CN107987645A - A kind of water-borne wood coating - Google Patents

A kind of water-borne wood coating Download PDF

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Publication number
CN107987645A
CN107987645A CN201711305487.4A CN201711305487A CN107987645A CN 107987645 A CN107987645 A CN 107987645A CN 201711305487 A CN201711305487 A CN 201711305487A CN 107987645 A CN107987645 A CN 107987645A
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China
Prior art keywords
water
borne wood
coating
wood coating
acid
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Pending
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CN201711305487.4A
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Chinese (zh)
Inventor
刘骏
匡成杰
黄武
蔡璐
杨针玉
石银波
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HUNAN TAIZI CHEMICAL PAINT CO Ltd
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HUNAN TAIZI CHEMICAL PAINT CO Ltd
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Priority to CN201711305487.4A priority Critical patent/CN107987645A/en
Publication of CN107987645A publication Critical patent/CN107987645A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of water-borne wood coating, including following components:Water-base resin, levelling agent, antiseptic, thickener, wetting agent, pH adjusting agent, scratching resistant, defoamer, wax emulsion, coalescents, deionized water.Base-material of the mixture of one or both of water alcohol acid of the present invention, water-and acrylate copolymer emulsion, aqueous polyurethane dispersion, Aqueous acrylic urethane's dispersion as coating, it coordinates water-borne wood coating made of deionized water to have the characteristics that paint film flexibility is good, strong adhesive force;The levelling agent used can be effectively improved the workability of coating, form smooth, bright and clean coating;The antiseptic used can effectively suppress the growth of the bacteriums such as Escherichia coli, staphylococcus aureus and Candida albicans, have the characteristics that sterilization, durable antibacterial effect, and harmless.

Description

A kind of water-borne wood coating
Technical field
The present invention relates to painting technical field, more particularly to a kind of water-borne wood coating.
Background technology
Woodwork coating is the important component of coatings industry, refers to be used for solid wood board, wood grain panel, bakelite plate, fiber Coating on equipment prepared by the raw material such as plate, is primarily adapted for use in furniture, floor, stationery sports goods, musical instrument and constructional ornamental material Deng.
The woodwork coating of existing market sale is mainly solvent-borne type, and common kind includes alcohol acids coating, acrylic compounds Coating and nitro class coating etc., the content of volatile organic compound in the coating of these kinds more than 50%, production and It can be evaporate into work progress in air, not only pollute air, but also the health of construction personnel can be endangered.Thus development is with water The woodwork coating of organic solvent is replaced to become an important development direction of woodwork coating from now on, water-borne wood coating as medium It is few with environment-protecting and non-poisonous, odorlessness, volatile matter without harmful substances such as benzene, dimethylbenzene, ethyl acetates, non-ignitable not quick-fried feature, It is a kind of environment-friendly type coating.
But existing water-borne wood coating also there are brush-out leveling is poor, antibacterial and mouldproof efficiency is low, be long placed in easily jaundice, Wear no resistance, dried coating film speed is slow and the shortcomings of poor water resistance.
The content of the invention
The present invention provides a kind of water-borne wood coating, to solve, existing woodwork coating brush-out leveling is poor, antibacterial and mouldproof Efficiency is low, wear no resistance, dried coating film speed is slow and the problems such as poor water resistance.
A kind of water-borne wood coating provided is provided, by weight percentage, including following components:
According to one embodiment of present invention, the water-base resin is water alcohol acid, water-and acrylate copolymer emulsion, water The mixture of one or both of property dispersions of polyurethanes, Aqueous acrylic urethane's dispersion.
According to one embodiment of present invention, the levelling agent is polyether-modified polydimethylsiloxanecopolymer copolymer class levelling One or more of mixtures in agent, organosilicon levelling agent, fluorocarbons class levelling agent, acrylic acid levelling agent.
According to one embodiment of present invention, the antiseptic be nano titanium dioxide anti-bacterial agent, it is nano silver antimicrobials, miscellaneous One or more of mixtures in ring class antiseptic, isothiazolinone antiseptic, zeolite carrying silver antimicrobials.
According to one embodiment of present invention, the thickener be non-ionic polyurethane association thickener, alkali soluble is swollen breast One kind in the non-association thickener of liquid, hydrophobic alkali swellable emulsions association thickener.
According to one embodiment of present invention, the wetting agent is 3- aminopropyl triethoxysilanes, 3- aminopropyl front threes Oxysilane, 3- aminopropyltriethoxies diethoxy silane, 3- aminopropyl ethyls diethoxy silane, 3- aminoethylaminopropyl front threes One kind in oxysilane, 3- aminopropyl diisopropyl Ethoxysilanes.
According to one embodiment of present invention, the pH adjusting agent is organic acid or inorganic acid, the organic acid is acetic acid, Alkyl sulfonic acid or the mixture of the two, the inorganic acid is hydrochloric acid, one or more of mixtures in sulfuric acid, phosphoric acid.
According to one embodiment of present invention, the scratching resistant is nano-aluminium oxide or silica flour.
According to one embodiment of present invention, the coalescents for alcohol ester-12, propandiol butyl ether, dipropylene, One or more of mixtures in propylene glycol phenylate.
A kind of water-borne wood coating provided by the invention is using water alcohol acid, water-and acrylate copolymer emulsion, water-based poly- Base-material of the mixture of one or both of urethane dispersion, Aqueous acrylic urethane's dispersion as coating, it coordinates Water-borne wood coating made of deionized water has the characteristics that paint film flexibility is good, strong adhesive force;The levelling agent used can have Effect improves the workability of coating, forms smooth, bright and clean coating;The antiseptic used can effectively suppress Escherichia coli, gold The growth of the bacterium such as staphylococcus aureus and Candida albicans, have the characteristics that sterilization, durable antibacterial effect, and to human body without Evil;The thickener used can increase the viscosity of coating, improve the wet-film thickness of an application, also with anti-precipitation and anti-layering Effect;The wetting agent used can improve wettability of the coating to woodenware, adhesive force of the increase coating to woodenware surface;Make PH adjusting agent can be such that coating more stablizes, in addition, coordinating the use of antiseptic can be into one by adjusting the pH of coating Step suppresses the growth and breeding of all kinds of bacteriums;The scratching resistant used can effectively lift the hardness and wear-resisting after coating film forming Degree;The coalescents used can improve the film forming of coating and dried coating film speed under cryogenic conditions.
Embodiment
Embodiment 1
A kind of water-borne wood coating, by weight percentage, including following components:Water-base resin 62%, levelling agent 0.5%, antiseptic 5%, thickener 1%, wetting agent 0.5%, pH adjusting agent 6%, scratching resistant 4%, defoamer 1%, wax breast Liquid 0.9%, coalescents 8%, deionized water 11.1%.
Water-base resin is water-and acrylate copolymer emulsion, and levelling agent is polyether-modified polydimethylsiloxanecopolymer copolymer class Levelling agent, antiseptic are nano titanium dioxide anti-bacterial agent and nano silver antimicrobials 1:1 mixing, thickener are formed for non-ionic polyurethane Thickener, wetting agent are 3- aminopropyl triethoxysilanes, and pH adjusting agent is acetic acid and alkyl sulfonic acid 1:1 mixing, it is anti-zoned It is nano-aluminium oxide to hinder agent, one kind in defoamer Tego920W, Tego830, Tego831, BYK022 and BYK028, The present embodiment selects Tego920W, and wax emulsion is polythene wax emulsion or oxidized polyethylene wax emulsion, and the present embodiment selects poly- second Alkene wax emulsion, coalescents are propandiol butyl ether and dipropylene 1:1 mixing.
Embodiment 2
A kind of water-borne wood coating, by weight percentage, including following components:Water-base resin 67%, levelling agent 0.4%, antiseptic 3.5%, thickener 0.7%, wetting agent 0.3%, pH adjusting agent 5.5%, scratching resistant 3.8%, defoamer 0.9%, wax emulsion 0.7%, coalescents 6%, deionized water 11.2%.
Water-base resin is aqueous polyurethane dispersion, and levelling agent is organosilicon levelling agent, and antiseptic is heterocyclic antiseptic, Thickener is the non-association thickener of alkali swellable emulsions, and wetting agent is 3- aminopropyl diisopropyl Ethoxysilanes, and pH is adjusted Agent is hydrochloric acid, sulfuric acid and the mixing of phosphoric acid equal proportion, and scratching resistant is nano-aluminium oxide, defoamer Tego920W, One kind in Tego830, Tego831, BYK022 and BYK028, the present embodiment select Tego830, and wax emulsion is Tissuemat E breast Liquid or oxidized polyethylene wax emulsion, the present embodiment select polythene wax emulsion, and coalescents are alcohol ester-12.
Embodiment 3
A kind of water-borne wood coating, by weight percentage, including following components:Water-base resin 70%, levelling agent 0.4%, antiseptic 3%, thickener 0.6%, wetting agent 0.2%, pH adjusting agent 3.6%, scratching resistant 3.1%, defoamer 0.7%, wax emulsion 0.5%, coalescents 7%, deionized water 10.9%.
Water-base resin is Aqueous acrylic urethane's dispersion, and levelling agent is fluorocarbons class levelling agent, and antiseptic is Zeolite carrying silver antimicrobials, thickener are hydrophobic alkali swellable emulsions association thickener, and wetting agent is 3- aminopropyltriethoxy diethoxies Base silane, pH adjusting agent are alkyl sulfonic acid, and scratching resistant is nano-aluminium oxide, defoamer Tego920W, Tego830, One kind in Tego831, BYK022 and BYK028, the present embodiment select Tego831, and wax emulsion is polythene wax emulsion or oxidation Polythene wax emulsion, the present embodiment select polythene wax emulsion, and coalescents are propandiol butyl ether.
Embodiment 4
A kind of water-borne wood coating, by weight percentage, including following components:Water-base resin 79%, levelling agent 0.3%, antiseptic 1.3%, thickener 0.4%, wetting agent 0.2%, pH adjusting agent 2.1%, scratching resistant 2.6%, defoamer 0.6%, wax emulsion 0.3%, coalescents 5%, deionized water 8.2%.
Water-base resin is water-and acrylate copolymer emulsion and aqueous polyurethane dispersion 1:1 mixing, levelling agent is propylene Sour levelling agent, antiseptic are isothiazolinone antiseptic, and thickener is non-ionic polyurethane association thickener, and wetting agent is 3- aminopropyl ethyl diethoxy silanes, pH adjusting agent are acetic acid, and scratching resistant is nano-aluminium oxide, and defoamer is One kind in Tego920W, Tego830, Tego831, BYK022 and BYK028, the present embodiment select BYK022, and wax emulsion is poly- Ethene wax emulsion or oxidized polyethylene wax emulsion, the present embodiment select oxidized polyethylene wax emulsion, and coalescents are dipropylene glycol Butyl ether.
Embodiment 5
A kind of water-borne wood coating, by weight percentage, including following components:Water-base resin 86%, levelling agent 0.1%, antiseptic 0.1%, thickener 0.2%, wetting agent 0.2%, pH adjusting agent 1.7%, scratching resistant 1.4%, defoamer 0.5%, wax emulsion 0.1%, coalescents 4%, deionized water 5.7%.
Water-base resin is water alcohol acid and water-and acrylate copolymer emulsion 1:1 mixing, levelling agent is organosilicon levelling agent With fluorocarbons class levelling agent 1:1 mixing, antiseptic is nano titanium dioxide anti-bacterial agent and zeolite carrying silver antimicrobials 1:1 is mixed Close, thickener is the non-association thickener of alkali swellable emulsions, and wetting agent is 3- aminoethylaminopropyl trimethoxy silanes, and pH is adjusted Agent is alkyl sulfonic acid, and scratching resistant is silica flour, defoamer Tego920W, Tego830, Tego831, BYK022 and BYK028 In one kind, the present embodiment selects BYK028, and wax emulsion be polythene wax emulsion or oxidized polyethylene wax emulsion, and the present embodiment selects With oxidized polyethylene wax emulsion, coalescents are propylene glycol phenylate.
In conclusion a kind of water-borne wood coating provided in an embodiment of the present invention, using water alcohol acid, water-and acrylate The mixture of one or both of copolymer emulsion, aqueous polyurethane dispersion, Aqueous acrylic urethane's dispersion is as painting The base-material of material, it coordinates water-borne wood coating made of deionized water to have the characteristics that paint film flexibility is good, strong adhesive force;Use Levelling agent can be effectively improved the workability of coating, form smooth, bright and clean coating;The antiseptic used can effectively press down The growth of the bacteriums such as Escherichia coli, staphylococcus aureus and Candida albicans processed, has sterilization, the spy of durable antibacterial effect Point, and it is harmless;The thickener used can increase the viscosity of coating, improve the wet-film thickness of an application, also have Anti- precipitation and the effect of anti-layering;The wetting agent used can improve wettability of the coating to woodenware, and increase coating is to woodenware The adhesive force on surface;The pH adjusting agent used can be such that coating more stablizes, in addition, coordinating antiseptic by adjusting the pH of coating Use can further suppress the growth and breeding of all kinds of bacteriums;After the scratching resistant used can effectively lift coating film forming Hardness and abrasion resistance;The coalescents used can improve the film forming of coating and dried coating film speed under cryogenic conditions.
Although the present invention has described it in detail and cited embodiments, but for those of ordinary skill in the art come Say, it is clear that various schemes, modification and the change that can be made as specified above, should be construed as being included in the claims in the present invention Within the scope of.

Claims (9)

  1. A kind of 1. water-borne wood coating, it is characterised in that by weight percentage, including following components:
  2. 2. water-borne wood coating according to claim 1, it is characterised in that the water-base resin is water alcohol acid, water-based The mixing of one or both of acrylate copolymer emulsion, aqueous polyurethane dispersion, Aqueous acrylic urethane's dispersion Thing.
  3. 3. water-borne wood coating according to claim 1, it is characterised in that the levelling agent is polyether-modified poly dimethyl Copolymeric siloxane species levelling agent, organosilicon levelling agent, fluorocarbons class levelling agent, one kind in acrylic acid levelling agent or several The mixture of kind.
  4. 4. water-borne wood coating according to claim 1, it is characterised in that the antiseptic is nanometer titanium dioxide antibiotic One or more in agent, nano silver antimicrobials, heterocyclic antiseptic, isothiazolinone antiseptic, zeolite carrying silver antimicrobials Mixture.
  5. 5. water-borne wood coating according to claim 1, it is characterised in that the thickener associates for non-ionic polyurethane One kind in type thickener, the non-association thickener of alkali swellable emulsions, hydrophobic alkali swellable emulsions association thickener.
  6. 6. water-borne wood coating according to claim 1, it is characterised in that the wetting agent is 3- aminopropyl-triethoxies Silane, 3- aminopropyl trimethoxysilanes, 3- aminopropyltriethoxies diethoxy silane, 3- aminopropyl ethyls diethoxy silane, One kind in 3- aminoethylaminopropyls trimethoxy silane, 3- aminopropyl diisopropyl Ethoxysilanes.
  7. 7. water-borne wood coating according to claim 1, it is characterised in that the pH adjusting agent is organic acid or inorganic Acid, the organic acid are acetic acid, alkyl sulfonic acid or the mixture of the two, and the inorganic acid is hydrochloric acid, one kind in sulfuric acid, phosphoric acid Or several mixture.
  8. 8. water-borne wood coating according to claim 1, it is characterised in that the scratching resistant is nano-aluminium oxide Or silica flour.
  9. 9. water-borne wood coating according to claim 1, it is characterised in that the coalescents are alcohol ester-12, propane diols One or more of mixtures in butyl ether, dipropylene, propylene glycol phenylate.
CN201711305487.4A 2017-12-11 2017-12-11 A kind of water-borne wood coating Pending CN107987645A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109355016A (en) * 2018-08-27 2019-02-19 大连理工高邮研究院有限公司 Sterilizing environmental protection coating and preparation method thereof
CN109439164A (en) * 2018-09-21 2019-03-08 贾锐 A kind of modified water-soluble environmental protection paint
CN109735225A (en) * 2019-01-25 2019-05-10 佛山市高明区首邦化工有限公司 A kind of woodenware bloom environmental protection paint and preparation method thereof
CN111117547A (en) * 2019-12-26 2020-05-08 佛山市红树水性印涂材料有限公司 Water-based plastic uptake glazing oil strongly adhered to PET (polyethylene terephthalate) and preparation method thereof
CN111334154A (en) * 2020-04-15 2020-06-26 上海君子兰新材料股份有限公司 Water-based wood coating for rotary cup electrostatic spraying and preparation method thereof
CN111423804A (en) * 2020-04-30 2020-07-17 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial water-based environment-friendly coating and preparation method thereof
CN111500127A (en) * 2020-04-30 2020-08-07 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial coating spray and preparation method thereof
CN112574630A (en) * 2021-01-14 2021-03-30 郑州大学 Long-acting anti-infection coating and preparation method and application thereof
CN112680080A (en) * 2020-12-17 2021-04-20 泉州博银信息科技有限公司 Environment-friendly water-based paint for PVC (polyvinyl chloride) floor and preparation method thereof
CN112680041A (en) * 2020-12-14 2021-04-20 成都展辰涂料有限公司 Water-based skin-feel wood coating and preparation method thereof
CN112680075A (en) * 2020-12-14 2021-04-20 成都展辰涂料有限公司 Non-mask aqueous colorant and preparation method thereof
CN112778896A (en) * 2021-01-12 2021-05-11 广东大自然家居科技研究有限公司 Ceramic tile-imitated wood floor and preparation method thereof
CN112778889A (en) * 2020-12-02 2021-05-11 甘彤 Process for preparing nano antibacterial mildew-resistant waterborne polyurethane coating
CN114058252A (en) * 2021-12-31 2022-02-18 福建龙兴九源科技股份有限公司 Water-based woodenware coating and preparation method thereof
CN114085577A (en) * 2021-12-23 2022-02-25 东莞市涂芭新材料有限公司 Water-based antiviral negative oxygen ion woodenware coating and preparation method thereof

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CN1730581A (en) * 2005-09-09 2006-02-08 广东赛特国际集团有限公司 Nanometre Ag antibacterial aqueous woodware paint and its preparation method
CN101659825A (en) * 2008-08-28 2010-03-03 上海富臣化工有限公司 Double-component aqueous nano scratch resistant wood coating and method for producing same
CN103059669A (en) * 2012-11-23 2013-04-24 高凡 Novel nano modified antimicrobial water-based woodware paint
CN106634293A (en) * 2016-10-28 2017-05-10 展辰新材料集团股份有限公司 Water-borne wood coating

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Publication number Priority date Publication date Assignee Title
CN1640973A (en) * 2004-11-04 2005-07-20 深圳市展辰达化工有限公司 Water-based antibacterial varnish for woodenware
CN1730581A (en) * 2005-09-09 2006-02-08 广东赛特国际集团有限公司 Nanometre Ag antibacterial aqueous woodware paint and its preparation method
CN101659825A (en) * 2008-08-28 2010-03-03 上海富臣化工有限公司 Double-component aqueous nano scratch resistant wood coating and method for producing same
CN103059669A (en) * 2012-11-23 2013-04-24 高凡 Novel nano modified antimicrobial water-based woodware paint
CN106634293A (en) * 2016-10-28 2017-05-10 展辰新材料集团股份有限公司 Water-borne wood coating

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109355016A (en) * 2018-08-27 2019-02-19 大连理工高邮研究院有限公司 Sterilizing environmental protection coating and preparation method thereof
CN109439164A (en) * 2018-09-21 2019-03-08 贾锐 A kind of modified water-soluble environmental protection paint
CN109735225A (en) * 2019-01-25 2019-05-10 佛山市高明区首邦化工有限公司 A kind of woodenware bloom environmental protection paint and preparation method thereof
CN109735225B (en) * 2019-01-25 2022-07-15 佛山市高明区首邦化工有限公司 High-gloss environment-friendly paint for woodware and preparation method thereof
CN111117547A (en) * 2019-12-26 2020-05-08 佛山市红树水性印涂材料有限公司 Water-based plastic uptake glazing oil strongly adhered to PET (polyethylene terephthalate) and preparation method thereof
CN111334154A (en) * 2020-04-15 2020-06-26 上海君子兰新材料股份有限公司 Water-based wood coating for rotary cup electrostatic spraying and preparation method thereof
CN111423804A (en) * 2020-04-30 2020-07-17 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial water-based environment-friendly coating and preparation method thereof
CN111500127A (en) * 2020-04-30 2020-08-07 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial coating spray and preparation method thereof
CN112778889A (en) * 2020-12-02 2021-05-11 甘彤 Process for preparing nano antibacterial mildew-resistant waterborne polyurethane coating
CN112680041A (en) * 2020-12-14 2021-04-20 成都展辰涂料有限公司 Water-based skin-feel wood coating and preparation method thereof
CN112680075A (en) * 2020-12-14 2021-04-20 成都展辰涂料有限公司 Non-mask aqueous colorant and preparation method thereof
CN112680080A (en) * 2020-12-17 2021-04-20 泉州博银信息科技有限公司 Environment-friendly water-based paint for PVC (polyvinyl chloride) floor and preparation method thereof
CN112778896A (en) * 2021-01-12 2021-05-11 广东大自然家居科技研究有限公司 Ceramic tile-imitated wood floor and preparation method thereof
CN112574630A (en) * 2021-01-14 2021-03-30 郑州大学 Long-acting anti-infection coating and preparation method and application thereof
CN114085577A (en) * 2021-12-23 2022-02-25 东莞市涂芭新材料有限公司 Water-based antiviral negative oxygen ion woodenware coating and preparation method thereof
CN114058252A (en) * 2021-12-31 2022-02-18 福建龙兴九源科技股份有限公司 Water-based woodenware coating and preparation method thereof

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Application publication date: 20180504