CN106589677A - Wear-resistant anti-aging outdoor sports floor - Google Patents
Wear-resistant anti-aging outdoor sports floor Download PDFInfo
- Publication number
- CN106589677A CN106589677A CN201611082148.XA CN201611082148A CN106589677A CN 106589677 A CN106589677 A CN 106589677A CN 201611082148 A CN201611082148 A CN 201611082148A CN 106589677 A CN106589677 A CN 106589677A
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- CN
- China
- Prior art keywords
- parts
- wear
- aging resistance
- outdoor activity
- floor
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to the technical field of polymer materials, and in particular, relates to a wear-resistant anti-aging outdoor sports floor prepared from the following raw materials in parts by weight: 4-8 parts of an alumina powder, 30-55 parts of glass fibers, 20-35 parts of high-impact-resistance polystyrene, 3-7 parts of modified aluminum hydroxide, 100-150 parts of polyvinyl chloride, 1-3 parts of a stabilizer, 0.5-1 part of an antioxidant, 70-90 parts of white carbon black, and 15-30 parts of calcium carbonate. The method adopts tiny calcium carbonate, and a cavity formed by other components can be filled with the tiny calcium carbonate, so that the produced floor can fully achieve the use requirements of a sports floor and also has good flexibility, the product surface has minimal shrinkage rate, and at the same time, the product has good toughness, corrosion resistance and wear resistance.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically with regard to a kind of wear-resisting aging resistance outdoor activity floor.
Background technology
At present, PVC plastic flooring material is international formal including the optimal of all ball game places including basketball
Select, may be used to lay the rooms such as internationally recognized shuttlecock, table tennis, vollyball, handball through the PVC athletic floors of certification
Interior competition area.The type athletic floor have it is certain it is fire-retardant, moistureproof, anti-skidding, the coefficient of expansion is extremely low, anti-chemical contamination, anti-
Electrostatic, termite-proof characteristic, which is removed in addition, movement is more convenient, daily especially to safeguard, has a wide range of applications.It is existing
Common plasticses athletic floor facestock can not meet the requirement growing to its performance, therefore, to existing floor need
Further to improve, improve its physical properties.
The content of the invention
It is an object of the invention to provide a kind of wear-resisting aging resistance outdoor activity floor, strong with elastic good, durable, toughness
Feature.
A kind of wear-resisting aging resistance outdoor activity floor, the floor includes that the raw material of following weight portion is made：Alumina powder
4-8 parts, glass fibre 30-55 parts, high impact polystyrene 20-35 parts, modified aluminium hydroxide 3-7 parts, polrvinyl chloride 100-150
Part, stabilizer 1-3 parts, antioxidant 0.5-1 parts, white carbon 60-90 parts, Calcium Carbonate 15-30 part.The modified aluminium hydroxide be by
Titanate coupling agent and micron aluminium-hydroxide powder are according to mass ratio 1:100 formula is added, then high-speed stirred is obtained.
Preferably, the wear-resisting aging resistance outdoor activity floor, the floor includes that the raw material of following weight portion is made：Oxygen
Change aluminium powder 5-8 parts, glass fibre 40-55 parts, high impact polystyrene 30-35 parts, modified aluminium hydroxide 3-5 parts, polrvinyl chloride
120-150 parts, stabilizer 1-2 parts, antioxidant 0.5-0.8 parts, white carbon 70-85 parts, Calcium Carbonate 15-25 part.
Preferably, the wear-resisting aging resistance outdoor activity floor, also including Polyethylene Glycol 10-20 parts.
Preferably, the wear-resisting aging resistance outdoor activity floor, is made up of the raw material of following weight portion：Alumina powder 6-8
Part, glass fibre 40-50 parts, high impact polystyrene 20-30 parts, modified aluminium hydroxide 4-7 parts, polrvinyl chloride 130-140 parts,
Stabilizer 2.5-3 parts, antioxidant 0.8-1 parts, white carbon 80-85 parts, Calcium Carbonate 20-25 part, Polyethylene Glycol 15-20 parts.
Preferably, the wear-resisting aging resistance outdoor activity floor, is made up of the raw material of following weight portion：7 parts of alumina powder,
It is 45 parts of glass fibre, 28 parts of high impact polystyrene, 5 parts of modified aluminium hydroxide, 135 parts of polrvinyl chloride, 2.5 parts of stabilizer, anti-
0.9 part of oxygen agent, 80 parts of white carbon, 25 parts of Calcium Carbonate, 18 parts of Polyethylene Glycol.
Preferably, the white carbon black grain size is 150-300 mesh.
Preferably, the Carbonate Particle Size is 150-200 mesh.
Preferably, the stabilizer is vinyl trichlorosilane, VTES and vinyl trimethoxy
One or more in silane.
Preferably, the antioxidant is Butylated hydroxyanisole (BHA), dibenzylatiooluene (BHT), gallic acid third
One or more in ester (PG) and tert-butyl hydroquinone (TBHQ).
Present invention also offers the preparation method on the wear-resisting aging resistance outdoor activity floor, comprises the following steps：
（1）Raw material mix homogeneously are taken by proportioning；
（2）The material for mixing is put in homogenizer and is stirred, with speed as 1000-1200 rev/min of high-speed stirred
Time 100-150s, then switch to 650 turns of wear-resisting aging resistance outdoor activity floors/wear-resisting aging resistance outdoor activity floor minute low speed
Stirring 60-80s, then proceeds in banbury, the wear-resisting aging resistance outdoor activity floors of refining modeling 150-200s at 150-160 DEG C；
（3）After refining modeling and processing, proceed in double screw extruder, wear-resisting aging resistance outdoor activity floor extruding pelletization, finally
Product is obtained through injection.
Beneficial effect of the present invention：Compared with prior art, the method for the invention adopts small Calcium Carbonate, can be filled into
In the cavity that other components are formed, so that the floor produced is entirely capable of the use requirement for reaching athletic floor, while having
Good elasticity and ageing resistance, also make product surface have minimum shrinkage factor, and the product also has very excellent fire-retardant
Characteristic, safety and environmental protection.High impact polystyrene can effectively strengthen the impact resistance on floor so as to good toughness.Glass
Glass fiber is improved can the mechanical strength of product, but the addition of high impact polystyrene can make up which and cause fragility big
Shortcoming, also makes product have good corrosion resistance, pH can be prevented less than 3 and the acid and alkali corrosion more than 10.Aluminium oxide can be carried
The hardness on the surface on high floor, is that floor is more resistant.
Specific embodiment
With reference to embodiment, the present invention is further described.
Embodiment 1
A kind of wear-resisting aging resistance outdoor activity floor, the floor includes that the raw material of following weight portion is made：4 parts of alumina powder,
It is 30 parts of glass fibre, 20 parts of high impact polystyrene, 3 parts of modified aluminium hydroxide, 100 parts of polrvinyl chloride, 1.5 parts of stabilizer, anti-
0.5 part of oxygen agent, 60 parts of white carbon, 15 parts of Calcium Carbonate.
Embodiment 2
A kind of wear-resisting aging resistance outdoor activity floor, the floor includes that the raw material of following weight portion is made：5 parts of alumina powder,
35 parts of glass fibre, 25 parts of high impact polystyrene, 7 parts of modified aluminium hydroxide, 125 parts of polrvinyl chloride, 2 parts of stabilizer, antioxygen
0.8 part of agent, 85 parts of white carbon, 20 parts of Calcium Carbonate.
Embodiment 3
A kind of wear-resisting aging resistance outdoor activity floor, the floor includes that the raw material of following weight portion is made：6 parts of alumina powder,
40 parts of glass fibre, 30 parts of high impact polystyrene, 4 parts of modified aluminium hydroxide, 120 parts of polrvinyl chloride, 1 part of stabilizer, antioxygen
0.8 part of agent, 85 parts of white carbon, 15 parts of Calcium Carbonate.
Embodiment 4
A kind of wear-resisting aging resistance outdoor activity floor, the floor includes that the raw material of following weight portion is made：7 parts of alumina powder,
45 parts of glass fibre, 35 parts of high impact polystyrene, 5 parts of modified aluminium hydroxide, 100 parts of polrvinyl chloride, 1 part of stabilizer, antioxygen
0.5 part of agent, 85 parts of white carbon, 15 parts of Calcium Carbonate.
Embodiment 5
A kind of wear-resisting aging resistance outdoor activity floor, is made up of the raw material of following weight portion：8 parts of alumina powder, glass fibre 55
Part, 32 parts of high impact polystyrene, 6 parts of modified aluminium hydroxide, 135 parts of polrvinyl chloride, 2.5 parts of stabilizer, 0.9 part of antioxidant,
80 parts of white carbon, 25 parts of Calcium Carbonate, 18 parts of Polyethylene Glycol.
Embodiment 6
A kind of wear-resisting aging resistance outdoor activity floor, is made up of the raw material of following weight portion：7 parts of alumina powder, glass fibre 45
Part, 28 parts of high impact polystyrene, 5 parts of modified aluminium hydroxide, 140 parts of polrvinyl chloride, 3 parts of stabilizer, 1 part of antioxidant, Linesless charcoal
Black 85 parts, 25 parts of Calcium Carbonate, 15 parts of Polyethylene Glycol.
Although reference be made herein to invention has been described for explanatory embodiment of the invention, when above-described embodiment is only this
Invention preferably one of embodiment, embodiments of the present invention are simultaneously not restricted to the described embodiments, it should be appreciated that this area
Technical staff can be designed that a lot of other modifications and embodiment, and these modifications and embodiment will fall in disclosure
Spirit and spirit within.
Claims (10)
1. a kind of wear-resisting aging resistance outdoor activity floor, it is characterised in that the floor includes that the raw material of following weight portion is made：
Alumina powder 4-8 parts, glass fibre 30-55 parts, high impact polystyrene 20-35 parts, modified aluminium hydroxide 3-7 parts, polychlorostyrene second
Alkene 100-150 parts, stabilizer 1-3 parts, antioxidant 0.5-1 parts, white carbon 60-85 parts, Calcium Carbonate 15-30 part.
2. wear-resisting aging resistance outdoor activity floor according to claim 1, it is characterised in that the floor includes following weight
The raw material of part is made：Alumina powder 5-8 parts, glass fibre 40-55 parts, high impact polystyrene 30-35 parts, modified aluminium hydroxide
3-5 parts, polrvinyl chloride 120-150 parts, stabilizer 1-2 parts, antioxidant 0.5-0.8 parts, white carbon 70-85 parts, Calcium Carbonate 15-25
Part.
3. wear-resisting aging resistance outdoor activity floor according to claim 1, it is characterised in that also including Polyethylene Glycol 10-20
Part.
4. wear-resisting aging resistance outdoor activity floor according to claim 3, it is characterised in that by the raw material system of following weight portion
Into：Alumina powder 6-8 parts, glass fibre 40-50 parts, high impact polystyrene 20-30 parts, modified aluminium hydroxide 4-7 parts, polychlorostyrene
Ethylene 130-140 parts, stabilizer 2.5-3 parts, antioxidant 0.8-1 parts, white carbon 80-85 parts, Calcium Carbonate 20-25 part, poly- second two
Alcohol 15-20 parts.
5. wear-resisting aging resistance outdoor activity floor according to claim 4, it is characterised in that by the raw material system of following weight portion
Into：7 parts of alumina powder, 45 parts of glass fibre, 28 parts of high impact polystyrene, 5 parts of modified aluminium hydroxide, 135 parts of polrvinyl chloride,
2.5 parts of stabilizer, 0.9 part of antioxidant, 80 parts of white carbon, 25 parts of Calcium Carbonate, 18 parts of Polyethylene Glycol.
6. according to the arbitrary wear-resisting aging resistance outdoor activity floor of claim 1-5, it is characterised in that：The white carbon black grain size
For 150-300 mesh.
7. according to the arbitrary wear-resisting aging resistance outdoor activity floor of claim 1-5, it is characterised in that：The Carbonate Particle Size
For 150-200 mesh.
8. according to the arbitrary wear-resisting aging resistance outdoor activity floor of claim 1-5, it is characterised in that：The stabilizer is second
One or more in thiazolinyl trichlorosilane, VTES and vinyltrimethoxy silane.
9. according to the arbitrary wear-resisting aging resistance outdoor activity floor of claim 1-5, it is characterised in that：The antioxidant is fourth
Base BHA (BHA), dibenzylatiooluene (BHT), propylgallate (PG) and tert-butyl hydroquinone (TBHQ)
In one or more.
10. as described in claim 1-5 is arbitrary wear-resisting aging resistance outdoor activity floor preparation method, it is characterised in that include
Following steps：
（1）Raw material mix homogeneously are taken by proportioning；
（2）The material for mixing is put in homogenizer and is stirred, with speed as 1000-1200 rev/min of high-speed stirred
Time 100-150s, then switch to 650 revs/min of stirring at low speed 60-80s, then proceed in banbury, refine at 150-160 DEG C
Modeling 150-200s；
（3）After refining modeling and processing, proceed in double screw extruder, extruding pelletization, eventually pass injection and obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611082148.XA CN106589677A (en) | 2016-11-30 | 2016-11-30 | Wear-resistant anti-aging outdoor sports floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611082148.XA CN106589677A (en) | 2016-11-30 | 2016-11-30 | Wear-resistant anti-aging outdoor sports floor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589677A true CN106589677A (en) | 2017-04-26 |
Family
ID=58594109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611082148.XA Pending CN106589677A (en) | 2016-11-30 | 2016-11-30 | Wear-resistant anti-aging outdoor sports floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106589677A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108034172A (en) * | 2017-12-29 | 2018-05-15 | 上海佑望科技发展有限公司 | A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
| CN103146094A (en) * | 2011-12-07 | 2013-06-12 | 滁州格美特科技有限公司 | Modified plastic, and preparation method and application thereof |
| CN104927245A (en) * | 2015-06-30 | 2015-09-23 | 青岛宇星智能科技开发有限公司 | Outdoor wearproof floor |
| CN104945776A (en) * | 2015-06-30 | 2015-09-30 | 青岛精石通精密机械制造有限公司 | Outdoor sports floorboard |
-
2016
- 2016-11-30 CN CN201611082148.XA patent/CN106589677A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
| CN103146094A (en) * | 2011-12-07 | 2013-06-12 | 滁州格美特科技有限公司 | Modified plastic, and preparation method and application thereof |
| CN104927245A (en) * | 2015-06-30 | 2015-09-23 | 青岛宇星智能科技开发有限公司 | Outdoor wearproof floor |
| CN104945776A (en) * | 2015-06-30 | 2015-09-30 | 青岛精石通精密机械制造有限公司 | Outdoor sports floorboard |
Non-Patent Citations (1)
| Title |
|---|
| 贾红兵等: "《高分子材料 第二版》", 31 December 2013 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108034172A (en) * | 2017-12-29 | 2018-05-15 | 上海佑望科技发展有限公司 | A kind of wear-resisting floor wearing floor leather material of material and preparation method thereof for integral new-energy passenger |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170426 |
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| RJ01 | Rejection of invention patent application after publication |