CN107987371A - A kind of environmental protection covering film formula - Google Patents

A kind of environmental protection covering film formula Download PDF

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Publication number
CN107987371A
CN107987371A CN201711382336.9A CN201711382336A CN107987371A CN 107987371 A CN107987371 A CN 107987371A CN 201711382336 A CN201711382336 A CN 201711382336A CN 107987371 A CN107987371 A CN 107987371A
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CN
China
Prior art keywords
parts
covering film
microwax
environmental protection
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711382336.9A
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Chinese (zh)
Inventor
仲伟嫱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Tianheng Nano Science And Technology Co Ltd
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Jiangsu Tianheng Nano Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Jiangsu Tianheng Nano Science And Technology Co Ltd filed Critical Jiangsu Tianheng Nano Science And Technology Co Ltd
Priority to CN201711382336.9A priority Critical patent/CN107987371A/en
Publication of CN107987371A publication Critical patent/CN107987371A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/132Phenols containing keto groups, e.g. benzophenones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of environmentally friendly covering film formula, it is characterised in that:Including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, 23 parts of polypropylene, 7 parts of dioctyl phthalate, 2, 43 parts of dihydroxy benaophenonels, 2, 2, 6, 3 parts of 6 tetramethyl, 4 piperidyl, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amide-type, 1 part of microwax poly butylene succinate, 2 parts of microwax, N, 3 parts of N ethylene bis stearamides, 1 part of talcum powder, 25 35 parts of disodium hydrogen phosphate, 10 30 parts of ethylene-vinyl alcohol copolymer, 13 parts of tartaric acid, 15 parts of antioxidant, 10 20 parts of polyimides, 46 parts of bi-myristoleyl, 0.5 2 parts of ultra-violet absorber;The covering film quality that this formula makes is good, and production cost is low, and covering film has stronger anti-ultraviolet property, resistance to low temperature, high mechanical performance and antistatic property, and degradation speed is fast, environmentally safe.

Description

A kind of environmental protection covering film formula
Technical field
The present invention relates to environmentally friendly covering film formulation art, more particularly to a kind of environmentally friendly covering film formula.
Background technology
China's plastic industry generally uses existing plastics covering film national standard at present.The standard is at the beginning of formulation due to me All many factors limitations such as state's agricultural economy condition are, it is specified that " covering film " minimum thickness calibration is 0.008mm;Recommend covering Usage time is -120 days 50 days.Traditional plastics covering film there are it is one very big the shortcomings that --- difficult degradation.And due to This shortcoming so that traditional plastics covering film also can continue development to agricultural and bring seriously while large-scale application Harm.In addition partly plastic manufacturing enterprise is in order to cater to the psychology that peasant household blindly reduces overlay film cost and pursues economic benefit, and one Plastics covering film inherent quality and thickness are reduced again, cause many plastics covering films to show using occurring as soon as season cracking less than two months As.Degradable environment-friendly plastics covering film by be from now on agricultural covering film research Main way.Treat one batch of crop maturity When plastics covering film is incoherent already, unrestrained Tian Tian all over the fields, can not accomplish effectively to recycle at all.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of environmentally friendly covering film.
In order to solve the above technical problems, the technical scheme is that:A kind of environmental protection covering film formula, its innovative point exist In:Including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, 23 parts of polypropylene, phthalic acid two 7 parts of monooctyl ester, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- 3 parts of tetramethyl -4- piperidyls, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amide-type, microwax poly-succinic -1 part of butanediol ester, 2 parts, N of microwax, N- ethylene bis stearamides 3 Part, 1 part of talcum powder, 25-35 parts of disodium hydrogen phosphate, 10-30 parts of ethylene-vinyl alcohol copolymer, 1-3 parts of tartaric acid, antioxidant 1-5 parts, 10-20 parts of polyimides, 4-6 parts of bi-myristoleyl, 0.5-2 parts of ultra-violet absorber.
The advantage of the invention is that:
1)The initial mechanical intensity of environmentally friendly covering film of the present invention is high, and durability is good, and degradation speed is fast, each functional, is not easy pair Soil damages, and the covering film quality that this formula makes is good, and production cost is low, and covering film has stronger uviolresistance Energy, resistance to low temperature, high mechanical performance and antistatic property, and degradation speed is fast, it is environmentally safe.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among the embodiment described scope.
Embodiment 1:
A kind of environmental protection covering film formula, including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, poly- third 23 parts of alkene, 7 parts of dioctyl phthalate, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- tetramethyl -4- piperazines 3 parts of piperidinyl, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amide-type, microwax poly-succinic -1 part of butanediol ester, microwax 2 Part, N, 3 parts of N- ethylene bis stearamides, 1 part of talcum powder, 25 parts of disodium hydrogen phosphate, 10 parts of ethylene-vinyl alcohol copolymer, 1 part of tartaric acid, 1 part of antioxidant, 10 parts of polyimides, 4 parts of bi-myristoleyl, 0.5 part of ultra-violet absorber.
Embodiment 2:
A kind of environmental protection covering film formula, including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, poly- third 23 parts of alkene, 7 parts of dioctyl phthalate, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- tetramethyl -4- piperazines 3 parts of piperidinyl, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amide-type, microwax poly-succinic -1 part of butanediol ester, microwax 2 Part, N, 3 parts of N- ethylene bis stearamides, 1 part of talcum powder, 30 parts of disodium hydrogen phosphate, 20 parts of ethylene-vinyl alcohol copolymer, 2 parts of tartaric acid, 3 parts of antioxidant, 15 parts of polyimides, 5 parts of bi-myristoleyl, 1.8 parts of ultra-violet absorber.
Embodiment 3:
A kind of environmental protection covering film formula, including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, poly- third 23 parts of alkene, 7 parts of dioctyl phthalate, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- tetramethyl -4- piperazines 3 parts of piperidinyl, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amide-type, microwax poly-succinic -1 part of butanediol ester, microwax 2 Part, N, 3 parts of N- ethylene bis stearamides, 1 part of talcum powder, 35 parts of disodium hydrogen phosphate, 30 parts of ethylene-vinyl alcohol copolymer, 3 parts of tartaric acid, 5 parts of antioxidant, 20 parts of polyimides, 6 parts of bi-myristoleyl, 2 parts of ultra-violet absorber.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention It is defined by the appending claims and its equivalent thereof.

Claims (1)

  1. A kind of 1. environmental protection covering film formula, it is characterised in that:Including following component, 50 parts of linear low density polyethylene, corn 10 parts of starch, 23 parts of polypropylene, 7 parts of dioctyl phthalate, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- 3 parts of tetramethyl -4- piperidyls, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amide-type, microwax poly-succinic-butanediol ester 1 part, 2 parts, N of microwax, 3 parts of N- ethylene bis stearamides, 1 part of talcum powder, 25-35 parts of disodium hydrogen phosphate, ethene-second 0-30 parts of enol copolymer 1,1-3 parts of tartaric acid, 1-5 parts of antioxidant, 10-20 parts of polyimides, 4-6 parts of bi-myristoleyl, 0.5-2 parts of ultra-violet absorber.
CN201711382336.9A 2017-12-20 2017-12-20 A kind of environmental protection covering film formula Pending CN107987371A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711382336.9A CN107987371A (en) 2017-12-20 2017-12-20 A kind of environmental protection covering film formula

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711382336.9A CN107987371A (en) 2017-12-20 2017-12-20 A kind of environmental protection covering film formula

Publications (1)

Publication Number Publication Date
CN107987371A true CN107987371A (en) 2018-05-04

Family

ID=62039186

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711382336.9A Pending CN107987371A (en) 2017-12-20 2017-12-20 A kind of environmental protection covering film formula

Country Status (1)

Country Link
CN (1) CN107987371A (en)

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Application publication date: 20180504