CN104328653A - Method for multifunctional sorting of textile by using graphene oxide derivative - Google Patents
Method for multifunctional sorting of textile by using graphene oxide derivative Download PDFInfo
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Abstract
The invention discloses a method for multifunctional sorting of a textile by using a graphene oxide derivative, belonging to the technical field of textile chemistry. The method comprises the following steps: immersing the textile with a graphene oxide derivative water solution; drying the textile and carrying out reduction so that the surface of the textile is covered with one layer of a reduced graphene oxide derivative; and repeating the steps to obtain the multifunctional textile with good conductive, anti-ultraviolet and water-repelling functions. By virtue of the method, the textile can obtain a lot of functions by one type of sorting and the multifunctional sorting of common textiles including cotton, wool, silk, dacron, chinlon and the like, and blended textiles or intertextures thereof can be realized; and the textile can be used for the fields including medical treatment, intelligent sensors, mobile power generation, military affairs and the like.
Description
Technical field
The invention belongs to technical field of textile chemistry, relate to a kind of ultraviolet light that adopts and the method that N doping prepares compliant conductive, uvioresistant, water repellent fabric is carried out to Graphene or derivatives thereof.
Background technology
Along with the raising of people's level of consumption, the product of single arrangement has been difficult to the demand meeting high-end market, and complex function arranges the new highlight becoming product development, and development functionality textiles is the important channel promoting China's textiles competitiveness simultaneously.But the functional finishing method of fabric arranges mainly with simple function is at present main, because may interaction be there is between each functional finishing agent, cause finishing agent poor with compatibility during bath, and the process conditions of various finishing functions are also not quite similar, therefore the Multifunctional finishing of fabric generally adopts the method repeatedly arranged at present, this not only causes complex procedures, and cost increases, and is also difficult to obtain good Multifunctional effect.Therefore, the more simple Multifunctional finishing method of Development and Production technique becomes the focus of research.
Graphene is made up of the flat film of hexagonal honeycomb lattice with sp2 hybridized orbit carbon atom, and only have the accurate two-dimensional material of a carbon atom thickness, is considered to the basic structural unit of fullerene, CNT (CNT) and graphite three.It has special electrology characteristic, and as quantum hall effect, under high electric field induce, Graphene still can keep the high mobility of carrier, makes this new material have very large potentiality in development of new electronic device.Graphene being applied to textile fabric field, to prepare flexible conducting material be development in recent years direction, usual way is functional fibre Graphene being added to obtained graphene-containing in spinning solution, or adopts the method for Final finishing to make Graphene and yarn or fabric that crosslinked obtained function fabric occur.Only limitation is in preparing synthetic fiber for front kind of method, and rear kind of method need add crosslinking agent or adhesive, affects the wearability of fabric.The mixed liquor that such as patent CN201310434293.X discloses a kind of Graphene and aqueous polyurethane pads baking finish fabric, makes fabric obtain the method for anti-ultraviolet anti-static Graphene coating weaving face fabric.
The first step of the present invention first adopts ultraviolet light to prepare N doping graphene oxide or derivatives thereof, again by textile impregnation N doping graphene oxide or derivatives thereof, then on fabric, N doping graphene oxide or derivatives thereof is reduced, fabric face is made to form nitrogen-doped graphene film, obtain the nitrogen-doped graphene conductive fabric with certain electric conductivity, because N doping graphene oxide or derivatives thereof mainly reduces on fabric, in reduction process, Graphene is combined with fabric tightness, avoid crosslinking agent, the use of adhesive, and the washability of finish fabric is excellent.
Summary of the invention
The object of the invention is to the method adopting self assembly, nitrogen-doped graphene and derivative thereof are applied on fabric, make fabric obtain conduction, uvioresistant and waterproofing function.
The present invention adopts following technical scheme:
1 adopts the mode of ultraviolet irradiation to prepare N doping graphene oxide or derivatives thereof mixed liquor, then carries out self assembly absorption and reduction treatment to fabric.
N doping graphene oxide or derivatives thereof mixed liquor preparation technology described in 2 is:
(1) graphene oxide or derivatives thereof mixed liquor is prepared: by the graphene oxide or derivatives thereof of 0.5 ~ 1 parts by mass, the anion surfactant of 0.01 ~ 0.5 parts by mass, join in the aqueous solution with 5 ~ 20 parts by mass nitrogen-containing compounds, at 20 ~ 60 DEG C, ultrasonic reaction 0.5 ~ 2h under 300-1000W power, obtain the homogeneous mixture solotion of graphene oxide or derivatives thereof, anion surfactant and nitrogen-containing compound;
(2) N doping graphene oxide or derivatives thereof mixed liquor is prepared: described to (1) mixed solution is placed in luminous intensity is 80-120W/cm, wavelength is irradiate 5-20min under the ultraviolet light of 365nm, make graphene oxide or derivatives thereof carry out N doping reaction, improve the electric conductivity of Graphene.
Described graphene oxide or derivatives thereof is at least one in graphene oxide, carboxylated graphene oxide, sulfonic group graphene oxide;
Described nitrogen-containing compound is at least one in urea, ammoniacal liquor;
Described anion surfactant is at least one in alkylsulfonate, alkylbenzenesulfonate, alkyl carboxylate, alkylbenzene carboxylates, alkylnaphthalene sulfonate, Fluhyzon carboxylate, alkyl-anthraquinone sulfonate, alkyl-anthraquinone carboxylate.
The technique of N doping graphene oxide or derivatives thereof mixed liquor to fabric self assembly absorption and reduction treatment described in 3 is:
(1) fabric self assembly adsorption of nitrogen doped with oxygen functionalized graphene or derivatives thereof solution: be in the aqueous solution of 2 ~ 6 to the pH of N doping graphene oxide or derivatives thereof by textile impregnation, dipping temperature 10 ~ 50 DEG C, dip time 0.2 ~ 2h, then by fabric in 40 ~ 100 DEG C of drying 0.5 ~ 4h, obtain the fabric of capping oxidation Graphene derivative;
(2) fabric covering N doping graphene oxide derivative is reduced: the dry fabric of capping oxidation Graphene derivative is impregnated in the reductant solution of 0.1 ~ 1% and reduces, reduction temperature 50 ~ 100 DEG C, recovery time 0.5 ~ 6h, finally wash, dry, obtain the conduction, uvioresistant, the water repellent fabric that cover redox graphene derivative;
Described reductant is at least one in sodium dithionite, sodium hydrogensulfite, glucose, shitosan, vitamin C, hydrazine hydrate, sodium borohydride.
Fabric after process described in 4 can repeat step 2 and 3, to strengthen textiles multifunctionality.
The invention has the beneficial effects as follows: adopt ultraviolet light to prepare N doping graphene oxide or derivatives thereof, adopt self-assembling method that nitrogen-doped graphene or derivatives thereof is applied to fabric face, technical scheme of the present invention is simple, convenient operation, to equipment without particular/special requirement, utilize conventional equipment for dyeing and finishing just can carry out large-scale production, have broad application prospects.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1
Graphene oxide derivative is used for a method for multifunctional finish of textiles, and its process is as follows:
By the graphene oxide or derivatives thereof of 0.5 parts by mass, the neopelex of 0.2 parts by mass, join in the aqueous solution with 10 parts by mass urea, at 20 DEG C, ultrasonic reaction 1h under 600W power, above-mentioned solution being placed in luminous intensity is 100W/cm, wavelength is irradiate 10min under the ultraviolet light of 365nm, be in the solution of 4 to above-mentioned pH by textile impregnation, dip time 1h, then by fabric in 80 DEG C of drying 1h, dry fabric is impregnated in the safety powder solution of 0.5% and reduces, reduction temperature 90 DEG C, recovery time 1h, finally wash, dry, obtain Graphene self assembly compliant conductive fabric, and there is good conduction, uvioresistant and waterproofing function.
Embodiment 2
Graphene conductive, uvioresistant, refuse the preparation method of water multifunctional fabric, its process is as follows:
By the graphene oxide or derivatives thereof of 0.8 parts by mass, the dodecyl sodium sulfate of 0.4 parts by mass, join in the aqueous solution with 20 parts by mass ammoniacal liquor, at 30 DEG C, ultrasonic reaction 0.6h under 800W power, above-mentioned solution being placed in luminous intensity is 80W/cm, wavelength is irradiate 20min under the ultraviolet light of 365nm, be in the solution of 6 to above-mentioned pH by textile impregnation, dip time 2h, then by fabric in 60 DEG C of drying 2h, dry fabric is impregnated in the safety powder solution of 0.4% and reduces, reduction temperature 95 DEG C, recovery time 0.5h, finally wash, dry, repeat above-mentioned steps 5 times, obtain Graphene self assembly compliant conductive fabric, and there is good conduction, uvioresistant and waterproofing function.
Embodiment 3
Graphene conductive, uvioresistant, refuse the preparation method of water multifunctional fabric, its process is as follows:
By the graphene oxide or derivatives thereof of 0.9 parts by mass, the neopelex of 0.1 parts by mass, join in the aqueous solution with 15 parts by mass ammoniacal liquor, at 40 DEG C, ultrasonic reaction 2h under 600W power, above-mentioned solution being placed in luminous intensity is 90W/cm, wavelength is irradiate 15min under the ultraviolet light of 365nm, be in the solution of 5 to above-mentioned pH by textile impregnation, dip time 0.6h, then by fabric in 70 DEG C of drying 1h, dry fabric is impregnated in the hydrazine hydrate solution of 0.4% and reduces, reduction temperature 85 DEG C, recovery time 2h, finally wash, dry, repeat above-mentioned steps 3 times, obtain Graphene self assembly compliant conductive fabric, and there is good conduction, uvioresistant and waterproofing function.
Embodiment 4
Graphene conductive, uvioresistant, refuse the preparation method of water multifunctional fabric, its process is as follows:
By the graphene oxide or derivatives thereof of 0.7 parts by mass, the dodecyl sodium sulfate of 0.6 parts by mass, join in the aqueous solution with 20 parts by mass urea, at 50 DEG C, ultrasonic reaction 1h under 800W power, above-mentioned solution being placed in luminous intensity is 90W/cm, wavelength is irradiate 10min under the ultraviolet light of 365nm, be in the solution of 3 to above-mentioned pH by textile impregnation, dip time 1.5h, then by fabric in 50 DEG C of drying 3h, dry fabric is impregnated in the hydrazine hydrate solution of 0.8% and reduces, reduction temperature 80 DEG C, recovery time 3h, finally wash, dry, repeat above-mentioned steps 6 times, obtain Graphene self assembly compliant conductive fabric, and there is good conduction, uvioresistant and waterproofing function.
Implementation result of the present invention
Fabric after embodiment 1-4 process, is tested it respectively as follows, and test result is in table 1.
1) test of fabric face resistance
On SZT-2A four-point probe, (Suzhou Electronics Co., Ltd. of Tontru) is upper measures.
2) test of fabric Ultraviolet Protection Factor
Measure on the blue luxuriant and rich with fragrance optics UV-2000F textiles ultraviolet protection performance tester of the U.S. according to Australia/New Zealand Standard AS/NZS 4399:1996.
3) test of fabric water repellency contact angle
The contact angle of fabric is in Germany
dSA100 type Drop Shape Analyzer measures, the contact angle of test droplets when the fabric face time is 3s.
As shown in Table 1, the resistance value of finish fabric obviously declines, and uvioresistant performance significantly improves, and contact angle reaches more than 120 °.As can be seen here, technical scheme provided by the present invention can give the excellent electric conductivity of polyester-cotton fabric, ultraviolet-resistent property and certain WATER REPELLENCY.
The test result of fabric implemented by table 1
Claims (4)
1. graphene oxide derivative is used for a method for multifunctional finish of textiles, it is characterized in that adopting the mode of ultraviolet irradiation to prepare N doping graphene oxide or derivatives thereof mixed liquor, then carries out self assembly absorption and reduction treatment to fabric.
2. a kind of graphene oxide derivative as claimed in claim 1 is used for the method for multifunctional finish of textiles, it is characterized in that described N doping graphene oxide or derivatives thereof mixed liquor preparation technology is:
(1) graphene oxide or derivatives thereof mixed liquor is prepared: by the graphene oxide or derivatives thereof of 0.5 ~ 1 parts by mass, the anion surfactant of 0.01 ~ 0.5 parts by mass, join in the aqueous solution with 5 ~ 20 parts by mass nitrogen-containing compounds, at 20 ~ 60 DEG C, ultrasonic reaction 0.5 ~ 2h under 300-1000W power, obtain the homogeneous mixture solotion of graphene oxide or derivatives thereof, anion surfactant and nitrogen-containing compound;
(2) N doping graphene oxide or derivatives thereof mixed liquor is prepared: described to (1) mixed solution is placed in luminous intensity is 80-120W/cm, wavelength is irradiate 5-20min under the ultraviolet light of 365nm, make graphene oxide or derivatives thereof carry out N doping reaction, improve the electric conductivity of Graphene.
Described graphene oxide or derivatives thereof is at least one in graphene oxide, carboxylated graphene oxide, sulfonic group graphene oxide;
Described nitrogen-containing compound is at least one in urea, ammoniacal liquor;
Described anion surfactant is at least one in alkylsulfonate, alkylbenzenesulfonate, alkyl carboxylate, alkylbenzene carboxylates, alkylnaphthalene sulfonate, Fluhyzon carboxylate, alkyl-anthraquinone sulfonate, alkyl-anthraquinone carboxylate.
3. a kind of graphene oxide derivative as claimed in claim 1 is used for the method for multifunctional finish of textiles, it is characterized in that the described technique of N doping graphene oxide or derivatives thereof mixed liquor to fabric self assembly absorption and reduction treatment is:
(1) fabric self assembly adsorption of nitrogen doped with oxygen functionalized graphene or derivatives thereof solution: be in the aqueous solution of 2 ~ 6 to the pH of N doping graphene oxide or derivatives thereof by textile impregnation, dipping temperature 10 ~ 50 DEG C, dip time 0.2 ~ 2h, then by fabric in 40 ~ 100 DEG C of drying 0.5 ~ 4h, obtain the fabric of capping oxidation Graphene derivative;
(2) fabric covering N doping graphene oxide derivative is reduced: the dry fabric of capping oxidation Graphene derivative is impregnated in the reductant solution of 0.1 ~ 1% and reduces, reduction temperature 50 ~ 100 DEG C, recovery time 0.5 ~ 6h, finally wash, dry, obtain the conduction, uvioresistant, the water repellent fabric that cover redox graphene derivative;
Described reductant is at least one in sodium dithionite, sodium hydrogensulfite, glucose, shitosan, vitamin C, hydrazine hydrate, sodium borohydride.
4. a kind of graphene oxide derivative as claimed in claim 1 is used for the method for multifunctional finish of textiles, it is characterized in that the fabric after described process can repeat the treatment process of claim 2 and 3, to strengthen textiles multifunctionality.
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| CN114318857A (en) * | 2020-10-10 | 2022-04-12 | 上海水星家用纺织品股份有限公司 | Preparation method of film heating home textile fabric |
| CN115627630A (en) * | 2022-10-24 | 2023-01-20 | 北京铜牛曙光科技有限公司 | Anti-pilling fabric and preparation method and application thereof |
| CN115627630B (en) * | 2022-10-24 | 2024-04-30 | 北京铜牛曙光科技有限公司 | Anti-pilling fabric and preparation method and application thereof |
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