CN108034172A - A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger - Google Patents

A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger Download PDF

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Publication number
CN108034172A
CN108034172A CN201711469467.0A CN201711469467A CN108034172A CN 108034172 A CN108034172 A CN 108034172A CN 201711469467 A CN201711469467 A CN 201711469467A CN 108034172 A CN108034172 A CN 108034172A
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China
Prior art keywords
parts
wear
resisting
floor
nano
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CN201711469467.0A
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Chinese (zh)
Inventor
吴三学
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Shanghai Bless Technology Development Co Ltd
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Shanghai Bless Technology Development Co Ltd
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Priority to CN201711469467.0A priority Critical patent/CN108034172A/en
Publication of CN108034172A publication Critical patent/CN108034172A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

Wear-resisting floor wearing floor leather material the invention discloses a kind of material and preparation method thereof for integral new-energy passenger.The wear-resisting floor wearing floor leather material includes the raw material of following parts by weight:25 40 parts of polyvinyl chloride resin, 10 15 parts of titanium diboride, 5 15 parts of a leukotrienes, 11 20 parts of ethylene propylene diene rubber, 6 15 parts of silica, 48 parts of zinc borate, 48 parts of basalt fibre, 48 parts of carbon black N330,3 10 parts of nano-calcium carbonate.The flooring laminate material of the present invention is prepared by polyvinyl chloride resin, ethylene propylene diene rubber, silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and a leukotrienes,, can with being preferably used for car material technical field with excellent wear-resisting property and corrosion resistance;Preparation process is simple, and raw material is easy to get, environmental protection, is conducive to industrialized production.

Description

A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger
Technical field
The present invention relates to ground material technical field, be specifically a kind of material for integral new-energy passenger wear-resisting floor wearing floor leather material and Its preparation method.
Background technology
New-energy automobile includes hybrid vehicle (HEV), pure electric automobile (BEV, including solar telephone), fuel electricity Pond electric automobile (FCEV), hydrogen engine automobile, other new energy (such as high-efficiency energy-storage device, dimethyl ether) automobile productions of all categories Product.Integral new-energy passenger is current China's automobile industry enterprise in new energy field development & production and the emphasis and focus of competition.
At present, the automobile-used ground material mainly to circulate on the market is broadly divided into following several, and one kind is made of elastomeric material, resistance to Mill property is poor, and corrosion resistance also has much room for improvement;Another kind is that have textile material and plastic material MULTILAYER COMPOSITE to form, this Floor is with respect to comfortable foot feeling, but material can cause the destruction of environment and the waste of resource, not environmentally friendly enough;In addition, for durability, Also there is an automobile-used solid wooden floor board, but the drawback is that cost is higher, it is necessary to using a large amount of timber, cause the wasting of resources.Therefore, this hair Bright wear-resisting floor wearing floor leather material that a kind of material is provided suitable for new-energy automobile and other cars and preparation method thereof.
The content of the invention
Wear-resisting floor wearing floor leather material and its preparation side it is an object of the invention to provide a kind of material for integral new-energy passenger Method, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical solution:
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 25-40 parts, 10-15 parts of titanium diboride, 5-15 parts of a- leukotrienes, 11-20 parts of ethylene propylene diene rubber, 6-15 parts of silica, boron Sour zinc 4-8 parts, 4-8 parts of basalt fibre, 4-8 parts of carbon black N330,3-10 parts of nano-calcium carbonate.
As the further scheme of the present invention:Include the raw material of following parts by weight:28-35 parts of polyvinyl chloride resin, titanium diboride 11-14 parts, 8-12 parts of a- leukotrienes, 14-18 parts of ethylene propylene diene rubber, 8-12 parts of silica, 5-7 parts of zinc borate, basalt 5-7 parts of fiber, 5-7 parts of carbon black N330,4-8 parts of nano-calcium carbonate.
As the further scheme of the present invention:Include the raw material of following parts by weight:32 parts of polyvinyl chloride resin, titanium diboride 12 Part, 10 parts of a- leukotrienes, 15 parts of ethylene propylene diene rubber, 0 part of silica 1,6 parts of zinc borate, 6 parts of basalt fibre, carbon black 6 parts of N330,5 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 180-225 DEG C and calcines 25-45min;(2) 100-200 mesh is ground up, sieved after upper step gains are cooled down;(3) by PVC Resin is mixed with ethylene propylene diene rubber, and 15-30min is stirred at 170-185 DEG C, step (2) gains is then added, in 210- 10-20min is stirred at 220 DEG C, is then extruded by extruder to obtain the final product.
As the further scheme of the present invention:Step (1) is by silica, carbon black N330, basalt fibre, nano-calcium carbonate Calcium, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly to be placed at 195 DEG C and calcine 30min.
As the further scheme of the present invention:Step (2) is ground up, sieved 120 mesh after upper step gains are cooled down.
As the further scheme of the present invention:Step (3) mixes polyvinyl chloride resin with ethylene propylene diene rubber, is stirred at 180 DEG C Mix 20min, then add step (2) gains, 15min is stirred at 215 DEG C, is then extruded by extruder to obtain the final product.
Compared with prior art, the beneficial effects of the invention are as follows:
The flooring laminate material of the present invention is fine by polyvinyl chloride resin, ethylene propylene diene rubber, silica, carbon black N330, basalt Dimension, nano-calcium carbonate, titanium diboride, zinc borate and a- leukotrienes are prepared, and have excellent wear-resisting property and corrosion resistance Can, can with being preferably used for car material technical field;Preparation process is simple, and raw material is easy to get, environmental protection, is conducive to industrialized production.
Embodiment
The technical solution of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 25 parts, 10 parts of titanium diboride, 5 parts of a- leukotrienes, 11 parts of ethylene propylene diene rubber, 6 parts of silica, 4 parts of zinc borate, basalt it is fine 4 parts of dimension, 4 parts of carbon black N330,3 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 180 DEG C and calcines 25min;(2) 100 mesh are ground up, sieved after upper step gains are cooled down;(3) by polyvinyl chloride resin and ternary EP rubbers mixes, and 15min is stirred at 170 DEG C, then adds step (2) gains, 10min is stirred at 210 DEG C, then Extruded by extruder to obtain the final product.
Embodiment 2
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 40 parts, 15 parts of titanium diboride, 15 parts of a- leukotrienes, 20 parts of ethylene propylene diene rubber, 5 parts of silica 1,8 parts of zinc borate, basalt 8 parts of fiber, 8 parts of carbon black N330,10 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 225 DEG C and calcines 45min;(2) 200 mesh are ground up, sieved after upper step gains are cooled down;(3) by polyvinyl chloride resin and ternary EP rubbers mixes, and 30min is stirred at 185 DEG C, then adds step (2) gains, 20min is stirred at 220 DEG C, then Extruded by extruder to obtain the final product.
Embodiment 3
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 32 parts, 12 parts of titanium diboride, 10 parts of a- leukotrienes, 15 parts of ethylene propylene diene rubber, 0 part of silica 1,6 parts of zinc borate, basalt 6 parts of fiber, 6 parts of carbon black N330,5 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 195 DEG C and calcines 30min.(2) 120 mesh are ground up, sieved after upper step gains are cooled down.(3) by polyvinyl chloride resin and ternary EP rubbers mixes, and 20min is stirred at 180 DEG C, then adds step (2) gains, 15min is stirred at 215 DEG C, then Extruded by extruder to obtain the final product.
Embodiment 4
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 28 parts, 11 parts of titanium diboride, 8 parts of a- leukotrienes, 14 parts of ethylene propylene diene rubber, 8 parts of silica, 5 parts of zinc borate, basalt it is fine 5 parts of dimension, 5 parts of carbon black N330,4 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 180 DEG C and calcines 25min;(2) 100 mesh are ground up, sieved after upper step gains are cooled down;(3) by polyvinyl chloride resin and ternary EP rubbers mixes, and 15min is stirred at 170 DEG C, then adds step (2) gains, 10min is stirred at 210 DEG C, then Extruded by extruder to obtain the final product.
Embodiment 5
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 35 parts, 14 parts of titanium diboride, 12 parts of a- leukotrienes, 18 parts of ethylene propylene diene rubber, 2 parts of silica 1,7 parts of zinc borate, basalt 7 parts of fiber, 7 parts of carbon black N330,8 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 225 DEG C and calcines 45min;(2) 200 mesh are ground up, sieved after upper step gains are cooled down;(3) by polyvinyl chloride resin and ternary EP rubbers mixes, and 30min is stirred at 185 DEG C, then adds step (2) gains, 20min is stirred at 220 DEG C, then Extruded by extruder to obtain the final product.
Embodiment 6
A kind of wear-resisting floor wearing floor leather material of material, includes the raw material of following parts by weight for integral new-energy passenger:Polyvinyl chloride resin 28 parts, 14 parts of titanium diboride, 11 parts of a- leukotrienes, 12 parts of ethylene propylene diene rubber, 9 parts of silica, 5 parts of zinc borate, basalt 6 parts of fiber, 7 parts of carbon black N330,9 parts of nano-calcium carbonate.
A kind of preparation method of the wear-resisting floor wearing floor leather material of material, comprises the following steps for integral new-energy passenger:(1) by two Silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and the mixing of a- leukotrienes, stir evenly It is placed at 185 DEG C and calcines 32min;(2) 160 mesh are ground up, sieved after upper step gains are cooled down;(3) by polyvinyl chloride resin and ternary EP rubbers mixes, and 25min is stirred at 182 DEG C, then adds step (2) gains, 16min is stirred at 214 DEG C, then Extruded by extruder to obtain the final product.
The flooring laminate material of the present invention is fine by polyvinyl chloride resin, ethylene propylene diene rubber, silica, carbon black N330, basalt Dimension, nano-calcium carbonate, titanium diboride, zinc borate and a- leukotrienes are prepared, and have excellent wear-resisting property and corrosion resistance Can, can with being preferably used for car material technical field;Preparation process is simple, and raw material is easy to get, environmental protection, is conducive to industrialized production.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, can also be on the premise of this patent objective not be departed from the knowledge that one skilled in the relevant art possesses Various changes can be made.

Claims (7)

1. the wear-resisting floor wearing floor leather material of a kind of material, it is characterised in that include the original of following parts by weight for integral new-energy passenger Material:25-40 parts of polyvinyl chloride resin, 10-15 parts of titanium diboride, 5-15 parts of a- leukotrienes, 11-20 parts of ethylene propylene diene rubber, silica 6-15 parts, 4-8 parts of zinc borate, 4-8 parts of basalt fibre, 4-8 parts of carbon black N330,3-10 parts of nano-calcium carbonate.
2. it is according to claim 1 for integral new-energy passenger material wear-resisting floor wearing floor leather material, it is characterised in that including with The raw material of lower parts by weight:28-35 parts of polyvinyl chloride resin, 11-14 parts of titanium diboride, 8-12 parts of a- leukotrienes, ethylene propylene diene rubber 14-18 parts, 8-12 parts of silica, 5-7 parts of zinc borate, 5-7 parts of basalt fibre, 5-7 parts of carbon black N330, nano-calcium carbonate 4-8 parts.
3. it is according to claim 1 for integral new-energy passenger material wear-resisting floor wearing floor leather material, it is characterised in that including with The raw material of lower parts by weight:32 parts of polyvinyl chloride resin, 12 parts of titanium diboride, 10 parts of a- leukotrienes, 15 parts of ethylene propylene diene rubber, dioxy 10 parts of SiClx, 6 parts of zinc borate, 6 parts of basalt fibre, 6 parts of carbon black N330,5 parts of nano-calcium carbonate.
A kind of 4. preparation side of wear-resisting floor wearing floor leather material according to any with the being used for integral new-energy passenger materials of claim 1-3 Method, it is characterised in that comprise the following steps:(1) by silica, carbon black N330, basalt fibre, nano-calcium carbonate, two boron Change titanium, zinc borate and the mixing of a- leukotrienes, stir evenly to be placed at 180-225 DEG C and calcine 25-45min;(2) by obtained by upper step 100-200 mesh is ground up, sieved after thing cooling;(3) polyvinyl chloride resin is mixed with ethylene propylene diene rubber, 15- is stirred at 170-185 DEG C 30min, then adds step (2) gains, 10-20min is stirred at 210-220 DEG C, is then extruded by extruder to obtain the final product.
5. the preparation method of the wear-resisting floor wearing floor leather material of material according to claim 4, its feature for integral new-energy passenger It is, step (1) is by silica, carbon black N330, basalt fibre, nano-calcium carbonate, titanium diboride, zinc borate and a- flax Acid mixing, stirs evenly to be placed at 195 DEG C and calcines 30min.
6. the preparation method of the wear-resisting floor wearing floor leather material of material according to claim 4, its feature for integral new-energy passenger It is, step (2) is ground up, sieved 120 mesh after upper step gains are cooled down.
7. the preparation method of the wear-resisting floor wearing floor leather material of material according to claim 4, its feature for integral new-energy passenger It is, step (3) mixes polyvinyl chloride resin with ethylene propylene diene rubber, and 20min is stirred at 180 DEG C, then adds step (2) institute Obtain thing, 15min is stirred at 215 DEG C, is then extruded by extruder to obtain the final product.
CN201711469467.0A 2017-12-29 2017-12-29 A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger Pending CN108034172A (en)

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Application Number Priority Date Filing Date Title
CN201711469467.0A CN108034172A (en) 2017-12-29 2017-12-29 A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110066474A (en) * 2019-03-11 2019-07-30 常州新之雅装饰材料有限公司 A kind of preparation method of low temperature resistant anti-aging flooring laminate
CN111690212A (en) * 2020-05-19 2020-09-22 佛山市亿翔塑胶有限公司 High-strength super-wear-resistant PVC floor leather

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103146094A (en) * 2011-12-07 2013-06-12 滁州格美特科技有限公司 Modified plastic, and preparation method and application thereof
CN104403151A (en) * 2014-12-22 2015-03-11 孙宝林 Elastic rubber floorboard
CN106351417A (en) * 2016-08-27 2017-01-25 湖州展邦实业有限公司 Waterproof wear-resistant floor and preparing method thereof
CN106589677A (en) * 2016-11-30 2017-04-26 四川中塑高分子材料有限公司 Wear-resistant anti-aging outdoor sports floor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103146094A (en) * 2011-12-07 2013-06-12 滁州格美特科技有限公司 Modified plastic, and preparation method and application thereof
CN104403151A (en) * 2014-12-22 2015-03-11 孙宝林 Elastic rubber floorboard
CN106351417A (en) * 2016-08-27 2017-01-25 湖州展邦实业有限公司 Waterproof wear-resistant floor and preparing method thereof
CN106589677A (en) * 2016-11-30 2017-04-26 四川中塑高分子材料有限公司 Wear-resistant anti-aging outdoor sports floor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110066474A (en) * 2019-03-11 2019-07-30 常州新之雅装饰材料有限公司 A kind of preparation method of low temperature resistant anti-aging flooring laminate
CN111690212A (en) * 2020-05-19 2020-09-22 佛山市亿翔塑胶有限公司 High-strength super-wear-resistant PVC floor leather

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Application publication date: 20180515

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