CN108003534A - A kind of durable type acryl plates and preparation method thereof - Google Patents
A kind of durable type acryl plates and preparation method thereof Download PDFInfo
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- CN108003534A CN108003534A CN201711420500.0A CN201711420500A CN108003534A CN 108003534 A CN108003534 A CN 108003534A CN 201711420500 A CN201711420500 A CN 201711420500A CN 108003534 A CN108003534 A CN 108003534A
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- maleic anhydride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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Abstract
A kind of durable type acryl plates, by weight including following components：0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2 3% nano-calcium carbonates, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin, acryl resin monomer to 100%；The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, and wherein the percentage by weight of polycarbonate resin and polymethyl methacrylate is 1:5.
Description
Technical field
The present invention is related to more particularly to a kind of durable type acryl plates and preparation method thereof.
Background technology
Acrylic, also known as organic glass, chemical name is polymethacrylates, is a kind of plastic macromolecule material,
There is the excellent and characteristics such as preferable transparent, chemical stability and weatherability, easy dyeing, easy processing, but it is anti-
Aging is but slightly insufficient, directly affects the use of acrylic product to a certain extent.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of durable type acryl plates：
A kind of durable type acryl plates, by weight including following components：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2-3% nano-calcium carbonates,
1.8% nano-graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin,
Acryl resin monomer is to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly-
The percentage by weight of carbonate resin and polymethyl methacrylate is 1:5.
A kind of durable type acryl plates, by weight including following components：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2.2% nano-calcium carbonate,
1.8% nano-graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin,
Acryl resin monomer is to 100%.
A kind of method for preparing durable type acryl plates, step are as follows：
S1：Trimethyl citrate, chloromethyl acetate, polystyrene resin, acryl resin monomer are added in reaction kettle,
It is 100 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound；
S2：Again by nano-calcium carbonate, nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, organosilicon
Resin is put into reaction kettle, in 160 DEG C, the pressure of 6MPa, is stirred continuously 2h and is sent to extruder extrusion.
The present invention has the advantages that：The present invention is by by trimethyl citrate, chloromethyl acetate, polystyrene tree
Fat, nano-calcium carbonate, nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, organic siliconresin, acrylic tree
Alicyclic monomer rationally compounds the durability and hardness that product is substantially increased while obtaining ageing-resistant.
Embodiment
The present invention is further described with reference to embodiment.
Embodiment 1：A kind of durable type acryl plates, by weight including following components：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2% nano-calcium carbonate, 1.8%
Nano-graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin, Ya Ke
Power resin monomer is to 100%.
Embodiment 2：A kind of durable type acryl plates, by weight including following components：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2.2% nano-calcium carbonate,
1.8% nano-graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin,
Acryl resin monomer is to 100%.
Embodiment 3：A kind of durable type acryl plates, by weight including following components：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 3% nano-calcium carbonate, 1.8%
Nano-graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin, Ya Ke
Power resin monomer is to 100%.
A kind of method for preparing durable type acryl plates, step are as follows：
S1：Trimethyl citrate, chloromethyl acetate, polystyrene resin, acryl resin monomer are added in reaction kettle,
It is 100 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound；
S2：Again by nano-calcium carbonate, nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, organosilicon
Resin is put into reaction kettle, in 160 DEG C, the pressure of 6MPa, is stirred continuously 2h and is sent to extruder extrusion.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The connotation changes and variations that derived from of invention still fall within protection scope of the present invention.
Claims (3)
1. a kind of durable type acryl plates, it is characterised in that by weight including following components：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2-3% nano-calcium carbonates, 1.8% are received
Rice graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin, acrylic
Resin monomer is to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly- carbonic acid
The percentage by weight of ester resin and polymethyl methacrylate is 1:5.
2. a kind of durable type acryl plates according to claim 1, it is characterised in that by weight including following groups
Point：
0.7% trimethyl citrate, 1% chloromethyl acetate, 1.2% polystyrene resin, 2.2% nano-calcium carbonate, 1.8% are received
Rice graphene, 8% nanometer silicon carbide, 0.7% maleic anhydride, 0.7% trimethoxy silane, 15% organic siliconresin, acrylic
Resin monomer is to 100%.
A kind of 3. method of the durable type acryl plates prepared described in claim 1, it is characterised in that step is as follows：
S1：Trimethyl citrate, chloromethyl acetate, polystyrene resin, acryl resin monomer are added in reaction kettle, heating
It is 100 DEG C to keep temperature, adherence pressure to 2MPA, and acquisition acrylic moulding compound is taken out after stirring 3h；
S2：Again by nano-calcium carbonate, nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, organic siliconresin
It is put into reaction kettle, in 160 DEG C, the pressure of 6MPa, is stirred continuously 2h and send to extruder extrusion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711420500.0A CN108003534A (en) | 2017-12-25 | 2017-12-25 | A kind of durable type acryl plates and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711420500.0A CN108003534A (en) | 2017-12-25 | 2017-12-25 | A kind of durable type acryl plates and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108003534A true CN108003534A (en) | 2018-05-08 |
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| CN201711420500.0A Pending CN108003534A (en) | 2017-12-25 | 2017-12-25 | A kind of durable type acryl plates and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942999A (en) * | 2019-03-05 | 2019-06-28 | 安徽迈明亚克力科技有限公司 | A kind of acryl plates and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262877A (en) * | 2014-09-10 | 2015-01-07 | 苏州云舒新材料科技有限公司 | Anti-aging acrylic resin and preparation method thereof |
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
| CN106751860A (en) * | 2016-12-21 | 2017-05-31 | 浙江龙游展宇有机玻璃有限公司 | A kind of anti-corrosion acrylic board and preparation method thereof |
-
2017
- 2017-12-25 CN CN201711420500.0A patent/CN108003534A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262877A (en) * | 2014-09-10 | 2015-01-07 | 苏州云舒新材料科技有限公司 | Anti-aging acrylic resin and preparation method thereof |
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
| CN106751860A (en) * | 2016-12-21 | 2017-05-31 | 浙江龙游展宇有机玻璃有限公司 | A kind of anti-corrosion acrylic board and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942999A (en) * | 2019-03-05 | 2019-06-28 | 安徽迈明亚克力科技有限公司 | A kind of acryl plates and preparation method thereof |
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Application publication date: 20180508 |
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