CN106947235A - A kind of acrylic diamond of high printing opacity - Google Patents
A kind of acrylic diamond of high printing opacity Download PDFInfo
- Publication number
- CN106947235A CN106947235A CN201710294699.0A CN201710294699A CN106947235A CN 106947235 A CN106947235 A CN 106947235A CN 201710294699 A CN201710294699 A CN 201710294699A CN 106947235 A CN106947235 A CN 106947235A
- Authority
- CN
- China
- Prior art keywords
- acrylic
- printing opacity
- high printing
- diamond
- acrylic diamond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C17/00—Gems or the like
- A44C17/007—Special types of gems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dental Preparations (AREA)
Abstract
A kind of acrylic diamond of high printing opacity, by weight including following components：Acryl resin monomer 30 40%；Compatilizer 0.25 1%；Curing agent 0.1 0.5%；The antioxidant 0.1 2% of compounding；Inorganic filler is to 100%；The acryl resin monomer is made up of the mixture of polycarbonate resin and polymethyl methacrylate, and wherein the percentage by weight of polycarbonate resin and polymethyl methacrylate is 5:1‑3.5.
Description
Technical field
The present invention relates to specifically related to a kind of acrylic diamond of high printing opacity and preparation method thereof.
Background technology
Molding acrylic diamond is prepared by the way that inorganic filler such as aluminium hydroxide is mixed into acrylic resinoid, this sub- gram
Power diamond has various excellent a functions and performance, such as outward appearance, soft feel, but be due to acrylic resinoid in itself
Characteristic make it that product has certain defect.
The content of the invention
In order to solve the above problems, the invention provides a kind of acrylic diamond of high printing opacity：
A kind of acrylic diamond of high printing opacity, by weight including following components：
Acryl resin monomer 30-40%；
Compatilizer 0.25-1%；
Curing agent 0.1-0.5%；
The antioxidant 0.1-2% of compounding；
Inorganic filler is to 100%；
The acryl resin monomer is made up of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly- carbonic acid
The percentage by weight of ester resin and polymethyl methacrylate is 5: 1-3.5.
It is preferred that, the compatilizer is polystyrene resin.
It is preferred that, the inorganic filler is one kind in aluminium hydroxide, silica, calcium carbonate, talcum powder or its mixing
Thing.
It is preferred that, described curing agent is one kind in organic peroxide, azo-compound.
It is preferred that, also including the one or more in reinforcing agent, colouring agent, shrinking agent.
A kind of preparation method of the acrylic diamond of high printing opacity, it is characterised in that：Step is as follows：Compounding is added in kneader
Antioxidant, acryl resin monomer, inorganic filler, curing agent, compatilizer, above-mentioned raw materials are mediated and obtain transparent acrylic
Moulding compound, acrylic moulding compound is filled into mould, is solidified under 100-145 degrees Celsius, 20-50MPa pressure, and Asia is made
Gram force diamond.
The present invention has the advantages that：This product substantially increases its transparency, still exists from regardless of whether seeing outside
Real diamond is all more nearly in its performance, and the process made is simple, is particularly suitable for industrialized production.
Embodiment
Embodiment 1：A kind of acrylic diamond of high printing opacity, by weight including following components：
Acryl resin monomer 30%（Polycarbonate resin 20%；Polymethyl methacrylate 10%）；
Compatilizer 0.7%（Polystyrene resin）；
Curing agent 0.1%；
The antioxidant 0.1% of compounding；
Colouring agent 0.5%；
Inorganic filler is to 100%（Silica；Calcium carbonate）；
Embodiment 2：A kind of acrylic diamond of high printing opacity, by weight including following components：
Acryl resin monomer 35%（Polycarbonate resin 25%；Polymethyl methacrylate 10%）；
Compatilizer 0.25%（Polystyrene resin）；
The % of curing agent 0.2；
The antioxidant 0.5% of compounding；
Colouring agent 0.5%；
Inorganic filler is to 100%（Silica：Calcium carbonate is 3:1 mixing match）.
Embodiment 3：A kind of acrylic diamond of high printing opacity, by weight including following components：
Acryl resin monomer 40%（Polycarbonate resin 30%；Polymethyl methacrylate 10%）；
Compatilizer 0.9%（Polystyrene resin）；
The % of curing agent 0.5；
The antioxidant 0.5% of compounding；
Colouring agent 0.5%；
Inorganic filler is to 100%（Silica：Calcium carbonate is 3:1 mixing match）.
A kind of preparation method of the acrylic diamond of high printing opacity, it is characterised in that：Step is as follows：Compounding is added in kneader
Antioxidant, acryl resin monomer, inorganic filler, curing agent, compatilizer, above-mentioned raw materials are mediated and obtain transparent acrylic
Moulding compound, acrylic moulding compound is filled into mould, is solidified under 100-145 degrees Celsius, 20-50MPa pressure, and Asia is made
Gram force diamond.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, it can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The obvious change or variation that the connotation of invention is amplified out still fall within protection scope of the present invention.
Claims (6)
1. a kind of acrylic diamond of high printing opacity, by weight including following components：
Acryl resin monomer 30-40%；
Compatilizer 0.25-1%；
Curing agent 0.1-0.5%；
The antioxidant 0.1-2% of compounding；
Inorganic filler is to 100%；
The acryl resin monomer is made up of the mixture of polycarbonate resin and polymethyl methacrylate, wherein poly- carbonic acid
The percentage by weight of ester resin and polymethyl methacrylate is 5: 1-3.5.
2. a kind of acrylic diamond of high printing opacity according to claim 1, it is characterised in that：The compatilizer is polyphenyl second
Olefine resin.
3. a kind of acrylic diamond of high printing opacity according to claim 1, it is characterised in that：The inorganic filler is hydrogen-oxygen
Change aluminium, silica, calcium carbonate, one kind in talcum powder or its mixture.
4. a kind of acrylic diamond of high printing opacity according to claim 1, it is characterised in that：Described curing agent is organic
One kind in peroxide, azo-compound.
5. a kind of acrylic diamond of high printing opacity according to claim 1, it is characterised in that：Also include reinforcing agent, coloring
One or more in agent, shrinking agent.
6. a kind of preparation method of the acrylic diamond of high printing opacity according to claim 1-5, it is characterised in that：Step is such as
Under：The antioxidant of compounding, acryl resin monomer, inorganic filler, curing agent, compatilizer are added in kneader, by above-mentioned raw materials
Mediate and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould, in 100-145 degrees Celsius, 20-
Solidify under 50MPa pressure, acrylic diamond is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710294699.0A CN106947235A (en) | 2017-04-28 | 2017-04-28 | A kind of acrylic diamond of high printing opacity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710294699.0A CN106947235A (en) | 2017-04-28 | 2017-04-28 | A kind of acrylic diamond of high printing opacity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106947235A true CN106947235A (en) | 2017-07-14 |
Family
ID=59477829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710294699.0A Pending CN106947235A (en) | 2017-04-28 | 2017-04-28 | A kind of acrylic diamond of high printing opacity |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106947235A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003536A (en) * | 2017-12-25 | 2018-05-08 | 温州中祥光电科技发展有限公司 | A kind of high printing opacity acryl plates and preparation method thereof |
| CN109438894A (en) * | 2018-10-30 | 2019-03-08 | 佛山市合宏泰业科技有限公司 | A kind of visual reaction kettle PC/PMMA alloy material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN102850754A (en) * | 2012-09-21 | 2013-01-02 | 常熟市凯力达蜂窝包装材料有限公司 | Flame retardant transparent polycarbonate/polymethyl methacrylate alloy material |
-
2017
- 2017-04-28 CN CN201710294699.0A patent/CN106947235A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN102850754A (en) * | 2012-09-21 | 2013-01-02 | 常熟市凯力达蜂窝包装材料有限公司 | Flame retardant transparent polycarbonate/polymethyl methacrylate alloy material |
Non-Patent Citations (3)
| Title |
|---|
| 吴培熙等: "《塑料制品生产工艺手册》", 30 October 2004, 化学工业出版社 * |
| 张蓓莉: "《系统宝石学》", 31 May 2006, 地质出版社 * |
| 王文广等: "《塑料配方设计》", 31 July 2004, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003536A (en) * | 2017-12-25 | 2018-05-08 | 温州中祥光电科技发展有限公司 | A kind of high printing opacity acryl plates and preparation method thereof |
| CN109438894A (en) * | 2018-10-30 | 2019-03-08 | 佛山市合宏泰业科技有限公司 | A kind of visual reaction kettle PC/PMMA alloy material |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170714 |
|
| RJ01 | Rejection of invention patent application after publication |