CN108024945A - The low-viscosity eye color make-up constituent of the content of wax - Google Patents

The low-viscosity eye color make-up constituent of the content of wax Download PDF

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Publication number
CN108024945A
CN108024945A CN201680054274.6A CN201680054274A CN108024945A CN 108024945 A CN108024945 A CN 108024945A CN 201680054274 A CN201680054274 A CN 201680054274A CN 108024945 A CN108024945 A CN 108024945A
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Prior art keywords
wax
constituent
color make
eye color
noncrystalline
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CN201680054274.6A
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CN108024945B (en
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张賐姬
韩恩实
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Amore Pacific Ltd By Share Ltd
Amorepacific Corp
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Amore Pacific Ltd By Share Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

The present invention provides a kind of low-viscosity eye color make-up constituent of the content of wax.Eye color make-up constituent of the present invention is characterized in that containing crystalline wax and noncrystalline wax at the same time.Therefore, eye color make-up constituent of the present invention also shows the characteristic of low-viscosity even if the content of wax, and the eye color make-up product of constituent is sprayed suitable for soft pen type or by nozzle.The eye color make-up constituent of the present invention is formed by oil phase substrate formulation, so as to show the endurance and water resistance being obviously improved.

Description

The low-viscosity eye color make-up constituent of the content of wax
Technical field
The present invention advocates the benefit of priority based on 2015 Nian9Yue30 South Korea patent grant 10-2015-0137555, All the elements disclosed in the document of related Korean Patent license as a part of the invention and are contained in this specification.
It is a kind of water proofing property the present invention relates to a kind of low-viscosity eye color make-up constituent containing crystalline wax and noncrystalline wax The eye color make-up constituent that can be lifted.
Background technology
It is a kind of easy to carry and using easy soft pen type eye-liner due to coloring nature, soft-touch and gain great popularity. But its head surface is easy to solidify soft pen type eye-liner when in use, it is therefore desirable to often cleans or when reusing Compression number increase, so more loaded down with trivial details.
Soft pen type eye-liner must pass through nozzle and eject content, thereby produce limitation, exactly fill to soft pen type The liquid formulation of the eye color make-up constituent of eye-liner necessarily low-viscosity (100~2000cps).Therefore, it is in the past most Soft pen type eye-liner cannot use the larger wax of viscosity ascensional range, but be prepared by substrate of aqueous phase substrate.
But in the case, bring the pigment adhesive force caused by not using wax and lowly drop and ask with powder Inscribe and because caused by persistence is low the problems such as dizzy dye.In order to improve the above problem, film forming agent is excessively used, because The problem of film forming agent has in atmosphere drying rapidly and forms the characteristic of overlay film, thus cause head surface easily to solidify again.
Brush head is solidified this problem and is greatly reduced using the satisfaction of color make-up product.In order to solve the problems, such as this, always Since carried out many research, then not think film forming agent is excessively used and adds wax to be only most effective solution party Case.
Meanwhile the constituent for adding wax and providing using oil phase substrate as substrate can be obviously improved endurance and water proofing property Can, therefore the formulation containing wax is can not only to have improved use feeling but also can put forward high performance optimal morphology, its necessity further highlights.
But when preparing the eye-liner constituent of the content of wax, the low-viscosity of 100~2000cps is shown, even if not excessive Persistence etc. is also ensured that using film forming agent, but is not that any be combined wax can just realize that there is technology easily On limitation.
[prior art document]
Ebrean Registered Patent the 1060805th, " a kind of good waterproof eye color make-up constituent of persistence ".
The content of the invention
To solve the above-mentioned problems, crystalline wax and noncrystalline wax are carried out being mixed with eye by the inventors of the present invention Color make-up constituent, it is thus identified that the eye color make-up constituent so prepared shows the characteristic and persistence and water resistance of low-viscosity Well, so as to complete the present invention.
Therefore, the eye that endurance and water resistance it is an object of the invention to provide a kind of content of wax are good and viscosity is low Color make-up constituent.
In order to solve the above problems, the present invention provides a kind of eye color make-up constituent containing crystalline wax and noncrystalline wax.
Invention effect:
The eye color make-up constituent that the present invention provides a kind of endurance of content of wax and water resistance is good and viscosity is low.Cause This, eye color make-up constituent of the invention is suitable for soft pen type or using the eye color make-up product by nozzle injection constituent.
Embodiment
The present invention provides a kind of eye color make-up constituent containing crystalline wax and noncrystalline wax.
Different from traditional aqueous phase substrate formulation, eye color make-up constituent of the invention is a kind of oil phase base of content of wax form The eye color make-up constituent of matter formulation.The composition of the eye color make-up constituent of the present invention includes wax, due to its combination and content Restriction and form 100~2, the viscosity of 000cps scopes, even if film forming agent is not excessively used, can also improve smear color make-up group Into the persistence after thing and pigment adhesive force.
Especially, when constituent to be used for the color make-up product of soft form of a stroke or a combination of strokes state, because the low characteristic of viscosity can make to be sprayed by nozzle The constituent penetrated keeps the level of appropriateness, and due to without excessive film forming agent, speckling with the soft brush head of constituent Surface is not easy to solidify, so use feeling is good.
Therefore, eye color make-up constituent of the invention is preferably formed with soft pen type eye color make-up product or by nozzle injection The eye color make-up product for other all forms that the mode that thing is directly smeared uses, can be used, for example, as soft pen type eye-liner constituent Deng, but it is not limited to this.
On the other hand, on term as used in this specification,
' crystalline wax ' refers to the wax for all kinds to form crystallization.But except following noncrystalline waxes.
' noncrystalline wax ', which refers to have, produces minimum crystallization or removal crystallization (amorphization) when being used in mixed way with crystalline wax The wax of this characteristic.
The present invention will be described in detail below.In order to help to understand the present invention, only described in the description below Most representational embodiment, but the interest field of the present invention is not limited to this, it is thus understood that the present invention is included with State the equivalent all scopes of content.
Wax (wax) is mutually changed into solid and liquid on the basis of fusing point, and the wax of fusing point implemented below crystallization is referred to as tying Brilliant wax, this crystalline wax are divided into plate crystal, acicular crystal, imperfect crystal formation according to the shape of crystallization.Unlike, fusing point with Under do not produce the wax of crystallization and be referred to as noncrystalline wax.
The crystallization attribute of wax is bigger, can more show the high characteristic of viscosity, and the overlay film of solidification wax is then shown and hard Hard characteristic again.On the contrary, crystallization attribute is smaller, then viscosity is lower, shows to be not easy the characteristic to form overlay film.
Crystalline wax and noncrystalline wax are applied in combination in the present invention, so as to balancedly maintain the viscosity of constituent.That is, when During using only crystalline wax, although persistence is good, be not suitable for the color make-up product of soft pen type because viscosity is higher, when using only During noncrystalline wax, although viscosity is relatively low, there are persistence it is low the problem of, if including the mixture of the various waxes, then It can obtain a kind of showing appropriate viscosity and the eye color make-up constituent of endurance.Also, the present invention is by described in control Content and the combination weight ratio of crystalline wax and noncrystalline wax and a kind of eye color make-up constituent that can embody optimal efficacy is provided.
Since eye color make-up constituent of the present invention contains crystalline wax, so even without using film forming agent, can also carry The surface rigidity of high constituent, improves the persistence after smearing and prevents dizzy dye.
Paraffin, Brazil wax, Tissuemat E, rice wax, ceresine, silk gum, candelila wax and bee can be selected in the crystalline wax One or more of group that wax is formed.
Specifically, paraffin is to use chemical formula CnH2n+2The alkane (alkane) that (n >=19, n=20~40 are preferable) represents is mixed Compound, is the room temperature solid matter that color is white and soft derived from oil, coal or oil shale.The paraffin, which has, not to be dissolved in Water, but it is soluble in the characteristic of ether, benzene, ester.
Brazil wax is the material obtained by babassu leaf, as the raw material for being contained in cosmetic composition, It is a kind of wax of hardness ten in common wax/high.Especially, have and harden into yellowish-brown-beige hardening, it is easily hard Change and frangible.In addition, be belong in plant wax more moist, glossiness, cardiotonic, hardening, microcrystalline etc. it is good one Kind wax.When containing the Brazil wax in cosmetic composition, it can be mixed with other greases or wax and improve fusing point, made Used time, the situation that its usage amount is less than the other waxes being used together are more.When mascara is when containing the Brazil wax, Also have the advantages that water resistance film can be formed.
Tissuemat E is the polyethylene of low molecular weight, and appearance is in the state of wax.The Tissuemat E have between paraffin and Molecular weight between polyethylene, therefore the intermediate intensity with two kinds of materials, intermediate heat resistant (fusing point).Because of the Tissuemat E Jointly comprised with paraffin, therefore melting point of paraffin wax and intensity can be increased.
Rice wax is otherwise known as rice bran wax (rice bran wax) or rice bran oil, can be extracted from rice bran.Principal component is advanced fat The ester of fat acid and higher alcohol, thus with of animal or plant nature wax and mineral wax, soap wax, glyceride type wax, hydrocarbon wax it is simultaneous Capacitive is good.Hydrophile-lipophile balance (HLB) value as low as 6~9 of the rice wax, Brazil wax, beeswax etc. are different from during use Native paraffin is, it is necessary to use emulsifying agent.Situation usually by being allowed a choice applied to cosmetic composition is more.
Ceresine is derived from the chloroflo of mineral matter or petroleum as a kind of natural minerals wax.The fusing point of above-mentioned ceresine For 65 DEG C, there is the microstructure that needle-shaped or short slab is formed.With the affinity and compatible particularly well with paraffin of oil.Example Such as, melting temperature can be down to 54 DEG C or so, the whole of constituent can be improved during the ceresine of addition 5~15% or so in paraffin Body physical property.When including the ceresine in cosmetic composition, have as a kind of water-insoluble tackifier and improve constituent The effect of viscosity and hardness.Also, the use feeling of softness can also be provided, unstable emulsified state is stabilized, smearing can be made Feel moist soft in the position of cosmetic composition.
In addition, the material for refining above-mentioned ceresine and obtaining is referred to as silk gum.
Candelila wax is that one kind extracts from Euphorbia cerifera Alcocer, Euphorbia The small candles such as antisyphilitica Zuccarini and Pedilanthus Boissier (Euphorbiaceae (Euphorbiaceae)) The natural esters of tree plant stem.When cosmetic composition includes the candelila wax, as a kind of water-insoluble tackifier And have the function that to make the unstable emulsified state of constituent stabilize and adjust cosmetic composition viscosity and hardness, can Overlay film is formed, is flexibly wrapped to protect smearing position and assign moist and flexibility.In addition can also prevent to smear position moisture Evaporation, assign repair function and keep moisture feeling.
Beeswax is otherwise known as beeswax, and component contains other a variety of fat based on the palmitate and cerinic acid of beeswax alcohol Acid alcohol and higher hydrocarbon etc., exist in the form of mixture.The fusing point of the beeswax is 62~63 DEG C, is characterized by having slightly Tackness.
Eye color make-up constituent of the present invention includes noncrystalline wax, so that constituent, which has, is capable of the suitable of smooth ejection When horizontal low-viscosity, and the formation of overlay film can be suppressed.
As the noncrystalline wax, this is not limited to, representational noncrystalline wax is microwax.
Microwax is the micro-crystalline wax being mainly made of isoalkane, and flexibility is strong and fusing point is of a relatively high.Above-mentioned crystallite When wax is mixed with other crystalline waxes (such as paraffin), there is the characteristic for crystallizing minimum or complete removal crystallization, therefore be divided into non- Crystalline wax.
The total content of the crystalline wax and noncrystalline wax is preferably 0.1~10 weight of eye color make-up constituent gross weight Measure %.When the total content of wax is not and during above range, it is difficult to give full play of Expected Results (such as pigment adhesive force of the present invention Deng), and when beyond above range, even in the case of including noncrystalline wax, the viscosity of its overall constituent can also become Height, makes constituent decline by the jet power of nozzle.
Also, contained crystalline wax and noncrystalline wax in the range of the total content is set to reach 1:0.1~1:0.7 Weight ratio.If the content of noncrystalline wax relative to the content of crystalline wax less than 10 weight % when, then the viscosity of constituent is just It can become excessive and be difficult to spray by nozzle, if it exceeds 70 weight %, then cere will become excessively soft, so as to hold Long property is deteriorated.
On the other hand, eye color make-up constituent of the invention with above-mentioned except containing this of crystalline wax and noncrystalline wax Outside basic structure, also pigment, loose powder can be optionally included in the range of without prejudice to the objects and effects of the present invention, disperseed Agent, preservative, tackifier, film forming agent and other functional components etc..
In order to contribute to the understanding of the present invention, embodiment, comparative example and assessment example are enumerated by open below.Under but It is only to be not limited to this with the composition of the present invention and the relevant example of effect, interest field of the invention to state content.
Embodiment 1~2 and comparative example 1~4
According to the composition disclosed in table 1 below, the eye color make-up constituent of embodiment 1~2 and comparative example 1~4 is prepared for. Specifically, the eye color make-up constituent is a kind of soft pen type eye-liner constituent.
Embodiment 1~2 is the eye color make-up constituent of the present invention, is not only to have included crystalline wax but also included the agent of noncrystalline wax Type.Specifically, the weight ratio of crystalline wax and noncrystalline wax is set to 3 in embodiment 1:2, by crystalline wax and non-in embodiment 2 The weight ratio of crystalline wax is set to 4.5:0.5, have differences the content ratio of wax in each example.
Comparative example 1 is traditional eye color make-up constituent, is free from wax and the aqueous phase substrate formulation comprising excessive film forming agent. Comparative example 2 is free from wax and the eye color make-up constituent of the oil phase substrate formulation comprising excessive film forming agent.Comparative example 3 is only to include The eye-liner constituent of the oil phase substrate formulation of crystalline wax, comparative example 4 are the eyes of the only oil phase substrate formulation comprising noncrystalline wax Portion's color make-up constituent.
Table 1
Experimental example 1:Jet power is tested
Measure the viscosity of the constituent of the embodiment 1~2 and comparative example 1~4, when above-mentioned constituent be applied to it is soft During pen type product, jet power of the constituent by nozzle is assessed.
Used appraisal procedure is to fill the constituent of above-described embodiment 1~2 and comparative example 1~4 to soft pen respectively Type eye-liner, presses the extraction location of content until brush head moistening, measures compression number at this time.
Assessment result such as table 2 below.
Table 2
Evaluation item Embodiment 1 Embodiment 2 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4
Viscosity (cps) 900 1,800 950 1,000 4,200 450
Spray compression number 5 8 6 5 X 2
With reference to table 2, as the eye color make-up constituent of the invention comprising crystalline wax and noncrystalline wax at the same time, embodiment 1 ~2 viscosity has been satisfied by the viscosity scope that can be sprayed by nozzle, the i.e. scope of 100cps~2,000cps.In comparative example, As a kind of comparative example 1~2 without cerate type and only the comparative example 4 comprising noncrystalline wax meets and can be sprayed by nozzle The viscosity scope.However, the situation of the only comparative example 3 comprising crystalline wax is:Excessive viscosity is formed, is not particularly suited for soft The constituent of pencil type.
Whether the jet power of the constituent to meeting the viscosity scope is moderately assessed again.In general, assess soft pen The appropriate jet power of type color make-up product be on the basis of whether brush head moisten within pressing 10 times, crystalline wax and noncrystalline wax Weight ratio is 3:2 embodiment 1 only presses 5 times, and brush head has just been wet, and in contrast, noncrystalline wax weight far smaller than crystallizes The situation of the embodiment 2 of wax is more by 3 times, that is, needs pressing 8 times.As described above, the difference of the concrete composition with wax, sticks Degree and jet power are also different, but can also confirm that embodiment 1~2 is respectively provided with the appropriate jet power under appropriate viscosity.
Experimental example 2:The test of head surface coagulation grade
After the surface that the constituent of above-described embodiment 1~2 and comparative example 1~4 has wet soft pen type brush head sprays, confirm The coagulation grade of head surface.Appraisal procedure is as follows.
Appraisal procedure
- the soft pen type eye color make-up product for having used more than 10 times is placed into 3 days (head surface is in drying regime) after, into Measure head surface soaks compression number used again after the above-mentioned jet power test of row.
-◎:Again compression number be 5 times within, zero:Compression number is 6 to 10 times, △ again:Compression number is 11 to 15 again Secondary, X:Compression number is more than 16 times again, thus assesses the coagulation grade of head surface.
- again compression number it is fewer, then the coagulation grade for being evaluated as head surface is smaller.
Assessment result see the table below 3.
Table 3
Evaluation item Embodiment 1 Embodiment 2 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4
Viscosity (cps) 900 1,800 950 1,000 4,200 450
The coagulation grade of head surface -
According to table 3, the feelings of the constituent of the comparative example 1 of traditional aqueous phase substrate formulation of film forming agent have been excessively used Under condition, then compression number is more than 16 times, and the coagulation grade of head surface also shows slightly hard, on the contrary, of the present invention The constituent of embodiment 1 and embodiment 2 is when reusing, even if its compression number is less than or equal to initially pressing time Number, can also be sufficiently humidified so as to brush head, surface is still soft.
The situation of comparative example 3 is ignored because that can not spray.On the other hand, the situation of comparative example 2 is, based on it Oil phase substrate, the surface of brush head remains soft, and the situation of comparative example 4 is, because individually being influenced be subject to noncrystalline wax, its surface Also maintain soft.
Experimental example 3:Use feeling is assessed
Related powder has been carried out to the soft pen type eye-liner of the constituent filled with above-described embodiment 1~2 and comparative example 1~4 The sensory evaluation of the characteristics such as end is dropped, dizzy dye persistence (resistance to dizzy dye degree), water resistance, rate of drying.
The sensory evaluation smears the embodiment 1~2 and comparative example 1~4 respectively using the group that 30 people form as object Constituent after, (wherein, X is assessed to following evaluation items with X, △, zero, ◎:Poor/△:Commonly/zero:Well/ ◎:It is very good).Above-mentioned every evaluation index is quantized by 1~5 point, the final of items is drawn by the average value of summation Assessment result.
Assessment result such as table 4 below.
Table 4
Evaluation item Embodiment 1 Embodiment 2 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4
Powder drops few X X
Dizzy dye persistence X
Water resistance X
Rate of drying
With reference to upper table 4, the embodiment 1 and embodiment 2 of eye color make-up constituent of the present invention can confirm that first Powder drops less, and dizzy dye persistence, water resistance and rate of drying are very good.It additionally can be seen that as a kind of tradition The not constituent of the aqueous phase substrate formulation of the content of wax, the assessment result of comparative example 1 be powder drop characteristic and water resistance it is particularly poor, On the contrary, in the constituent of embodiment 1~2, the powder problem that drops is improved because of the content of wax, and water resistance is also because being prepared into Oil phase substrate formulation is improved.
It additionally can be seen that confirmed jet power is strong in above-mentioned experimental example 1 and experimental example 2 and head surface keeps soft Comparative example 2 and the powder of comparative example 4 drop serious with dizzy dye problem, use feeling is low, and the rate of drying of comparative example 4 is also very Difference, confirmation are a kind of formulations for being not suitable for coming into operation.
Especially, will it is identical on this point of being prepared into oil phase substrate formulation and whether the content of wax on this point have differences Comparative example 2 and the embodiment of the present invention 1, embodiment 2 be compared, it can be seen that content of wax this point to the adhesive force of pigment with And smear the persistence after constituent and produce big influence.
Also, it will only contain the comparative example 4 and embodiment 1, the assessment knot of embodiment 2 of the oil phase substrate formulation of noncrystalline wax Fruit is compared, it is known that crystalline wax plays raising pigment adhesive force and persistent important effect.

Claims (7)

1. a kind of eye color make-up constituent, includes crystalline wax and noncrystalline wax.
2. the eye color make-up constituent according to entitlement requests item 1, it is characterised in that:
The crystalline wax is selected from paraffin, Brazil wax, Tissuemat E, rice wax, ceresine, silk gum, candelila wax and beeswax institute structure Into one or more of group.
3. the eye color make-up constituent according to entitlement requests item 1, it is characterised in that:
The noncrystalline wax is microwax.
4. the eye color make-up constituent according to entitlement requests item 1, it is characterised in that:
The total content of the crystalline wax and noncrystalline wax is the weight of 0.1 weight %~10 relative to the gross weight of constituent entirety Measure %.
5. the eye color make-up constituent according to entitlement requests item 1, it is characterised in that:
The weight ratio of the crystalline wax and noncrystalline wax is 1:0.1~1:0.7.
6. the eye color make-up constituent according to entitlement requests item 1, it is characterised in that:
The viscosity of the eye color make-up constituent is 100~2,000cps.
7. the eye color make-up constituent according to entitlement requests item 1, it is characterised in that:
The eye color make-up constituent is used for the eye-liner of soft pen type.
CN201680054274.6A 2015-09-30 2016-09-27 Low viscosity eye color cosmetic composition containing wax Active CN108024945B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2015-0137555 2015-09-30
KR1020150137555A KR102429029B1 (en) 2015-09-30 2015-09-30 Low viscosity eye make-up cosmetic composition comprising wax
PCT/KR2016/010796 WO2017057889A1 (en) 2015-09-30 2016-09-27 Low-viscosity eye makeup composition comprising wax

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CN108024945A true CN108024945A (en) 2018-05-11
CN108024945B CN108024945B (en) 2021-04-20

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CN (1) CN108024945B (en)
HK (1) HK1255054A1 (en)
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Citations (2)

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KR20150024001A (en) * 2013-08-26 2015-03-06 (주)아모레퍼시픽 Lip cosmetic composition

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US6503516B1 (en) * 1998-11-06 2003-01-07 L'oreal S.A. Make-up composition containing a blend of waxes
KR101060805B1 (en) 2009-05-29 2011-08-30 (주)아모레퍼시픽 Waterproof eye makeup composition with excellent durability
KR101114137B1 (en) * 2009-09-30 2012-03-13 (주)아모레퍼시픽 Method for preparing lip cosmetics by low-temperature dispersion
WO2013192632A1 (en) * 2012-06-22 2013-12-27 Kobo Products, Inc. Concentrated mascara and eyeliner systems for development of new cosmetic products

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US5948393A (en) * 1992-11-30 1999-09-07 Shiseido Company, Ltd. Make-up cosmetic composition
KR20150024001A (en) * 2013-08-26 2015-03-06 (주)아모레퍼시픽 Lip cosmetic composition

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KR20170038323A (en) 2017-04-07
TWI699217B (en) 2020-07-21
HK1255054A1 (en) 2019-08-02
TW201713310A (en) 2017-04-16
KR102429029B1 (en) 2022-08-04
WO2017057889A1 (en) 2017-04-06

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