CN105778621B - A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof - Google Patents
A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof Download PDFInfo
- Publication number
- CN105778621B CN105778621B CN201610326536.1A CN201610326536A CN105778621B CN 105778621 B CN105778621 B CN 105778621B CN 201610326536 A CN201610326536 A CN 201610326536A CN 105778621 B CN105778621 B CN 105778621B
- Authority
- CN
- China
- Prior art keywords
- water
- resistant type
- preparation
- based polyurethane
- ink binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6484—Polysaccharides and derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water-resistant type water-based polyurethane ink binders and preparation method thereof, the main constituents of the ink adhesive are the bacteria cellulose and Waterborne Polyurethane Prepolymer by silane coupler modified processing, wherein the length of bacteria cellulose is 200 ~ 500nm, a diameter of 60 ~ 100nm；A kind of water-resistant type water-based polyurethane ink binder of the present invention and preparation method thereof takes following steps：Five stages such as the synthesis of the modification of hydrolysis, bacteria cellulose, the synthesis of Waterborne Polyurethane Prepolymer, aqueous polyurethane emulsion including silane coupling agent and the preparation of water-resistant type water-based polyurethane ink binder；A kind of water absorption rate for 24 hours of water-resistant type water-based polyurethane ink binder of the present invention is less than 8.0%；A kind of preparation method of water-resistant type water-based polyurethane ink binder of the present invention is simple, meets the environmental protection requirement of sustainable development.
Description
Technical field
The invention belongs to high-molecular organic material preparing technical field, specifically, being to be related to one kind with bacteria cellulose
With the water-resistant type water-based polyurethane ink binder and preparation method thereof based on the cross-linked structure of polyurethane molecular chain.
Background technology
The performance of water-based ink is directly influenced by binder, and the water-based ink binder of early stage is mainly by rosin and horse
Come the resin of sour modification, poor-performing.Later, people started the copolymer of acrylate monomer and styrene being applied to water
In property ink, although can have more prominent performance in glossiness, weatherability etc., the improvement of its water resistance is still
Unobvious.
At present, the degree of cross linking for improving ink film, common approach are focused primarily upon about the research of water-based ink water resistance
Including interior crosslinking, external crosslinking and inside and outside dual crosslinking, the compound of introducing crosslinked structure can be the tripolymer of diisocyanate,
Trimethylolpropane etc. [Wang Haiqiao, Zhang Lin, He Lifan, Lee imitate the silane coupler modified acrylic emulsions used for water color ink of jade,
New Chemical Materials, 2010,38；The synthesis of the clear TDI tripolymer modified aqueous polyurethane dispersoids of Xiang Bo, Li Shaomao, Zhai Jin
With performance, Chinese leather, 2010,39；Jiang Hongquan, Song Zhanqian, Shang Shibin wait the castor oil modified polyether type aqueous polyurethane breasts of
The performance of liquid, chemical industry progress, 2010,29；The cross-linking modified styrene-acrylic emulsions of Lian Kunpeng, Zhu Liyong, Liu Runlin, Zhao quintessence are aqueous
Application in ink, Chinese adhesive, 2011,20].It is in addition, poly- by being connected to after the double bond of Polymerizable Emulsifier is opened
The methods of on adduct molecule chain, can also stablize ink adhesive molecular chain structure, so as to improve the water resistance of ink film
[preparation and application of the big of Zhang Song, Duan Yufeng, Zhang Shulan, Huo Yandong, Li Fangfang, Li Ya acrylic emulsions used for water color ink, packet
Dress engineering, 2014,5；Liu Xu, China fir of getting a bit thin on top, Wu Jia, the conjunction of clock sheet and epoxy modified aqueous acrylic acid resins used for water color ink
Into, Packaging Engineering, 2008,7；The preparation of Cao Li, Cao Xinxiang, Wang Zhengping, Hou Xiu plum water-based acrylic resins and its water solubility
Research, bonding, 2006,5；Cai Dongyu, Xiang Shanglin, Chen Xianyi, text is using polyurethane polyacrylate lotion as binder
The development of plastic gravure waterborne ink, Packaging Engineering, 2005,3].
Introducing crosslinked network structure can improve the water resistance of water-based ink in ink coating structure, but currently used for
The compound for improving the ink substrate degree of cross linking is generally chemosynthesis product, can be consumed during preparation and use a large amount of
Chemical reagent simultaneously generates volatile pollutant, is unfavorable for environmental protection and sustainable development.
Invention content
The technical problems to be solved by the invention are to be directed to the problem of water-based polyurethane ink binder water resistance is insufficient, are carried
A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof is supplied.The aqueous poly- ammonia of a kind of water-resistant type of the present invention
Ester oil ink connecting material is centered on the bacteria cellulose Jing Guo silane coupler modified processing, is existed using types of attachment such as hydrogen bonds
Water-based polyurethane ink binder inside configuration forms stable cross-linked structure, so as to make the aqueous polyurethane after film-forming oily
24 hours water absorption rates of ink connecting material are down to less than 8.0%.
In order to solve the above technical problems, the present invention uses following technical scheme：
A kind of water-resistant type water-based polyurethane ink binder, it is mixed by the component of following weight percentage：Water
Property polyaminoester emulsion 50% ~ 55%, mass fraction be 12% ammonium hydroxide 5% ~ 15% and Sodium Polyacrylate 35% ~ 40%.
24 hours water absorption rates after the water-resistant type water-based polyurethane ink binder film-forming reach less than 8.0%.
The preparation method of the water-resistant type water-based polyurethane ink binder, includes the following steps：
（1）Ethanol-hydrogen chloride system is obtained with the pH value of hydrochloric acid adjusting absolute ethyl alcohol to 3 ~ 4 at normal temperatures, then by silane
Coupling agent, which is added in ethanol-hydrogen chloride system, is hydrolyzed reaction, obtains the mixed solution of silanol and ethanol-hydrogen chloride, and hydrolysis is thorough
The mark at bottom is mixed solution clear；
（2）Bacteria cellulose is added to step（1）Surface modification is carried out in mixed solution obtained, obtains modified bacteria
Cellulose；
（3）Prepare Waterborne Polyurethane Prepolymer；
（4）By step（2）Modified bacteria cellulose obtained, step（3）Waterborne Polyurethane Prepolymer and chain extension obtained
Agent in mass ratio 5 ~ 20：70~90：5 ~ 10 mixing and mechanical agitation obtains aqueous polyurethane emulsion at room temperature；
（5）By weight ratio by step（4）Aqueous polyurethane emulsion obtained, the ammonium hydroxide and poly- third that mass fraction is 12%
Olefin(e) acid sodium is mixed and stirred for uniformly, water-resistant type water-based polyurethane ink binder being made.
The step（1）In, silane coupling agent is 3- methacryloxypropyl trimethoxy silanes or 3- (2,3- rings
The third oxygen of oxygen) propyl trimethoxy silicane.
The step（1）In, the volume ratio of silane coupling agent and ethanol-hydrogen chloride system is 1:8~1:10, it is silane coupled
The hydrolysis equation of agent is as follows：
In formula：X is methacryloxy or 2,3- glycidoxies.
The step（2）Middle bacteria cellulose grows 200 ~ 500nm, 60 ~ 100nm of diameter, and bacteria cellulose is molten with mixing
Liquid is according to mass ratio 1:After 100 mixing, surface modification, reaction are carried out under conditions of 60 DEG C, mechanical agitation rotating speed is 60r/min
Time is 2h, and reaction equation is as follows：
In formula：X is methacryloxy or 2,3- glycidoxy, and Y is bacteria cellulose.
The step（3）The preparation method of middle Waterborne Polyurethane Prepolymer is as follows：After polyalcohol is placed in conical flask
It is put in 60 DEG C of water-bath, 80 DEG C is warming up to after being slowly added to diisocyanate, obtained after reaction 4h under conditions of 60r/min
Obtain Waterborne Polyurethane Prepolymer；Wherein the mass ratio of polyalcohol and diisocyanate is 3:1~5:1.
The polyalcohol is polycarbonate glycol either polycaprolactone glycol or polyoxypropyleneglycol；Diisocyanate
Ester is toluene di-isocyanate(TDI) either isophorone diisocyanate or Methylcyclohexyl diisocyanate.
The step（4）In chain extender be ethylenediamine, ethylene glycol, isophorone diamine or 1,4- butanediols.
The step（4）Middle mechanical agitation rotating speed is 120r/min, mixing time 20min.
The beneficial effects of the present invention are：(1) using bacteria cellulose, to prepare water-resistant type aqueous the present invention provides a kind of
The effective way of polyurethane oil ink connecting material；(2) present invention is using bacteria cellulose and aqueous polyurethane strand, aqueous
Stable cross-linked structure is formd in polyurethane oil ink connecting material matrix structure；(3) present invention is made using modified bacteria cellulose
For additive, 24 hours water absorption rates of water-based polyurethane ink binder can be made to be down to less than 8.0%；(4) present invention is a kind of
The preparation method of water-resistant type water-based polyurethane ink binder is easily combined with the prior art, it can be achieved that industrialized production；(5) originally
It invents in a kind of preparation process of water-resistant type water-based polyurethane ink binder and is not related to toxicity additive, in printing process not
There are the emission problems of organic pollution, are the advantageous starting materials for preparing environment-friendly type printing ink.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.It should be understood that following embodiment is merely to illustrate this
The range of invention and is not intended to limit the present invention, the person skilled in the art in the field can make one according to the content of foregoing invention
A little nonessential modifications and adaptations.
Embodiment 1
A kind of preparation method of water-resistant type water-based polyurethane ink binder of the present embodiment is as follows：
(1) 200ml absolute ethyl alcohols are taken, it is 3 ~ 4 that hydrochloric acid is added dropwise thereto and adjusts to pH value, then measures 3- metering systems
Acryloxypropylethoxysilane trimethoxy silane 25ml, which is added in ethanol-hydrogen chloride system, carries out the hydrolysis of 30min thoroughly to mixed solution
Clear, room temperature stand for standby use；
(2) 1.0g bacteria celluloses are weighed and hydrolyze thorough silanol and the mixed solution of ethanol-hydrogen chloride system with 100.0g
It is placed in conical flask, the Process of Surface Modification of bacteria cellulose needs 60 DEG C, reaction time 2h of reaction temperature, and mechanical agitation turns
Speed is 60r/min, and will wash 3 times with absolute ethyl alcohol after bacteria cellulose vacuum filter after modified-reaction prepares modification
Bacteria cellulose 1.06g；
(3) polycaprolactone glycol for weighing 12.0g is placed in the heating water bath of 60 DEG C of progress in conical flask, is slowly added dropwise
Waterborne Polyurethane Prepolymer 15.5g is obtained after 80 DEG C of reaction 4h are warming up to after 4.0g toluene di-isocyanate(TDI)s；
(4) 1.0g modified bacteria celluloses, 14.0g Waterborne Polyurethane Prepolymers and 2.0g ethylene glycol are weighed and is placed in taper
It is uniformly mixed in bottle, mechanical agitation rotating speed is 120r/min, mixing time 20min, and aqueous polyurethane emulsion 16.3g is made；
(5) 12.0g aqueous polyurethane emulsions, the ammonium hydroxide that 2.4g mass fractions are 12% and 9.6g Sodium Polyacrylates are put
It is stirred evenly in conical flask, you can water-resistant type water-based polyurethane ink binder 23.6g is made.
It is taken out being soaked in distilled water after 15.0g water-resistant type water-based polyurethane ink binder curing dryings afterwards for 24 hours,
16.1g, water absorption rate 7.3% are weighed as after drying the moisture of its surface attachment.
Embodiment 2
A kind of preparation method of water-resistant type water-based polyurethane ink binder of the present embodiment is as follows：
(1) 300ml absolute ethyl alcohols are taken, it is 3 ~ 4 that hydrochloric acid is added dropwise thereto and adjusts to pH value, then measures 3- (2,3- epoxies
Third oxygen) propyl trimethoxy silicane 34ml be added in above-mentioned ethanol-hydrogen chloride system carry out 30min hydrolysis it is thoroughly molten to mixing
Liquid clear, room temperature stand for standby use；
(2) 2.0g bacteria celluloses are weighed and hydrolyze thorough silanol and the mixed solution of ethanol-hydrogen chloride system with 200.0g
It is placed in conical flask, the Process of Surface Modification of bacteria cellulose needs 60 DEG C, reaction time 2h of reaction temperature, and mechanical agitation turns
Speed is 60r/min, and will wash 3 times with absolute ethyl alcohol after bacteria cellulose vacuum filter after modified-reaction prepares modification
Bacteria cellulose 2.05g；
(3) polycaprolactone glycol for weighing 15.0g is placed in the heating water bath of 60 DEG C of progress in conical flask, is slowly added dropwise
Waterborne Polyurethane Prepolymer 17.2g is obtained after 80 DEG C of reaction 4h are warming up to after 3.0g isophorone diisocyanate；
(4) 2.0g modified bacteria celluloses, 15.0g Waterborne Polyurethane Prepolymers and 2.0g ethylene glycol are weighed and is placed in taper
It is uniformly mixed in bottle, mechanical agitation rotating speed is 120r/min, mixing time 20min, and aqueous polyurethane emulsion 17.9g is made；
(5) by 15.0g aqueous polyurethane emulsions, the ammonium hydroxide that 4.5g mass fractions are 12% and 10.5g Sodium Polyacrylates
It is placed in conical flask and stirs evenly, you can water-resistant type water-based polyurethane ink binder 28.7g is made.
It is taken out being soaked in distilled water after 20.0g water-resistant type water-based polyurethane ink binder curing dryings afterwards for 24 hours,
21.3g, water absorption rate 6.5% are weighed as after drying the moisture of its surface attachment.
Embodiment 3
A kind of preparation method of water-resistant type water-based polyurethane ink binder of the present embodiment is as follows：
(1) 200ml absolute ethyl alcohols are taken, it is 3 ~ 4 that hydrochloric acid is added dropwise thereto and adjusts to pH value, then measures 3- (2,3- epoxies
Third oxygen) propyl trimethoxy silicane 20ml be added in above-mentioned ethanol-hydrogen chloride system carry out 30min hydrolysis it is thoroughly molten to mixing
Liquid clear, room temperature stand for standby use；
(2) 1.5g bacteria celluloses are weighed and hydrolyze thorough silanol and the mixed solution of ethanol-hydrogen chloride system with 150.0g
It is placed in conical flask, the Process of Surface Modification of bacteria cellulose needs 60 DEG C, reaction time 2h of reaction temperature, and mechanical agitation turns
Speed is 60r/min, and will wash 3 times with absolute ethyl alcohol after bacteria cellulose vacuum filter after modified-reaction prepares modification
Bacteria cellulose 1.49g；
(3) polyoxypropyleneglycol for weighing 16.0g is placed in the heating water bath of 60 DEG C of progress in conical flask, is slowly added dropwise
Waterborne Polyurethane Prepolymer 19.1g is obtained after 80 DEG C of reaction 4h are warming up to after 4.0g Methylcyclohexyl diisocyanates；
(4) 1.2g modified bacteria celluloses, 6.4g Waterborne Polyurethane Prepolymers and 0.4g ethylene glycol are weighed and is placed in conical flask
In be uniformly mixed, mechanical agitation rotating speed is 120r/min, mixing time 20min, and aqueous polyurethane emulsion 7.7g is made；
(5) 5.5g aqueous polyurethane emulsions, the ammonium hydroxide that 1.0g mass fractions are 12% and 3.5g Sodium Polyacrylates are put
It is stirred evenly in conical flask, you can water-resistant type water-based polyurethane ink binder 9.2g is made.
It is taken out being soaked in distilled water after 5.0g water-resistant type water-based polyurethane ink binder curing dryings afterwards for 24 hours,
5.23g, water absorption rate 4.6% are weighed as after drying the moisture of its surface attachment.
Embodiment 4
A kind of preparation method of water-resistant type water-based polyurethane ink binder of the present embodiment is as follows：
(1) 300ml absolute ethyl alcohols are taken, it is 3 ~ 4 that hydrochloric acid is added dropwise thereto and adjusts to pH value, then measures 3- metering systems
Acryloxypropylethoxysilane trimethoxy silane 32ml is added to the hydrolysis that 30min is carried out in above-mentioned ethanol-hydrogen chloride system thoroughly to mixing
Solution clear, room temperature stand for standby use；
(2) 3.0g bacteria celluloses are weighed and hydrolyze thorough silanol and the mixed solution of ethanol-hydrogen chloride system with 300.0g
It is placed in conical flask, the Process of Surface Modification of bacteria cellulose needs 60 DEG C, reaction time 2h of reaction temperature, and mechanical agitation turns
Speed is 60r/min, and will wash 3 times with absolute ethyl alcohol after bacteria cellulose vacuum filter after modified-reaction prepares modification
Bacteria cellulose 3.11g；
(3) the polycarbonate glycol for weighing 15.0g is placed in the heating water bath of 60 DEG C of progress in conical flask, is slowly added dropwise
Waterborne Polyurethane Prepolymer 19.4g is obtained after 80 DEG C of reaction 4h are warming up to after 5.0g toluene di-isocyanate(TDI)s；
(4) 2.0g modified bacteria celluloses, 8.5g Waterborne Polyurethane Prepolymers and 1.0g ethylene glycol are weighed and is placed in conical flask
In be uniformly mixed, mechanical agitation rotating speed is 120r/min, mixing time 20min, and aqueous polyurethane emulsion 10.8g is made；
(5) by 8.25g aqueous polyurethane emulsions, the ammonium hydroxide that 0.75g mass fractions are 12% and 6.0g Sodium Polyacrylates
It is placed in conical flask and stirs evenly, you can water-resistant type water-based polyurethane ink binder 14.3g is made.
It is taken out being soaked in distilled water after 10.0g water-resistant type water-based polyurethane ink binder curing dryings afterwards for 24 hours,
10.31g, water absorption rate 3.1% are weighed as after drying the moisture of its surface attachment.
Basic principle of the invention and main feature and advantages of the present invention has been shown and described above.The skill of the industry
Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe
The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these
Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and
Its equivalent thereof.
Claims (9)
1. a kind of preparation method of water-resistant type water-based polyurethane ink binder, it is characterised in that include the following steps：
（1）Ethanol-hydrogen chloride system is obtained with the pH value of hydrochloric acid adjusting absolute ethyl alcohol to 3 ~ 4 at normal temperatures, it then will be silane coupled
Agent, which is added in ethanol-hydrogen chloride system, is hydrolyzed reaction, obtains the mixed solution of silanol and ethanol-hydrogen chloride, and hydrolysis is thorough
Indicate for mixed solution clear；
（2）Bacteria cellulose is added to step（1）Surface modification is carried out in mixed solution obtained, obtains modified bacteria fiber
Element；
（3）Prepare Waterborne Polyurethane Prepolymer；
（4）By step（2）Modified bacteria cellulose obtained, step（3）Waterborne Polyurethane Prepolymer obtained is pressed with chain extender
Mass ratio 5 ~ 20：70~90：5 ~ 10 mixing and mechanical agitation obtains aqueous polyurethane emulsion at room temperature；
（5）By weight ratio by step（4）Aqueous polyurethane emulsion obtained, the ammonium hydroxide and polyacrylic acid that mass fraction is 12%
Sodium is mixed and stirred for uniformly, water-resistant type water-based polyurethane ink binder being made；
The water-resistant type water-based polyurethane ink binder is mixed by the component of following weight percentage：Aqueous poly- ammonia
Ester lotion 50% ~ 55%, the ammonium hydroxide 5% ~ 15% that mass fraction is 12% and Sodium Polyacrylate 35% ~ 40%.
2. the preparation method of water-resistant type water-based polyurethane ink binder according to claim 1, it is characterised in that：It is described
Water-resistant type water-based polyurethane ink binder film-forming after 24 hours water absorption rates reach less than 8.0%.
3. the preparation method of water-resistant type water-based polyurethane ink binder described in claim 1, it is characterised in that：The step
（1）In, silane coupling agent is 3- methacryloxypropyl trimethoxy silanes or 3- (2,3- the third oxygen of epoxy) propyl front three
Oxysilane.
4. the preparation method of water-resistant type water-based polyurethane ink binder described in claim 1, it is characterised in that：The step
Suddenly（1）In, the volume ratio of silane coupling agent and ethanol-hydrogen chloride system is 1:8~1:10, the hydrolysis equation of silane coupling agent
Formula is as follows：
In formula：X is methacryloxy or 2,3- glycidoxies.
5. the preparation method of water-resistant type water-based polyurethane ink binder according to claim 1, it is characterised in that：It is described
The step of（2）Middle bacteria cellulose grows 200 ~ 500nm, 60 ~ 100nm of diameter, by bacteria cellulose and mixed solution according to quality
Than 1:After 100 mixing, the progress surface modification under conditions of 60 DEG C, mechanical agitation rotating speed is 60r/min, reaction time 2h,
Reaction equation is as follows：
In formula：X is methacryloxy or 2,3- glycidoxy, and Y is bacteria cellulose.
6. the preparation method of water-resistant type water-based polyurethane ink binder according to claim 1, it is characterised in that：It is described
The step of（3）The preparation method of middle Waterborne Polyurethane Prepolymer is as follows：60 DEG C of water is put in after polyalcohol is placed in conical flask
In bath, 80 DEG C are warming up to after being slowly added to diisocyanate, aqueous polyurethane is obtained after reaction 4h under conditions of 60r/min
Performed polymer；Wherein the mass ratio of polyalcohol and diisocyanate is 3:1~5:1.
7. the preparation method of water-resistant type water-based polyurethane ink binder according to claim 6, it is characterised in that：It is described
Polyalcohol be polycarbonate glycol, polycaprolactone glycol or polyoxypropyleneglycol；The diisocyanate is toluene two
Isocyanates, isophorone diisocyanate or Methylcyclohexyl diisocyanate.
8. the preparation method of water-resistant type water-based polyurethane ink binder according to claim 1, it is characterised in that：It is described
Step（4）In chain extender be ethylenediamine, ethylene glycol, isophorone diamine or 1,4- butanediols.
9. the preparation method of water-resistant type water-based polyurethane ink binder according to claim 1, it is characterised in that：It is described
Step（4）Middle mechanical agitation rotating speed is 120r/min, mixing time 20min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610326536.1A CN105778621B (en) | 2016-05-17 | 2016-05-17 | A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610326536.1A CN105778621B (en) | 2016-05-17 | 2016-05-17 | A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105778621A CN105778621A (en) | 2016-07-20 |
| CN105778621B true CN105778621B (en) | 2018-06-29 |
Family
ID=56379941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610326536.1A Active CN105778621B (en) | 2016-05-17 | 2016-05-17 | A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105778621B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497224B (en) * | 2016-11-25 | 2019-08-02 | 河南工程学院 | A kind of ink adhesive and preparation method thereof based on bacteria cellulose |
| CN108641577A (en) * | 2018-05-25 | 2018-10-12 | 袁杰 | A kind of bi-component anti-settling type polyurethane water-proof paint |
| CN117779482B (en) * | 2024-02-06 | 2024-07-12 | 德州兴隆皮革制品有限公司 | Manufacturing method of antibacterial mildew-proof sofa leather |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101585904A (en) * | 2008-05-21 | 2009-11-25 | 北京高盟燕山科技有限公司 | Method for preparing binder resin for water-based ink and application thereof |
| CN104974381A (en) * | 2014-04-08 | 2015-10-14 | 上海耐特复合材料制品有限公司 | Starch-based biodegradable composite material and preparation method thereof |
| CN105060861A (en) * | 2015-08-06 | 2015-11-18 | 河南工程学院 | Porous ceramics catalyst carrier possessing two-dimensional nanopores and preparation method thereof |
| CN105542710A (en) * | 2016-02-03 | 2016-05-04 | 北京林业大学 | Waterproof soybean meal adhesive and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20021228A1 (en) * | 2002-06-06 | 2003-12-09 | Ausimont Spa | COMPOSITIONS OF CROSS-LINKABLE POLYURETHANE |
-
2016
- 2016-05-17 CN CN201610326536.1A patent/CN105778621B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101585904A (en) * | 2008-05-21 | 2009-11-25 | 北京高盟燕山科技有限公司 | Method for preparing binder resin for water-based ink and application thereof |
| CN104974381A (en) * | 2014-04-08 | 2015-10-14 | 上海耐特复合材料制品有限公司 | Starch-based biodegradable composite material and preparation method thereof |
| CN105060861A (en) * | 2015-08-06 | 2015-11-18 | 河南工程学院 | Porous ceramics catalyst carrier possessing two-dimensional nanopores and preparation method thereof |
| CN105542710A (en) * | 2016-02-03 | 2016-05-04 | 北京林业大学 | Waterproof soybean meal adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 水性聚氨酯的性能改善研究;陈丽红;《中国优秀硕士学位论文全文数据库（工程科技Ⅰ辑）》;20150115(第1期);B018-10 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105778621A (en) | 2016-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106318091B (en) | A kind of aqueous dual-component organic-inorganic hybridization coating resin and preparation method thereof | |
| CN107075341B (en) | Stripping film is with re-releasing additive and stripping film organopolysiloxane composition and stripping film | |
| CN100577755C (en) | Double-component polyurethane coating and production method and construction method | |
| CN105778621B (en) | A kind of water-resistant type water-based polyurethane ink binder and preparation method thereof | |
| CN110330881B (en) | Photocuring environment-friendly flexible PVC stain-resistant matte finish paint and preparation method thereof | |
| CN106543877B (en) | The modified polyurethane woodwork coating of water polyacrylic acid containing organosilicon and its preparation method and application | |
| CN106752857A (en) | A kind of preparation method of the super hydrophilic antifogging coating of dual cure acrylate | |
| CN105001422B (en) | A kind of addition-type silicon rubber tackifier and preparation method thereof and addition-type silicon rubber | |
| CN108384014A (en) | A kind of hydrogeneous thickening crosslinking agent of addition-type silicon rubber organosilicon and preparation method thereof | |
| CN105111360B (en) | The preparation method of multiple cross-linked water-based acrylic resin | |
| CN112662346B (en) | Glue for masking tape and preparation method thereof | |
| KR20130066754A (en) | Hard coating composition | |
| CN110156997A (en) | It is a kind of can moisture solidification organic silicon block copolymer and preparation method thereof | |
| CN101857674B (en) | Method for synthesizing high-temperature resistant organic silicon resin | |
| CN111349242A (en) | Preparation method of isocyanate-containing silicon rubber tackifier | |
| CN103666241B (en) | A kind of composite Nano waterborne UV coating and preparation method thereof | |
| CN113829770B (en) | Glazing process for replacing adhesive film | |
| CN105949396B (en) | A kind of water based silicone resin and preparation method thereof | |
| CN104232009A (en) | Preparation method and application of vinyl MQ resin modified organosilicone packaging adhesive | |
| CN102212309B (en) | Method for preparing unsaturated polyester polyurethane block copolymer solventless coating | |
| CN105505275B (en) | Full fitting liquid optical cement | |
| CN110041504A (en) | A kind of polyurethane-modified polyacrylate polymer and its resin combination obtained with highly -branched degree | |
| CN104311863B (en) | A kind of methyl silicon resin film and preparation method thereof | |
| CN110938374A (en) | Boiling-resistant coating, preparation method and application thereof | |
| CN104861780B (en) | A kind of dispersion resin liquid and ink for glass baseplate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200813 Address after: 518000 1213, building 49, No.3, Queshan Yunfeng Road, Gaofeng community, Dalang street, Longhua District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Lijie Intellectual Property Service Co.,Ltd. Address before: 451191 No. 1 Xianghe Road, Xinzheng, Henan, Zhengzhou, Longhu Patentee before: HENAN INSTITUTE OF ENGINEERING |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210106 Address after: 363600 Nanjing high tech Industrial Park, Nanjing County, Zhangzhou City, Fujian Province Patentee after: HERUI (ZHANGZHOU) AUXILIARY Co.,Ltd. Address before: 518000 1213, building 49, No.3, Yunfeng Road, Queshan, Gaofeng community, Dalang street, Longhua District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Lijie Intellectual Property Service Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A water resistant water-based polyurethane ink connecting material and its preparation method Effective date of registration: 20230901 Granted publication date: 20180629 Pledgee: Nanjing County Rural Credit Cooperative Association Pledgor: HERUI (ZHANGZHOU) AUXILIARY CO.,LTD. Registration number: Y2023350000195 |