CN107997294A - A kind of women's shoes with high adhesion face coat - Google Patents
A kind of women's shoes with high adhesion face coat Download PDFInfo
- Publication number
- CN107997294A CN107997294A CN201711369346.9A CN201711369346A CN107997294A CN 107997294 A CN107997294 A CN 107997294A CN 201711369346 A CN201711369346 A CN 201711369346A CN 107997294 A CN107997294 A CN 107997294A
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- CN
- China
- Prior art keywords
- face coat
- shoes
- women
- band
- high adhesion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B7/00—Footwear with health or hygienic arrangements
- A43B7/38—Elevating, i.e. height increasing
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/22—Soles made slip-preventing or wear-resisting, e.g. by impregnation or spreading a wear-resisting layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Abstract
The present invention provides a kind of women's shoes with high adhesion face coat, it is characterised in that the face coat includes the component of following parts by weight：Methyl acrylate 16 24, two anisidine diisocyanate 19 35, polyhexamethylene guanidine propionate 13 21, azodiisobutyronitrile 9 14, methyl methacrylate 8 17, dispersant 59, thickener 28, fungicide 23 57, defoamer 13, pH adjusting agent 4 11,3,3 ' dimethyl, 4,4 ' diamino-dicyclohexyl methane 59 73, cyclohexyl acetate 16 28, distilled water 33 56.The face coat of the present invention can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property, used suitable for large-scale promotion.
Description
Technical field
The present invention relates to footwear technology, and in particular to a kind of women's shoes with high adhesion face coat.
Background technology
Coating composition is used in numerous industry.These industry can include, but not limited to land transport vehicle for example
Car, truck, sport vehicle, motorcycle；Marine equipment such as ship, ship and submarine；Aircraft such as aircraft
And helicopter；Industrial such as business equipment and structure, including wall and roof；Build such as Construction traffic and structure, bag
Include wall and roof, military such as military vehicle, such as tank and brave horse transport vehicle, and military structure body, including wall and roof,
Such as caisson and battery case etc..
In these industry, coating for example protects various parts from because of corrosion, wear, impact, change for numerous purposes
Damage caused by product, ultraviolet light, flame and heat and other environmental exposures, and for their components deposited thereon well
Assign shellproof and explosion-proof buffering performance (balllistic and blast mitigation properties).Therefore,
Huge effort is taken to develop the coating composition for having and improving performance.
Coating usually can be used for footwear industry.Footwear (footwear) generally fall into two parts, vamp and sole.Vamp
The part for being designed as cosily encapsulating foot of footwear, and sole be footwear be designed as provide attachment frictional force
(traction), the part on protection, damping and/or endurable surface.
Vamp is typically made of many different components, these components are usually made from a variety of materials.The material
Including, such as natural leather, synthetic leather, vinyl material and fabric such as nylon；Other fabrics can also be used.Even in
During the normal use of footwear, many upper members, particularly " toe-cap " may experience loss and/or abrasions.
Similarly, sole generally includes the different components being made from a different material.Midsole typically by foam for example
Ethylene vinyl acetate (EVA) foam or polyurethane such as TPU foams are made.These materials application load, for example exist
By elastic compression under foot and the power of leg generation during body movement.Many footwear, particularly sport footwear are included in another shoes department part example
Filling damping element or bladder in such as midsole, footwear outer bottom.The bladder can be by that can show resistance to compression
To provide expandable insert made of the polymeric material of additional cushioning effect for footwear wearer.These bladders can use-case
As plasma, water or other fluids such as air or nitrogen are filled.Footwear outer bottom is usually by synthesizing and/or natural rubber, such as
Silica-filled rubber composition is made.During the normal use of footwear, footwear outer bottom may also undergo loss and/or
Abrasion.
Therefore, it is intended that article of footwear to being lost, wearing and improved resistance, durability and the antibiotic property of other damages
Energy.
The content of the invention
In view of this, the present invention provides a kind of a kind of new women's shoes with high adhesion face coat, of the invention
Face coat can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property,
Used suitable for large-scale promotion.
The technical scheme is that：A kind of women's shoes with high adhesion face coat, including sole, after the sole
Side is equipped with heel part, and the top of the sole is equipped with first and fixes band, the second fixation band, main supporting part, side supporting part, rear support
Band, described first fixes the front end area that band is equipped with the sole, and the side supporting part is symmetrically set in the both sides at sole rear, institute
State collateral support band top and be connected with the second fixation band, the main supporting part fixes band with the described first fixation band, second respectively
Intermediate region connects, and the rear support band is arranged on the stub area of the sole, and the rear support band fixes band with described second
Connection；The sole is equipped with face coat, and the face coat includes the component of following parts by weight：Methyl acrylate 16-24,
Two anisidine diisocyanate 19-35, polyhexamethylene guanidine propionate 13-21, azodiisobutyronitrile 9-14, methacrylic acid
Methyl esters 8-17, dispersant 5-9, thickener 2-8, fungicide 23-57, defoamer 1-3, pH adjusting agent 4-11,3,3 '-two
Methyl -4,4 '-diamino-dicyclohexyl methane 59-73, cyclohexyl acetate 16-28, distilled water 33-56.
Further, the face coat includes the component of following parts by weight：Methyl acrylate 19-22, two anisidines
Diisocyanate 24-31, polyhexamethylene guanidine propionate 15-19, azodiisobutyronitrile 10-12, methyl methacrylate 11-
15th, dispersant 6-7, thickener 4-7, fungicide 31-46, defoamer 2-3, pH adjusting agent 5-9,3,3 '-dimethyl -4,
4 '-diamino-dicyclohexyl methane 63-70, cyclohexyl acetate 21-25, distilled water 39-45.
Further, the face coat includes the component of following parts by weight：Methyl acrylate 21, two anisidines two are different
Cyanate 27, polyhexamethylene guanidine propionate 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, thickening
Agent 5, fungicide 39, defoamer 2, pH adjusting agent 8,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 67, acetic acid
Cyclohexyl 23, distilled water 42.
Further, the fungicide is graphene oxide.Particularly, fungicide of the invention, which mixes, enters ethyl cyclohexyl
Adsorbed in ester, form slowly releasing effect, long-acting antibacterial layer is formed in coating surface.
Further, the coalescents are propane diols, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dipropyl
One kind in glycol dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol butyl ether.
Further, the dispersant is lauryl sodium sulfate, methyl anyl alcohol, two anisidine diisocyanate, Gu Er
One kind in glue, fatty acid polyethylene glycol ester.The dispersant is the poly- diethanol that molecular weight is 5000 and molecular weight is 4000
Poly- diethanol 4:The mixture of 5 mass ratioes, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of face coat of the present invention is：S1. butyl acrylate, two anisidine diisocyanate, propionic acid are gathered
Shaken up after hexa-methylene guanidine, azodiisobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.After shaking up
Solution is heated to 40-50 DEG C, and stirs 60-90min with 60r/min, obtains mixed solution；S2. by polyimides tiny balloon
Mixed with fungicide；S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with 4000-
The rate of dispersion of 5500r/min disperses 20-40min.
Compounded by the synergistic of each component of the present invention, the present invention can significantly improve article of footwear to being lost, wear and
Resistance, durability and the anti-microbial property of other damages, use suitable for large-scale promotion.
Brief description of the drawings
Fig. 1 is the structure diagram of the present invention.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only part of the embodiment of the present invention to apply example, instead of all the embodiments.
Embodiment 1
The present embodiment provides a kind of women's shoes with high adhesion face coat, including sole 1, the sole rear to be equipped with heel
Portion 2, the top of the sole are equipped with first and fix the fixation of band 11, second band 12, main supporting part 13, side supporting part 14, rear support
Band 15, described first fixes the front end area that band is equipped with the sole, and the side supporting part is symmetrically set in the both sides at sole rear,
The collateral support band top is connected with the second fixation band, and the main supporting part fixes band, the second fixation band with described first respectively
Intermediate region connection, the rear support band be arranged on the sole stub area, the rear support band with described second fix
Band connection；The sole is equipped with face coat 16, and the face coat includes the component of following parts by weight：Methyl acrylate
21st, two anisidine diisocyanate 27, polyhexamethylene guanidine propionate 17, azodiisobutyronitrile 11, methyl methacrylate
13rd, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8,3,3 '-dimethyl -4,4 '-diaminourea two
Cyclohexyl-methane 67, cyclohexyl acetate 23, distilled water 42.
Further, the fungicide is graphene oxide.
Particularly, fungicide of the invention is mixed to enter in cyclohexyl acetate and adsorbed, and slowly releasing effect is formed, in coating table
Face forms long-acting antibacterial layer.
Further, the coalescents are propandiol butyl ether.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of face coat of the present invention is：S1. butyl acrylate, two anisidine diisocyanate, propionic acid are gathered
Shaken up after hexa-methylene guanidine, azodiisobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.After shaking up
Solution is heated to 40-50 DEG C, and stirs 60-90min with 60r/min, obtains mixed solution；S2. by polyimides tiny balloon
Mixed with fungicide；S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with 4000-
The rate of dispersion of 5500r/min disperses 20-40min.
Embodiment 2
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 21, two anisidine diisocyanate 27, propionic acid poly- six is sub-
Methylguanidine 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, thickener 5, fungicide 39, defoaming
Agent 2, pH adjusting agent 8,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 67, cyclohexyl acetate 23, distilled water
42。
Further, the fungicide is graphene oxide.
Further, the coalescents are propane diols.
Further, the dispersant is the poly- diethanol that molecular weight is 5000 and the poly- diethanol that molecular weight is 4000
4:The mixture of 5 mass ratioes, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 3
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：The face coat includes the component of following parts by weight：Methyl acrylate
19th, two anisidine diisocyanate 24, polyhexamethylene guanidine propionate 15, azodiisobutyronitrile 10, methyl methacrylate
11st, dispersant 6, thickener 4, fungicide 31, defoamer 2, pH adjusting agent 5,3,3 '-dimethyl -4,4 '-diaminourea two
Cyclohexyl-methane 63, cyclohexyl acetate 21, distilled water 39.
Further, the fungicide is graphene oxide.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is lauryl sodium sulfate, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 4
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 24, two anisidine diisocyanate 35, propionic acid poly- six is sub-
Methylguanidine 21, azodiisobutyronitrile 14, methyl methacrylate 17, dispersant 9, thickener 8, fungicide 57, defoaming
Agent 3, pH adjusting agent 11,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 73, cyclohexyl acetate 28, distilled water
56。
Further, the fungicide is graphene oxide.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 5
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 22, two anisidine diisocyanate 31, propionic acid poly- six is sub-
Methylguanidine 19, azodiisobutyronitrile 12, methyl methacrylate 15, dispersant 7, thickener 7, fungicide 46, defoaming
Agent 3, pH adjusting agent 9,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 70, cyclohexyl acetate 25, distilled water
45。
Further, the fungicide is graphene oxide.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is two anisidine diisocyanate, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 6
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 16, two anisidine diisocyanate 19, propionic acid poly- six is sub-
Methylguanidine 13, azodiisobutyronitrile 9, methyl methacrylate 8, dispersant 5, thickener 2, fungicide 23, defoamer
1st, pH adjusting agent 4,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 59, cyclohexyl acetate 16, distilled water 33.
Further, the fungicide is graphene oxide.
Further, the coalescents are dimethyl ether.
Further, the dispersant is guar gum, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 1
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 21, two anisidine diisocyanate 27, propionic acid poly- six is sub-
Methylguanidine 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, thickener 5, defoamer 2, pH are adjusted
Agent 8,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 67, cyclohexyl acetate 23, distilled water 42.
Further, the coalescents are diethylene glycol monoethyl ether.
Further, the dispersant is fatty acid polyethylene glycol ester, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 2
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 21, two anisidine diisocyanate 27, propionic acid poly- six is sub-
Methylguanidine 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, thickener 5, fungicide 39, defoaming
Agent 2, pH adjusting agent 8,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 67, distilled water 42.
Further, the fungicide is graphene oxide.
Further, the coalescents are tripropylene glycol butyl ether.
Further, the dispersant is two anisidine diisocyanate.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 3
The present embodiment provides a kind of women's shoes with high adhesion face coat consistent with embodiment 1, the difference is that described
Face coat includes the component of following parts by weight：Methyl acrylate 21, two anisidine diisocyanate 27, propionic acid poly- six is sub-
Methylguanidine 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, thickener 5, fungicide 39, defoaming
Agent 2, pH adjusting agent 8, cyclohexyl acetate 23, distilled water 42.
Further, the fungicide is graphene oxide.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Coating property is tested
Salt spray resistance
Face coat in embodiment and comparative example is coated on wooden test piece respectively and in aluminium alloy test piece, aluminium alloy test piece is selected
With 6063.After paint spraying, tested when standing 48 is small after film forming is fully cured in coating.Adhesive force is carried out to above-mentioned coating
Test, neutral salt spray test, test method according to《GB/T 1720-1979 paint film adhesion determination methods》、《GB/T 10125-
2012 artificial atmosphere corrosion test salt spray tests》Carry out；Anti-microbial property test, test are carried out according to GB/T 21866-2008
As a result such as following table.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can pass through this
Field any prior art is realized.
Claims (7)
1. a kind of women's shoes with high adhesion face coat, it is characterised in that including sole, the sole rear is equipped with heel
Portion, the top of the sole are equipped with first and fix band, second fix band, main supporting part, side supporting part, rear support band, and described the
One fixes the front end area that band is equipped with the sole, and the side supporting part is symmetrically set in the both sides at sole rear, the collateral support
Band top is connected with the second fixation band, and the main supporting part fixes band, the intermediate region of the second fixation band with described first respectively
Connection, the rear support band are arranged on the stub area of the sole, and the rear support band fixes band connection with described second；It is described
Sole is equipped with face coat, and the face coat includes the component of following parts by weight：Methyl acrylate 16-24, two anisidines
Diisocyanate 19-35, polyhexamethylene guanidine propionate 13-21, azodiisobutyronitrile 9-14, methyl methacrylate 8-
17th, dispersant 5-9, thickener 2-8, fungicide 23-57, defoamer 1-3, pH adjusting agent 4-11,3,3 '-dimethyl -4,
4 '-diamino-dicyclohexyl methane 59-73, cyclohexyl acetate 16-28, distilled water 33-56.
2. a kind of women's shoes with high adhesion face coat according to claim 1, it is characterised in that the surface applies
Layer includes the component of following parts by weight：Methyl acrylate 19-22, two anisidine diisocyanate 24-31, propionic acid poly- six is sub-
Methylguanidine 15-19, azodiisobutyronitrile 10-12, methyl methacrylate 11-15, dispersant 6-7, thickener 4-7, kill
Microbial inoculum 31-46, defoamer 2-3, pH adjusting agent 5-9,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 63-70,
Cyclohexyl acetate 21-25, distilled water 39-45.
3. a kind of women's shoes with high adhesion face coat according to claim 1, it is characterised in that the surface applies
Layer includes the component of following parts by weight：Methyl acrylate 21, two anisidine diisocyanate 27, polyhexamethylene guanidine propionate
17th, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH
Conditioning agent 8,3,3 '-dimethyl -4,4 '-diamino-dicyclohexyl methane 67, cyclohexyl acetate 23, distilled water 42.
A kind of 4. women's shoes with high adhesion face coat according to claim 1, it is characterised in that the fungicide
For graphene oxide.
5. a kind of women's shoes with high adhesion face coat according to claim 1, it is characterised in that the film forming helps
Agent for propane diols, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dimethyl ether, diethylene glycol monoethyl ether,
One kind in tripropylene glycol butyl ether.
A kind of 6. women's shoes with high adhesion face coat according to claim 1, it is characterised in that the dispersant
For one kind in lauryl sodium sulfate, methyl anyl alcohol, two anisidine diisocyanate, guar gum, fatty acid polyethylene glycol ester.
A kind of 7. women's shoes with high adhesion face coat according to claim 1, it is characterised in that the thickener
For hydroxyethyl ether cellulose, defoamer is tributyl phosphate, and pH adjusting agent is diethanol amine.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711369346.9A CN107997294A (en) | 2017-12-18 | 2017-12-18 | A kind of women's shoes with high adhesion face coat |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711369346.9A CN107997294A (en) | 2017-12-18 | 2017-12-18 | A kind of women's shoes with high adhesion face coat |
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| CN107997294A true CN107997294A (en) | 2018-05-08 |
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| CN201711369346.9A Pending CN107997294A (en) | 2017-12-18 | 2017-12-18 | A kind of women's shoes with high adhesion face coat |
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| CN205492741U (en) * | 2016-01-23 | 2016-08-24 | 浙江卓诗尼控股有限公司 | Sandal |
| CN205624709U (en) * | 2016-05-10 | 2016-10-12 | 吉林省温馨鸟集团有限公司 | Embellishment detachable sandals |
| CN206453335U (en) * | 2017-02-23 | 2017-09-01 | 广州优瑞塑料有限公司 | A kind of silver ion deodorizing antibacterial insoles |
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Application publication date: 20180508 |