CN108034524A - Foam cleaning agent and foaming detergent device - Google Patents
Foam cleaning agent and foaming detergent device Download PDFInfo
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- CN108034524A CN108034524A CN201711366657.XA CN201711366657A CN108034524A CN 108034524 A CN108034524 A CN 108034524A CN 201711366657 A CN201711366657 A CN 201711366657A CN 108034524 A CN108034524 A CN 108034524A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/181—Hydrocarbons linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/185—Hydrocarbons cyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The invention discloses foaming cleaning agent and foaming detergent device.The foaming cleaning agent includes the component of following parts by weight:0.5 4 parts of sodium benzoate, 0.05 0.5 parts of benzotriazole, 0.2 2 parts of EDTA 4Na, 0.5 5 parts of quaternary surfactant, cation, 0.1 2 parts of surfactant, 15 parts of JFC bleeding agents, 0.1 2 parts of foaming agent, 70 90 parts of deionized water, 7 12 parts of the absolute ethyl alcohol of nonionic compounding;The foaming agent is the one or several kinds in pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane;The detergent device that foams include spray cans, load in the spray cans as 5 any one of them of claim 1 foams cleaning agent and propellant, the propellant be butane, and the weight ratio of the propellant and the foaming cleaning agent is 1:25‑15.Foaming cleaning agent of the present invention, it is strong to come into full contact with spot, dirt-removing power.
Description
Technical field
The present invention relates to cleaning agent technical field, and in particular to foaming cleaning agent and foaming detergent device.
Background technology
Industry cleaning link has not simply pulled on the fast development in every profession and trade field, has brought huge economy as new industry
With social benefit, and life, the quality of working environment are improved.Wherein industrial cleaning agent is as very important fine chemistry industry
Product, plays the important and pivotal role.
Aqueous cleaning agent is as one of industrial cleaning agent three major types unlike oil base cleaning agent and semi-aqueous cleaning agent are because containing
The volatile explosive material of machine and bring security risk, it is mainly made of water, surfactant, auxiliary agent etc., have application it is wide,
Of low cost, the advantages that operating type is various, thus using more and more extensive.
Aerosol-type aqueous cleaning agent product is to be fabricated to cleaning agent liquid, sprays out to form foam-like, is used
It is convenient, it is easy to operate, it is widely used in the fields such as automobile washing, kitchen cleaning, cleaning air conditioner, is increasingly subject to the green grass or young crops by user
Look at.
But there is also shortcoming for aerosol-type aqueous cleaning agent:Aerosol products gush out, and foam is excessively abundant, some health
Dead angle, fine crack crack or pipeline internal washing agent foam penetration are not entered, and foam surface decontamination active matter can not be with polluting table
Face acts on, and causes less cleaning position or unclean etc., and for those crust tough stains, especially deposit dust and
The defects of mixed dirt of greasy dirt, existing cleaning agent generally existing cleaning force are inadequate.
The content of the invention
Based on this, present invention offer is a kind of to come into full contact with the strong foaming cleaning agent of spot, dirt-removing power.
The present invention also provides one kind foaming detergent device.
In order to achieve the object of the present invention, the present invention uses following technical scheme:
One kind foaming cleaning agent, it includes the component of following parts by weight:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface-active
0.5-5 parts of agent, cation, nonionic compounding 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent,
70-90 parts of deionized water, 7-12 parts of absolute ethyl alcohol;The foaming agent is pentane ex hoc genus anne isomers, dimethoxym ethane, methyl ring penta
One or several kinds in alkane.
Above-mentioned foaming cleaning agent, the surfactant compounded, through experiment, can rapidly remove various greasy dirts,
Strengthen cleaning capacity;Different boiling blowing agent combination so that spray liquid energy enough stabilizations and constantly foam, expand active matter and dirt
Contact area, dirty dust and greasy dirt are brought out, further strengthen cleaning capacity;The cleaning agent is not all of steeping after spraying
Foam, liquid accounting is larger, is capable of the dirt face in the sufficiently various dead angles of wetting contact, gap, then foams again, strengthens decontamination energy
Power.
In some of embodiments, the foaming cleaning agent, includes the components of following parts by weight:Sodium benzoate 0.5-4
Part, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, 0.5-5 parts of quaternary surfactant, cation, it is non-from
It is 0.1-2 parts of the surfactant of son compounding, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent, 70-90 parts of deionized water, anhydrous
It is 6-10 parts of ethanol, plain boiled water 1-2 parts anti-;The foaming agent is one in pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane
Kind is several.
In some of embodiments, the foaming cleaning agent, further includes the components of following parts by weight:1-5 parts of organic base.
In some of embodiments, the organic base is triethanolamine.
In some of embodiments, the foaming cleaning agent, includes the components of following parts by weight:1.5 parts of sodium benzoate,
0.1 part of benzotriazole, 0.5 part of EDTA-4Na, 3 parts of quaternary surfactant, cation, the surface of nonionic compounding are lived
1 part of agent of property, 2 parts of JFC bleeding agents, 1 part of methyl cyclopentane foaming agent, 78.4 parts of deionized water, 8 parts of absolute ethyl alcohol, anti-plain boiled water 1.5
Part.
The present invention also adopts the following technical scheme that:
One kind foaming detergent device, it include spray cans, in the loading spray cans as described in claim any one of 1-5
Foaming cleaning agent and propellant, the propellant is butane, and the weight ratio of the propellant and the foaming cleaning agent is 1:
25-15。
Above-mentioned foaming detergent device, using the butane of low pressure as propellant, and strictly controls the ratio of propellant,
So that the device ejecta is essentially liquid, it is capable of the dirt face in the sufficiently various dead angles of wetting contact, gap.
In some of embodiments, the preparation method of the foaming detergent device is:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface are provided
0.5-5 parts of activating agent, cation, 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, the foaming agent 0.1-2 of nonionic compounding
Part, 70-90 parts of deionized water, 7-12 parts of absolute ethyl alcohol;The foaming agent is pentane ex hoc genus anne isomers, dimethoxym ethane, methyl
One or several kinds in pentamethylene;
Take sodium benzoate, benzotriazole and EDTA-4Na to add in absolute ethyl alcohol, be stirred, form the first mixing
Thing;
Quaternary surfactant, cation, the surfactant of nonionic compounding and JFC bleeding agents is taken to add deionization
In water, stir evenly, form the second mixture;
First mixture and the second mixture are mixed and stirred for uniformly, to form the 3rd mixture;
3rd mixture is loaded in the spray cans, then adds the foaming agent;
In the spray cans plus valve, sealing, the propellant is finally filled with.
In some of embodiments, the preparation method of the foaming detergent device is:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface are provided
0.5-5 parts of activating agent, cation, 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, the foaming agent 0.1-2 of nonionic compounding
It is part, 70-90 parts of deionized water, 6-10 parts of absolute ethyl alcohol, plain boiled water 1-2 parts anti-;The foaming agent is pentane ex hoc genus anne isomery
One or several kinds in body, dimethoxym ethane, methyl cyclopentane;
Take sodium benzoate, benzotriazole and EDTA-4Na to add in absolute ethyl alcohol, be stirred, form the first mixing
Thing;
Quaternary surfactant, cation, the surfactant of nonionic compounding and JFC bleeding agents is taken to add deionization
Water forms the second mixture with the mixed liquor of anti-plain boiled water, stirring evenly;
First mixture and the second mixture are mixed and stirred for uniformly, to form the 3rd mixture;
3rd mixture is loaded in the spray cans, then adds the foaming agent;
In the spray cans plus valve, sealing, the propellant is finally filled with.
In some of embodiments, the preparation method of the foaming detergent device, is also provided with 1-5 parts of machine alkali, by institute
State organic base to add in the 3rd mixture, adjust pH value to 9-10.
In some of embodiments, the spray cans is tinplate spray cans.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But the present invention can be with perhaps
More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make
Understanding more thorough and comprehensive to the disclosure.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention
The normally understood implication of technical staff is identical.Term used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
Foaming cleaning agent of the present invention, the spot for every field clean.
The foaming cleaning agent, it includes the component of following parts by weight:0.5-4 parts of sodium benzoate, benzotriazole
0.05-0.5 parts, the surface work of 0.2-2 parts of EDTA-4Na, 0.5-5 parts of quaternary surfactant, cation, nonionic compounding
0.1-2 parts of agent of property, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent, 70-90 parts of deionized water, 7-12 parts of absolute ethyl alcohol;Wherein
Foaming agent be the one or several kinds in pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane.
Further, the foaming cleaning agent, includes the component of following parts by weight:0.5-4 parts of sodium benzoate, benzene a pair of horses going side by side three
0.05-0.5 parts of nitrogen azoles, 0.2-2 parts of EDTA-4Na, 0.5-5 parts of quaternary surfactant, cation, the table of nonionic compounding
Activating agent 0.1-2 parts of face, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent, 70-90 parts of deionized water, 6-10 parts of absolute ethyl alcohol,
Anti- plain boiled water 1-2 parts;The foaming agent is the one or several kinds in pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane.
Further, the foaming cleaning agent, further includes the component of following parts by weight:1-5 parts of organic base.The organic base
Preferably triethanolamine.Organic base is used for the pH value for adjusting cleaning agent so that cleaning agent acid-base value is in OK range, to be applicable in
In more fields.
The surfactant that quaternary surfactant is compounded with cation, nonionic is collocated with each other use, can not only
It is efficient to remove animal and plant fat greasy dirt, also efficiently remove ore grease greasy dirt.And there is low foaming performance, for it most
The wetting of limits and penetrated soil reduce resistance.
Using fatty alcohol polyethenoxy ether class nonionic penetrant, that is, JFC bleeding agents, coordinate with surfactant, can make molten
Liquid surface tension is remarkably decreased, and considerably increases wetting and the osmosis of solution.
One or several kinds of materials of pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane are selected as foaming agent,
Such boiling point substance is not not high low, between 10 DEG C~70 DEG C degrees Celsius, closest environment temperature.And several different boilings
The combination of foaming agent, can make foaming agent volatilization period, successional generation, and foaming effect can become more persistently, efficiently.
In conclusion above-mentioned foaming cleaning agent, the surfactant compounded, through experiment, can rapidly remove
Various greasy dirts, strengthen cleaning capacity;Different boiling blowing agent combination so that spray liquid energy enough stabilizations and constantly foam, expand and live
The contact area of property thing and dirt, dirty dust and greasy dirt are brought out, further strengthen cleaning capacity;After cleaning agent ejection not
It is whole foams, liquid accounting is larger, is capable of the dirt face in the sufficiently various dead angles of wetting contact, gap, strengthens dirt-removing power.
Above-mentioned foaming cleaning agent, can also add the auxiliary agents such as defoamer.
In some of embodiments, the foaming cleaning agent, includes the components of following parts by weight:1.5 parts of sodium benzoate,
0.1 part of benzotriazole, 0.5 part of EDTA-4Na, 3 parts of quaternary surfactant, cation, the surface of nonionic compounding are lived
1 part of agent of property, 2 parts of JFC bleeding agents, 1 part of methyl cyclopentane foaming agent, 78.4 parts of deionized water, 8 parts of absolute ethyl alcohol, anti-plain boiled water 1.5
Part.
Using the foaming detergent device of above-mentioned foaming cleaning agent, it includes spray cans, loads the spray for the present invention also protection
Foaming cleaning agent and propellant in tank, the propellant are butane, and the weight ratio of propellant and foaming cleaning agent is 1:25-15.
Spray cans is tinplate inhalator jar.Using the butane of low pressure as propellant, and strictly control the ratio of propellant so that the device
Ejecta is essentially liquid, is capable of the dirt face in the sufficiently various dead angles of wetting contact, gap.
It is described foaming detergent device preparation method be:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface are provided
0.5-5 parts of activating agent, cation, 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, the foaming agent 0.1-2 of nonionic compounding
Part, 70-90 parts of deionized water, 7-12 parts of absolute ethyl alcohol;The foaming agent is pentane ex hoc genus anne isomers, dimethoxym ethane, methyl
One or several kinds in pentamethylene;
Take sodium benzoate, benzotriazole and EDTA-4Na to add in absolute ethyl alcohol, be stirred, form the first mixing
Thing;
Quaternary surfactant, cation, the surfactant of nonionic compounding and JFC bleeding agents is taken to add deionization
In water, stir evenly, form the second mixture;
First mixture and the second mixture are mixed and stirred for uniformly, to form the 3rd mixture;
3rd mixture is loaded in the spray cans, then adds the foaming agent;
In the spray cans plus valve, sealing, the propellant is finally filled with.
Alternatively, the preparation method of the foaming detergent device is:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface are provided
0.5-5 parts of activating agent, cation, 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, the foaming agent 0.1-2 of nonionic compounding
It is part, 70-90 parts of deionized water, 6-10 parts of absolute ethyl alcohol, plain boiled water 1-2 parts anti-;The foaming agent is pentane ex hoc genus anne isomery
One or several kinds in body, dimethoxym ethane, methyl cyclopentane;
Take sodium benzoate, benzotriazole and EDTA-4Na to add in absolute ethyl alcohol, be stirred, form the first mixing
Thing;
Quaternary surfactant, cation, the surfactant of nonionic compounding and JFC bleeding agents is taken to add deionization
Water forms the second mixture with the mixed liquor of anti-plain boiled water, stirring evenly;
First mixture and the second mixture are mixed and stirred for uniformly, to form the 3rd mixture;
3rd mixture is loaded in the spray cans, then adds the foaming agent;
In the spray cans plus valve, sealing, the propellant is finally filled with.
In some of embodiments, the preparation method of above-mentioned foaming detergent device, is also provided with 1-5 parts of machine alkali, by institute
State organic base to add in the 3rd mixture, adjust pH value to 9-10.
Spray cans therein is preferably tinplate spray cans.
The implementation of the present invention will be further illustrated by several embodiments below.
Embodiment one
Foaming cleaning agent described in the embodiment of the present invention, is made of the component of following parts by weight:1.5 parts of sodium benzoate, benzene
Parallel 0.1 part of triazole, 0.5 part of EDTA-4Na, 3 parts of quaternary surfactant, cation, the surface-active of nonionic compounding
1 part of agent, 2 parts of JFC bleeding agents, 1 part of methyl cyclopentane foaming agent, 78.4 parts of deionized water, 8 parts of absolute ethyl alcohol, anti-plain boiled water 1.5
Part.
Above-mentioned foaming cleaning agent, its preparation method are:Sodium benzoate, benzotriazole and EDTA-4Na is taken to add nothing
In water-ethanol, it is stirred, forms the first mixture;Quaternary surfactant, cation, the surface of nonionic compounding is taken to live
Property agent and JFC bleeding agents add in the mixed liquor of deionized water and anti-plain boiled water, stir evenly, form the second mixture;By first
Mixture and the second mixture are mixed and stirred for uniformly, forming the 3rd mixture;Foaming agent is taken to add in the 3rd mixture, stirring
Uniformly, the foaming cleaning agent is obtained, triethanolamine is then added and adjusts the pH value of the foaming cleaning agent to 9-10.
Using the foaming detergent device of above-mentioned foaming cleaning agent, including spray cans, load foaming cleaning agent in spray cans and
Propellant, the propellant are butane, and the weight ratio of propellant and foaming cleaning agent is 1:20.
The preparation method of the foaming detergent device is:First the 3rd mixture is loaded in spray cans, is then charged into foaming agent,
Plus valve, sealing in spray cans, propellant is finally filled with.
Embodiment two
Foaming cleaning agent described in the embodiment of the present invention, is made of the component of following parts by weight:0.5 part of sodium benzoate, benzene
Parallel 0.05 part of triazole, 0.2 part of EDTA-4Na, 0.5 part of quaternary surfactant, cation, the surface of nonionic compounding are lived
0.1 part of agent of property, 1 part of JFC bleeding agents, 0.1 part of methyl cyclopentane foaming agent, 70 parts of deionized water, 6 parts of absolute ethyl alcohol, anti-plain boiled water 1
Part.
Above-mentioned foaming cleaning agent, its preparation method are:Sodium benzoate, benzotriazole and EDTA-4Na is taken to add nothing
In water-ethanol, it is stirred, forms the first mixture;Quaternary surfactant, cation, the surface of nonionic compounding is taken to live
Property agent and JFC bleeding agents add in the mixed liquor of deionized water and anti-plain boiled water, stir evenly, form the second mixture;By first
Mixture and the second mixture are mixed and stirred for uniformly, forming the 3rd mixture;Foaming agent is taken to add in the 3rd mixture, stirring
Uniformly, the foaming cleaning agent is obtained, triethanolamine is then added and adjusts the pH value of the foaming cleaning agent to 9-10.
Using the foaming detergent device of above-mentioned foaming cleaning agent, including spray cans, load foaming cleaning agent in spray cans and
Propellant, the propellant are butane, and the weight ratio of propellant and foaming cleaning agent is 1:15.
The preparation method of the foaming detergent device is:First the 3rd mixture is loaded in spray cans, is then charged into foaming agent,
Plus valve, sealing in spray cans, propellant is finally filled with.
Embodiment three
Foaming cleaning agent described in the embodiment of the present invention, is made of the component of following parts by weight:4 parts of sodium benzoate, benzene a pair of horses going side by side
0.5 part of triazole, 2 parts of EDTA-4Na, 5 parts of quaternary surfactant, cation, the surfactant 2 of nonionic compounding
Part, 5 parts of JFC bleeding agents, 2 parts of dimethoxym ethane foaming agent, 90 parts of deionized water, 10 parts of absolute ethyl alcohol, 2 parts of anti-plain boiled water.
Above-mentioned foaming cleaning agent, its preparation method are:Sodium benzoate, benzotriazole and EDTA-4Na is taken to add nothing
In water-ethanol, it is stirred, forms the first mixture;Quaternary surfactant, cation, the surface of nonionic compounding is taken to live
Property agent and JFC bleeding agents add in the mixed liquor of deionized water and anti-plain boiled water, stir evenly, form the second mixture;By first
Mixture and the second mixture are mixed and stirred for uniformly, forming the 3rd mixture;Foaming agent is taken to add in the 3rd mixture, stirring
Uniformly, the foaming cleaning agent is obtained, triethanolamine is then added and adjusts the pH value of the foaming cleaning agent to 9-10.
Using the foaming detergent device of above-mentioned foaming cleaning agent, including spray cans, load foaming cleaning agent in spray cans and
Propellant, the propellant are butane, and the weight ratio of propellant and foaming cleaning agent is 1:25.
The preparation method of the foaming detergent device is:First the 3rd mixture is loaded in spray cans, is then charged into foaming agent,
Plus valve, sealing in spray cans, propellant is finally filled with.
Example IV
Foaming cleaning agent described in the embodiment of the present invention, is made of the component of following parts by weight:2.5 parts of sodium benzoate, benzene
Parallel 0.4 part of triazole, 1.5 parts of EDTA-4Na, 3 parts of quaternary surfactant, cation, the surface-active of nonionic compounding
1.2 parts of agent, 3 parts of JFC bleeding agents, 1.5 parts of foaming agent, 88 parts of deionized water, 7 parts of absolute ethyl alcohol.
Above-mentioned foaming cleaning agent, its preparation method are:Sodium benzoate, benzotriazole and EDTA-4Na is taken to add nothing
In water-ethanol, it is stirred, forms the first mixture;Quaternary surfactant, cation, the surface of nonionic compounding is taken to live
Property agent and JFC bleeding agents add deionized water in, stir evenly, formed the second mixture;First mixture is mixed with second
Thing is mixed and stirred for uniformly, forming the 3rd mixture;Take foaming agent to add in the 3rd mixture, stir evenly, obtain the hair
Cleaning agent is steeped, triethanolamine is then added and adjusts the pH value of the foaming cleaning agent to 9-10.
Using the foaming detergent device of above-mentioned foaming cleaning agent, including spray cans, load foaming cleaning agent in spray cans and
Propellant, the propellant are butane, and the weight ratio of propellant and foaming cleaning agent is 1:20.
The preparation method of the foaming detergent device is:First the 3rd mixture is loaded in spray cans, is then charged into foaming agent,
Plus valve, sealing in spray cans, propellant is finally filled with.
Embodiment five
Foaming cleaning agent described in the embodiment of the present invention, is made of the component of following parts by weight:1 part of sodium benzoate, benzene a pair of horses going side by side
0.3 part of triazole, 0.25 part of EDTA-4Na, 2 parts of quaternary surfactant, cation, the surfactant of nonionic compounding
1.4 parts, 2 parts of JFC bleeding agents, 1 part of foaming agent, 78 parts of deionized water, 12 parts of absolute ethyl alcohol.
Above-mentioned foaming cleaning agent, its preparation method are:Sodium benzoate, benzotriazole and EDTA-4Na is taken to add nothing
In water-ethanol, it is stirred, forms the first mixture;Quaternary surfactant, cation, the surface of nonionic compounding is taken to live
Property agent and JFC bleeding agents add deionized water in, stir evenly, formed the second mixture;First mixture is mixed with second
Thing is mixed and stirred for uniformly, forming the 3rd mixture;Take foaming agent to add in the 3rd mixture, stir evenly, obtain the hair
Cleaning agent is steeped, triethanolamine is then added and adjusts the pH value of the foaming cleaning agent to 9-10.
Using the foaming detergent device of above-mentioned foaming cleaning agent, including spray cans, load foaming cleaning agent in spray cans and
Propellant, the propellant are butane, and the weight ratio of propellant and foaming cleaning agent is 1:18.
The preparation method of the foaming detergent device is:First the 3rd mixture is loaded in spray cans, is then charged into foaming agent,
Plus valve, sealing in spray cans, propellant is finally filled with.
Embodiment six
The embodiment of the present invention prepares the foaming cleaning agent described in 100g:Take 2g sodium benzoates, 0.05g benzotriazoles,
1gEDTA-4Na is added in 81.45g deionized waters, is stirred evenly;Add 3g quaternary surfactants and 1g cations,
The surfactant of nonionic compounding, stirs evenly;It is eventually adding 3g alcamines organic base, 1.5g bleeding agents, the defoaming of 6g alcohols
Agent, 1g ethers defoamers, stir evenly.After the completion of preparation, pour into can, add 0.3g pentanes, 0.3g isopentane,
0.4g methyl cyclopentanes are as foaming agent;Valve is put into, seals, 7g butane is filled with as propellant, with upper nozzle and jet pipe.
Embodiment seven
The embodiment of the present invention prepares the foaming cleaning agent described in 100g:Take 1g sodium benzoates, 0.15g benzotriazoles,
0.5gEDTA-4Na is added in 80.35g deionized waters, is stirred evenly.Add 1g quaternary surfactants, 1g cations
With surfactant, the 2g alkoxylated alcohols surfactants of nonionic compounding, stir evenly.Being eventually adding 3g alcamines has
Machine alkali, 3g bleeding agents, 8g alcohol defoaming agents, stir evenly.After the completion of preparation, pour into can, add 0.6g methyl rings
Pentane and 0.6g dimethoxym ethanes are as foaming agent;Valve is put into, seals, 5g butane is filled with as propellant, with upper nozzle and jet pipe.
Embodiment eight
The embodiment of the present invention prepares the foaming cleaning agent described in 100g:Parallel three nitrogen of 1.5g sodium benzoates, 0.1g benzene are taken respectively
Azoles, 0.5gEDTA-4Na are added in 77.4g deionized waters, are stirred evenly.Add 3g cations and the table of nonionic compounding
Face activating agent, 3g alkoxylated alcohols surfactants, stir evenly.It is eventually adding 3g alcamines organic base, 2g bleeding agents, 8g
Alcohol defoaming agent, 1.5g ethers defoamers, stir evenly.After the completion of preparation, pour into can, addition 0.4g isopentane,
0.6g methyl cyclopentanes are as foaming agent;Valve is put into, seals, 6g butane is filled with as propellant, with upper nozzle and jet pipe.
Comparative example
A kind of foam type fumes from cleaning agent, it contains following component and each component accounts for the matter of the foam type fumes from cleaning agent
Measuring percentage is:
Surfactant:
Sodium secondary alkyl sulfonate 0.5-8%,
Fatty acid methyl ester sulfonate 0.03-1.5%,
Fatty acid methyl ester ethoxylate 0.1-5%;
Alkaline assistant:
Sodium hydroxide 0.2-2%,
Soda ash 1-15%;
Solvent:
Propandiol butyl ether 1-5%,
Butyl 5-10%,
D- limonenes 0.1-0.5%;
Corrosion inhibiter:
Sodium benzoate 0.1-1%,
Sodium nitrite 0.1-1%;
Propellant:
Liquefied petroleum gas 5-20%,
Dimethyl ether 5-20%;
Moisturizer:
Glycerine 0.5-2%;
Water surplus.
Cleaning effect of the embodiment one to embodiment eight and comparative example will be tested below.
1st, cleaning force
Under the conditions of 25 DEG C, with the frequency of 60 pendulum/min, self-control greasy dirt (gasoline, lithium saponify, soybean oil, carbon black) will be coated
Aluminium test piece or stainless steel test piece, put and wash in the beaker for filling 500ml cleaning agents, pendulum wash after dry.Record test piece before pendulum is washed
Mass M 0, greasy dirt mass M 1, and pendulum wash rear test piece and greasy dirt gross mass M2.Cleaning force W calculation formula:
Test data is shown in Table one.
2nd, surface tension
Using method as defined in GB/T 22237-2008, the BZY-1 full automatic watches of Shanghai Hengping Instrument & Meter Plant are used
Face/interfacial tensimeter measure surface tension Y.
Test data is shown in Table one.
3rd, coefficient of foaming
Under the conditions of 25 DEG C, using the cleaning agent that foams after the aerial fog type prepared, it is some to be directed at the graduated cylinder injection of 100ml,
Record foam stop expansion after volume V1, and after lather collapse liquid volume V2.The calculation formula of coefficient of foaming N:
Test data is shown in Table one.
Table one
It can be seen from table one compared with the prior art, the cleaning dynamics of the foaming cleaning agent described in the embodiment of the present invention are big
It is big to improve, it is especially stronger to the cleaning force of greasy dirt.
Embodiment described above only expresses the several embodiments of the present invention, its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. one kind foaming cleaning agent, it is characterised in that include the component of following parts by weight:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary surfactant
0.5-5 parts, cation, 0.1-2 parts of the surfactant of nonionic compounding, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent, go
70-90 parts of ionized water, 7-12 parts of absolute ethyl alcohol;The foaming agent is pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane
In one or several kinds.
2. foaming cleaning agent according to claim 1, it is characterised in that include the component of following parts by weight:Sodium benzoate
0.5-4 parts, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, 0.5-5 parts of quaternary surfactant, cation,
0.1-2 parts of the surfactant of nonionic compounding, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent, 70-90 parts of deionized water, nothing
It is 6-10 parts of water-ethanol, plain boiled water 1-2 parts anti-;The foaming agent is in pentane ex hoc genus anne isomers, dimethoxym ethane, methyl cyclopentane
It is one or several kinds of.
3. foaming cleaning agent according to claim 1 or 2, it is characterised in that further include the component of following parts by weight:It is organic
1-5 parts of alkali.
4. foaming cleaning agent according to claim 3, it is characterised in that further include the component of following parts by weight:It is described to have
Machine alkali is triethanolamine.
5. foaming cleaning agent according to claim 1 or 2, it is characterised in that include the component of following parts by weight:Benzoic acid
1.5 parts of sodium, 0.1 part of benzotriazole, 0.5 part of EDTA-4Na, 3 parts of quaternary surfactant, cation, nonionic compounding
1 part of surfactant, 2 parts of JFC bleeding agents, 1 part of methyl cyclopentane foaming agent, 78.4 parts of deionized water, 8 parts of absolute ethyl alcohol,
Anti- 1.5 parts of plain boiled water.
6. one kind foaming detergent device, it is characterised in that including spray cans, load in the spray cans as claim 1-5 appoints
Foaming cleaning agent and propellant described in one, the propellant are the weight of butane, the propellant and the foaming cleaning agent
Amount is than being 1:25-15.
7. foaming detergent device according to claim 6, it is characterised in that its preparation method is:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface-active are provided
0.5-5 parts of agent, cation, nonionic compounding 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent,
70-90 parts of deionized water, 7-12 parts of absolute ethyl alcohol;The foaming agent is pentane ex hoc genus anne isomers, dimethoxym ethane, methyl ring penta
One or several kinds in alkane;
Take sodium benzoate, benzotriazole and EDTA-4Na to add in absolute ethyl alcohol, be stirred, form the first mixture;
Quaternary surfactant, cation, the surfactant of nonionic compounding and JFC bleeding agents is taken to add deionized water
In, stir evenly, form the second mixture;
First mixture and the second mixture are mixed and stirred for uniformly, to form the 3rd mixture;
3rd mixture is loaded in the spray cans, then adds the foaming agent;
In the spray cans plus valve, sealing, the propellant is finally filled with.
8. foaming detergent device according to claim 6, it is characterised in that its preparation method is:
0.5-4 parts of sodium benzoate, 0.05-0.5 parts of benzotriazole, 0.2-2 parts of EDTA-4Na, quaternary ammonium salt surface-active are provided
0.5-5 parts of agent, cation, nonionic compounding 0.1-2 parts of surfactant, 1-5 parts of JFC bleeding agents, 0.1-2 parts of foaming agent,
It is 70-90 parts of deionized water, 6-10 parts of absolute ethyl alcohol, plain boiled water 1-2 parts anti-;The foaming agent is pentane ex hoc genus anne isomers, first
One or several kinds in acetal, methyl cyclopentane;
Take sodium benzoate, benzotriazole and EDTA-4Na to add in absolute ethyl alcohol, be stirred, form the first mixture;
Take quaternary surfactant, cation, surfactant and the JFC bleeding agents of nonionic compounding add deionized water and
In the mixed liquor of anti-plain boiled water, stir evenly, form the second mixture;
First mixture and the second mixture are mixed and stirred for uniformly, to form the 3rd mixture;
3rd mixture is loaded in the spray cans, then adds the foaming agent;
In the spray cans plus valve, sealing, the propellant is finally filled with.
9. the foaming detergent device according to claim 7 or 8, it is characterised in that 1-5 parts of machine alkali is also provided with, by institute
State organic base to add in the 3rd mixture, adjust pH value to 9-10.
10. foaming detergent device according to claim 6, it is characterised in that the spray cans is tinplate spray cans.
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