CN108017279A - One kind is without nickel black cigarette ash system glassware formula and its glassware manufacturing process - Google Patents
One kind is without nickel black cigarette ash system glassware formula and its glassware manufacturing process Download PDFInfo
- Publication number
- CN108017279A CN108017279A CN201711415306.3A CN201711415306A CN108017279A CN 108017279 A CN108017279 A CN 108017279A CN 201711415306 A CN201711415306 A CN 201711415306A CN 108017279 A CN108017279 A CN 108017279A
- Authority
- CN
- China
- Prior art keywords
- batch
- cigarette ash
- glassware
- cobalt oxide
- potassium permanganate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/10—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce uniformly-coloured transparent products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses one kind without nickel black cigarette ash system glassware formula, it is made of following components according to ratio of weight and number：Chrome green 1 1.5, potassium permanganate 2 2.5, cobalt oxide 0.34 0.4, batch 220 260；The batch is silica flour, feldspar powder, borax, fluorspar powder one kind therein or its any combination.The invention also discloses the glassware manufacturing process of above application formula.The present invention is made of no nickel material, nontoxic in whole production process, and glass colour can reach the standard requirement of cigarette ash color, put into mass production.During present invention manufacture glass, since no harmful substance produces, thus it is more secure to worker's health nor pollute the environment, meanwhile, the product manufactured is more environmentally-friendly, enjoys client to like.
Description
Technical field
The present invention relates to a kind of glassware, more particularly to one kind without nickel black cigarette ash system glassware formula and its glass
Vessel manufacturing process.
Background technology
Need to use soot during smoked glass is manufactured, this black smoke ash component is mainly nickel oxide or Asia
Nickel, it is that this soot is hazardous to the human body there are problem, component itself is harmful poisonous, and cost of material is high, causes to produce
Product added cost.
Therefore manufactured it is applicant's understanding that one kind can be developed without nickel black cigarette ash system glassware formula and its glassware
Technique, the glassware grey for making to manufacture and the indistinction manufactured using nickel oxide or sub- nickel, but it is not nickeliferous, therefore
It is nontoxic in production process, the health and environment of operator can be protected, while be also that product is more environmentally-friendly.
The content of the invention
In view of the drawbacks described above of the prior art, the technical problems to be solved by the invention are to provide one kind without nickel black cigarette ash
It is glassware formula and its glassware manufacturing process.
To achieve the above object, pressed the present invention provides one kind without nickel black cigarette ash system glassware formula by following components
Formed according to ratio of weight and number：Chrome green 1-1.5, potassium permanganate 2-2.5, cobalt oxide 0.34-0.4, batch 220-260；
The batch is silica flour, feldspar powder, borax, fluorspar powder one kind therein or its any combination.
A kind of glassware manufacturing process, includes the following steps：
S1, chrome green, potassium permanganate, cobalt oxide, batch wear into particle diameter and are not more than 80 mesh powders；
Chrome green, potassium permanganate, cobalt oxide, be uniformly mixed by S2, obtains no nickel black cigarette ash；
Under S3, oxidizing atmosphere, glass melting temperature will add in 1300-1400 DEG C of crucible furnace to be melted without nickel black cigarette ash material, is continued
Be melted, and open the cylinder time for 9 it is small when；
S4, can increase the allotment experiment of bubbling auxiliary clarification many times before opening cylinder, in colour stability of the crucible furnace to material side, material
Property, the coefficient of expansion, under manual operations and different temperatures, under different atmosphere color change, change test in glass is most
Material side's color is determined afterwards, and repeatedly goes out sample contrast, confirms specific proportioning with final.
The beneficial effects of the invention are as follows：
1st, the present invention is made of no nickel material, nontoxic in whole production process, and glass colour can reach cigarette ash
The standard requirement of color, has put into mass production.
2nd, during present invention manufacture glass, since no harmful substance produces, therefore relatively have to worker's health
Ensure nor pollute the environment, meanwhile, the product manufactured is more environmentally-friendly, enjoys client to like.
Embodiment
With reference to embodiment, the invention will be further described：
Embodiment one
One kind is made of without nickel black cigarette ash system glassware formula following components according to ratio of weight and number：Chrome green 1.25, permanganic acid
Potassium 2.1, cobalt oxide 0.37, batch 250；
The batch is silica flour, borax equal proportion mixes.
Embodiment two
One kind is made of without nickel black cigarette ash system glassware formula following components according to ratio of weight and number：Chrome green 1.3, permanganic acid
Potassium 2.2, cobalt oxide 0.36, batch 260；The batch is silica flour.
Embodiment three
One kind is made of without nickel black cigarette ash system glassware formula following components according to ratio of weight and number：Chrome green 1.5, permanganic acid
Potassium 2, cobalt oxide 0.35, batch 240；The batch is silica flour, fluorspar powder equal proportion mixes.
Example IV
A kind of glassware manufacturing process, includes the following steps：
S1, chrome green, potassium permanganate, cobalt oxide, batch wear into particle diameter and are not more than 80 mesh powders；
Chrome green, potassium permanganate, cobalt oxide, be uniformly mixed by S2, obtains no nickel black cigarette ash；
Under S3, oxidizing atmosphere, glass melting temperature will melt in 1350 DEG C of crucible furnace without nickel black cigarette ash material, continue to be melted, and open
When the cylinder time is 9 small.
Preferred embodiment of the invention described in detail above.It should be appreciated that those of ordinary skill in the art without
Need creative work to conceive according to the present invention and make many modifications and variations.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical solution, all should be in the protection domain being defined in the patent claims.
Claims (7)
1. it is a kind of without nickel black cigarette ash system glassware formula, it is characterized in that：It is made of following components according to ratio of weight and number：Chrome green
1-1.5, potassium permanganate 2-2.5, cobalt oxide 0.34-0.4, batch 220-260；
The batch is silica flour, feldspar powder, borax, fluorspar powder one kind therein or its any combination.
2. as claimed in claim 1 without nickel black cigarette ash system glassware formula, it is characterized in that：By following components according to parts by weight
Number is than forming：Chrome green 1.25, potassium permanganate 2.1, cobalt oxide 0.37, batch 250；The batch is silica flour, borax
Equal proportion mixes.
3. as claimed in claim 1 without nickel black cigarette ash system glassware formula, it is characterized in that：By following components according to parts by weight
Number is than forming：Chrome green 1.3, potassium permanganate 2.2, cobalt oxide 0.36, batch 260；The batch is silica flour.
4. as claimed in claim 1 without nickel black cigarette ash system glassware formula, it is characterized in that：By following components according to parts by weight
Number is than forming：Chrome green 1.5, potassium permanganate 2, cobalt oxide 0.35, batch 240；The batch is silica flour, fluorspar powder etc.
Ratio mixes.
5. a kind of glassware manufacturing process, it is characterized in that：Include the following steps：
S1, chrome green, potassium permanganate, cobalt oxide, batch wear into particle diameter and are not more than 80 mesh powders；
Chrome green, potassium permanganate, cobalt oxide, be uniformly mixed by S2, obtains no nickel black cigarette ash；
Under S3, oxidizing atmosphere, glass melting temperature will add in 1300-1400 DEG C of crucible furnace to be melted without nickel black cigarette ash material, is continued
Be melted, and open the cylinder time for 9 it is small when.
6. glassware manufacturing process as claimed in claim 1, it is characterized in that：Include the following steps：
S1, chrome green, potassium permanganate, cobalt oxide, batch wear into particle diameter and are not more than 80 mesh powders；
Chrome green, potassium permanganate, cobalt oxide, be uniformly mixed by S2, obtains no nickel black cigarette ash；
Under S3, oxidizing atmosphere, glass melting temperature will melt in 1350 DEG C of crucible furnace without nickel black cigarette ash material, continue to be melted, and open
When the cylinder time is 9 small.
7. the glassware manufacturing process as described in claim 5 or 6, it is characterized in that：Further include following steps：
S4, can increase the allotment experiment of bubbling auxiliary clarification many times before opening cylinder, in colour stability of the crucible furnace to material side, material
Property, the coefficient of expansion, under manual operations and different temperatures, under different atmosphere color change, change test in glass is most
Material side's color is determined afterwards, and repeatedly goes out sample contrast, confirms specific proportioning with final.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711415306.3A CN108017279A (en) | 2017-12-25 | 2017-12-25 | One kind is without nickel black cigarette ash system glassware formula and its glassware manufacturing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711415306.3A CN108017279A (en) | 2017-12-25 | 2017-12-25 | One kind is without nickel black cigarette ash system glassware formula and its glassware manufacturing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108017279A true CN108017279A (en) | 2018-05-11 |
Family
ID=62072902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711415306.3A Pending CN108017279A (en) | 2017-12-25 | 2017-12-25 | One kind is without nickel black cigarette ash system glassware formula and its glassware manufacturing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108017279A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004026257A1 (en) * | 2004-04-19 | 2005-11-10 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Glass composition used in the production of glass products, e.g. windows, has inner lying parts of the glass supporting a color marker |
| CN101003419A (en) * | 2006-09-11 | 2007-07-25 | 福耀集团双辽有限公司 | Gray coated glass, and preparation method |
| CN101219858A (en) * | 2008-01-22 | 2008-07-16 | 方久华 | Tinted glass produced by using chromium-containing waste slag and method for producing the same |
| US8932967B2 (en) * | 2012-02-21 | 2015-01-13 | Vetriceramici S.P.A. | Composition for colouring glass and uses thereof |
| CN107056065A (en) * | 2016-12-15 | 2017-08-18 | 璐哄悍 | A kind of devitrified glass and preparation method thereof |
-
2017
- 2017-12-25 CN CN201711415306.3A patent/CN108017279A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004026257A1 (en) * | 2004-04-19 | 2005-11-10 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Glass composition used in the production of glass products, e.g. windows, has inner lying parts of the glass supporting a color marker |
| CN101003419A (en) * | 2006-09-11 | 2007-07-25 | 福耀集团双辽有限公司 | Gray coated glass, and preparation method |
| CN101219858A (en) * | 2008-01-22 | 2008-07-16 | 方久华 | Tinted glass produced by using chromium-containing waste slag and method for producing the same |
| US8932967B2 (en) * | 2012-02-21 | 2015-01-13 | Vetriceramici S.P.A. | Composition for colouring glass and uses thereof |
| CN107056065A (en) * | 2016-12-15 | 2017-08-18 | 璐哄悍 | A kind of devitrified glass and preparation method thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180511 |
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| RJ01 | Rejection of invention patent application after publication |