CN104478217A - Environment-friendly copper ruby glass glaze, preparation method of environment-friendly copper ruby glass glaze and method for preparing copper ruby glass glaze surface from environment-friendly copper ruby glass glaze - Google Patents
Environment-friendly copper ruby glass glaze, preparation method of environment-friendly copper ruby glass glaze and method for preparing copper ruby glass glaze surface from environment-friendly copper ruby glass glaze Download PDFInfo
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- CN104478217A CN104478217A CN201410678251.5A CN201410678251A CN104478217A CN 104478217 A CN104478217 A CN 104478217A CN 201410678251 A CN201410678251 A CN 201410678251A CN 104478217 A CN104478217 A CN 104478217A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses environment-friendly copper ruby glass glaze for float-process flat glass surface decoration, a production method of the environment-friendly copper ruby glass glaze and a method for preparing a copper ruby glass glaze surface from the environment-friendly copper ruby glass glaze. The glass glaze disclosed by the invention is prepared from parent glaze and a colorant, wherein the parent glaze is prepared from the following components: 30-75% of SiO2, 5-20% of B2O3, 5-19% of ZnO, 1-15% of Al2O3, 3-5% of Bi2O3 and 4-25% of R2O (R comprises Li, Na or K) or 3-30% of RO (R comprises Mg, Ca, Ba or Sr). The colorant is one or a mixture of copper oxide, cuprous oxide and copper carbonate. The copper ruby glass glaze disclosed by the invention is free of lead and cadmium, is capable of avoiding injuring a human body or damaging the environment and is specially used for manufacturing a float-process flat glass surface. The copper ruby glass glaze can be regulated to different red colors as required, is suitable for common float-process flat glass and can be tempered and sintered.
Description
Technical field
The present invention relates to a kind of lead-free and cadmium-free environmental protection copper ruby glass glaze and preparation method thereof, be also exclusively used in common float flat glass maybe can sinter environmental protection glass copper red color glaze and preparation method thereof and be prepared the method for glaze paint by it by tempering in particular to a kind of.
Background technology
Colored glazed glass has wear-resisting, resistance to acids and bases, is widely used in the aspects such as architectural decoration, family property glass, electronic glass.The colored glazed glass that copper is prepared as tinting material, has low cost, bright-colored, can according to being made into orange, red, the multiple color such as scarlet, garnet.Traditional glass glaze introduce red use in iron content, leaded, the oxide compound containing chromium or the sulfide containing cadmium more one or more be glass glaze introducing redness.But lead, cadmium, chromium are all heavy metal elements, have certain injury to environment and human body, oxidation iron rule has certain side effect.Rough flambe Application comparison in pottery is extensive, adopts copper-containing substance as chromogenic reagent, through firing with reductive flame rough flambe in preparation process.If but adopt the method for making of traditional ceramics rough flambe and inadvisable at glass surface, because general rough flambe is all that glaze wherein adds the reductive agents such as the oxide compound of carbon dust or tin cupric ion is reduced.In the preparation process of glass glaze, tin and carbon dust are all easy makes glass glaze irregular colour because of skewness, affects decorative effect.
In view of this, need to invent a kind of be adapted to prepare rough flambe surface glass novel lead-free, without cadmium environmental protection color glaze, make it have color even, the advantages such as preparation cost is cheap, safety and environmental protection.
Summary of the invention
Technical problem to be solved by this invention be to provide a kind of raw material cheap, be adapted to leadless environment-friendly glass glaze preparing rough flambe surface glass and preparation method thereof.
The present invention still further provides the method that the above-mentioned copper ruby glass glaze of the high employing of a kind of yield rate prepares copper ruby glass glaze paint.
In order to solve the problems of the technologies described above, the technical scheme of copper ruby glass color glaze of the present invention is as follows: for the environmental protection copper ruby glass glaze of float flat glass surface decoration, it comprises parent glaze, and described parent glaze comprises the component of following weight percent:
SiO
2 30-75%；
B
2O
3 5-20%；
ZnO 5-25%；
Al
2O
3 0.5-15%；
Bi
2O
3 3-5%；
R
2o 4-25% wherein R comprises Li and/or Na and/or K;
RO 3-30% wherein R comprises Mg and/or Ca and/or Ba and/or Sr.
Preferably, described parent glaze comprises the component of following weight percent:
30-70%SiO
2；
5-25%ZnO；
1-15%CaO+MgO；
0-15%BaO；
0-15%SrO；
5-20%B
2O
3；
0.5-15%Al
2O
3；
0.1-10%TiO
2；
0-10%ZrO
2；
1-25%K
2O+Na
2O；
1-10%Li
2O。
furtherpreferably, described parent glaze comprises the component of following weight percent:
31-60%SiO
2；
5-19%ZnO；
1-10%CaO+MgO；
0-10%BaO；
0-10%SrO；
5-20%B
2O
3；
0.5-10%Al
2O
3；
0.5-10%TiO
2；
0-5%ZrO
2；
2-20%K
2O+Na
2O；
1-8%Li
2O。
Preferably, described glass glaze is also comprising toner.Described tinting material is 0.1-20% by raw material weight per-cent.
Preferably, described tinting material is selected from following raw material: one or more mixtures of cupric oxide, Red copper oxide, copper carbonate.
The preparation method of above-mentioned environmental protection copper ruby glass glaze provided by the present invention comprises the following steps:
(1) the parent glaze component of following weight percent is taken by weight percentage: 25-70%SiO
2; 5-30%ZnO; 1-15%CaO+MgO; 0-15%BaO; 0-15%SrO; 5-33%B
2o
3; 0.5-15%Al
2o
3; 0.1-10%TiO
2; 0-10%ZrO
2; 1-25%K
2o+Na
2o; 1-10%Li
2o; The compound of 0.1-20% copper;
(2) all raw materials that step (1) takes are put into stirrer to stir or ball mill ball milling ball milling 10-30 minute, its rotating speed is 60-100 rev/min, mixes;
(3) mixture that step (2) obtains is founded at 1000-1350 DEG C, make the complete melting of mixture, obtain melten glass liquid;
(4) melten glass liquid shrend step (3) obtained;
(5) frit after step (4) shrend is put into ball mill ball milling 1-6 hour, its rotating speed is 60-100 rev/min, obtains glass powder;
(6) glass powder crossed by step (5) ball milling is 80-120 DEG C of oven dry in loft drier, and gained powder is copper ruby glass glaze.
The method preparing copper ruby glass glaze paint by above-mentioned copper ruby glass glaze provided by the present invention comprises the following steps:
(1) lead-free and cadmium-free environmental protection copper ruby glass glaze provided by the present invention will be got, and add blender and be prepared into glaze slip;
(2) after sheet glass substrate of making even cleaning, by the glaze slip that step (1) obtains, glazing on a glass substrate, dry;
(3) the glass basis feeding annealing furnace of dry for step (2) rear band glaze or roller kiln are burnt till, second face that obtains is red rough flambe surface glass.
Preferably, described glass basis is common float flat glass.
Preferably, step (3) firing temperature is 630-680 DEG C.
The beneficial effect adopting such scheme to produce is:
1, the present invention through the composite of Multiple components and screen the glass glaze that provides unleaded, without cadmium, can avoid human body and environmental pollution;
2, copper ruby glass glaze of the present invention is consistent with the sheet glass coefficient of expansion, avoids glaze paint and breaks, peels off, and the long-time glaze paint that uses can not come off;
3, copper ruby glass glaze of the present invention is used for the copper red colored glaze glass that float flat glass is made, chemical stability good (chemical stability of glaze paint relates generally to: resistance to acids and bases, erosion resistance, weathering resistance), and utilize the rich tin face of float glass itself, without the need to adding reductive agent, reduce raw materials cost;
4, copper ruby glass glaze of the present invention is used for the rich tin face of glass, and the tin in rich tin face is evenly distributed, therefore made glaze paint color even, no color differnece, the amount of adjustment tinting material can be needed to reach different redness according to concrete.Get its colourity of point measurement at the different positions of the enamelled glass sample of a square metre that makes, colourity is all consistent.
5, copper ruby glass glaze of the present invention is used for the enamelled glass made of float flat glass, and can maybe can burn till by tempering according to actual needs, the security of tempering colored glazed glass is high, and sintering colored glazed glass can secondary processing, as cutting, punching etc.;
6, the step of the preparation method of copper ruby glass glaze provided by the present invention and the preparation method of glaze paint is simple, and energy consumption is low, is applicable to suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in more detail, but protection scope of the present invention is not limited in this.
Embodiment 1
The present embodiment glass glaze is made up of parent glaze and tinting material, and each composition of parent glaze counts by weight percentage as follows: 45%SiO
2; 25%ZnO; 3%CaO+MgO; 2%BaO; 1%SrO; 6%B
2o
3; 0.5%Al
2o
3; 2%TiO
2; 4%ZrO
2; 6%K
2o+Na
2o; 3%Li
2o; 2.5%CuO; The manufacturing process of glass enamel is as follows:
The all raw materials taken are put into ball mill ball milling ball milling 15 minutes, and its rotating speed is 80 revs/min, mixes;
Obtained compound is founded at 1250 DEG C, makes the complete melting of mixture, obtain melten glass liquid;
By the shrend of melten glass liquid, the frit after shrend puts into ball mill ball milling 3 hours, and its rotating speed is 100 revs/min, obtains glass powder;
The glass powder crossed by ball milling is dried in 120 DEG C, loft drier, and gained powder is copper ruby glass glaze.
By obtained copper ruby glass glaze, be prepared into glaze slip with blender in the ratio of 70:30 and blender; Blender be existing glass enamel conventional be used for a powdered frit furnishing glaze slip, make colored glaze powder can be dispersed wherein, keep suspended state, not easily precipitate; The glaze slip of certain viscosity can be formed after mediation is good, and to Glass body, there is certain sticking power.The blender of such as color glaze has frankincense, rosin ester, rosinol, dextrin, agar, methylcellulose gum, polyvinyl alcohol, polymethylmethacrylate etc.
After getting the cleaning of float flat glass substrate, tin face is used to judge that rich tin face determined by instrument;
By obtained glaze slip, the rich tin face of glass substrate adopts the mode glazing of silk screen printing, dry;
By the glass basis of band glaze through 660 DEG C of sintering, second face that namely obtains is henna qualified rough flambe surface glass.
Embodiment 2
A kind of glass enamel is formed primarily of parent glaze and tinting material, and each composition of parent glaze counts by weight percentage as follows: 50%SiO
2; 15%ZnO; 5%CaO+MgO; 2%BaO; 1%SrO; 10%B
2o
3; 1%Al
2o
3; 2%TiO
2; 2%ZrO
2; 8%K
2o+Na
2o; 3%Li
2o; 1%CuCO
3; The manufacturing process of glass enamel is as follows:
The all raw materials taken are put into ball mill ball milling ball milling 15 minutes, and its rotating speed is 80 revs/min, mixes;
Obtained compound is founded at 1300 DEG C, makes the complete melting of mixture, obtain melten glass liquid;
By the shrend of melten glass liquid, the frit after shrend puts into ball mill ball milling 3 hours, and its rotating speed is 100 revs/min, obtains glass powder;
The glass powder crossed by ball milling is dried in 120 DEG C, loft drier, and gained powder is copper ruby glass glaze.
By obtained copper ruby glass glaze, be prepared into glaze slip with blender according to the ratio of 65:35 and blender;
After getting the cleaning of float flat glass substrate, tin face is used to judge that rich tin face determined by instrument;
By obtained glaze slip, the rich tin face of glass substrate adopts the mode glazing of spraying, dry;
By the glass basis of band glaze through 680 DEG C of sintering, second face that namely obtains is the qualified rough flambe surface glass of orange.
Embodiment 3
A kind of glass enamel is formed primarily of parent glaze and tinting material, and each composition of parent glaze counts by weight percentage as follows: 55%SiO
2; 15%ZnO; 5%CaO+MgO; 1%BaO; 1%SrO; 8%B
2o
3; 1%Al
2o
3; 0.5%TiO
2; 11%K
2o+Na
2o; 1%Li
2o; 1.5%CuO; The manufacturing process of glass enamel is as follows:
The all raw materials taken are put into ball mill ball milling ball milling 20 minutes, and its rotating speed is 80 revs/min, mixes;
Obtained compound is founded at 1300 DEG C, makes the complete melting of mixture, obtain melten glass liquid;
By the shrend of melten glass liquid, the frit after shrend puts into ball mill ball milling 4 hours, and its rotating speed is 100 revs/min, obtains glass powder;
The glass powder crossed by ball milling is dried in 120 DEG C, loft drier, and gained powder is copper ruby glass glaze.
By obtained copper ruby glass glaze, be prepared into glaze slip with blender according to the ratio of 70:30 and blender;
After getting the cleaning of float flat glass substrate, tin face is used to judge that rich tin face determined by instrument;
By obtained glaze slip, the rich tin face of glass substrate adopts the mode glazing of spraying, dry;
By the glass basis of band glaze through 670 DEG C of sintering, second face that namely obtains is red rough flambe surface glass.
Embodiment 4
A kind of glass enamel is formed primarily of parent glaze and tinting material, and each composition of parent glaze counts by weight percentage as follows: 42%SiO
2; 15%ZnO; 5%CaO+MgO; 1%BaO; 1%SrO; 15%B
2o
3; 2%Al
2o
3; 2%TiO
2; 2%ZrO
2; 11%K
2o+Na
2o; 1%Li
2o; 2%Cu
2o; The manufacturing process of glass enamel is as follows:
The all raw materials taken are put into ball mill ball milling ball milling 10 minutes, and its rotating speed is 100 revs/min, mixes;
Obtained compound is founded at 1250 DEG C, makes the complete melting of mixture, obtain melten glass liquid;
By the shrend of melten glass liquid, the frit after shrend puts into ball mill ball milling 4 hours, and its rotating speed is 100 revs/min, obtains glass powder;
The glass powder crossed by ball milling is dried in 120 DEG C, loft drier, and gained powder is copper ruby glass glaze.
By obtained copper ruby glass glaze, be prepared into glaze slip with blender according to the ratio of 70:30 and blender;
After getting the cleaning of float flat glass substrate, tin face is used to judge that rich tin face determined by instrument;
By obtained glaze slip, the rich tin face of glass substrate adopts the mode glazing of spraying, dry;
By the glass basis of band glaze through 630 DEG C of sintering, second face that namely obtains is bolarious rough flambe surface glass.Property of glaze prepared by table 1. above-described embodiment:
Above-mentioned performance index are industry common index, and wherein stability generally refers to acid and alkali-resistance, the weathering resistance of glaze paint.Opacifying power refers to the covering degree of glaze in the face of glass, and be generally the transparency seeing glaze paint after making glaze paint, then opacifying power is good to can't see other object through glaze paint.Melt fastness altogether and refer to whether glass glaze becomes to be integrated with glass basis.
To sum up, lead-free and cadmium-free copper ruby glass glaze provided by the invention possesses good stability, opacifying power, and color can specifically regulate according to actual needs.Melting fastness is altogether 100%, eutectic temperature 630-680 DEG C.
This copper ruby glass glaze possess unleaded, without cadmium, environmental protection, advantage that raw material is cheap, this preparation method is simple, time prepared by this copper ruby glass glaze paint, step is simple, and yield rate is high.
The above embodiment is only the preferred embodiments of the present invention, and and the feasible enforcement of non-invention exhaustive.For persons skilled in the art, to any apparent change that it is made under the prerequisite not deviating from the principle of the invention and spirit, all should be contemplated as falling with within claims of the present invention.
Claims (10)
1., for an environmental protection copper ruby glass glaze for float flat glass surface decoration, it is characterized in that: it comprises parent glaze, described parent glaze comprises the component of following weight percent:
SiO
2 30-75%；
B
2O
3 5-20%；
ZnO 5-25%；
Al
2O
3 0.5-15%；
Bi
2O
3 3-5%；
R
2o 4-25% wherein R comprises Li and/or Na and/or K;
RO 3-30% wherein R comprises Mg and/or Ca and/or Ba and/or Sr.
2. a kind of environmental protection copper ruby glass glaze for float flat glass surface decoration according to claim 1, is characterized in that: described parent glaze comprises the component of following weight percent:
31-60%SiO
2；
5-19%ZnO；
1-10%CaO+MgO；
0-10%BaO；
0-10%SrO；
5-20%B
2O
3；
0.5-10%Al
2O
3；
0.5-10%TiO
2；
0-5%ZrO
2；
2-20%K
2O+Na
2O；
1-8%Li
2O。
3. a kind of environmental protection copper ruby glass glaze for float flat glass surface decoration according to claim 1, is characterized in that: described glass glaze is also comprising toner, and the weight percent that described tinting material accounts for described parent glaze is 0.1-20%.
4., according to a kind of environmental protection copper ruby glass glaze for float flat glass surface decoration described in claim 3, it is characterized in that: described tinting material is selected from following raw material: one or more mixtures of cupric oxide, Red copper oxide, copper carbonate.
5. a kind of preparation method without environmental protection copper ruby glass glaze for float flat glass surface decoration described in any one of claim 1-4, is characterized in that: comprise the following steps:
(1) following parent glaze raw material is taken by weight percentage: 25-70%SiO
2; 5-30%ZnO; 1-15%CaO+MgO; 0-15%BaO; 0-15%SrO; 5-33%B
2o
3; 0.5-15%Al
2o
3; 0.1-10%TiO
2; 0-10%ZrO
2; 1-25%K
2o+Na
2o; 1-10%Li
2o; The compound of 0.1-20% copper;
(2) all raw materials that step (1) takes are put into stirrer to stir or ball mill ball milling 10-30 minute, its rotating speed is 60-100 rev/min, mixes;
(3) mixture that step (2) obtains is founded at 1000-1350 DEG C, make the complete melting of mixture, obtain melten glass liquid;
(4) melten glass liquid shrend step (3) obtained;
(5) frit after step (4) shrend is put into ball mill ball milling 1-6 hour, its rotating speed is 60-100 rev/min, obtains glass powder;
(6) glass powder crossed by step (5) ball milling is 80-120 DEG C of oven dry in loft drier, and gained powder is copper ruby glass glaze.
6. copper ruby glass glaze prepares a method for copper ruby glass glaze paint, it is characterized in that: adopt copper ruby glass glaze according to claim 5, it comprises the following steps:
(1) get this environmental protection copper ruby glass glaze, add blender and be prepared into glaze slip;
(2) after sheet glass substrate of making even cleaning, by the glaze slip that step (1) obtains, glazing on a glass substrate, dry;
(3) the glass basis feeding annealing furnace of dry for step (2) rear band glaze or roller kiln are burnt till, second face that obtains is red rough flambe surface glass.
7. a kind of copper ruby glass glaze according to claim 6 prepares the method for copper ruby glass glaze paint, it is characterized in that: in step (2), glass substrate used is the substrate of float glass.
8. a kind of copper ruby glass glaze according to claim 6 prepares the method for copper ruby glass glaze paint, it is characterized in that: the glass-based of glazing is unilateral in step (2) is the rich tin face of float glass.
9. a kind of copper ruby glass glaze according to claim 6 prepares the method for copper ruby glass glaze paint, it is characterized in that: the temperature that step (3) is burnt till is 630-680 DEG C.
10. a kind of copper ruby glass glaze according to claim 6 prepares the method for copper ruby glass glaze paint, it is characterized in that: the conditioning agent in described step (1) is the organic solvent adjusting glaze conventional.
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|---|---|---|---|
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|---|---|---|---|
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Cited By (7)
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|---|---|---|---|---|
| CN105837027A (en) * | 2016-03-28 | 2016-08-10 | 伍治东 | Preparation process of tempered glass with surface being coated with copper-based composite coating |
| CN106477888A (en) * | 2016-10-20 | 2017-03-08 | 沈阳建筑大学 | A kind of copper oxide pink potassium feldspar glaze and preparation method thereof |
| CN106495484A (en) * | 2016-10-20 | 2017-03-15 | 沈阳建筑大学 | A kind of Barium monoxide frit red ceramic glaze and preparation method thereof |
| CN108069619A (en) * | 2018-01-31 | 2018-05-25 | 和县晶晶玻璃制品有限公司 | A kind of manufacturing method of color glaze-surface glass |
| CN110683764A (en) * | 2019-11-15 | 2020-01-14 | 黄山市晶特美新材料有限公司 | Glass powder for environment-friendly high-acid-resistance automobile glass slurry and preparation method thereof |
| CN110950538A (en) * | 2018-09-27 | 2020-04-03 | 湖南嘉业达电子有限公司 | Preparation method of low-expansion high-temperature-resistant environment-friendly medium-low-temperature transparent glass glaze |
| CN111377610A (en) * | 2020-03-13 | 2020-07-07 | 宜兴市金鱼陶瓷有限公司 | Celadon transmutation glaze and preparation method thereof |
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