CN109763345A - A kind of fabric free-floride spill resistant is spraying and preparation method thereof - Google Patents
A kind of fabric free-floride spill resistant is spraying and preparation method thereof Download PDFInfo
- Publication number
- CN109763345A CN109763345A CN201811560617.3A CN201811560617A CN109763345A CN 109763345 A CN109763345 A CN 109763345A CN 201811560617 A CN201811560617 A CN 201811560617A CN 109763345 A CN109763345 A CN 109763345A
- Authority
- CN
- China
- Prior art keywords
- solution
- spraying
- floride
- parts
- spill resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
It is spraying and preparation method thereof the present invention relates to a kind of fabric free-floride spill resistant, preparation method each component by weight: without 2~25 parts by weight of fluoro water proofing agent；0.5~15 parts by weight of crosslinking agent；1~25 parts by weight of synergist；0.05~1 parts by weight of conventional additives；Appropriate pH adjusting agent；Surplus is deionized water, amounts to 100 parts.Fabric free-floride spill resistant of the invention is a aqua type liquid spray product by spraying, is safely carried, and is easy to use, gently a spray, water proof anti-soil；Water-proof finish for household fabrics such as common synthetic fabrics, footwear and tablecloth chair covers；Nonflammable, without harmful volatile organic compounds (VOCs), fluorocarbon-containing compound, is not free of PFOA, PFOS and APEO, nonirritant unpleasant peculiar smell is no dangerous spraying, safety and environmental protection.
Description
Technical field
The present invention relates to the antifouling fields of fabric waterproof, and in particular to a kind of fabric free-floride spill resistant is spraying and its preparation side
Method.
Background technique
New charges clothing when being invaded by rainwater, and rainwater can be allowed to form droplet in clothing surface and tumbled naturally,
Moisture is not allowed to penetrate into fabric, here it is DWR (water-proofing treatments of water-proof jacket).The outer shell fabric of outdoor fabric all can be by DWR
Reason forms not hydrophilic protective coating, to prevent outer shell fabric from being soaked in water infiltration, guarantee aqueous vapor without being adhered on fabric,
It not will form moisture film, reach the effect of surface waterproofing.But DWR coating is worn in washing process in long-time, due to by outer
The influence of boundary's active force causes adhesive bond that slowly declining occurs until fracture, coating activating agent fall off, and the water repellent of textile surface is refused
The decrease of oily effect slowly even disappears, and here it is outdoor fabrics to use the original for meeting water surface no longer waterproof after a period of time
Cause.
The waterproof and oilproof processing of textile is exactly to use the finishing agent with special molecular structure to it on the surface of textile
Processing is sprayed or is padded, handling by external condition makes it be firmly attached to fiber surface or carry out chemical bonded refractory with fiber
Close, make the surface tension of fabric be reduced to than water or oil it is low, soak fabric no longer by water or oily substance, to reach
The purpose of waterproof and oilproof.
Spill resistant product on domestic market is substantially aerosol spray type, and using metal canned bottle, filling is easy
Explosive propellant is fired, containing fluorine carbon water repellent component, the product feature of environmental protection and safety be not high, be not suitable for high temperature long-distance transport,
Also it is unfavorable for storing.Perfluoro caprylic acid and its esters (PFOA) and perfluorooctane sulfonate (PFOS) are production fluorine carbon waterproof agents
By-product has potential carcinogenicity, harmful to human.It is using fluorine carbon waterproof agent, although mesh that disclosed patented technology is also mostly
Preceding classic water-refusing oil-refusing finishing agent is fluorine-containing organic polymer, but these auxiliary agents mostly contain PFOA or its derivative
Object, biological degradability is poor, to environment nocuousness.In addition, a large amount of volatile organic solvents are used in such product formula, taste thorn
Nose, when use, are harmful to people.
Summary of the invention
Safely carried in view of this, the present invention provides one kind, be easy to use, it is environmentally protective dedicated for restore fabric outside
A kind of fabric free-floride spill resistant of shell fabric spill resistant performance is spraying and preparation method thereof.It is formulated mildly, to fabric and skin
It is nonirritant；Without harmful volatile organic compounds (VOCs), propellant is free of, it is no dangerous spraying, it is nonirritant unpleasant different
Taste；Not fluorocarbon-containing compound is free of PFOA, PFOS and APEO, safety and environmental protection；After use, fabric surface can quickly form one layer
Uniform nano protecting layer, generates lotus leaf effect, water proof anti-soil, while not influencing original gas permeability, extends clothing and uses the longevity
Life.
In order to solve the problems existing in the prior art, the technical scheme is that a kind of fabric free-floride spill resistant is spraying,
It is characterized in that: including following raw material:
The parts by weight summation of each component is 100.
Described is modified acroleic acid esters polymer without fluoro water proofing agent, the mixed liquor of acrylate copolymer and paraffin, changes
Property urethane derivative, organic silicon emulsion, one or more of modified hydrocarbon resin aqueous solution mixture.
The crosslinking agent is the mixed of one or more of reactive organic silicon, water-based polyurethane, metallic salt
Close object.
The synergist is bio-ethanol, ethylene glycol, polyethylene glycol, propylene glycol, propandiol butyl ether, dipropylene
One or more of mixture.
The conventional additives are conventional preservative, essence, pigment.
The pH adjusting agent is one of malic acid, citric acid, glacial acetic acid.
A kind of preparation method that fabric free-floride spill resistant is spraying, which is characterized in that the preparation method is real according to the following steps
It applies:
Step 1: it stocks up by following raw material:
The parts by weight summation of each component is 100.
Step 2: under room temperature, pH adjusting agent being added in deionized water, after being uniformly mixed, tests its pH value and reaches
3.5-7.0 obtains solution A；
Step 3: solution A being divided into three parts A1, A2, A3, synergist is added in A1, stirring is obtained to being uniformly mixed
To clear solution B；
Step 4: floride-free water repellent component being added dropwise in A2, is slowly stirred to being uniformly dissolved, obtains solution C；
Step 5: in A3, crosslinking agent is added dropwise, continues to be slowly stirred to being uniformly mixed, obtains solution D；
Step 6: solution C being poured slowly into solution B, is slowly stirred to being uniformly mixed, obtains solution E；
Step 7: solution D being poured slowly into solution E, is slowly stirred to being uniformly mixed, obtains solution F；
Step 8: conventional additives are added in solution F, are stirred to being uniformly dissolved, are finally obtained milky liquid G,
I.e. fabric free-floride spill resistant is spraying.
Compared with prior art, advantages of the present invention is as follows:
1, the present invention has selected the mixed liquor of modified hydrocarbon resin aqueous solution, acrylate copolymer and paraffin, organosilicon cream
Liquid without fluoro water proofing agent, while providing waterproofing protection for fabric, do not influence the original feel of fabric, coloured light and gas permeability, nothing
Fluoro water proofing agent is free of freon, is free of PFOA, PFOS, APEO, compared to fluorine system waterproofing agent, no fluoro water proofing agent is not easy in organism
Interior deposition is easy degradation, is harmless, is the product of more safety and environmental protection；
2, present invention employs the solvents of safety and environmental protection does not add throwing without harmful volatile organic compounds (VOCs)
Agent is penetrated, is had no irritating odor, it is no dangerous spraying, it is nonflammable, it is non-explosive, transportation safety is stored, to user without potential hazard；
3, the present invention is a aqua type liquid spray product, and plastic bottle is safe to carry, easy to use, after use, meeting
Nano-lotus leaf effect is formed in fabric surface, realizes the purpose of water proof anti-soil；
4, the raw materials used in the present invention safety and environmental protection, harmless, production technology green is easy, safe operation.
Detailed description of the invention
The comparison diagram that the spill resistant produced of Fig. 1 embodiment of the present invention one is spraying and commercial products are in terms of water repellency.
The comparison diagram that the spill resistant produced of Fig. 2 embodiment of the present invention one is spraying and commercial products are in terms of oil preventing performance.
The spill resistant produced of Fig. 3 embodiment of the present invention two is spraying and commercial products are in the true anti-wine of cotton piece waterproof and oilproof
Performance comparison figure in terms of smart spot；
The spill resistant produced of Fig. 4 embodiment of the present invention two is spraying and commercial products are anti-in the waterproof and oilproof of mylar on piece
Performance comparison figure in terms of alcohol spot；
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment one:
A kind of fabric free-floride spill resistant is spraying, including following raw material: without 2 parts of fluoro water proofing agent, 0.5 part of crosslinking agent,
1 part of synergist, 0.05 part of conventional additives, pH adjusting agent dosage are to adjust amount, the deionized water surplus of pH value of solution to 4.5, respectively
The parts by weight summation of component is 100.
Described is the mixture of modified acroleic acid esters polymer and organic silicon emulsion without fluoro water proofing agent.
The crosslinking agent is reactive organic silicon.
The synergist is the mixture of bio-ethanol and propylene glycol.
The conventional additives are conventional preservative, essence, pigment.
The pH adjusting agent is citric acid.
A kind of preparation method that fabric free-floride spill resistant is spraying is implemented according to the following steps:
Step 1: stock up by following raw material: 2 parts of no fluoro water proofing agent, 0.5 part of crosslinking agent, 1 part of synergist, routine add
Adding 0.05 part of agent, pH adjusting agent dosage is to adjust amount, the deionized water surplus of pH value of solution to 4.5, and the parts by weight of each component are total
Be 100；
Step 2: under room temperature, pH adjusting agent being added in deionized water, after being uniformly mixed, tests its pH value and reaches
3.5-7.0 obtains solution A；
Step 3: solution A being divided into three parts A1, A2, A3, alcohols synergist is added in A1, stirring is equal to mixing
It is even, obtain clear solution B；
Step 4: floride-free water repellent component being added dropwise in A2, is slowly stirred to being uniformly dissolved, obtains solution C；
Step 5: in A3, crosslinking agent is added dropwise, continues to be slowly stirred to being uniformly mixed, obtains solution D；
Step 6: solution C being poured slowly into solution B, is slowly stirred to being uniformly mixed, obtains solution E；
Step 7: solution D being poured slowly into solution E, is slowly stirred to being uniformly mixed, obtains solution F；
Step 8: conventional additives are added in solution F, are stirred to being uniformly dissolved, are finally obtained milky liquid G,
I.e. fabric free-floride spill resistant is spraying.
Embodiment two:
A kind of fabric free-floride spill resistant is spraying, including following raw material: without 25 parts of fluoro water proofing agent, 15 parts of crosslinking agent,
25 parts of synergist, 1 part of conventional additives, pH adjusting agent dosage are to adjust amount, the deionized water surplus of pH value of solution to 5.5, each group
The parts by weight summation divided is 100.
The mixture without mixed liquor and organic silicon emulsion that fluoro water proofing agent is acrylate copolymer and paraffin.
The crosslinking agent is the mixture of reactive organic silicon and metallic salt.
The synergist is the mixture of bio-ethanol and ethylene glycol.
The conventional additives are conventional preservative, essence, pigment.
The pH adjusting agent is malic acid.
A kind of preparation method that fabric free-floride spill resistant is spraying is implemented according to the following steps:
Step 1: stocking up by following raw material: without 25 parts of fluoro water proofing agent, 15 parts of crosslinking agent, 25 parts of synergist, routine
1 part of additive, pH adjusting agent dosage are to adjust amount, the deionized water surplus of pH value of solution to 5.5, the parts by weight summation of each component
It is 100；
Step 2: under room temperature, pH adjusting agent being added in deionized water, after being uniformly mixed, tests its pH value and reaches
3.5-7.0 obtains solution A；
Step 3: solution A being divided into three parts A1, A2, A3, alcohols synergist is added in A1, stirring is equal to mixing
It is even, obtain clear solution B；
Step 4: floride-free water repellent component being added dropwise in A2, is slowly stirred to being uniformly dissolved, obtains solution C；
Step 5: in A3, crosslinking agent is added dropwise, continues to be slowly stirred to being uniformly mixed, obtains solution D；
Step 6: solution C being poured slowly into solution B, is slowly stirred to being uniformly mixed, obtains solution E；
Step 7: solution D being poured slowly into solution E, is slowly stirred to being uniformly mixed, obtains solution F；
Step 8: conventional additives are added in solution F, are stirred to being uniformly dissolved, are finally obtained milky liquid G,
I.e. fabric free-floride spill resistant is spraying.
Embodiment three:
A kind of fabric free-floride spill resistant is spraying, including following raw material: without 20 parts of fluoro water proofing agent, 10 parts of crosslinking agent,
23 parts of synergist, 0.08 part of conventional additives, pH adjusting agent dosage are to adjust amount, the deionized water surplus of pH value of solution to 6.0, respectively
The parts by weight summation of component is 100.
The mixture for being modified polyurethane derivative without fluoro water proofing agent and be modified in hydrocarbon resin aqueous solution.
The crosslinking agent is reactive water-based polyurethane.
The synergist is the mixture of polyethylene glycol and propylene glycol.
The conventional additives are conventional preservative, essence, pigment.
The pH adjusting agent is glacial acetic acid.
A kind of preparation method that fabric free-floride spill resistant is spraying is implemented according to the following steps:
Step 1: stocking up by following raw material: without 20 parts of fluoro water proofing agent, 10 parts of crosslinking agent, 23 parts of synergist, routine
0.08 part of additive, pH adjusting agent dosage are to adjust amount, the deionized water surplus of pH value of solution to 6.0, the parts by weight of each component
Summation is 100；
Step 2: under room temperature, pH adjusting agent being added in deionized water, after being uniformly mixed, tests its pH value and reaches
3.5-7.0 obtains solution A；
Step 3: solution A being divided into three parts A1, A2, A3, alcohols synergist is added in A1, stirring is equal to mixing
It is even, obtain clear solution B；
Step 4: floride-free water repellent component being added dropwise in A2, is slowly stirred to being uniformly dissolved, obtains solution C；
Step 5: in A3, crosslinking agent is added dropwise, continues to be slowly stirred to being uniformly mixed, obtains solution D；
Step 6: solution C being poured slowly into solution B, is slowly stirred to being uniformly mixed, obtains solution E；
Step 7: solution D being poured slowly into solution E, is slowly stirred to being uniformly mixed, obtains solution F；
Step 8: conventional additives are added in solution F, are stirred to being uniformly dissolved, are finally obtained milky liquid G,
I.e. fabric free-floride spill resistant is spraying.
The following are the spraying performance test explanations of fabric free-floride spill resistant according to the present invention:
Experiment 1:
The comparison that the spill resistant produced of testing example one is spraying and commercial products are in terms of water repellent oil preventing performance.
According to after water-proof finish in waterproof performance testing standard AATCC 22-2005, the GB/T4745-1997 of textile
Test method, devise simulated experiment, the method is as follows:
Specific step is as follows:
(1) the identical white meal cotton paper towel of size material is chosen, is divided into two, it is spare.Half is dripped, the other half drop
Oil needs blank control.
(2) water-soluble bright blue pigment is added in water, enhances observability；Using chilli oil, color clear is conducive to see
Examine comparison.
(3) sample to be tested is packed into 50mL plastic mist spray bottle, spare.
(4) white paper towels are laid on experimental bench, label.Even application is carried out apart from paper handkerchief 10-15cm with sample to be tested
(press spray head in the sink in advance, it is to be sprayed uniformly after reuse), soaked to paper handkerchief, stand about 10min.Afterwards with hair dryer heat
Wind file dries up paper handkerchief, hangs about 1h.
(5) it is dripped at paper handkerchief 10cm with dropper, oil dripping, observes and records water, oil respectively in the state on paper handkerchief surface, clap
According to.
Test result record as depicted in figs. 1 and 2, in Fig. 1 the spill resistant produced of embodiment one be sprayed a and city purchased items t,
Water droplet state on the cotton paper towel of q processing, o is blank；The spill resistant produced of embodiment one is sprayed a and city's purchased items t, q in Fig. 2
Oil droplet state on the cotton paper towel of processing, o are blank；
Experiment 2:
The spill resistant produced of testing example two is spraying and commercial products are in the anti-of true cotton piece and mylar on piece
Performance comparison in terms of the grease proofing anti-alcohol spot of water.
It is described in experimental method and the same experiment 1 of step.Pieces of cloth are having a size of 15cm*7cm, one dividing into three, each area size
For 5cm*7cm.
As shown in Figure 3 and Figure 4, the spill resistant produced of embodiment two is sprayed a, f and city's purchased items to test result record in Fig. 3
The state of water, oil, alcohol on the cotton of t processing, o is blank；In Fig. 4 the spill resistant produced of embodiment two be sprayed a f with
The state of water, oil, alcohol on the mylar of city purchased items t processing；
Experiment 3:
According to standard AATCC 22-2005, the spill resistant produced of AATCC118 testing example three is sprayed and city's purchased items
Water and oil-resistant.
Test result is as follows:
The waterproof and oilproof test result of 1 optimization formula of table and commercial products
Experiment 4:
The spill resistant produced of testing example two is compared with the pH value of commercial products by spraying.It 25 DEG C of test temperature, uses
The thunder magnetic PHS-3B pH meter of upper Nereid section is measured stoste.
Test result is as follows:
| Sample name | Embodiment two | Commercially available product is 1. | Commercially available product is 2. |
| PH value | 5.29 | 4.20 | 4.15 |
The contents of the present invention are not limited to cited by embodiment, and those of ordinary skill in the art are by reading description of the invention
And to any equivalent replacement that technical solution of the present invention is taken, all are covered by the claims of the invention.
Claims (7)
1. a kind of fabric free-floride spill resistant is spraying, it is characterised in that: including following raw material:
Without 2~25 parts of fluoro water proofing agent
0.5~15 part of crosslinking agent
1~25 part of synergist
0.05~1 part of conventional additives
It is 3.5-7.0 that pH adjusting agent, which adjusts pH value,
Deionized water surplus
The parts by weight summation of each component is 100.
2. a kind of fabric free-floride spill resistant according to claim 1 is spraying, which is characterized in that the no fluoro water proofing agent is
Modified acroleic acid esters polymer, the mixed liquor of acrylate copolymer and paraffin, modified polyurethane derivative, organic silicon emulsion,
The mixture of one or more of modified hydrocarbon resin aqueous solution.
3. a kind of fabric free-floride spill resistant according to claim 1 or 2 is spraying, which is characterized in that the crosslinking agent is
The mixture of one or more of reactive organic silicon, water-based polyurethane, metallic salt.
4. a kind of fabric free-floride spill resistant according to claim 3 is spraying, which is characterized in that the synergist is biology
The mixture of one or more of ethyl alcohol, ethylene glycol, polyethylene glycol, propylene glycol, propandiol butyl ether, dipropylene.
5. a kind of fabric free-floride spill resistant according to claim 1 is spraying, which is characterized in that the conventional additives are
Preservative, the essence, pigment of routine.
6. a kind of fabric free-floride spill resistant according to claim 1 is spraying, which is characterized in that the pH adjusting agent is apple
One of tartaric acid, citric acid, glacial acetic acid.
7. a kind of preparation method that fabric free-floride spill resistant is spraying as described in claim 1, which is characterized in that the preparation side
Method is implemented according to the following steps:
Step 1: it stocks up by following raw material:
Without 2~25 parts of fluoro water proofing agent
0.5~15 part of crosslinking agent
1~25 part of synergist
0.05~1 part of conventional additives
It is 3.5-7.0 that pH adjusting agent, which adjusts pH value,
Deionized water surplus
The parts by weight summation of each component is 100；
Step 2: under room temperature, pH adjusting agent being added in deionized water, after being uniformly mixed, tests its pH value and reaches 3.5-
7.0, obtain solution A；
Step 3: solution A being divided into three parts A1, A2, A3, synergist is added in A1, stirring is obtained to being uniformly mixed
Bright solution B；
Step 4: floride-free water repellent component being added dropwise in A2, is slowly stirred to being uniformly dissolved, obtains solution C；
Step 5: in A3, crosslinking agent is added dropwise, continues to be slowly stirred to being uniformly mixed, obtains solution D；
Step 6: solution C being poured slowly into solution B, is slowly stirred to being uniformly mixed, obtains solution E；
Step 7: solution D being poured slowly into solution E, is slowly stirred to being uniformly mixed, obtains solution F；
Step 8: adding conventional additives in solution F, stir to being uniformly dissolved, finally obtain milky liquid G, that is, knit
Object free-floride spill resistant is spraying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811560617.3A CN109763345B (en) | 2018-12-20 | 2018-12-20 | Fluorine-free anti-splashing fabric spray and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811560617.3A CN109763345B (en) | 2018-12-20 | 2018-12-20 | Fluorine-free anti-splashing fabric spray and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109763345A true CN109763345A (en) | 2019-05-17 |
| CN109763345B CN109763345B (en) | 2021-04-02 |
Family
ID=66451801
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811560617.3A Active CN109763345B (en) | 2018-12-20 | 2018-12-20 | Fluorine-free anti-splashing fabric spray and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109763345B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110670364A (en) * | 2019-11-13 | 2020-01-10 | 福建华峰新材料有限公司 | Organic silicon fluorine-free waterproof agent, preparation method thereof and waterproof fabric |
| CN111041830A (en) * | 2019-12-31 | 2020-04-21 | 江苏瑞洋安泰新材料科技有限公司 | Fluorine-free waterproof agent for cotton |
| CN111335041A (en) * | 2020-03-13 | 2020-06-26 | 东莞市百思兰鞋材科技有限公司 | Fluoride-free waterproof agent and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4555419A (en) * | 1983-09-13 | 1985-11-26 | Wacker-Chemie Gmbh | Method of impregnating textile materials made from organic fibers |
| CN103572603A (en) * | 2013-10-24 | 2014-02-12 | 广东德美精细化工股份有限公司 | Fluoride-free waterproof agent for textile, preparation method thereof and textile |
| CN103572602A (en) * | 2013-10-24 | 2014-02-12 | 广东德美精细化工股份有限公司 | Fluoride-free waterproof agent, preparation method and textile |
| CN103628324A (en) * | 2013-12-02 | 2014-03-12 | 广东德美精细化工股份有限公司 | Fluorine-free water-proofing agent and preparation method thereof as well as textile |
| CN105088796A (en) * | 2015-09-11 | 2015-11-25 | 无锡市长安曙光手套厂 | Textile fluoride-free water-proofing agent, preparation method and application thereof |
| CN105463857A (en) * | 2015-11-16 | 2016-04-06 | 上海华峰超纤材料股份有限公司 | Environmentally friendly anti-siphon afterfinishing method for suede microfiber synthetic leather |
| CN105899726A (en) * | 2013-11-12 | 2016-08-24 | 英威达技术有限公司 | Water repellent, soil resistant, fluorine-free compositions |
| CN106120349A (en) * | 2016-08-01 | 2016-11-16 | 太仓中化环保化工有限公司 | A kind of environment-friendly type abietyl is without fluoro water proofing agent and preparation method thereof |
| CN106637976A (en) * | 2016-11-29 | 2017-05-10 | 广东德美高新材料有限公司 | High-efficiency fluorine-free waterproof agent for cotton fabrics subjected to low-temperature dyeing and finishing processing |
| CN106676900A (en) * | 2016-12-31 | 2017-05-17 | 鲁丰织染有限公司 | Fluoride-free water-proof finishing method for pure cotton fabric |
| CN107700214A (en) * | 2017-10-24 | 2018-02-16 | 广东德美精细化工集团股份有限公司 | High-efficient, no-freon waterproofing agent and preparation method comprising telechelic polymer |
-
2018
- 2018-12-20 CN CN201811560617.3A patent/CN109763345B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4555419A (en) * | 1983-09-13 | 1985-11-26 | Wacker-Chemie Gmbh | Method of impregnating textile materials made from organic fibers |
| CN103572603A (en) * | 2013-10-24 | 2014-02-12 | 广东德美精细化工股份有限公司 | Fluoride-free waterproof agent for textile, preparation method thereof and textile |
| CN103572602A (en) * | 2013-10-24 | 2014-02-12 | 广东德美精细化工股份有限公司 | Fluoride-free waterproof agent, preparation method and textile |
| CN105899726A (en) * | 2013-11-12 | 2016-08-24 | 英威达技术有限公司 | Water repellent, soil resistant, fluorine-free compositions |
| CN103628324A (en) * | 2013-12-02 | 2014-03-12 | 广东德美精细化工股份有限公司 | Fluorine-free water-proofing agent and preparation method thereof as well as textile |
| CN105088796A (en) * | 2015-09-11 | 2015-11-25 | 无锡市长安曙光手套厂 | Textile fluoride-free water-proofing agent, preparation method and application thereof |
| CN105463857A (en) * | 2015-11-16 | 2016-04-06 | 上海华峰超纤材料股份有限公司 | Environmentally friendly anti-siphon afterfinishing method for suede microfiber synthetic leather |
| CN106120349A (en) * | 2016-08-01 | 2016-11-16 | 太仓中化环保化工有限公司 | A kind of environment-friendly type abietyl is without fluoro water proofing agent and preparation method thereof |
| CN106637976A (en) * | 2016-11-29 | 2017-05-10 | 广东德美高新材料有限公司 | High-efficiency fluorine-free waterproof agent for cotton fabrics subjected to low-temperature dyeing and finishing processing |
| CN106676900A (en) * | 2016-12-31 | 2017-05-17 | 鲁丰织染有限公司 | Fluoride-free water-proof finishing method for pure cotton fabric |
| CN107700214A (en) * | 2017-10-24 | 2018-02-16 | 广东德美精细化工集团股份有限公司 | High-efficient, no-freon waterproofing agent and preparation method comprising telechelic polymer |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110670364A (en) * | 2019-11-13 | 2020-01-10 | 福建华峰新材料有限公司 | Organic silicon fluorine-free waterproof agent, preparation method thereof and waterproof fabric |
| CN111041830A (en) * | 2019-12-31 | 2020-04-21 | 江苏瑞洋安泰新材料科技有限公司 | Fluorine-free waterproof agent for cotton |
| CN111335041A (en) * | 2020-03-13 | 2020-06-26 | 东莞市百思兰鞋材科技有限公司 | Fluoride-free waterproof agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109763345B (en) | 2021-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109763345A (en) | A kind of fabric free-floride spill resistant is spraying and preparation method thereof | |
| CN105088788B (en) | A kind of fluorine-containing textile finishing agent composition and preparation method thereof | |
| CN104928944B (en) | A kind of waterproof dehumidifying vapor-permeable type synthetic leather and clean preparation method thereof | |
| CN110527014A (en) | A kind of free-floride cationic polyacrylate waterproofing agent and preparation method thereof | |
| CN106884327A (en) | Fabric waterproof composition for treating dispersion liquid | |
| CN106758232A (en) | Bafta special-purpose water-proof oil-proofing agent, preparation method and its bafta processed through full low-temperature dyeing and finishing | |
| CN104894888A (en) | A dyeing and finishing process of a mosquito- and fly- repelling waterproof flame-retardant tent fabric | |
| CN104015459A (en) | Processing process for lining cloth | |
| CN107057577A (en) | It is a kind of for water colour paint of Wood-bar pencil and preparation method thereof | |
| CN111286982B (en) | Water-repellent and oil-repellent finishing agent, preparation method and application thereof, and water-repellent and oil-repellent treatment method | |
| CN110205818A (en) | A kind of fluorine-free ecological waterproofing agent and preparation method thereof of highly crosslinkable energy | |
| CN101798759B (en) | Finishing method of flocking fabric | |
| CN107325719A (en) | One kind is without fluoro water proofing agent | |
| CN108137988A (en) | Water proofing property plastic formulation | |
| JANKAUSKAITĖ et al. | Comparable evaluation of leather waterproofing behaviour upon hide quality. II. Influence of finishing on leather properties | |
| US3042642A (en) | Aqueous textile coating composition containing a perfluoroalkyl acrylate and a methyl pyridinium halide | |
| CN104328664A (en) | Compound function fabric and preparation method thereof | |
| CN101663434A (en) | Method for treating textiles | |
| CN105019240B (en) | Water and oil repellent agent | |
| CN104651078B (en) | A kind of shield suede liquid detergent that efficiently deoils of coating fabric or high-density fabric down products | |
| CN106637942A (en) | Environment-friendly waterproof swimming suit fabric and preparation process thereof | |
| CN109233477A (en) | A kind of self-cleaning spray of waterproof and oilproof and preparation method thereof | |
| US3476583A (en) | Method for rendering fibrous material oil and water repellent | |
| CN104018342A (en) | Aerosol can type water and oil repellent product and preparation method thereof | |
| JP2006200083A (en) | Water repellant composition for fiber, method for water repellence-treating fibrous product and silk fibrous product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210823 Address after: 710075 No. 15 Science and Technology Road, Xi'an City, Shaanxi Province Patentee after: XI'AN KAIMI Co.,Ltd. Address before: 201808 No. 2288 Xupan Road, Xuhang Industrial Park, Jiading District, Shanghai Patentee before: SHANGHAI KAIMI TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right |