CN108018097A - A kind of additive of power saving function - Google Patents

A kind of additive of power saving function Download PDF

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Publication number
CN108018097A
CN108018097A CN201711127602.3A CN201711127602A CN108018097A CN 108018097 A CN108018097 A CN 108018097A CN 201711127602 A CN201711127602 A CN 201711127602A CN 108018097 A CN108018097 A CN 108018097A
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CN
China
Prior art keywords
gasoline
fatty alcohol
diesel oil
additive
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711127602.3A
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Chinese (zh)
Inventor
徐叶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mianyang Shuang Gan Technology Co Ltd
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Mianyang Shuang Gan Technology Co Ltd
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Publication date
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Priority to CN201711127602.3A priority Critical patent/CN108018097A/en
Publication of CN108018097A publication Critical patent/CN108018097A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1915—Esters ester radical containing compounds; ester ethers; carbonic acid esters complex esters (at least 3 ester bonds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention relates to kind to have antifreeze and power saving function additive to gasoline, diesel oil, the additive is in terms of system total weight percent, by the paraffin of the 10 98% sour fatty alcohol vinegar of mountain weighing apparatus, 0 50% palmitin fatty alcohol, the stearyl alcohol of stearic acid fatty alcohol vinegar 0 2.5% of O 15%, 0 2.5% soft lipidol, 0 7% behenic acid, 0 10% fatty alcohol polyoxyethylene ether and O 5%, at a temperature of 100 150 DEG C, melting mixing is made.Add the 60ppm 90ppm additives by weight in gasoline, diesel oil, play the role of to gasoline, diesel oil it is antifreeze, energy saving, motor-vehicle tail-gas black smoke reduce, content of carbon oxide reduce by more than 50%, energy saving more than 15%.

Description

A kind of additive of power saving function
Technical field:The invention belongs to fuel oil for vehicles additive agent field, more specifically to-kind to gasoline, ' diesel oil has There is antifreeze and power saving function additive.
Background technology：Gasoline, diesel oil are the important energy, they be the fuel used principal item of Modern Engine it-, As automobile, motorcycle and yacht engine use gasoline or diesel oil.As motor vehicle is increased, the consumption of gasoline and diesel oil Amount increases increasingly, saves most important using gasoline and diesel oil.In addition, gasoline, diesel oil imperfect combustion, largely have producing Evil gas and black smoke, such as-carbonoxide and unburned coke, their environmental pollutions are serious, and cause the waste of the energy.For solution Certainly this problem, Chinese patent CNI 088963A disclose-kind of solid " gasoline saving agent for vehicle fuel ", exist by 0.04% amount The gas saver is added in gasoline, gas saver can be completely dissolved in gasoline, using its surface-active action, eliminate the product in cylinder body Carbon, reduces after burning in tail gas-the content about more than 50% of carbonoxide and alkane, therefore improves the efficiency of combustion of gasoline, oil consumption Reduce by 15%.But this gas saver also has the following disadvantages:(l) fatty amine used in the gas saver is poisonous, to skin and glues Film is irritant；(2) whether this gas saver has diesel oil oil-saving effect, does not illustrate in specification:(3) on this basis, The fuel-saving efficiency of gas saver can be improved into-step, that is, reduces gas saver additive amount in the oil, and oil-saving effect is identical, by This also reduces cost, this is the problem of having much room for improvement.
The content of the invention：In cold winter, especially in the north, with mercury dropped, gasoline, the viscosity of diesel oil increase, Gasoline, diesel oil retrogradation, or even solidification, mobility is bad, and causes starting motor-driven vehicle not.Can be by gasoline, diesel oil Middle addition-kind of additive, reach can improve gasoline, diesel oil mobility and play the effect of fuel-economizing, namely this addition Agent has the function of gasoline, diesel oil antifreeze and energy saving.
The purpose of the present invention aiming at it is set forth above the problem of, there is provided-it is kind nontoxic, efficiently have to gasoline, diesel oil Have antifreeze and power saving function solid additive, it overcome oneself have gasoline, diesel oil cannot be played at the same time in technology it is antifreeze and Energy saving effect, and additive amount smaller of this additive in gasoline, diesel oil, energy-saving effect is more notable, and energy-saving efficiency reaches More than 15%, it is of low cost.
It is provided by the present invention that there is antifreeze and power saving function additive to gasoline, diesel oil, with system gross weight percentage Than meter, it is formed and content is as follows:
Behenic acid aliphatic alcohol ester 10-98%；
Palmitin fatty alcohol 0-50%；
Stearate fatty alcohol 0-15%；
Stearyl alcohol 0-2.5%；
Soft lipidol O-2.5%:
Behenic acid 0-7%；
Fatty alcohol polyoxyethylene ether O-10%；
Paraffin wax O-5%.
Wherein behenic acid aliphatic alcohol ester is behenic acid C16-C25 straight chain fatties alcohol ester or behenic acid C16-25 mixing straight chain fat Fat alcohol vinegar；Palmitin fatty alcohol is palmitic acid C16-C20 straight-chain fatty alcohols vinegar or palmitic acid C16-20 mixing straight-chain fatty alcohols Ester；Stearate fatty alcohol is stearic acid C16-C20 straight chain fatties alcohol phenol or stearic acid C16-20 mixing straight chain fatty alcohol esters.
For the behenic acid aliphatic alcohol ester of the present invention, mixed for behenic acid C16-25 straight chain fatties alcohol ester or behenic acid C16-25 Straight chain fatty alcohol ester is closed, preferably using behenic acid C16 { 20 straight chain fatty alcohol esters or behenic acid C16-20 mixing straight-chain fatty alcohols Vinegar, most preferably with behenic acid palmitin alcohol ester.Palmitic acid fatty alcohol vinegar for the present invention is palmitic acid C16-CZO straight chain fatties 20 mixing straight-chain fatty alcohol vinegar under alcohol ester or palmitic acid C16, preferably using palmitic acid soft lipidol vinegar.Stearic acid for the present invention Aliphatic alcohol ester is stearic acid C16-C20 straight-chain fatty alcohols vinegar or stearic acid C16-20 mixing straight chain fatty alcohol esters, preferably using hard Resin acid soft lipidol vinegar.Behenic acid fatty alcohol vinegar, palmitic acid fatty alcohol vinegar and stearate fatty alcohol can be by classical organic conjunctions Into method, it is made by corresponding sour and corresponding alcohol direct esterification.
Stearyl alcohol, soft lipidol, behenic acid, fatty alcohol polyoxyethylene ether and paraffin wax used in the present invention are common Fine Organic Chemicals, it is cheap and easy to get.Wherein fatty alcohol polyoxyethylene ether is-kind of nonionic surfactant, alias AEO, Such as AEO-3 or AEO-5.
The present invention's is as follows to the preparation method of gasoline, diesel oil with antifreeze and power saving function additive:Respectively by 10- 98% behenic acid aliphatic alcohol ester, O-5 palmitin fatty alcohol both, the stearate fatty alcohol of O-15%, 0-2.5% it is hard Lipidol, the soft lipidol of O-2.5%, the behenic acid of 0-7%, the paraffin wax of the fatty alcohol polyoxyethylene ether of O-10% and O-5% add In reaction kettle, 100-150 DEG C is stirred and heated to, after whole consolutes, insulation continues to stir 30-60min, then-side stirring- While be cooled to room temperature, sheet, granular or powdered can be made after cooling by requirement, then packed.
Add the additive of the 60ppm-90ppm present invention by weight in gasoline, diesel oil, it can be dissolved in gasoline or bavin rapidly In oil, gasoline, the solidification point and viscosity of diesel oil are reduced, improves its mobility.In cold winter, especially in the north, temperature Low, gasoline, the increase of diesel oil viscosity, retrogradation, or even solidification, such as O diesel oil, solidification point is 0 DEG C, and No. 0 diesel oil is very during O DEG C of temperature Sticky, when O DEG C of motor vehicle, uses O diesel oil, and engine start is not got up.When adding 60ppm- by weight in gasoline, diesel oil The additive of the 90PPm present invention, since it can reduce gasoline, the solidification point of diesel oil and viscosity, gasoline, the mobility of diesel oil obtain Improve, thus when temperature is very low, by adding the additive of the present invention, gasoline or diesel oil in gasoline or diesel oil, especially Diesel oil can be well applied to motor vehicle, i.e., the additive has the function of gasoline, diesel oil antifreeze.
Due to adding the additive of the 60ppm--9oppm present invention by weight in gasoline, diesel oil, it reduce gasoline or The solidification point and viscosity of diesel oil, make it reduce in cylinder wall adhesion strength, reduce to cylinder wall carbon distribution, while cone angle when making its atomization Increase, droplet attenuates, and range becomes near, gasoline or diesel oil is limited quick burning high temperature and is caused in quick burning and ormal combustion period smooth combustion Soot emission and cylinder wall carbon distribution；Since additive makes gasoline, diesel oil atomization quality good, droplet distribution is into fine particle or oil Mist, increases gasoline or the surface area of diesel oil and air contact, can uniformly be mixed with more oxygen, make gasoline, diesel combustion complete, The pernicious gases such as reduction-carbonoxide generate, and improve gasoline, the efficiency of combustion of diesel oil, so as to achieve the purpose that energy saving, and protection ring The good result in border.
The opposite prior art of the present invention, has the following advantages that:
1. the additive of the present invention, all the components are nontoxic, safe to the human body.
2. the only behenic acid containing O-770 in the additive of the present invention, additive amount of the additive in gasoline, diesel oil is very It is small, 6OpPm-90pPm is calculated as by gasoline, diesel oil weight, thus the additive of the present invention is harmless to various types of vehicles parts.
3. the additive of the present invention, adds the amount of 6OPPm-90ppm by weight in gasoline, diesel oil, energy-saving effect is more aobvious Write, vehicle exhaust black smoke is reduced, and in tail gas-content of carbon oxide reduces by more than 50%, hydrocarbon reduces by more than 60%, energy saving 15% and environmental protection, and the additive amount of gas saver is 400ppm in 1 088963A of Chinese patent prospectus CN, both Compare, additive energy-saving effect of the invention is more notable；It plays antifreeze effect again at the same time, improves gasoline, diesel oil in the winter time Mobility.
4. the additive of the present invention, raw material is easy to get extensively, of low cost, simple production process.
5. being solid under the additive room temperature of the present invention, transport, easy to carry and non-toxic and safe, can be made each on request The sample of kind shape and weight, in order to use.
With reference to embodiment to the present invention make into-step explanation.
Embodiment 1:
In a kettle, add 7809 behenic acid soft lipidol vinegar, 259 stearyl alcohols, 259 soft lipidols, 709 behenic acids, 50gAEO-3 and 509 paraffin waxes, are stirred and heated to 127 DEG C -132 DEG C, and after whole consolutes, insulation continues to stir 40min, so Afterwards-while stirring-while cool down, be compressed into tablet form after cooling, every 1.59 weights, then packed.
Obtained additive as stated above is taken, 60pPm by weight is added in gasoline, and 2000 type Santana use the vapour Oil, carries out driving experiment, tail gas is tested according to a conventional method, the results showed that, exhaust emissions black smoke unobvious ,-carbonoxide Content reduces by 50%, and hydrocarbons content reduces by 60%, energy saving 15.7%.
Embodiment 2:
In a kettle, 9809 behenic acid C16-20 mixed fatty alcohols vinegar and 209AEO-3 are added, is stirred and heated to 140OC-145 DEG C, after whole consolutes, insulation continue stir 3Omin, then-while stirring-while cool down, it is tabletted after cooling Shape, every 1.59 weights, then packed.
Obtained additive as stated above is taken, 90ppm by weight is added in diesel oil, and 1.2 tons of lorries of Isuzu Motors use The diesel oil, carries out driving experiment, tail gas is tested according to a conventional method, the results showed that, exhaust emissions black smoke unobvious ,-oxygen Changing carbon content reduces by 50%, and hydrocarbons content reduces by 50%, energy saving 15%.
Embodiment 3:
In a kettle, 5009 behenic acid stearyl alcohol vinegar, 3009 palmitic acid palmitin alcohol esters, 909 stearic acid soft lipidols are added Ester, 259 stearyl alcohols, 249 soft lipidols, 479 behenic acids and 14gAEO-3 are added in reaction kettle, are stirred and heated to 120 DEG C -130 DEG C, after whole consolutes, insulation continue stir 40min, then-while stirring-while cool down, granular, every 1. shops are made after cooling Weight, then packed.
Obtained additive as stated above is taken .80pPm by weight is added in No. 0 diesel oil, in the winter time outside air temperature O DEG C when, 1.2 tons of lorries of Isuzu Motors use the diesel oil, carry out driving experiment, tail gas is tested according to a conventional method, as a result table Bright, exhaust emissions black smoke unobvious ,-content of carbon oxide reduces by 45%, and hydrocarbons content reduces by 45%, energy saving 15%.
Embodiment 4:
In a kettle, 1009 behenic acid palmitin alcohol phenol, 5009 palmitic acid palmitin alcohol esters, 1509 stearic acid soft lipidols are added Ester, 259 stearyl alcohols, 259 soft lipidols, 709 behenic acids, 8OgAEO-5 and 509 paraffin waxes, are stirred and heated to 105 DEG C -110 DEG C, After whole consolutes, insulation continue stir 60min, then-while stirring-while cool down, granular, every 1.59 weights are made after cooling, Packed again.
Obtained additive as stated above is taken, 75ppm by weight is added in gasoline, and 2000 type Santana use the vapour Oil, carries out driving experiment, tail gas is tested according to a conventional method, the results showed that, exhaust emissions black smoke unobvious ,-carbonoxide Content reduces by 50%, and hydrocarbons content reduces by 50%, energy saving 15%.

Claims (7)

  1. A kind of 1. additive of power saving function, it is characterised in that:
    The additive is in terms of system total weight percent, it is formed and content is as follows:
    Behenic acid aliphatic alcohol ester 10-98%
    Palmitin fatty alcohol O-50%
    Stearate fatty alcohol 0-15%
    Stearyl alcohol O-2.5%；
    Soft lipidol 0-2.5%；
    Behenic acid O-7%；
    Fatty alcohol polyoxyethylene ether 0-10%
    Paraffin wax O-5%.
  2. 2. there is antifreeze and power saving function additive to gasoline, diesel oil as described in claim 1, it is characterised in that:It is described Behenic acid aliphatic alcohol ester be behenic acid C16-C25 straight-chain fatty alcohols vinegar or behenic acid C16-25 mixing straight chain fatty alcohol esters；Institute The palmitin fatty alcohol stated is palmitic acid C16-C20 straight-chain fatty alcohols vinegar or palmitic acid C16-20 mixing straight chain fatty alcohol esters； The stearic acid fatty alcohol vinegar is stearic acid C16-C20 straight-chain fatty alcohols vinegar or the stearic acid C16-20 mixing straight-chain fatty alcohol tenth of the twelve Earthly Branches Purport.
  3. 3. there is antifreeze and power saving function additive to gasoline, diesel oil as described in claim 1 or 2, it is characterised in that:Institute The behenic acid acid aliphatic alcohol ester stated is behenic acid C16-20 straight chain lipidol esters or behenic acid C16-20 mixing straight-chain fatty alcohol vinegar.
  4. 4. there is antifreeze and power saving function additive to gasoline, diesel oil as described in claim 1,2 or 3, it is characterised in that: The behenic acid aliphatic alcohol ester is behenic acid palmitin alcohol ester.
  5. 5. there is antifreeze and power saving function additive to gasoline, diesel oil as described in claim 1 or 2, it is characterised in that:Institute The palmitic acid fatty alcohol vinegar stated is palmitic acid palmitin alcohol ester.
  6. 6. there is antifreeze and power saving function additive to gasoline, diesel oil as described in claim 1 or 2, it is characterised in that:Institute The stearic acid fatty alcohol vinegar stated is stearic acid palmitin alcohol ester.
  7. 7. there is antifreeze and power saving function additive to gasoline, diesel oil as described in claim 1, it is characterised in that:It is described Fatty alcohol polyoxyethylene ether be AEO-3 or AEO-5.
CN201711127602.3A 2017-11-15 2017-11-15 A kind of additive of power saving function Pending CN108018097A (en)

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CN201711127602.3A CN108018097A (en) 2017-11-15 2017-11-15 A kind of additive of power saving function

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CN108018097A true CN108018097A (en) 2018-05-11

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1318626A (en) * 2001-05-24 2001-10-24 祝强 Antifreezing and energy saving gasoline and diesel oil additive
CN107586574A (en) * 2017-11-06 2018-01-16 都江堰惠农生物技术有限责任公司 A kind of additive of power saving function

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1318626A (en) * 2001-05-24 2001-10-24 祝强 Antifreezing and energy saving gasoline and diesel oil additive
CN107586574A (en) * 2017-11-06 2018-01-16 都江堰惠农生物技术有限责任公司 A kind of additive of power saving function

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Application publication date: 20180511