CN108003536A - A kind of high printing opacity acryl plates and preparation method thereof - Google Patents
A kind of high printing opacity acryl plates and preparation method thereof Download PDFInfo
- Publication number
- CN108003536A CN108003536A CN201711421826.5A CN201711421826A CN108003536A CN 108003536 A CN108003536 A CN 108003536A CN 201711421826 A CN201711421826 A CN 201711421826A CN 108003536 A CN108003536 A CN 108003536A
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- Prior art keywords
- glass fibre
- printing opacity
- high printing
- acrylic
- acryl
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of high printing opacity acryl plates, by weight including following components：0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder, 8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, acryl resin monomer to 100%；The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, and wherein the percentage by weight of polycarbonate resin and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into honeycomb laminated structure.
Description
Technical field
The present invention is related to more particularly to a kind of high printing opacity acryl plates and preparation method thereof.
Background technology
Existing acryl plates have the function of that chemical stability, easy dyeing etc. be excellent and characteristic, but its toughness is but
It is slightly insufficient, it directly affects the use of acrylic to a certain extent.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of high printing opacity acryl plates：
A kind of high printing opacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder,
8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, Ya Ke
Power resin monomer is to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly-
The percentage by weight of carbonate resin and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre
Into honeycomb laminated structure.
Preferably, a kind of high printing opacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder,
8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, Ya Ke
Power resin monomer is to 100%.
A kind of preparation method of high printing opacity acryl plates, step are as follows：
S1：Cyano methyl formate, chloromethyl acetate, dimethacrylate diethanol, acryl resin monomer are added anti-
Answer in kettle, it is 120 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound, by its point
For two parts；
S2：First glass fibre is added in cellular mould, adding acrylic moulding compound makes glass fibre mutual
Random interleaved arrangement congeals into the glass fiber sheets of honeycomb laminated structure, then glass fiber sheets are filled into acrylic board mould
In；
S3：Fluorspar Powder, nanometer silicon carbide, maleic anhydride, trimethoxy silane, magnesium stearate, acrylic moulding compound are put
Enter in reaction kettle, in 165 DEG C, the pressure of 35MPa, pour into mould with glass fiber sheets adhesive solidification, obtain after being stirred continuously 2h
Obtain acryl plates.
The present invention has the advantages that：The transparency of acryl plates under the action of nanometer silicon carbide and Fluorspar Powder
Height, then be made up of the glass fiber sheets in honeycomb laminated structure the skeleton of acrylic board, substantially increase its toughness with it is strong
Degree, and the process made is simple, is particularly suitable for industrialized production.
Embodiment
The present invention is further described with reference to embodiment.
Embodiment 1：A kind of high printing opacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder,
8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, Ya Ke
Power resin monomer is to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly-
The percentage by weight of carbonate resin and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre
Into honeycomb laminated structure.
Embodiment 2：A kind of high printing opacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder,
8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, Ya Ke
Power resin monomer is to 100%.
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly-
The percentage by weight of carbonate resin and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre
Into honeycomb laminated structure.
Embodiment 3：A kind of high printing opacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder,
8% nanometer silicon carbide, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, Ya Ke
Power resin monomer is to 100%.
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly-
The percentage by weight of carbonate resin and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre
Into honeycomb laminated structure.
A kind of preparation method of high printing opacity acryl plates, step are as follows：
S1：Cyano methyl formate, chloromethyl acetate, dimethacrylate diethanol, acryl resin monomer are added anti-
Answer in kettle, it is 120 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound, by its point
For two parts；
S2：First glass fibre is added in cellular mould, adding acrylic moulding compound makes glass fibre mutual
Random interleaved arrangement congeals into the glass fiber sheets of honeycomb laminated structure, then glass fiber sheets are filled into acrylic board mould
In；
S3：Fluorspar Powder, nanometer silicon carbide, maleic anhydride, trimethoxy silane, magnesium stearate, acrylic moulding compound are put
Enter in reaction kettle, in 165 DEG C, the pressure of 35MPa, pour into mould with glass fiber sheets adhesive solidification, obtain after being stirred continuously 2h
Obtain acryl plates.
The skeleton of acrylic board is made up of the glass fiber sheets in honeycomb laminated structure, substantially increase its toughness with
Intensity, and the process made is simple, is particularly suitable for industrialized production.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The connotation changes and variations that derived from of invention still fall within protection scope of the present invention.
Claims (3)
1. a kind of high printing opacity acryl plates, it is characterised in that by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder, 8% are received
Rice carborundum, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, acrylic tree
Alicyclic monomer is to 100%；
The acryl resin monomer is made of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly- carbonic acid
The percentage by weight of ester resin and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into bee
Nest laminated structure.
2. a kind of high printing opacity acryl plates according to claim 1, it is characterised in that by weight including following groups
Point：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.2% dimethacrylate diethanol, 1.8% Fluorspar Powder, 8% are received
Rice carborundum, 0.5% maleic anhydride, 0.5% trimethoxy silane, 0.5% magnesium stearate, 15% glass fibre, acrylic tree
Alicyclic monomer is to 100%.
A kind of 3. method for preparing the high printing opacity acryl plates described in claim 1, it is characterised in that step is as follows：
S1：Cyano methyl formate, chloromethyl acetate, dimethacrylate diethanol, acryl resin monomer are added into reaction kettle
In, it is 120 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound, is classified as two
Part；
S2：First glass fibre is added in cellular mould, adding acrylic moulding compound makes glass fibre mutually random
Then interleaved arrangement congeals into the glass fiber sheets of honeycomb laminated structure, then glass fiber sheets are filled into acrylic board mould；
S3：Fluorspar Powder, nanometer silicon carbide, maleic anhydride, trimethoxy silane, magnesium stearate, acrylic moulding compound are put into instead
Answer in kettle, in 165 DEG C, the pressure of 35MPa, pour into mould with glass fiber sheets adhesive solidification, obtain sub- after being stirred continuously 2h
Gram force plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711421826.5A CN108003536A (en) | 2017-12-25 | 2017-12-25 | A kind of high printing opacity acryl plates and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711421826.5A CN108003536A (en) | 2017-12-25 | 2017-12-25 | A kind of high printing opacity acryl plates and preparation method thereof |
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| CN108003536A true CN108003536A (en) | 2018-05-08 |
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| CN201711421826.5A Pending CN108003536A (en) | 2017-12-25 | 2017-12-25 | A kind of high printing opacity acryl plates and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109336467A (en) * | 2018-10-31 | 2019-02-15 | 苏州观上文化科技有限公司 | A kind of manufacturing method of plastic light transmitting stone and plastic light transmitting stone |
| CN109825020A (en) * | 2019-02-25 | 2019-05-31 | 安徽迈明亚克力科技有限公司 | A kind of high intensity high light transmission acryl plates and preparation method thereof |
| CN112223794A (en) * | 2020-09-10 | 2021-01-15 | 苏州西雅克水族科技有限公司 | Bending and shaping method for acrylic thick plate |
| CN112250788A (en) * | 2020-09-16 | 2021-01-22 | 苏州西雅克水族科技有限公司 | Method for preparing acrylic thick plate by water bath cooling |
| CN112266436A (en) * | 2020-09-08 | 2021-01-26 | 苏州西雅克水族科技有限公司 | High-transparency high-strength acrylic plate and preparation method thereof |
| CN112961483A (en) * | 2021-02-08 | 2021-06-15 | 广东乔艺塑胶有限公司 | PMAA composition applied to cosmetic container and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103112203A (en) * | 2013-03-07 | 2013-05-22 | 辽阳艺蒙织毯有限公司 | Honeycomb core board |
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
| CN106947235A (en) * | 2017-04-28 | 2017-07-14 | 苍南县通普工艺礼品有限公司 | A kind of acrylic diamond of high printing opacity |
-
2017
- 2017-12-25 CN CN201711421826.5A patent/CN108003536A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103112203A (en) * | 2013-03-07 | 2013-05-22 | 辽阳艺蒙织毯有限公司 | Honeycomb core board |
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
| CN106947235A (en) * | 2017-04-28 | 2017-07-14 | 苍南县通普工艺礼品有限公司 | A kind of acrylic diamond of high printing opacity |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109336467A (en) * | 2018-10-31 | 2019-02-15 | 苏州观上文化科技有限公司 | A kind of manufacturing method of plastic light transmitting stone and plastic light transmitting stone |
| CN109825020A (en) * | 2019-02-25 | 2019-05-31 | 安徽迈明亚克力科技有限公司 | A kind of high intensity high light transmission acryl plates and preparation method thereof |
| CN112266436A (en) * | 2020-09-08 | 2021-01-26 | 苏州西雅克水族科技有限公司 | High-transparency high-strength acrylic plate and preparation method thereof |
| CN112223794A (en) * | 2020-09-10 | 2021-01-15 | 苏州西雅克水族科技有限公司 | Bending and shaping method for acrylic thick plate |
| CN112250788A (en) * | 2020-09-16 | 2021-01-22 | 苏州西雅克水族科技有限公司 | Method for preparing acrylic thick plate by water bath cooling |
| CN112961483A (en) * | 2021-02-08 | 2021-06-15 | 广东乔艺塑胶有限公司 | PMAA composition applied to cosmetic container and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20180508 |