CN109439164A - A kind of modified water-soluble environmental protection paint - Google Patents

A kind of modified water-soluble environmental protection paint Download PDF

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Publication number
CN109439164A
CN109439164A CN201811106767.7A CN201811106767A CN109439164A CN 109439164 A CN109439164 A CN 109439164A CN 201811106767 A CN201811106767 A CN 201811106767A CN 109439164 A CN109439164 A CN 109439164A
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CN
China
Prior art keywords
modified
environmental protection
water
protection paint
nano
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Pending
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CN201811106767.7A
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Chinese (zh)
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贾锐
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Individual
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Priority to CN201811106767.7A priority Critical patent/CN109439164A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention provides a kind of modified water-soluble environmental protection paint, the modified water-soluble environmental protection paint is by rare earth mixing with nano silver modified ultra-branching nano titania slurry, polyacrylate dispersion, coalescing agent, wetting agent, waterborne polyurethane resin is dissolved using sol-gal process simultaneously, aqueous organic titanium modified polyurethane dispersion composition, it is in terms of 100% by the gross mass of modified water-soluble environmental protection paint, each component mass percentage is as follows: polyacrylate dispersion 15~65%, waterborne polyurethane resin 20~40%, rare earth mixing with nano silver modified ultra-branching nano titania slurry 5~15%, aqueous organic titanium modified polyurethane dispersion 3~15%, coalescing agent 1~3%, wetting agent 0.5~1.5%.Modest viscosity is made in the invention, and stock dispersion is uniform, good physical performance, and film forming, levelability, thermal stability and glossiness are good, and antiultraviolet, antifouling, wear-resisting property is good, strong operability, no waste, pollution-free, the modified water-soluble environmental protection paint of safety and environmental protection.

Description

A kind of modified water-soluble environmental protection paint
Technical field
The invention belongs to technical field of coatings, more particularly, to a kind of modified water-soluble environmental protection paint.
Background technique
Traditional paint is using vegetable oil, synthetic resin as main film forming substance, and with various auxiliary agents and pigment, when use needs to be added The organic solvent dilutings such as toluene, dimethylbenzene, in organic solvent there are volatile harmful substance be easy it is carcinogenic, to human body and environment It damages.Small molecule in synthetic resin is easy to be absorbed by the body, and damages to human organ, currently on the market aqueous Paint has the disadvantage in that moisture content height, and dry difficult after coating, film forming is poor, gloss difference, wears no resistance, defoams difficulty.This hair It is bright create one of modified water-soluble environmental protection paint, modest viscosity, stock dispersion is uniform, good physical performance, film forming, levelability, Thermal stability and glossiness are good, and antiultraviolet, antifouling, wear-resisting property is good, strong operability, can be carried out in a manner of simply rubbing It uses, no waste, pollution-free, the modified water-soluble environmental protection paint of safety and environmental protection.
Summary of the invention
The problem to be solved by the invention is to provide a kind of modified water-soluble environmental protection paint, it is especially suitable for solving to be not easy to do Dry, film forming is poor, the environment-friendly water-based paint that gloss difference, wears no resistance, defoam difficult these problems.
In order to solve the above technical problems, the invention the technical solution adopted is that: a kind of modified water-soluble environmental protection paint, it is special Sign is that the modified water-soluble environmental protection paint is by rare earth mixing with nano silver modified ultra-branching nano titania slurry, polyacrylic acid Ester lotion, coalescing agent, wetting agent, while polyurethane resin, aqueous organic titanium modified polyurethane are dissolved using sol-gal process Dispersion composition, is in terms of 100% by the gross mass of modified water-soluble environmental protection paint, each component mass percentage is as follows: rear-earth-doped Rare earth mixing with nano silver modified ultra-branching nano titania slurry 5~15%, polyacrylate dispersion 25~50%, film forming help Agent 1~3%, wetting agent 0.5~1.5%, waterborne polyurethane resin 20~40%, aqueous organic titanium modified polyurethane dispersion 3 ~15%.
The rare earth mixing with nano silver modified ultra-branching nano titania slurry, by nano silver, nano-titanium dioxide, dilute Soil, water-based fluorocarbon resin are made for raw material, with the gross mass of rare earth mixing with nano silver modified ultra-branching nano titania slurry It is counted for 100%, the mass percentage of each component is as follows: nano silver 2~5%, nano-titanium dioxide 40~60%, rare earth 3~ 5%, water-based fluorocarbon resin 30~55%.
The sol-gal process are as follows: polyurethane resin, aqueous organic titanium modified polyurethane dispersion are put into water-bath, 40~80 DEG C of 2.5~4.5h of stirring use titration outfit in whipping process, inject dihydromethyl propionic acid and polyethers with 2~15g/h Polyalcohol.
The rare earth is La rear earth ion (such as La3+、Nd3+、Pr3+、Sm3+、Eu3+)。
The coalescing agent is propandiol butyl ether, a contracting propylene glycol methyl ether acetate, one in propylene glycol methyl ether acetate Kind.
The wetting agent is one of soybean lecithin, thio-alcohol, hydrazides and mercaptan acetals.
The water paint needs 0.5~1.5h of ultrasonic disperse.
The invention has the advantages and positive effects of:
(1) the invention is by rare earth ion doped, so that the thermal stability of water paint；
(2) by rare earth ion doped nano modification, the wearability of water paint can be effectively improved；
(3) by rare earth ion doped nano modification, it can effectively improve the hydrophily of water paint；
(4) by rare earth ion doped nano-titanium dioxide, it can effectively improve the retention cycle of water paint；
(5) rare earth ion doped nano modification can effectively improve the physicochemical properties of water paint.
In order to make content described in the invention easily facilitate understanding, the present invention is created With reference to embodiment It makes the scheme to be described further, but the invention is not limited only to this.
Embodiment 1
A kind of modified water-soluble environmental protection paint, by rare earth mixing with nano silver modified ultra-branching nano titania slurry, polypropylene Acid esters lotion, coalescing agent, wetting agent, while using sol-gal process dissolution polyurethane resin, the modified poly- ammonia of aqueous organic titanium Ester dispersion composition, each component mass percentage are as follows: rear-earth-doped rare earth mixing with nano silver modified ultra-branching nano-silica Change titanium slurry 10%, polyacrylate dispersion 35%, coalescing agent 1%, wetting agent 1%, waterborne polyurethane resin 40%, aqueous Organic titanium modified polyurethane dispersion 8%, 5% rare earth Eu3+。
Rare earth mixing with nano silver modified ultra-branching nano titania slurry, by nano silver, nano-titanium dioxide, rare earth, Water-based fluorocarbon resin for raw material be made, the mass percentage of each component is as follows: nano silver 3%, nano-titanium dioxide 45%, 4% rare earth Pr3+, water-based fluorocarbon resin 48%.
The sol-gal process are as follows: polyurethane resin, aqueous organic titanium modified polyurethane dispersion are put into water-bath, 0.5h is stirred at room temperature；It starts to warm up, when temperature is raised to 40 DEG C, setting constant temperature stirs 1h；Then, continue to heat up, work as temperature When being raised to 80 DEG C, setting constant temperature stirs 2h；In whipping process use titration outfit, with 2~15g/h injection dihydromethyl propionic acid and Polyether polyol.
The coalescing agent is propandiol butyl ether.
The wetting agent is isoniazid.
Ultrasonic disperse 1h.
Embodiment 2
A kind of modified water-soluble environmental protection paint, by rare earth mixing with nano silver modified ultra-branching nano titania slurry, polypropylene Acid esters lotion, coalescing agent, wetting agent, while using sol-gal process dissolution polyurethane resin, the modified poly- ammonia of aqueous organic titanium Ester dispersion composition, each component mass percentage are as follows: rare earth mixing with nano silver modified ultra-branching nano titania slurry 13%, polyacrylate dispersion 45%, coalescing agent 3%, wetting agent 1%, waterborne polyurethane resin 30%, aqueous organic titanium change Property dispersions of polyurethanes 8%.
The rare earth mixing with nano silver modified ultra-branching nano titania slurry, by nano silver, nano-titanium dioxide, dilute Soil, water-based fluorocarbon resin are made for raw material, and the mass percentage of each component is as follows: nano silver 5%, nano-titanium dioxide 45%, rare earth Nd3+4%, water-based fluorocarbon resin 46%.
The sol-gal process are as follows: polyurethane resin, aqueous organic titanium modified polyurethane dispersion are put into water-bath, 1h is stirred at room temperature；It starts to warm up, when temperature is raised to 40 DEG C, setting constant temperature stirs 0.5h；Then, continue to heat up, work as temperature When being raised to 80 DEG C, setting constant temperature stirs 2.5h；Titration outfit is used in whipping process, and dihydromethyl propionic acid is injected with 2~15g/h And polyether polyol.
The coalescing agent is propylene glycol methyl ether acetate.
The wetting agent is soybean lecithin.
Ultrasonic disperse 1.5h.
The other embodiment of the invention is described in detail above, but the content is only the invention Preferred embodiment should not be considered as limiting the invention the practical range of creation.It is all to be made according to the invention application range All the changes and improvements etc., shall remain within the patent scope covered by the invention.

Claims (7)

1. a kind of modified water-soluble environmental protection paint, which is characterized in that the modified water-soluble environmental protection paint is modified super by rare earth mixing with nano silver Branching nano titania slurry, polyacrylate dispersion, coalescing agent, wetting agent, at the same it is poly- using sol-gal process dissolution Urethane resin, aqueous organic titanium modified polyurethane dispersion composition, are in terms of 100%, respectively by the gross mass of modified water-soluble environmental protection paint Constituent mass percentage composition is as follows: rear-earth-doped rare earth mixing with nano silver modified ultra-branching nano titania slurry 5~15%, Polyacrylate dispersion 25~50%, coalescing agent 1~3%, wetting agent 0.5~1.5%, waterborne polyurethane resin 20~ 40%, aqueous organic titanium modified polyurethane dispersion 3~15%.
2. a kind of modified water-soluble environmental protection paint according to claim 1, it is characterised in that: the rare earth mixing with nano silver is modified Hyperbranched nano titania slurry is made, with dilute for raw material by nano silver, nano-titanium dioxide, rare earth, water-based fluorocarbon resin The gross mass of native doping nano-Ag modified ultra-branching nano titania slurry is 100% meter, the mass percentage of each component It is as follows: nano silver 2~5%, nano-titanium dioxide 40~60%, rare earth 3~5%, water-based fluorocarbon resin 30~55%.
3. a kind of modified water-soluble environmental protection paint according to claim 1, it is characterised in that: the sol-gal process are as follows: will gather Urethane resin, aqueous organic titanium modified polyurethane dispersion are put into water-bath, 40~80 DEG C of stirring 2.5~4.5h, stirred Titration outfit is used in journey, and dihydromethyl propionic acid and polyether polyol are injected with 2~15g/h.
4. a kind of modified water-soluble environmental protection paint according to claim 1, it is characterised in that: the rare earth is La rear earth ion (such as La3+、Nd3+、Pr3+、Sm3+、Eu3+)。
5. a kind of modified water-soluble environmental protection paint according to claim 1, it is characterised in that: the coalescing agent is propylene glycol fourth One of ether, a contracting propylene glycol methyl ether acetate, propylene glycol methyl ether acetate.
6. a kind of modified water-soluble environmental protection paint according to claim 1, it is characterised in that: the wetting agent is soybean lecithin One of rouge, thio-alcohol, hydrazides and mercaptan acetals.
7. a kind of modified water-soluble environmental protection paint according to claim 1, it is characterised in that: the water paint needs ultrasonic disperse 0.5-1.5h。
CN201811106767.7A 2018-09-21 2018-09-21 A kind of modified water-soluble environmental protection paint Pending CN109439164A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201811106767.7A CN109439164A (en) 2018-09-21 2018-09-21 A kind of modified water-soluble environmental protection paint

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103374273A (en) * 2012-04-25 2013-10-30 衡水圣伯莱涂料有限公司 Low-VOC (volatile organic compounds) environment-friendly antibacterial emulsion paint and preparation method for same
WO2014005753A1 (en) * 2012-07-06 2014-01-09 Akzo Nobel Coatings International B.V. Method for producing a nanocomposite dispersion comprising composite particles|of inorganic nanoparticles and organic polymers
CN107987645A (en) * 2017-12-11 2018-05-04 湖南太子化工涂料有限公司 A kind of water-borne wood coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103374273A (en) * 2012-04-25 2013-10-30 衡水圣伯莱涂料有限公司 Low-VOC (volatile organic compounds) environment-friendly antibacterial emulsion paint and preparation method for same
WO2014005753A1 (en) * 2012-07-06 2014-01-09 Akzo Nobel Coatings International B.V. Method for producing a nanocomposite dispersion comprising composite particles|of inorganic nanoparticles and organic polymers
CN107987645A (en) * 2017-12-11 2018-05-04 湖南太子化工涂料有限公司 A kind of water-borne wood coating

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
原燃料化学工业部涂料技术训练班组织: "《涂料工艺第六分册》", 30 June 1982, 石油化学工业出版社 *
杨金田等: "《材料科学与技术》", 31 May 2012, 浙江大学出版社 *
江国华: "《超支化聚合物的合成与应用》", 30 June 2012, 东北师范大学出版社 *

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Application publication date: 20190308