CN108002814A - A kind of ceramic material for 3D printing and its preparation method and application - Google Patents
A kind of ceramic material for 3D printing and its preparation method and application Download PDFInfo
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- CN108002814A CN108002814A CN201711343564.5A CN201711343564A CN108002814A CN 108002814 A CN108002814 A CN 108002814A CN 201711343564 A CN201711343564 A CN 201711343564A CN 108002814 A CN108002814 A CN 108002814A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/6303—Inorganic additives
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6026—Computer aided shaping, e.g. rapid prototyping
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Abstract
The invention discloses a kind of ceramic material for 3D printing, including following component in parts by weight：100 200 parts of polyethylene, 20 50 parts of ceramic, 10 30 parts of 5 toluphenazine Methylsulfate, adjacent 10 25 parts of sulfonamide benzoic acid methyl esters, 5 15 parts of tributyl phosphate, 4 11 parts of Potassium Hydrogen Phthalate, 5 11 parts of tea polyphenols, 38 parts of ammonium molybdate.Ceramic material of the present invention is used for 3D printing technique field, has excellent low temperature resistant effect, and cryogenic tensile intensity is high, low temperature impact strength is high, and brittle temperature is low, suitable for extremely cold low temperature environment, preparation method is simple, has preferable economic value and social value.
Description
Technical field
The present invention relates to 3D printing technique field, be specifically a kind of ceramic material for 3D printing and preparation method thereof with
Using.
Background technology
3D printing, also referred to as the one kind for for increasing material manufacturing, being rapid shaping technique, is known as " the third time industrial revolution "
Core technology.Compared with traditional manufacturing technology, 3D printing need not manufacture mould in advance, it is not necessary to remove in the fabrication process big
The material of amount, also can be obtained by final products without going through complicated forging technology, therefore, structure can be realized in production
Optimization, save material and save the energy.3D printing technique be suitable for new product development, quick-acting single and parts in small batch manufacture,
The manufacture of complicated shape part, the design of mould and manufacture etc., be also suitable for the manufacture of difficult-to-machine material, configuration design inspection,
Assembly test and Rapid reverse engineering etc..Therefore, 3D printing industry receives concern more and more extensive both at home and abroad, under becoming
One tool rising industry with broad prospects for development.Existing 3D printing material has the following disadvantages：Low temperature resistant effect is poor, low temperature
Lower impact strength is low.Therefore, the present invention provides a kind of ceramic material for 3D printing and its preparation method and application.
The content of the invention
It is an object of the invention to provide a kind of ceramic material for 3D printing and its preparation method and application, to solve
Problem proposed in the above background technology.
To achieve the above object, the present invention provides following technical solution：
A kind of ceramic material for 3D printing, including following component in parts by weight：100-200 parts of polyethylene,
20-50 parts of ceramic, 10-30 parts of 5- toluphenazine Methylsulfates, adjacent 10-25 parts of sulfonamide benzoic acid methyl esters, tricresyl phosphate fourth
5-15 parts of ester, 4-11 parts of Potassium Hydrogen Phthalate, 5-11 parts of tea polyphenols, 3-8 parts of ammonium molybdate.
As the further scheme of the present invention：Including following component in parts by weight：125-180 parts of polyethylene, pottery
25-40 parts of porcelain micro mist, 18-25 parts of 5- toluphenazine Methylsulfates, adjacent 16-20 parts of sulfonamide benzoic acid methyl esters, tributyl phosphate
8-12 parts, 8-10 parts of Potassium Hydrogen Phthalate, 6-8 parts of tea polyphenols, 4-7 parts of ammonium molybdate.
As the further scheme of the present invention：Including following component in parts by weight：155 parts of polyethylene, ceramics are micro-
38 parts of powder, 20 parts of 5- toluphenazines Methylsulfate, adjacent 18 parts of sulfonamide benzoic acid methyl esters, 10 parts of tributyl phosphate, O-phthalic
9 parts of potassium hydrogen phthalate, 7 parts of tea polyphenols, 5 parts of ammonium molybdate.
A kind of preparation method of ceramic material for 3D printing, comprises the following steps：(1) by 5- toluphenazine sulfuric acid first
Ester, Potassium Hydrogen Phthalate and ammonium molybdate mixing, add the water of 3-5 times of weight of mixture, are uniformly mixed, obtain mixture A；
(2) adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed, adds the 50-65%'s of 5-7 times of weight of mixture
Ethanol, is uniformly mixed, obtains mixture B；(3) mixture A is mixed with mixture B, adds polyethylene and ceramic,
1-2h is stirred at 60-85 DEG C, then heats to 125-140 DEG C, mixes 20-35min；(4) upper step gains are placed in extruder
Middle extrusion, gets product.
As the further scheme of the present invention：Mixture A is added drop-wise in mixture B by step (3), rate of addition 10-
20 drops/min.
A kind of application of ceramic material for 3D printing, the ceramic material are used for 3D printing technique field.
Compared with prior art, the beneficial effects of the invention are as follows：
Ceramic material of the present invention is used for 3D printing technique field, has excellent low temperature resistant effect, and cryogenic tensile intensity is high,
Low temperature impact strength is high, and brittle temperature is low, and suitable for extremely cold low temperature environment, preparation method is simple, has preferable
Economic value and social value.
Embodiment
The technical solution of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of ceramic material for 3D printing, including following component in parts by weight：100 parts of polyethylene, ceramics
20 parts of micro mist, 10 parts of 5- toluphenazines Methylsulfate, adjacent 10 parts of sulfonamide benzoic acid methyl esters, 5 parts of tributyl phosphate, O-phthalic
4 parts of potassium hydrogen phthalate, 5 parts of tea polyphenols, 3 parts of ammonium molybdate.
A kind of preparation method of ceramic material for 3D printing, comprises the following steps：(1) by 5- toluphenazine sulfuric acid first
Ester, Potassium Hydrogen Phthalate and ammonium molybdate mixing, add the water of 3 times of weight of mixture, are uniformly mixed, obtain mixture A；(2)
Adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed, add 50% ethanol of 5 times of weight of mixture, are mixed
Close uniformly, obtain mixture B；(3) mixture A is mixed with mixture B, mixture A is added drop-wise in mixture B, speed is added dropwise
Spend for 10 drops/min；Then polyethylene and ceramic are added, 1h is stirred at 60 DEG C, then heats to 125 DEG C, mixing
20min；(4) upper step gains are placed in extruder and extruded, got product.The ceramic material is led for 3D printing technique
Domain.
Embodiment 2
A kind of ceramic material for 3D printing, including following component in parts by weight：200 parts of polyethylene, ceramics
50 parts of micro mist, 30 parts of 5- toluphenazines Methylsulfate, adjacent 25 parts of sulfonamide benzoic acid methyl esters, 15 parts of tributyl phosphate, adjacent benzene two
11 parts of first potassium hydrogen phthalate, 11 parts of tea polyphenols, 8 parts of ammonium molybdate.
A kind of preparation method of ceramic material for 3D printing, comprises the following steps：(1) by 5- toluphenazine sulfuric acid first
Ester, Potassium Hydrogen Phthalate and ammonium molybdate mixing, add the water of 5 times of weight of mixture, are uniformly mixed, obtain mixture A；(2)
Adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed, add 65% ethanol of 7 times of weight of mixture, are mixed
Close uniformly, obtain mixture B；(3) mixture A is mixed with mixture B, mixture A is added drop-wise in mixture B, speed is added dropwise
Spend for 20 drops/min；Then polyethylene and ceramic are added, 2h is stirred at 85 DEG C, then heats to 140 DEG C, mixing
35min；(4) upper step gains are placed in extruder and extruded, got product.The ceramic material is led for 3D printing technique
Domain.
Embodiment 3
A kind of ceramic material for 3D printing, including following component in parts by weight：155 parts of polyethylene, ceramics
38 parts of micro mist, 20 parts of 5- toluphenazines Methylsulfate, adjacent 18 parts of sulfonamide benzoic acid methyl esters, 10 parts of tributyl phosphate, adjacent benzene two
9 parts of first potassium hydrogen phthalate, 7 parts of tea polyphenols, 5 parts of ammonium molybdate.
A kind of preparation method of ceramic material for 3D printing, comprises the following steps：(1) by 5- toluphenazine sulfuric acid first
Ester, Potassium Hydrogen Phthalate and ammonium molybdate mixing, add the water of 4 times of weight of mixture, are uniformly mixed, obtain mixture A；(2)
Adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed, add 58% ethanol of 6 times of weight of mixture, are mixed
Close uniformly, obtain mixture B；(3) mixture A is mixed with mixture B, mixture A is added drop-wise in mixture B, speed is added dropwise
Spend for 15 drops/min；Then polyethylene and ceramic are added, 1.6h is stirred at 65 DEG C, then heats to 130 DEG C, mixing
25min；(4) upper step gains are placed in extruder and extruded, got product.The ceramic material is led for 3D printing technique
Domain.
Embodiment 4
A kind of ceramic material for 3D printing, including following component in parts by weight：125 parts of polyethylene, ceramics
25 parts of micro mist, 18 parts of 5- toluphenazines Methylsulfate, adjacent 16 parts of sulfonamide benzoic acid methyl esters, 8 parts of tributyl phosphate, O-phthalic
8 parts of potassium hydrogen phthalate, 6 parts of tea polyphenols, 4 parts of ammonium molybdate.
A kind of preparation method of ceramic material for 3D printing, comprises the following steps：(1) by 5- toluphenazine sulfuric acid first
Ester, Potassium Hydrogen Phthalate and ammonium molybdate mixing, add the water of 3.5 times of weight of mixture, are uniformly mixed, obtain mixture A；
(2) adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed, adds 52% second of 5.5 times of weight of mixture
Alcohol, is uniformly mixed, obtains mixture B；(3) mixture A is mixed with mixture B, mixture A is added drop-wise in mixture B, dripped
Acceleration is 13 drops/min；Then polyethylene and ceramic are added, 1.3h is stirred at 72 DEG C, then heats to 128 DEG C, is mixed
Close 28min；(4) upper step gains are placed in extruder and extruded, got product.The ceramic material is led for 3D printing technique
Domain.
Embodiment 5
A kind of ceramic material for 3D printing, including following component in parts by weight：180 parts of polyethylene, ceramics
40 parts of micro mist, 25 parts of 5- toluphenazines Methylsulfate, adjacent 20 parts of sulfonamide benzoic acid methyl esters, 12 parts of tributyl phosphate, adjacent benzene two
10 parts of first potassium hydrogen phthalate, 8 parts of tea polyphenols, 7 parts of ammonium molybdate.
A kind of preparation method of ceramic material for 3D printing, comprises the following steps：(1) by 5- toluphenazine sulfuric acid first
Ester, Potassium Hydrogen Phthalate and ammonium molybdate mixing, add the water of 4.5 times of weight of mixture, are uniformly mixed, obtain mixture A；
(2) adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed, adds 62% second of 6.7 times of weight of mixture
Alcohol, is uniformly mixed, obtains mixture B；(3) mixture A is mixed with mixture B, mixture A is added drop-wise in mixture B, dripped
Acceleration is 18 drops/min；Then polyethylene and ceramic are added, 1.8h is stirred at 81 DEG C, then heats to 136 DEG C, is mixed
Close 32min；(4) upper step gains are placed in extruder and extruded, got product.The ceramic material is led for 3D printing technique
Domain.
Comparative example 1
A kind of ceramic material for 3D printing, including following component in parts by weight：155 parts of polyethylene, ceramics
38 parts of micro mist, adjacent 18 parts of sulfonamide benzoic acid methyl esters, 10 parts of tributyl phosphate, 9 parts of Potassium Hydrogen Phthalate, 7 parts of tea polyphenols, molybdenum
Sour 5 parts of ammonium.
Comparative example 2
A kind of ceramic material for 3D printing, including following component in parts by weight：155 parts of polyethylene, ceramics
38 parts of micro mist, 20 parts of 5- toluphenazines Methylsulfate, 10 parts of tributyl phosphate, 9 parts of Potassium Hydrogen Phthalate, 7 parts of tea polyphenols, molybdenum
Sour 5 parts of ammonium.
Comparative example 3
A kind of ceramic material for 3D printing, including following component in parts by weight：155 parts of polyethylene, ceramics
38 parts of micro mist, 10 parts of tributyl phosphate, 9 parts of Potassium Hydrogen Phthalate, 7 parts of tea polyphenols, 5 parts of ammonium molybdate.
Experimental example
The 3D printing material prepared to embodiment 3 and comparative example 1-3 is tested for the property, as a result as follows.
| Project | Cryogenic tensile intensity MPa | Low temperature impact strength J/m2 | Brittle temperature DEG C |
| Embodiment 1 | 205.6 | 30.7 | -108 |
| Comparative example 1 | 132.7 | 14.6 | -65 |
| Comparative example 2 | 161.5 | 16.1 | -58 |
| Comparative example 3 | 130.8 | 14.5 | -42 |
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from the knowledge that one skilled in the relevant art possesses
Make a variety of changes.
Claims (6)
1. a kind of ceramic material for 3D printing, it is characterised in that including following component in parts by weight：Polyethylene
100-200 parts, 20-50 parts of ceramic, 10-30 parts of 5- toluphenazine Methylsulfates, adjacent sulfonamide benzoic acid methyl esters 10-25
Part, 5-15 parts of tributyl phosphate, 4-11 parts of Potassium Hydrogen Phthalate, 5-11 parts of tea polyphenols, 3-8 parts of ammonium molybdate.
2. the ceramic material according to claim 1 for 3D printing, it is characterised in that including it is following in parts by weight
Component：125-180 parts of polyethylene, 25-40 parts of ceramic, 18-25 parts of 5- toluphenazine Methylsulfates, adjacent sulfonamide phenyl first
Sour methyl esters 16-20 parts, 8-12 parts of tributyl phosphate, 8-10 parts of Potassium Hydrogen Phthalate, 6-8 parts of tea polyphenols, 4-7 parts of ammonium molybdate.
3. the ceramic material according to claim 1 for 3D printing, it is characterised in that including it is following in parts by weight
Component：155 parts of polyethylene, 38 parts of ceramic, 20 parts of 5- toluphenazines Methylsulfate, adjacent sulfonamide benzoic acid methyl esters 18
Part, 10 parts of tributyl phosphate, 9 parts of Potassium Hydrogen Phthalate, 7 parts of tea polyphenols, 5 parts of ammonium molybdate.
A kind of 4. preparation method of ceramic material for 3D printing as described in claim 1-3 is any, it is characterised in that bag
Include following steps：(1) 5- toluphenazines Methylsulfate, Potassium Hydrogen Phthalate and ammonium molybdate are mixed, adds 3-5 times of mixture
The water of weight, is uniformly mixed, obtains mixture A；(2) adjacent sulfonamide benzoic acid methyl esters, tributyl phosphate and tea polyphenols are mixed,
The ethanol of the 50-65% of 5-7 times of weight of mixture is added, is uniformly mixed, obtains mixture B；(3) by mixture A and mixture B
Mixing, adds polyethylene and ceramic, 1-2h is stirred at 60-85 DEG C, then heats to 125-140 DEG C, mixes 20-
35min；(4) upper step gains are placed in extruder and extruded, got product.
5. the preparation method of the ceramic material according to claim 4 for 3D printing, it is characterised in that step (3) will
Mixture A is added drop-wise in mixture B, and rate of addition is 10-20 drops/min.
A kind of 6. application of ceramic material for 3D printing as described in claim 1-3 is any, it is characterised in that the pottery
Ceramic material is used for 3D printing technique field.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108530734A (en) * | 2018-05-16 | 2018-09-14 | 柏浩 | A kind of 3D printing modified low-density polyethylene material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103980593A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | Modified high density polyethylene 3D printing moulding material and preparation method |
| CN104526838A (en) * | 2014-12-30 | 2015-04-22 | 宁波伏尔肯机械密封件制造有限公司 | Method for 3D ceramic printing forming |
| CN107311640A (en) * | 2017-06-23 | 2017-11-03 | 四川大学 | Composition and application method with open pores ceramics are prepared for 3D printing |
-
2017
- 2017-12-15 CN CN201711343564.5A patent/CN108002814A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103980593A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | Modified high density polyethylene 3D printing moulding material and preparation method |
| CN104526838A (en) * | 2014-12-30 | 2015-04-22 | 宁波伏尔肯机械密封件制造有限公司 | Method for 3D ceramic printing forming |
| CN107311640A (en) * | 2017-06-23 | 2017-11-03 | 四川大学 | Composition and application method with open pores ceramics are prepared for 3D printing |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108530734A (en) * | 2018-05-16 | 2018-09-14 | 柏浩 | A kind of 3D printing modified low-density polyethylene material and preparation method thereof |
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Application publication date: 20180508 |