CN108003537A - A kind of high temperature resistant acryl plates and preparation method thereof - Google Patents
A kind of high temperature resistant acryl plates and preparation method thereof Download PDFInfo
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- CN108003537A CN108003537A CN201711421868.9A CN201711421868A CN108003537A CN 108003537 A CN108003537 A CN 108003537A CN 201711421868 A CN201711421868 A CN 201711421868A CN 108003537 A CN108003537 A CN 108003537A
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- acryl
- high temperature
- resin monomer
- temperature resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of high temperature resistant acryl plates, by weight including following components：0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid butadienestyrene copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% organic siliconresin, acryl resin monomer to 100%；The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, and wherein the percentage by weight of polycarbonate resin and polymethyl methacrylate is 1:5.
Description
Technical field
The present invention is related to more particularly to a kind of high temperature resistant acryl plates and preparation method thereof.
Background technology
Acrylic, also known as organic glass, chemical name is polymethacrylates, is a kind of plastic macromolecule material,
There is the excellent and characteristics such as preferable transparent, chemical stability and weatherability, easy dyeing, easy processing, but its is resistance to
It is high temperatures but slightly insufficient, it directly affects the use of acrylic product to a certain extent.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of high temperature resistant acryl plates：
A kind of high temperature resistant acryl plates, by weight including following components：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-benzene
Ethylene copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane,
0.5% magnesium stearate, 15% organic siliconresin, acryl resin monomer to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly-
The percentage by weight of carbonate resin and polymethyl methacrylate is 1:5.
A kind of high temperature resistant acryl plates, by weight including following components：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-benzene
Ethylene copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane,
0.5% magnesium stearate, 15% organic siliconresin, acryl resin monomer to 100%.
A kind of method for preparing heat safe acryl plates, step are as follows：
S1：By trimethyl citrate, resorcinol tetraphenyldiphosphate, methacrylic acid-butadiene-styrene copolymer
Thing, acryl resin monomer are added in reaction kettle, and it is 100 DEG C that heating, which keeps temperature, and adherence pressure to 2MPA, takes out after stirring 3h
Obtain acrylic moulding compound；
S2：Again by nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, magnesium stearate, organosilicon tree
Fat is put into reaction kettle, in 160 DEG C, the pressure of 6MPa, is stirred continuously 2h and is sent to extruder extrusion.
The present invention has the advantages that：The present invention is by by trimethyl citrate, resorcinol tetraphenyl diphosphonic acid
Ester, Methacrylate-butadiene-styrene, nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silicon
Rationally compounding substantially increases product while obtaining ageing-resistant for alkane, magnesium stearate, organic siliconresin, acryl resin monomer
Hardness and high temperature resistant degree.
Embodiment
The present invention is further described with reference to embodiment.
Embodiment 1：A kind of high temperature resistant acryl plates, by weight including following components：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-benzene
Ethylene copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane,
0.5% magnesium stearate, 15% organic siliconresin, acryl resin monomer to 100%.
Embodiment 2：A kind of high temperature resistant acryl plates, by weight including following components：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-benzene
Ethylene copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane,
0.5% magnesium stearate, 15% organic siliconresin, acryl resin monomer to 100%.
Embodiment 3：A kind of high temperature resistant acryl plates, by weight including following components：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-benzene
Ethylene copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane,
0.5% magnesium stearate, 15% organic siliconresin, acryl resin monomer to 100%.
A kind of method for preparing heat safe acryl plates, step are as follows：
S1：By trimethyl citrate, resorcinol tetraphenyldiphosphate, methacrylic acid-butadiene-styrene copolymer
Thing, acryl resin monomer are added in reaction kettle, and it is 100 DEG C that heating, which keeps temperature, and adherence pressure to 2MPA, takes out after stirring 3h
Obtain acrylic moulding compound；
S2：Again by nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, magnesium stearate, organosilicon tree
Fat is put into reaction kettle, in 160 DEG C, the pressure of 6MPa, is stirred continuously 2h and is sent to extruder extrusion.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The connotation changes and variations that derived from of invention still fall within protection scope of the present invention.
Claims (3)
1. a kind of high temperature resistant acryl plates, it is characterised in that by weight including following components：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-styrene
It is copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% hard
Fatty acid magnesium, 15% organic siliconresin, acryl resin monomer to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly- carbonic acid
The percentage by weight of ester resin and polymethyl methacrylate is 1:5.
2. a kind of high temperature resistant acryl plates according to claim 1, it is characterised in that by weight including following groups
Point：
0.5% trimethyl citrate, 1% resorcinol tetraphenyldiphosphate, 1.2% methacrylic acid-butadiene-styrene
It is copolymer, 1.8% nano-graphene, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% hard
Fatty acid magnesium, 15% organic siliconresin, acryl resin monomer to 100%.
A kind of 3. method for preparing the heat safe acryl plates described in claim 1, it is characterised in that step is as follows：
S1：By trimethyl citrate, resorcinol tetraphenyldiphosphate, Methacrylate-butadiene-styrene,
Acryl resin monomer is added in reaction kettle, and it is 100 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out and is obtained after stirring 3h
Obtain acrylic moulding compound；
S2：Nano-graphene, nanometer silicon carbide, maleic anhydride, trimethoxy silane, magnesium stearate, organic siliconresin are put again
Enter in reaction kettle, in 160 DEG C, the pressure of 6MPa, be stirred continuously 2h and send to extruder extrusion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711421868.9A CN108003537A (en) | 2017-12-25 | 2017-12-25 | A kind of high temperature resistant acryl plates and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711421868.9A CN108003537A (en) | 2017-12-25 | 2017-12-25 | A kind of high temperature resistant acryl plates and preparation method thereof |
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| CN108003537A true CN108003537A (en) | 2018-05-08 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233169A (en) * | 2018-09-10 | 2019-01-18 | 天长市瑞慈有机玻璃有限公司 | A kind of high temperature resistant lucite tube |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
-
2017
- 2017-12-25 CN CN201711421868.9A patent/CN108003537A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233169A (en) * | 2018-09-10 | 2019-01-18 | 天长市瑞慈有机玻璃有限公司 | A kind of high temperature resistant lucite tube |
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Application publication date: 20180508 |
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