CN107435239A - Conductive wool fabric is prepared with ionic liquid - Google Patents
Conductive wool fabric is prepared with ionic liquid Download PDFInfo
- Publication number
- CN107435239A CN107435239A CN201710787643.9A CN201710787643A CN107435239A CN 107435239 A CN107435239 A CN 107435239A CN 201710787643 A CN201710787643 A CN 201710787643A CN 107435239 A CN107435239 A CN 107435239A
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- Prior art keywords
- wool fabric
- lysate
- ionic liquid
- wool
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 210000002268 wool Anatomy 0.000 title claims abstract description 50
- 239000004744 fabric Substances 0.000 title claims abstract description 39
- 239000002608 ionic liquid Substances 0.000 title claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000019441 ethanol Nutrition 0.000 claims abstract description 18
- 239000006166 lysate Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000011259 mixed solution Substances 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 239000000243 solution Substances 0.000 claims abstract description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- GHKCSRZBNZQHKW-UHFFFAOYSA-N 1-sulfanylethanol Chemical class CC(O)S GHKCSRZBNZQHKW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000005909 ethyl alcohol group Chemical group 0.000 claims abstract description 6
- 230000010355 oscillation Effects 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 238000005660 chlorination reaction Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- ZXLOSLWIGFGPIU-UHFFFAOYSA-N 1-ethyl-3-methyl-1,2-dihydroimidazol-1-ium;acetate Chemical compound CC(O)=O.CCN1CN(C)C=C1 ZXLOSLWIGFGPIU-UHFFFAOYSA-N 0.000 claims description 2
- IBZJNLWLRUHZIX-UHFFFAOYSA-N 1-ethyl-3-methyl-2h-imidazole Chemical compound CCN1CN(C)C=C1 IBZJNLWLRUHZIX-UHFFFAOYSA-N 0.000 claims description 2
- HCGMDEACZUKNDY-UHFFFAOYSA-N 1-butyl-3-methyl-1,2-dihydroimidazol-1-ium;acetate Chemical compound CC(O)=O.CCCCN1CN(C)C=C1 HCGMDEACZUKNDY-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910021389 graphene Inorganic materials 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000002105 nanoparticle Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- -1 1- ethyl -3- methyl Imidazoles acetate Chemical class 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 description 1
- BSKSXTBYXTZWFI-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;acetate Chemical compound CC([O-])=O.CCCC[N+]=1C=CN(C)C=1 BSKSXTBYXTZWFI-UHFFFAOYSA-M 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides a kind of method that conductive wool fabric is prepared using ionic liquid, this method comprises the following steps:(1)The preparation of lysate:20 50g ionic liquids and 4 10g mercaptoethanols are added in 100ml absolute ethyl alcohols, mixed solution is formed, 0.1 1.5g nano conducting powderses is then added in mixed solution, obtain being dispersed with the lysate of nano conducting powderses under sonic oscillation;(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained;(3)Wool fabric after padding is removed into ethanol, vacuum 0.1MPa, temperature 60oC in vacuum desiccator;(4)The wool fabric for removing ethanol is irradiated under microwave;(5)Wool fabric after irradiation is impregnated in saturated sodium-chloride water solution and solidified, then washes, dry.This technology of preparing is simple and easy, and cost is cheap, small to the strength damage of wool fabric, does not change wool surface performance, and nano conducting powderses have good fastness on wool fabric;Any adhesive is not used in this preparation process, it is nontoxic.
Description
Technical field
The present invention relates to a kind of preparation method of function fabric, especially one kind to prepare conductive wool using ionic liquid and knit
The method of thing.
Background technology
Nano-particle is introduced into textile fabric, functional fiber material can be prepared.Nano-particle is drawn at present
It is many to enter the preparation method of wool fiber, such as:Absorption method, sol-gal process, layer assembly method, coating etc..However, absorption method
By mainly making nano-particle be adsorbed onto wool surface by intermolecular Van der Waals force and ionic forces, washing fastness compared with
It is low;The technical process of sol-gal process and layer assembly method is longer, and more difficult control;Coating is to utilize adhesive by nanoparticle
Son is adhered to wool surface, reduces skin-friendly of the wool fiber to human body.
Ionic liquid refers in room temperature or close to liquid, the salt that is made up of completely zwitterion is presented at room temperature,
Referred to as low temperature molten salt.Ionic liquid is the power solvents of rising in recent years.At present, it is usually used in the ionic liquid of protein dissolution
Have:1- butyl -3- methylimidazole acetate BmimAc, chlorination -1- pi-allyl -3- methylimidazoles AmimCl, 1- ethyl -3- methyl
Imidazoles acetate EmimAc, 1- ethyl-3-methylimidazole villaumite EmimCl etc..
The content of the invention
The technical problems to be solved by the invention be the shortcomings that presence for above prior art propose a kind of use from
The method that sub- liquid prepares conductive wool fabric.The technology of preparing is simple and easy, and cost is cheap, to the strength damage of wool fabric
It is small, do not change wool surface performance, nano conducting powderses have good fastness on wool fabric;In the preparation process
Any adhesive is not used, it is nontoxic.
To achieve these goals, the solution taken of the present invention is:One kind prepares conductive wool using ionic liquid
The method of fabric, it is characterised in that comprise the following steps:
(1)The preparation of lysate:20-50g ionic liquids and 4-10g mercaptoethanols are added in 100ml absolute ethyl alcohols, formed
Mixed solution, then adds 0.1-1.5g nano conducting powderses in mixed solution, obtains under sonic oscillation being dispersed with nanometer and leads
The lysate of charged particle;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained;
(3)Wool fabric after padding is removed into ethanol in vacuum desiccator, vacuum is -0.1MPa, temperature 60oC;
(4)The wool fabric for removing ethanol is irradiated into 3-10min under 100-200W microwaves;
(5)Wool fabric after irradiation is impregnated in saturated sodium-chloride water solution and solidified, then washes, dry.
The beneficial effects of the present invention are,(1)Limited ionic liquid is set mainly to be distributed using padding method and vacuum drying
In the surface of wool fiber, the microwave irradiation of short time can only be partly dissolved to wool surface, without damaging sheep
Inside wool fibre, reduce the damage to wool fiber and fabric;(2)It is partly soluble in wool surface
Wool protein forms protein compression solution, has adhesive attraction to nano-particle;(3)The protein compression that wool surface is formed
Solution solidifies again in saturated sodium-chloride water solution, plays bonding to nano-particle, package action;(4)In preparation process
Any adhesive is not used, it is nontoxic.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic is not construed as isolated, and they can be mutually combined so as to reach more preferable
Technique effect.
Embodiment 1
(1)The preparation of lysate:25g ionic liquid chlorination -1- pi-allyl -3- methylimidazole AmimCl and 5g mercaptoethanols are added
Enter into 100ml absolute ethyl alcohols, form mixed solution, 1.2g Nano graphite powders, sonic oscillation are then added in mixed solution
Under obtain being dispersed with the lysate of Nano graphite powder;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained, pick-up 100%;
(3)Wool fabric after padding is removed into ethanol in vacuum desiccator, vacuum is -0.1MPa, temperature 60oC;
(4)The wool fabric for removing ethanol is irradiated into 10min under 100W microwaves;
(5)Wool fabric after irradiation is impregnated in saturated sodium-chloride water solution and solidifies 10min, then washes, dry.
Embodiment 2
(1)The preparation of lysate:30g ionic liquid 1-butyl-3-methyl imidazolium acetate BmimAc and 6g mercaptoethanols are added
Enter into 100ml absolute ethyl alcohols, form mixed solution, 0.8g nanometer carboxylic graphite alkene is then added in mixed solution, surpass
Obtain being dispersed with the lysate of nanometer carboxylic graphite alkene under sound oscillation;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained, pick-up 120%;
(3)Wool fabric after padding is removed into ethanol in vacuum desiccator, vacuum is -0.1MPa, temperature 60oC;
(4)The wool fabric for removing ethanol is irradiated into 3min under 200W microwaves;
(5)Wool fabric after irradiation is impregnated in saturated sodium-chloride water solution and solidifies 10min, then washes, dry.
Embodiment 3
(1)The preparation of lysate:35g ionic liquid 1- ethyl-3-methylimidazole acetate EmimAc and 9g mercaptoethanols are added
Enter into 100ml absolute ethyl alcohols, form mixed solution, then the addition 1.4g CNTs in mixed solution, under sonic oscillation
Obtain being dispersed with the lysate of CNT;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained, pick-up 70%;
(3)Wool fabric after padding is removed into ethanol in vacuum desiccator, vacuum is -0.1MPa, temperature 60oC;
(4)The wool fabric for removing ethanol is irradiated into 6min under 150W microwaves;
(5)Wool fabric after irradiation is impregnated in saturated sodium-chloride water solution and solidifies 10min, then washes, dry.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no
Restriction that should be using the embodiments herein as interest field of the present invention.
Claims (3)
- A kind of 1. method that conductive wool fabric is prepared using ionic liquid, it is characterised in that comprise the following steps:(1)The preparation of lysate:20-50g ionic liquids and 4-10g mercaptoethanols are added in 100ml absolute ethyl alcohols, formed Mixed solution, then adds 0.1-1.5g nano conducting powderses in mixed solution, obtains under sonic oscillation being dispersed with nanometer and leads The lysate of charged particle;(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained;(3)Wool fabric after padding is removed into ethanol in vacuum desiccator, vacuum is -0.1MPa, temperature 60oC;(4)The wool fabric for removing ethanol is irradiated into 3-10min under 100-200W microwaves;(5)Wool fabric after irradiation is impregnated in saturated sodium-chloride water solution and solidified, then washes, dry.
- A kind of 2. method that conductive wool fabric is prepared using ionic liquid according to claim 1, it is characterised in that:From Sub- liquid is 1- butyl -3- methylimidazole acetate BmimAc, chlorination -1- pi-allyl -3- methylimidazoles AmimCl, 1- ethyl - 3- methylimidazole acetate EmimAc, 1- ethyl-3-methylimidazole villaumites EmimCl etc..
- A kind of 3. method that conductive wool fabric is prepared using ionic liquid according to claim 1, it is characterised in that:Receive Rice conducting particles has Nano graphite powder, carboxylated graphene, CNT etc..
Priority Applications (1)
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CN201710787643.9A CN107435239A (en) | 2017-09-04 | 2017-09-04 | Conductive wool fabric is prepared with ionic liquid |
Applications Claiming Priority (1)
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CN201710787643.9A CN107435239A (en) | 2017-09-04 | 2017-09-04 | Conductive wool fabric is prepared with ionic liquid |
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CN201710787643.9A Pending CN107435239A (en) | 2017-09-04 | 2017-09-04 | Conductive wool fabric is prepared with ionic liquid |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110777466A (en) * | 2019-09-24 | 2020-02-11 | 江阴兴吴呢绒科技有限公司 | Manufacturing method of graphene wool fabric and obtained fabric |
CN111364237A (en) * | 2020-03-13 | 2020-07-03 | 旷达纤维科技有限公司 | Graphene composite antibacterial fiber |
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2017
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CN102190894A (en) * | 2011-03-25 | 2011-09-21 | 郑州大学 | Method for preparing collagen-based composite material |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110777466A (en) * | 2019-09-24 | 2020-02-11 | 江阴兴吴呢绒科技有限公司 | Manufacturing method of graphene wool fabric and obtained fabric |
CN111364237A (en) * | 2020-03-13 | 2020-07-03 | 旷达纤维科技有限公司 | Graphene composite antibacterial fiber |
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Application publication date: 20171205 |