) | Fire-fighting foam composition | |
| CN108042966A (en) | A kind of fire-extinguishing chemical | |
| CN107715363A (en) | A kind of environment-friendly type water-based extinguishing agent | |
| CN107648786A (en) | Water-based extinguishing agent | |
| CN107899173A (en) | A kind of alcohol foam extinguishing chemical of continuous-stable | |
| CN108014442A (en) | A kind of lithium battery extinguishing chemical | |
| CN104403674B (en) | Soil conditioner for adjusting soil physical and chemical property and preparation method thereof | |
| CN103725400B (en) | A kind of water base environmental protection cutting fluid and preparation method thereof | |
| CN108865509A (en) | A kind of environmental-friendly plant automobile cleaning agent | |
| CN102165959A (en) | Glyphosate environment-friendly aqueous agent using biodiesel as synergist | |
| CN114590918A (en) | Technical principle for blue algae treatment and application method thereof | |
| KR101263571B1 (en) | Composition for action of fire-extinguishing and Peparing method thereof | |
| BR0306796A (en) | alkylglycol alkoxylate or alkyldiglycol alkoxylate, mixing and use of C 4-8-alkyl-glycols or -diglycol C 2-5-alkoxylates, washing, cleaning or humidifying or cosmetic agents, pharmaceutical or crop protection formulations, and, inks, color formulations, for spray applications, coating agent, adhesive, for leather, metal and textile treatment, flotation and foaming aids, and humectant | |
| AR040878A1 (en) | AGENTS WITH CARBOXYL ACID CONTENT AND ITS USE IN CROP PLANTS | |
| CN114796965B (en) | Environment-friendly fluorine-containing water film-forming fire extinguishing agent and preparation method and application thereof | |
| CN106492393B (en) | Fire extinguishing agent, preparation method and application thereof | |
| WO2023067444A1 (en) | Fire-fighting foam composition | |
| CN108641829A (en) | A kind of radioactive element scavenger and preparation method thereof and the application in aerosol | |
| CN108069784A (en) | A kind of special disease-preventing and yield-increasing selenium-rich Foliage Absorption nutrient solution of rice and preparation method thereof | |
| CN106492394B (en) | Fire extinguishing agent, preparation method and application thereof | |
| CN112772669A (en) | Iprodione and procymidone suspending agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180518 |
|
| WD01 | Invention patent application deemed withdrawn after publication |