CN107447508A - Conductive wool fabric is prepared with mercaptoacetic acid solution - Google Patents
Conductive wool fabric is prepared with mercaptoacetic acid solution Download PDFInfo
- Publication number
- CN107447508A CN107447508A CN201710787499.9A CN201710787499A CN107447508A CN 107447508 A CN107447508 A CN 107447508A CN 201710787499 A CN201710787499 A CN 201710787499A CN 107447508 A CN107447508 A CN 107447508A
- Authority
- CN
- China
- Prior art keywords
- wool fabric
- lysate
- wool
- nano
- decatize
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 210000002268 wool Anatomy 0.000 title claims abstract description 44
- 239000004744 fabric Substances 0.000 title claims abstract description 33
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 title claims abstract description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000006166 lysate Substances 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims abstract description 9
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 6
- 238000004090 dissolution Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 6
- 230000010355 oscillation Effects 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 12
- 239000000835 fiber Substances 0.000 description 6
- 239000002105 nanoparticle Substances 0.000 description 6
- 208000014903 transposition of the great arteries Diseases 0.000 description 6
- 238000005406 washing Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- 238000012032 thrombin generation assay Methods 0.000 description 3
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229960003067 cystine Drugs 0.000 description 2
- -1 graphite alkene Chemical class 0.000 description 2
- BPMFZUMJYQTVII-UHFFFAOYSA-N guanidinoacetic acid Chemical compound NC(=N)NCC(O)=O BPMFZUMJYQTVII-UHFFFAOYSA-N 0.000 description 2
- 241001494479 Pecora Species 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000003396 thiol group Chemical class [H]S* 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides a kind of method that conductive wool fabric is prepared using mercaptoacetic acid solution, this method comprises the following steps:(1)The preparation of lysate:TGA, lithium chloride and lauryl sodium sulfate are added to the water, mixed dissolution liquid is formed, sodium hydroxide regulation pH value is 9 10, and sodium hydroxide regulation pH value is 9 10, then nano conducting powderses are added in lysate, obtain being dispersed with the lysate of nano conducting powderses under sonic oscillation;(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained;(3)Wool fabric after padding carries out decatize;(4)Wool fabric after decatize is impregnated in polyvinyl alcohol water solution and solidified, then washes, dry.This technology of preparing is simple and easy, and cost is cheap, small to the strength damage of wool fabric, does not change wool surface performance, and nano conducting powderses have good fastness on wool fabric;Any adhesive is not used in this preparation process, it is nontoxic.
Description
Technical field
The present invention relates to a kind of preparation method of function fabric, especially one kind to prepare conductive sheep using mercaptoacetic acid solution
The method of wool fabric.
Background technology
Nano-particle is introduced into textile fabric, functional fiber material can be prepared.Nano-particle is drawn at present
It is many to enter the preparation method of wool fiber, such as:Absorption method, sol-gal process, layer assembly method, coating etc..However, absorption method
By mainly making nano-particle be adsorbed onto wool surface by intermolecular Van der Waals force and ionic forces, washing fastness compared with
It is low;The technical process of sol-gal process and layer assembly method is longer, and more difficult control;Coating is to utilize adhesive by nanoparticle
Son is adhered to wool surface, reduces skin-friendly of the wool fiber to human body.
TGA(TGA)Both had the response feature of hydroxy acid, and had the response feature of sulfydryl again, most important of which reaction is
Reaction between disulphide.Reacted particularly under alkalescence condition with the cystine in wool fibre, cut off cystine(-S-
S-)Key, generation are easy to the cysteine of curling.
The content of the invention
The technical problems to be solved by the invention are the shortcomings that presence for above prior art, propose that one kind uses mercapto
The method that guanidine-acetic acid solution prepares conductive wool fabric.The technology of preparing is simple and easy, and cost is cheap, to the strength of wool fabric
Damage small, do not change wool surface performance, nano conducting powderses have good fastness on wool fabric;This was prepared
Any adhesive is not used in journey, it is nontoxic.
To achieve these goals, the solution taken of the present invention is:One kind is prepared conductive using mercaptoacetic acid solution
The method of wool fabric, it is characterised in that comprise the following steps:
(1)The preparation of lysate:TGA, lithium chloride and lauryl sodium sulfate are added to the water, form mixed dissolution
Liquid, sodium hydroxide regulation pH value are 9-10, and sodium hydroxide regulation pH value is 9-10, and conductive nano grain is then added in lysate
Son, obtain being dispersed with the lysate of nano conducting powderses under sonic oscillation;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained;
(3)By the wool fabric after padding at 100-120 DEG C decatize 5-30min;
(4)Wool fabric after decatize is impregnated in polyvinyl alcohol water solution and solidified, then washes, dry.
The beneficial effects of the present invention are,(1)Limited mercaptoacetic acid solution is set to be distributed mainly on wool using padding method
The surface of fiber, the decatize of short time can only be partly dissolved to wool surface, without damaging inside wool fiber,
Reduce the damage to wool fiber and fabric;(2)In the partly soluble wool protein shape of wool surface
Into protein compression solution, there is adhesive attraction to nano-particle;(3)The protein compression solution that wool surface is formed is in poly- second
Solidified again in the enol aqueous solution, play bonding to nano-particle, package action;(4)It is not used in preparation process any viscous
Mixture, it is nontoxic.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic is not construed as isolated, and they can be mutually combined so as to reach more preferable
Technique effect.
Embodiment 1
(1)The preparation of lysate:30g TGAs, 2g lithium chlorides and 3g lauryl sodium sulfate are added in 100ml water,
Mixed dissolution liquid is formed, sodium hydroxide regulation pH value is 9-10,0.3g Nano graphite powders is then added in lysate, ultrasound is shaken
Obtain being dispersed with the lysate of Nano graphite powder under swinging;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained, pick-up 70%;
(3)By the wool fabric after padding at 120 DEG C decatize 10min;
(4)Wool fabric after decatize is impregnated in polyvinyl alcohol water solution(Mass fraction is 12%)Middle solidification 10min, then
Washing, drying.
Embodiment 2
(1)The preparation of lysate:40g TGAs, 2g lithium chlorides and 3g lauryl sodium sulfate are added in 100ml water,
Mixed dissolution liquid is formed, sodium hydroxide regulation pH value is 9-10, and 0.6g nanometer carboxylic graphite alkene is then added in lysate,
Obtain being dispersed with the lysate of nanometer carboxylic graphite alkene under sonic oscillation;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained, pick-up 100%;
(3)By the wool fabric after padding at 120 DEG C decatize 8min;
(4)Wool fabric after decatize is impregnated in polyvinyl alcohol water solution(Mass fraction is 14%)Middle solidification 10min, then
Washing, drying.
Embodiment 3
(1)The preparation of lysate:45g TGAs, 3g lithium chlorides and 4g lauryl sodium sulfate are added in 100ml water,
Mixed dissolution liquid is formed, sodium hydroxide regulation pH value is 9-10, and 0.8g CNTs, sonic oscillation are then added in lysate
Under obtain being dispersed with the lysate of CNT;
(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained, pick-up 110%;
(3)By the wool fabric after padding at 110 DEG C decatize 25min;
(4)Wool fabric after decatize is impregnated in polyvinyl alcohol water solution(Mass fraction is 18%)Middle solidification 10min, then
Washing, drying.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no
Restriction that should be using the embodiments herein as interest field of the present invention.
Claims (2)
- A kind of 1. method that conductive wool fabric is prepared using mercaptoacetic acid solution, it is characterised in that comprise the following steps:(1)The preparation of lysate:TGA, lithium chloride and lauryl sodium sulfate are added to the water, form mixed dissolution Liquid, sodium hydroxide regulation pH value are 9-10, and sodium hydroxide regulation pH value is 9-10, and conductive nano grain is then added in lysate Son, obtain being dispersed with the lysate of nano conducting powderses under sonic oscillation;(2)By wool fabric in step(1)Repeatedly padded in the lysate of gained;(3)By the wool fabric after padding at 100-120 DEG C decatize 5-30min;(4)Wool fabric after decatize is impregnated in polyvinyl alcohol water solution and solidified, then washes, dry.
- 2. a kind of method that conductive wool fabric is prepared using mercaptoacetic acid solution according to claim 1, its feature are existed In:Nano conducting powderses have Nano graphite powder, carboxylated graphene, CNT etc..
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710787499.9A CN107447508A (en) | 2017-09-04 | 2017-09-04 | Conductive wool fabric is prepared with mercaptoacetic acid solution |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710787499.9A CN107447508A (en) | 2017-09-04 | 2017-09-04 | Conductive wool fabric is prepared with mercaptoacetic acid solution |
Publications (1)
Publication Number | Publication Date |
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CN107447508A true CN107447508A (en) | 2017-12-08 |
Family
ID=60495061
Family Applications (1)
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CN201710787499.9A Withdrawn CN107447508A (en) | 2017-09-04 | 2017-09-04 | Conductive wool fabric is prepared with mercaptoacetic acid solution |
Country Status (1)
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115161996A (en) * | 2022-07-14 | 2022-10-11 | 江南大学 | Washable conductive protein fiber fabric and preparation method and application thereof |
-
2017
- 2017-09-04 CN CN201710787499.9A patent/CN107447508A/en not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115161996A (en) * | 2022-07-14 | 2022-10-11 | 江南大学 | Washable conductive protein fiber fabric and preparation method and application thereof |
CN115161996B (en) * | 2022-07-14 | 2024-03-01 | 江南大学 | Washable conductive protein fiber fabric and preparation method and application thereof |
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PB01 | Publication | ||
PB01 | Publication | ||
WW01 | Invention patent application withdrawn after publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171208 |