CN105238252B - No-solvent type elastic polyurethane floor - Google Patents

No-solvent type elastic polyurethane floor Download PDF

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Publication number
CN105238252B
CN105238252B CN201510814221.7A CN201510814221A CN105238252B CN 105238252 B CN105238252 B CN 105238252B CN 201510814221 A CN201510814221 A CN 201510814221A CN 105238252 B CN105238252 B CN 105238252B
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component
coat
layer
solvent type
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CN105238252A (en
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陈遵厚
陈亮
谢桂秀
苗建程
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Fuzhou Royal Floor Co Ltd
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Fuzhou Royal Floor Co Ltd
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Abstract

The present invention relates to a kind of no-solvent type elastic polyurethane floor and its manufacture method, from bottom to top including priming coat, screed-coat, elastic layer, top coat layer;And carry out according to the following steps:(1) primary coat is scraped one time to form priming coat in uniform painting on surface of base;(2) with trowel by levelling coating point multiple tracks scratch on base coating surface to form screed-coat, with apply scrape rear surfacing untill;(3) elastomeric material is scratched in levelling layer surface to form elastic layer with trowel;(4)With roller by face apply point multiple tracks roller coating in elastic layer surface to form top coat layer.The no-solvent type elastic polyurethane floor of the present invention not only has damping, the effect of buffering, volatile organic solvent is not contained simultaneously, substantial amounts of VOC will not be distributed to air, health environment-friendly, is widely used in motion court, residential area, market, school, commune hospital, parking lot and some public places.

Description

No-solvent type elastic polyurethane floor
Technical field
The invention belongs to the preparation field of terrace, and in particular to a kind of no-solvent type elastic polyurethane floor.
Background technology
As the improvement of people's living standards, the requirement to terrace also becomes higher, except require with certain intensity, Outside the performance such as rigidity, waterproof, protection against the tide, warming, wear-resisting, corrosion-resistant, in some places(Such as stadium of track and field, motion court)Also Ask terrace have damping, buffering effect, can reduce because violent shock and caused by injury.Meanwhile, environmental protection is all the time All it is that all trades and professions are advocated, therefore, the demand of environmental protection floor also becomes increasingly vigorous.Traditional solvent-borne type floor material is about Containing 50% organic solvent, during the manufacture of coating, processing, dry and film-forming, given out into air a large amount of VOC(VOC), very big pollution and threat is caused to the ecological environment of the mankind.Therefore, a kind of tool is invented The no-solvent type elastic polyurethane floor for having damping, buffering effect environmental protection simultaneously is necessary.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of no-solvent type elastic polyurethane floor and its Manufacture method.There is anti-skidding, damping, the effect of buffering through no-solvent type elastic polyurethane floor produced by the present invention, be good for simultaneously Kang Huanbao, being particularly suitable for motion court, residential area, market, school, commune hospital, parking lot and some public places makes With.
To achieve the above object, the present invention is adopted the following technical scheme that:
No-solvent type elastic polyurethane floor, from bottom to top including priming coat, screed-coat, elastic layer and top coat layer;It is described Elastic layer be made up of A, B component, be calculated as by weight:Component A is:40-60 parts of 2,4 toluene diisocyanate, glycerine 20-30 parts, to 0-10 parts of tert-butyl-phenyl glycidol ether, 0.8-1.5 parts of tolysulfonyl isocyanates, organically-modified poly- silicon 0.1-0.15 parts of oxygen alkane, 10-15 parts of talcum powder, 5-10 parts of blanc fixe, 0.6-1.0 parts of modified polyurethane and BYK-370 2-3 Part;B component is:10-15 parts of fatty amine;Described A, the ratio of B component are 5:1.
The preparation method of described elastic layer is:Component A is heated to 80-100 DEG C, is cooled to after 20-40 DEG C, with 1000-1500 turn/min stir 20-40 minute, during construction B in A, B component ratio be 5:1 add, with 1500-2500 turn/ Min stirs.
Described priming coat is made up of following components by weight:30-35 parts of 2,4 toluene diisocyanate, 20-30 parts of butanediol, to 0-10 parts of tert-butyl-phenyl glycidol ether, 0.8-1.5 parts of tolysulfonyl isocyanates and organic 0.1-0.15 parts of modified polyorganosiloxane.
Described screed-coat is made up of following components by weight:30-35 parts of 2,4 toluene diisocyanate, 20-30 parts of butanediol, to 0-10 parts of tert-butyl-phenyl glycidol ether, 0.8-1.5 parts of tolysulfonyl isocyanates, organic 0.6-1.0 parts of 0.1-0.15 parts of modified polyorganosiloxane, 10-25 parts of talcum powder and modified polyurethane.
Described top coat layer is made up of A, B and component C, is calculated as by weight:Component A is:Dicyclohexyl methyl hydride two is different 20-30 parts of 40-60 parts of cyanate and glycerine;B component is:To 0-10 parts of tert-butyl-phenyl glycidol ether, tolysulfonyl 0.8-1.5 parts of isocyanates, 0.1-0.15 part of organic modified polyorganosiloxane, 10-15 parts of talcum powder, 5-10 parts of blanc fixe, change Property 1-10 parts of 0.6-1.0 parts of polyurethane, 2-3 parts of BYK-370 and mill base;Component C is:10-15 parts of fatty amine and stannous octoate 0.5-1.0 parts;Described A, B component sum and component C ratio are 5:1-1.5;Described A, the ratio of B component are 1:1.
The preparation method of described top coat layer is:Component A is heated to 80-100 DEG C, is cooled to after 20-40 DEG C, with 1000-1500 turns/min is stirred 20-40 minutes, then B component is added, and is stirred with 1500-2500 turns/min, handle during construction C is 5 in A, B component sum and component C ratio:1-1.5 ratios are added.
A kind of method for preparing the no-solvent type elastic polyurethane floor required as described above, including following steps:(1) Primary coat is scraped one time to form priming coat in uniform painting on surface of base;(2) with trowel by levelling coating point multiple tracks scratch in To form screed-coat on base coating surface, untill applying and scrape rear surfacing;(3) elastomeric material is scratched in screed-coat with trowel Surface is to form elastic layer;(4)With roller by face apply point multiple tracks roller coating in elastic layer surface to form top coat layer.
The beneficial effects of the present invention are:
(1)The no-solvent type elastic polyurethane floor of the present invention includes priming coat, screed-coat, elastic layer, top coat layer, has Anti-skidding, damping, buffering effect, can reduce because violent shock and caused by injury.
(2)The no-solvent type elastic polyurethane floor is free of volatile organic solvent, compared with traditional solvent-borne terrace, During manufacture, processing, drying and the film-forming of coating, substantial amounts of VOC, environmental protection, health will not be distributed to air Safety.
(3)The top coat layer of the present invention uses three components, enhances the performance of material, makes the validity period of terrace, shelf-life more It is long, do manual work and more optimize compared with traditional elastic polyurethane floor material.
(4)The no-solvent type elastic polyurethane floor has a wide range of application, it is adaptable to move court, residential area, market, School, commune hospital, parking lot and some public places are used.
Embodiment
The present invention further illustrates the present invention with the following example, but protection scope of the present invention is not limited to following reality Apply example.
Embodiment 1
No-solvent type elastic polyurethane floor, from bottom to top including priming coat, screed-coat, elastic layer and top coat layer;It is described Elastic layer be made up of A, B component, be calculated as by weight:Component A is:40 parts of 2,4 toluene diisocyanate, glycerine 20 Part, 0.8 part of tolysulfonyl isocyanates, 0.1 part of organic modified polyorganosiloxane, 10 parts of talcum powder, 5 parts of blanc fixe, modification 2 parts of 0.6 part of polyurethane and BYK-370;B component is:10 parts of fatty amine;Described A, the ratio of B component are 5:1.
The preparation method of described elastic layer is:Component A is heated to 100 DEG C, is cooled to after 30 DEG C, with 1400 turns/min Stirring 30 minutes, during construction B by A, B component ratio be 5:1 adds, and is stirred with 2000 turns/min.
Described priming coat is made up of following components by weight:30 parts of 2,4 toluene diisocyanate, fourth two 0.1 part of 20 parts of alcohol, 0.8 part of tolysulfonyl isocyanates and organic modified polyorganosiloxane.
Described screed-coat is made up of following components by weight:30 parts of 2,4 toluene diisocyanate, fourth two 20 parts of alcohol, 0.8 part of tolysulfonyl isocyanates, 0.1 part of organic modified polyorganosiloxane, 10 parts of talcum powder and modified polyurethane 0.6 part.
Described top coat layer is made up of A, B and component C, is calculated as by weight:Component A is:Dicyclohexyl methyl hydride two is different 20 parts of 40 parts of cyanate and glycerine;B component is:0.8 part of tolysulfonyl isocyanates, 0.1 part of organic modified polyorganosiloxane, 1 part of 10 parts of talcum powder, 5 parts of blanc fixe, 0.6 part of modified polyurethane, 2 parts of BYK-370 and mill base;Component C is:Fatty amine 10 0.5 part of part and stannous octoate;Described A, B component sum and component C ratio are 5:1;Described A, the ratio of B component are 1: 1。
The preparation method of described top coat layer is:Component A is heated to 100 DEG C, is cooled to after 30 DEG C, with 1400 turns/min Stirring 30 minutes, then B component is added, stirred with 2000 turns/min, C by A, B component sum and component C during construction Ratio is 5:1 ratio is added.
A kind of method for preparing the no-solvent type elastic polyurethane floor required as described above, including following steps:(1) Primary coat is scraped one time to form priming coat in uniform painting on surface of base;(2) with trowel by levelling coating point multiple tracks scratch in To form screed-coat on base coating surface, untill applying and scrape rear surfacing;(3) elastomeric material is scratched in screed-coat with trowel Surface is to form elastic layer;(4)With roller by face apply point multiple tracks roller coating in elastic layer surface to form top coat layer.
Embodiment 2
No-solvent type elastic polyurethane floor, from bottom to top including priming coat, screed-coat, elastic layer and top coat layer;It is described Elastic layer be made up of A, B component, be calculated as by weight:Component A is:60 parts of 2,4 toluene diisocyanate, glycerine 30 Part, to 10 parts of tert-butyl-phenyl glycidol ether, 1.5 parts of tolysulfonyl isocyanates, 0.15 part of organic modified polyorganosiloxane, 3 parts of 15 parts of talcum powder, 10 parts of blanc fixe, 1.0 parts of modified polyurethane and BYK-370;B component is:15 parts of fatty amine;It is described A, B component ratio be 5:1.
The preparation method of described elastic layer is:Component A is heated to 100 DEG C, is cooled to after 30 DEG C, with 1400 turns/min Stirring 30 minutes, during construction B by A, B component ratio be 5:1 adds, and is stirred with 2000 turns/min.
Described priming coat is made up of following components by weight:35 parts of 2,4 toluene diisocyanate, fourth two 30 parts of alcohol, to 10 parts of tert-butyl-phenyl glycidol ether, 1.5 parts of tolysulfonyl isocyanates and organic modified polyorganosiloxane 0.15 part.
Described screed-coat is made up of following components by weight:35 parts of 2,4 toluene diisocyanate, fourth two 30 parts of alcohol, to 10 parts of tert-butyl-phenyl glycidol ether, 1.5 parts of tolysulfonyl isocyanates, organic modified polyorganosiloxane 1.0 parts of 0.15 part, 25 parts of talcum powder and modified polyurethane.
Described top coat layer is made up of A, B and component C, is calculated as by weight:Component A is:Dicyclohexyl methyl hydride two is different 30 parts of 60 parts of cyanate and glycerine;B component is:To 10 parts of tert-butyl-phenyl glycidol ether, tolysulfonyl isocyanates 1.5 parts, 0.15 part of organic modified polyorganosiloxane, 15 parts of talcum powder, 10 parts of blanc fixe, 1.0 parts of modified polyurethane, BYK-370 3 parts and 10 parts of mill base;Component C is:1.0 parts of 15 parts of fatty amine and stannous octoate;Described A, B component sum and component C ratio Example is 5: 1.5;Described A, the ratio of B component are 1:1.
The preparation method of described top coat layer is:Component A is heated to 100 DEG C, is cooled to after 30 DEG C, with 1400 turns/min Stirring 30 minutes, then B component is added, stirred with 2000 turns/min, C by A, B component sum and component C during construction Ratio is 5:1.2 ratios are added.
A kind of method for preparing the no-solvent type elastic polyurethane floor required as described above, including following steps:(1) Primary coat is scraped one time to form priming coat in uniform painting on surface of base;(2) with trowel by levelling coating point multiple tracks scratch in To form screed-coat on base coating surface, untill applying and scrape rear surfacing;(3) elastomeric material is scratched in screed-coat with trowel Surface is to form elastic layer;(4)With roller by face apply point multiple tracks roller coating in elastic layer surface to form top coat layer.
Embodiment 3
No-solvent type elastic polyurethane floor, from bottom to top including priming coat, screed-coat, elastic layer and top coat layer;It is described Elastic layer be made up of A, B component, be calculated as by weight:Component A is:50 parts of 2,4 toluene diisocyanate, glycerine 25 Part, to 5 parts of tert-butyl-phenyl glycidol ether, 1.2 parts of tolysulfonyl isocyanates, 0.12 part of organic modified polyorganosiloxane, 2.5 parts of 12 parts of talcum powder, 8 parts of blanc fixe, 0.8 part of modified polyurethane and BYK-370;B component is:12 parts of fatty amine;It is described A, B component ratio be 5:1.
The preparation method of described elastic layer is:Component A is heated to 100 DEG C, is cooled to after 30 DEG C, with 1400 turns/min Stirring 30 minutes, during construction B by A, B component ratio be 5:1 adds, and is stirred with 2000 turns/min.
Described priming coat is made up of following components by weight:32 parts of 2,4 toluene diisocyanate, fourth two 25 parts of alcohol, to 5 parts of tert-butyl-phenyl glycidol ether, 1.2 parts of tolysulfonyl isocyanates and organic modified polyorganosiloxane 0.12 part.
Described screed-coat is made up of following components by weight:32 parts of 2,4 toluene diisocyanate, fourth two 25 parts of alcohol, to 5 parts of tert-butyl-phenyl glycidol ether, 1.2 parts of tolysulfonyl isocyanates, organic modified polyorganosiloxane 0.12 0.8 part of part, 18 parts of talcum powder and modified polyurethane.
Described top coat layer is made up of A, B and component C, is calculated as by weight:Component A is:Dicyclohexyl methyl hydride two is different 25 parts of 50 parts of cyanate and glycerine;B component is:To 5 parts of tert-butyl-phenyl glycidol ether, tolysulfonyl isocyanates 1.2 parts, 0.12 part of organic modified polyorganosiloxane, 12 parts of talcum powder, 8 parts of blanc fixe, 0.8 part of modified polyurethane, BYK-370 2.5 parts and 5 parts of mill base;Component C is:0.8 part of 12 parts of fatty amine and stannous octoate;Described A, B component sum and component C ratio Example is 5:1-1.2;Described A, the ratio of B component are 1:1.
The preparation method of described top coat layer is:Component A is heated to 100 DEG C, is cooled to after 30 DEG C, with 1400 turns/min Stirring 30 minutes, then B component is added, stirred with 2000 turns/min, C by A, B component sum and component C during construction Ratio is 5:1.5 ratios are added.
A kind of method for preparing the no-solvent type elastic polyurethane floor required as described above, including following steps:(1) Primary coat is scraped one time to form priming coat in uniform painting on surface of base;(2) with trowel by levelling coating point multiple tracks scratch in To form screed-coat on base coating surface, untill applying and scrape rear surfacing;(3) elastomeric material is scratched in levelling with trowel Layer surface is to form elastic layer;(4)With roller by face apply point multiple tracks roller coating in elastic layer surface to form top coat layer.
The foregoing is only presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, should all belong to the covering scope of the present invention.

Claims (4)

1. a kind of no-solvent type elastic polyurethane floor, it is characterised in that:Include priming coat, screed-coat, elastic layer from bottom to top And top coat layer;Described elastic layer is made up of A, B component, is calculated as by weight:Component A is:2,4 toluene diisocyanate 40-60 parts, 20-30 parts of glycerine, to 0-10 parts of tert-butyl-phenyl glycidol ether, tolysulfonyl isocyanates 0.8-1.5 Part, 0.1-0.15 parts of organic modified polyorganosiloxane, 10-15 parts of talcum powder, 5-10 parts of blanc fixe, modified polyurethane 0.6-1.0 2-3 parts of part and BYK-370;B component is:10-15 parts of fatty amine;Described A, the ratio of B component are 5:1;Described priming coat It is made up of following components by weight:30-35 parts of 2,4 toluene diisocyanate, 20-30 parts of butanediol, to tertiary fourth 0-10 parts of base phenyl glycidyl ether, 0.8-1.5 parts of tolysulfonyl isocyanates and organic modified polyorganosiloxane 0.1-0.15 Part;Described screed-coat is made up of following components by weight:30-35 parts of 2,4 toluene diisocyanate, butanediol 20-30 parts, to 0-10 parts of tert-butyl-phenyl glycidol ether, 0.8-1.5 parts of tolysulfonyl isocyanates, organically-modified poly- 0.6-1.0 parts of 0.1-0.15 parts of siloxanes, 10-25 parts of talcum powder and modified polyurethane;Described top coat layer is by A, B and C group It is grouped into, is calculated as by weight:Component A is:20-30 parts of 40-60 parts of dicyclohexyl methyl hydride diisocyanate and glycerine;B groups It is divided into:To 0-10 parts of tert-butyl-phenyl glycidol ether, 0.8-1.5 parts of tolysulfonyl isocyanates, organically-modified poly- silica 0.1-0.15 part of alkane, 10-15 parts of talcum powder, 5-10 parts of blanc fixe, 0.6-1.0 parts of modified polyurethane, 2-3 parts of BYK-370 With 1-10 parts of mill base;Component C is:0.5-1.0 parts of 10-15 parts of fatty amine and stannous octoate;Described A, B component sum and C groups The ratio divided is 5:1-1.5;Described A, the ratio of B component are 1:1.
2. no-solvent type elastic polyurethane floor according to claim 1, it is characterised in that:The preparation of described elastic layer Method is:Component A is heated to 80-100 DEG C, is cooled to after 20-40 DEG C, is stirred 20-40 minutes with 1000-1500 turns/min, During construction B in A, B component ratio be 5:1 adds, and is stirred with 1500-2500 turns/min.
3. no-solvent type elastic polyurethane floor according to claim 1, it is characterised in that:The preparation side of the top coat layer Method is:Component A is heated to 80-100 DEG C, is cooled to after 20-40 DEG C, is stirred 20-40 minutes with 1000-1500 turns/min, then B component is added, turned with 1500-2500/min stirs, C by A, B component sum and component C ratio is 5 during construction: 1-1.5 ratios are added.
4. a kind of method for preparing no-solvent type elastic polyurethane floor as claimed in claim 1, it is characterised in that:Including with Under several steps:(1) primary coat is scraped one time to form priming coat in uniform painting on surface of base;(2) screed-coat is applied with trowel Material a point multiple tracks scratch on base coating surface to form screed-coat, with painting scrape rear surfacing untill;(3) with trowel by elastic material Material scratches in levelling layer surface to form elastic layer;(4)With roller by face apply point multiple tracks roller coating in elastic layer surface to be formed Top coat layer.
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CN107474721B (en) * 2016-06-08 2020-05-12 济南汉斯曼时代技术有限公司 Double-component polyurethane environment-friendly flame-retardant floor coating and preparation method thereof
CN107417884A (en) * 2017-08-01 2017-12-01 福州皇家地坪有限公司 Crack resistence multifunction structure layer material
CN109575719B (en) * 2018-12-05 2020-12-25 福建乐动体育场材料有限公司 Wear-resisting anti-skidding silicon PU elasticity court
CN110094039A (en) * 2019-05-06 2019-08-06 山东扬名新材料技术有限公司 A kind of elastic grinding stone terrace
CN113549389B (en) * 2021-07-30 2022-06-24 上海岩皇环保科技有限公司 Renewable elastic polyurethane millstone material and application thereof

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