CN107988824A - A kind of printing method of the graphene oxide or derivatives thereof to fabric - Google Patents
A kind of printing method of the graphene oxide or derivatives thereof to fabric Download PDFInfo
- Publication number
- CN107988824A CN107988824A CN201711257929.2A CN201711257929A CN107988824A CN 107988824 A CN107988824 A CN 107988824A CN 201711257929 A CN201711257929 A CN 201711257929A CN 107988824 A CN107988824 A CN 107988824A
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- China
- Prior art keywords
- fabric
- graphene oxide
- derivatives
- graphene
- printing
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/70—Material containing nitrile groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
- D06P3/8228—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Printing method the invention discloses a kind of graphene oxide or derivatives thereof to fabric, belongs to technical field of textile chemistry.The present invention is by preparing pure zirconia graphene mill base, fabric is printed using graphene oxide mill base, it will be reduced again after fabric infrared baking, fabric face is set to cover one layer of redox graphene or derivatives thereof, clear, fine redox graphene floral designs are formed in fabric, obtain conductive excellent Flexible graphene conductive fabric.This method can obtain the graphene compliant conductive fabric of distribution according to need by the printing method of pure zirconia graphene mill base, which can be applied to the fields such as health care, intelligence sensor, dislocation generation, military affairs, intelligent monitoring.
Description
Technical field
The invention belongs to technical field of textile chemistry, is related to one kind using graphene oxide or derivatives thereof mill base to fabric
Carry out the method that printing prepares compliant conductive circuit fabric.
Background technology
Flexible conducting material refers to there is certain pliability and flexible as its name suggests, while keeps good conductive again
Property material, conventional conducting materials are more based on metallic conductor or metal oxide, and material pliability itself is poor, thus use
Scope is very restricted, and does not meet conductive material in following development, for meet current electronic equipment it is flexible, can
Wearing and implantable development trend, the research of flexible conducting material will receive significant attention.
Graphene flexible conducting material is being the hot spot of Recent study, common at present to prepare graphene fiber and function painting
Layer method obtains graphene flexible conducting material, and the method for printing distributed according to need is saving graphene raw material, obtaining decorative pattern figure
Case, control graphene conductive etc. have unique advantage, increasingly attract attention.Prepare the method for graphene fiber only
Limitation is in preparing synthetic fibers, and what functional coating method obtained is the graphene conductive fabric of large area, and method for printing generally requires
The viscosity of other non-conductive material increase mill bases or ink is added in mill base or ink, but graphene conductive can be caused
Very big influence.Such as 106085275 A of CN disclose it is a kind of by graphene, nonionic EDTA, solvent and UV glue prepare
Conductive glue,.The glue has good electric conductivity and thermal diffusivity, can quickly, be firmly adhered in a variety of materials, thus
It can be used for graphene conductive glue as the basic material of printing circuit board in the production of existing wiring board, easy to wiring board
The design and production of miniaturization.105513676 B of CN disclose it is a kind of by graphene oxide 100-110, viscosity modifier 2-4,
FC-4430 fluorosurfactants 1-1.2, dimethyl carbonate 40-50, silane coupling agent kh560 0.7-1,2- mercaptos benzene a pair of horses going side by side
Imidazoles 2-3, lauryl mercaptan 3-4, fluoboric acid 4-5, polyoxyethylene sorbitan monoleate 0.1-0.2, calcium stearate 2-4, alum 0.8-
1st, the inkjet printing graphene ink of ammonium molybdate 0.7-2, N hydroxymethyl acrylamide 0.5-1 composition.
The present invention is by preparing pure zirconia graphene or derivatives thereof mill base, using graphene oxide or derivatives thereof mill base
Fabric is printed, then will be reduced after fabric drying, fabric face is covered one layer of redox graphene, in fabric
Clear, fine redox graphene floral designs are formed, obtain conductive excellent Flexible graphene conductive fabric.This method
Fabric is printed using pure zirconia graphene mill base, avoids the shadow to graphene conductive such as former paste of adhesive, stamp
Ring, obtained graphene conductive circuit fabric profile is clear, soft, excellent conductivity.
The content of the invention
It is an object of the invention to which graphene oxide or derivatives thereof mill base is applied on fabric using method for printing, make to knit
Thing obtains electric conductivity, and decalcomania is clear.
The present invention adopts the following technical scheme that：
1. a kind of graphene oxide or derivatives thereof is to the printing method of fabric, it is characterized in that using following processing step：
(1) graphene oxide or derivatives thereof mill base is prepared：By the graphene oxide of 1-5 mass parts, amination oxidation stone
Black alkene, carboxylated graphene oxide or sulfonic group graphene oxide are mixed with 95-99 mass parts distilled water, adjust pH value 4-8,
The ultrasonic reaction 1-5h under the power of 0-20 DEG C of temperature 300-1000W, obtain concentration for 10-50g/L graphene oxides or its
Derivative mill base；
(2) fabric printing graphene oxide or derivatives thereof mill base：Using method for printing by graphene oxide or derivatives thereof
Mill base is printed on fabric, infrared preliminary drying 2-10min, obtains the fabric of graphene oxide or derivatives thereof printing；
(3) fabric for printing graphene oxide or derivatives thereof is reduced：Will printing graphene oxide or its derivative
The dry fabric of thing is impregnated into the reducing agent compound solution of 0.2-0.5% and is reduced, 70-120 DEG C of reduction temperature, reduction
Time 2-180min, finally washes, dries, obtain the conductive fabric of printing redox graphene.
Graphene oxide or derivatives thereof, water and pH adjusting agent have been contained only in the printing mill base.The graphite oxide
Alkene mill base is to the printing method of fabric using silk screen printing, ink-jet printed, roller printing method one kind.
The method that the preliminary drying of fabric uses infrared preliminary drying is printed, infrared preliminary drying power is 600-2000W.The preliminary drying side
The situation of method existing serious migration before efficiently solving graphene oxide solution on the fabric, and contactless preliminary drying is prevented
The only appearance of contamination issues of the fabric in Continuous maching.During infrared preliminary drying, the graphene oxide of part also can be red
Reduced at a temperature of outer preliminary drying, improve the reduction degree of graphene oxide.
The reducing agent compound is glucose, is a kind of and sodium dithionite, sulfurous acid in chitosan, vitamin C
A kind of compound in hydrogen sodium, hydrazine hydrate, sodium borohydride, compounding mass value are 2:3.The reducing agent compound reduction effect is dashed forward
Go out, dosage is few.
The fabric is cotton, fiber crops, silk, wool, terylene, polyamide fibre, acrylic fibers or its blended fabric, the fabric scope of application
Extensively.
The beneficial effects of the invention are as follows：It can be obtained without adhesive or thickener using graphene oxide or derivatives thereof
Pure zirconia graphene or derivatives thereof mill base, graphene oxide or derivatives thereof dividing on demand on the fabric is realized using method for printing
Match somebody with somebody, technical scheme is simple, easy to operation, to equipment without particular/special requirement, can be carried out greatly using conventional printing equipment
Large-scale production, has broad application prospects.
Embodiment
With reference to specific implementation case, the invention will be further described.
Embodiment 1：
A kind of graphene oxide or derivatives thereof is as follows to the printing method of fabric, its process：
By 50g graphene oxides and 945ml water mixing wiring solution-formings, it is 4 to adjust solution ph with acetum, 10
DEG C, ultrasonic reaction 4h under 800W power, graphene oxide mill base is made, above-mentioned mill base is printed on by the way of PLATE SCREAM PRINTING
On fabric, then by fabric in preliminary drying drying 10min 80 DEG C infrared, dry fabric is impregnated into 0.2% chitosan and 0.3%
Hydrazine hydrate mixed solution in reduced, 70 DEG C, recovery time 180min of reduction temperature, finally wash, dry, obtain stone
Black alkene compliant conductive fabric.
Embodiment 2：
A kind of graphene oxide or derivatives thereof is as follows to the printing method of fabric, its process：
By 40g carboxylated graphene oxides and 975ml water mixing wiring solution-formings, solution is adjusted with acetic acid and sodium acetate solution
PH value is 6, the ultrasonic reaction 5h under 5 DEG C, 300W power, and carboxylated graphene oxide mill base is made, by above-mentioned mill base using spray
Ink-printed mode is printed on fabric, and then dry fabric is impregnated into fabric in preliminary drying drying 6min 90 DEG C infrared
Reduced in the mixed solution of 0.2% vitamin C and 0.3% sodium borohydride, 95 DEG C of reduction temperature, the recovery time
20min, finally washes, dries, obtain graphene compliant conductive fabric.
Embodiment 3：
A kind of graphene oxide or derivatives thereof is as follows to the printing method of fabric, its process：
By 30g aminations graphene oxide and 965ml water mixing wiring solution-formings, with sodium acetate and manganese hydrogen sodium regulating solution
PH is 8, the ultrasonic reaction 2h under 15 DEG C, 600W power, and amination graphene oxide mill base is made, above-mentioned mill base is used roller
The mode of stamp is printed on fabric, and then dry fabric is impregnated into fabric in preliminary drying drying 10min 60 DEG C infrared
Reduced in the mixed solution of 0.2% glucose and 0.3% sodium borohydride, 100 DEG C of reduction temperature, the recovery time
10min, finally washes, dries, obtain graphene compliant conductive fabric.
Embodiment 4：
A kind of graphene oxide or derivatives thereof is as follows to the printing method of fabric, its process：
By 10g hydroxylatings graphene oxide and 945ml water mixing wiring solution-formings, adjusting pH value of solution with acetic acid and sodium acetate is
5, the ultrasonic reaction 1h under 20 DEG C, 1000W power, are made hydroxylating graphene oxide mill base, and above-mentioned mill base is printed using cylinder
Colored mode is printed on fabric, and fabric then is impregnated into 0.2% by dry fabric in preliminary drying drying 5min 120 DEG C infrared
Glucose and 0.3% sodium borohydride mixed solution in reduced, 120 DEG C, recovery time 2min of reduction temperature, finally
Washing, drying, obtain graphene compliant conductive fabric.
The implementation result of the present invention
Fabric after embodiment 1-4 processing, is tested it, test result is shown in Table 1 as follows respectively.
The test of fabric face resistance：Surveyed on SZT-2A four-point probes in (Suzhou Electronics Co., Ltd. of Tontru)
It is fixed.
As shown in Table 1, the resistance value for printing fabric is decreased obviously, it can be seen that, technical solution energy provided by the present invention
Enough assign fabric excellent electric conductivity.
Table 1 implements the test result of fabric
Claims (6)
1. a kind of graphene oxide or derivatives thereof is to the printing method of fabric, it is characterized in that using following processing step：
(1) graphene oxide or derivatives thereof mill base is prepared：By the graphene oxide of 1-5 mass parts, amination graphene oxide,
Carboxylated graphene oxide or sulfonic group graphene oxide are mixed with 95-99 mass parts distilled water, pH value 4-8 are adjusted, in 0-
Ultrasonic reaction 1-5h under the power of 20 DEG C of temperature 300-1000W, obtains concentration as 10-50g/L graphene oxides or its derivative
Look for slurry；
(2) fabric printing graphene oxide or derivatives thereof mill base：Using method for printing by graphene oxide or derivatives thereof mill base
It is printed on fabric, infrared preliminary drying 2-10min, obtains the fabric of graphene oxide or derivatives thereof printing；
(3) fabric for printing graphene oxide or derivatives thereof is reduced：Graphene oxide or derivatives thereof will be printed
Dry fabric is impregnated into the reducing agent compound solution of 0.2-0.5% and is reduced, 70-120 DEG C of reduction temperature, the recovery time
2-180min, finally washes, dries, obtain the conductive fabric of printing redox graphene.
2. a kind of graphene oxide according to claim 1 or derivatives thereof is to the printing method of fabric, it is characterised in that
Graphene oxide or derivatives thereof, water and pH adjusting agent have been contained only in the printing mill base.
3. a kind of graphene oxide according to claim 1 or derivatives thereof is to the printing method of fabric, it is characterised in that
The graphene oxide mill base is to the printing method of fabric using silk screen printing, ink-jet printed, roller printing method one kind.
4. a kind of graphene oxide according to claim 1 or derivatives thereof is to the printing method of fabric, it is characterised in that
The infrared preliminary drying power is 600-2000W.
5. a kind of graphene oxide according to claim 1 or derivatives thereof is to the printing method of fabric, it is characterised in that
The reducing agent compound is glucose, is a kind of and sodium dithionite, sodium hydrogensulfite, hydration in chitosan, vitamin C
A kind of compound in hydrazine, sodium borohydride, compounding mass value are 2:1.
6. a kind of graphene oxide according to claim 1 or derivatives thereof is to the printing method of fabric, it is characterised in that
The fabric is cotton, fiber crops, silk, wool, terylene, polyamide fibre, acrylic fibers or its blended fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711257929.2A CN107988824A (en) | 2017-12-04 | 2017-12-04 | A kind of printing method of the graphene oxide or derivatives thereof to fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711257929.2A CN107988824A (en) | 2017-12-04 | 2017-12-04 | A kind of printing method of the graphene oxide or derivatives thereof to fabric |
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| Publication Number | Publication Date |
|---|---|
| CN107988824A true CN107988824A (en) | 2018-05-04 |
Family
ID=62035330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711257929.2A Pending CN107988824A (en) | 2017-12-04 | 2017-12-04 | A kind of printing method of the graphene oxide or derivatives thereof to fabric |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108797098A (en) * | 2018-07-03 | 2018-11-13 | 嘉兴学院 | A method of based on cellulosic fabric surface printing conducting wire |
| CN110042681A (en) * | 2019-04-29 | 2019-07-23 | 新昌县高纤纺织有限公司 | Environment-friendly digital printing inks and preparation method thereof |
| CN110093776A (en) * | 2018-08-30 | 2019-08-06 | 东华大学 | A kind of preparation method of photothermal conversion heat-accumulation temperature-adjustment cotton fabric |
| CN110453494A (en) * | 2019-08-29 | 2019-11-15 | 南通强生石墨烯科技有限公司 | A kind of Graphene antibiosis fabric and preparation method thereof |
| CN110924194A (en) * | 2019-11-14 | 2020-03-27 | 南通大学 | Preparation method of efficient photo-thermal steam conversion material |
| CN111778715A (en) * | 2019-04-03 | 2020-10-16 | 上海水星家用纺织品股份有限公司 | Preparation method of graphene fabric |
| CN114920235A (en) * | 2022-04-02 | 2022-08-19 | 浙江理工大学 | Preparation method of reduced graphene oxide conductive silk fabric with screen-printed complex texture structure |
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| CN104294584A (en) * | 2014-09-29 | 2015-01-21 | 黄勇 | Fabric with doped-type graphene coating and preparation process of fabric |
| CN104328653A (en) * | 2014-10-11 | 2015-02-04 | 江南大学 | Method for multifunctional sorting of textile by using graphene oxide derivative |
| CN105064000A (en) * | 2015-09-16 | 2015-11-18 | 天津工业大学 | Graphene finish fabric wave-absorbing material and preparation method thereof |
| CN105088749A (en) * | 2015-08-28 | 2015-11-25 | 东华大学 | Graphene/cotton cloth flexible conducting fabric and preparing method of graphene/cotton cloth flexible conducting fabric |
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| CN106835672A (en) * | 2017-01-11 | 2017-06-13 | 郑宋滨 | Graphene printed textile and preparation method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108797098A (en) * | 2018-07-03 | 2018-11-13 | 嘉兴学院 | A method of based on cellulosic fabric surface printing conducting wire |
| CN110093776A (en) * | 2018-08-30 | 2019-08-06 | 东华大学 | A kind of preparation method of photothermal conversion heat-accumulation temperature-adjustment cotton fabric |
| CN110093776B (en) * | 2018-08-30 | 2021-04-02 | 东华大学 | Preparation method of photothermal conversion heat storage and temperature regulation cotton fabric |
| CN111778715A (en) * | 2019-04-03 | 2020-10-16 | 上海水星家用纺织品股份有限公司 | Preparation method of graphene fabric |
| CN110042681A (en) * | 2019-04-29 | 2019-07-23 | 新昌县高纤纺织有限公司 | Environment-friendly digital printing inks and preparation method thereof |
| CN110453494A (en) * | 2019-08-29 | 2019-11-15 | 南通强生石墨烯科技有限公司 | A kind of Graphene antibiosis fabric and preparation method thereof |
| CN110924194A (en) * | 2019-11-14 | 2020-03-27 | 南通大学 | Preparation method of efficient photo-thermal steam conversion material |
| CN114920235A (en) * | 2022-04-02 | 2022-08-19 | 浙江理工大学 | Preparation method of reduced graphene oxide conductive silk fabric with screen-printed complex texture structure |
| CN114920235B (en) * | 2022-04-02 | 2023-12-12 | 浙江理工大学 | Preparation method of reduced graphene oxide conductive silk fabric with screen printing complex tissue structure |
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Application publication date: 20180504 |