CN107417984A - A kind of Degradable environment-friendlyplastic plastic - Google Patents

A kind of Degradable environment-friendlyplastic plastic Download PDF

Info

Publication number
CN107417984A
CN107417984A CN201710497156.9A CN201710497156A CN107417984A CN 107417984 A CN107417984 A CN 107417984A CN 201710497156 A CN201710497156 A CN 201710497156A CN 107417984 A CN107417984 A CN 107417984A
Authority
CN
China
Prior art keywords
degradable environment
friendlyplastic plastic
synthetic resin
modified starch
solubilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710497156.9A
Other languages
Chinese (zh)
Inventor
方晓
王伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAICANG CHENZHOU PLASTIC INDUSTRY Co Ltd
Original Assignee
TAICANG CHENZHOU PLASTIC INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAICANG CHENZHOU PLASTIC INDUSTRY Co Ltd filed Critical TAICANG CHENZHOU PLASTIC INDUSTRY Co Ltd
Priority to CN201710497156.9A priority Critical patent/CN107417984A/en
Publication of CN107417984A publication Critical patent/CN107417984A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of Degradable environment-friendlyplastic plastic, and it is comprised the following raw materials by weight percent:Including:Modified starch, cellulose, sensitising agent, PHA polymer, PE synthetic resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30 45, cellulose 3.5 8, sensitising agent 15, PHA polymer 2 10, PE synthetic resin 5 10, solubilizer 0.5 3, coupling agent 25, the sensitising agent are the organic compound or salt of transition metal.By the above-mentioned means, a kind of a kind of plastics of the Degradable environment-friendlyplastic plastic of the present invention for light degradation and microbial combination, it has the characteristics of light and micro-biological degradable plastic simultaneously, is easier to degrade in natural environment, and the influence to environment is reduced to minimum.

Description

A kind of Degradable environment-friendlyplastic plastic
Technical field
The present invention relates to molecular material field, more particularly to a kind of Degradable environment-friendlyplastic plastic.
Background technology
It is reported that the degraded of common plasticses needs 200-300, white pollution be present, ecological environment, which is destroyed, etc. asks Topic, and be to solve this problem, degradation plastic arises at the historic moment, and on long terms, Environmental Protection in China consciousness enhancing is domestic degradable The production technology of plastics is reached its maturity, and cost, which is gradually decrease to downstream, can receive scope, and the maturation with each side condition is matched somebody with somebody Close, degradation plastic has more vast potential for future development.
The content of the invention
A kind of Degradable environment-friendlyplastic plastic of the present invention is a kind of plastics of light degradation and microbial combination, and it has light simultaneously And the characteristics of micro-biological degradable plastic, it is easier to degrade in natural environment, can be degraded under natural environmental condition after use The material of environmental sound.
In order to solve the above technical problems, one aspect of the present invention is:Modified starch, cellulose, sensitising agent, PHA polymer, PE synthetic resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30-45, cellulose 3.5-8, sensitising agent 1-5, PHA polymer 2-10, PE synthetic resin 5-10, solubilizer 0.5-3, coupling agent 2-5, the sensitising agent For the organic compound or salt of transition metal.
In a preferred embodiments of the invention, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch 30th, cellulose 3.5, sensitising agent 1, PHA polymer 5, PE synthetic resin 8, solubilizer 0.5, coupling agent 2.
In a preferred embodiments of the invention, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch 35th, cellulose 5, sensitising agent 2, PHA polymer 7, PE synthetic resin 6, solubilizer 1, coupling agent 3.
In a preferred embodiments of the invention, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch 40th, cellulose 6, sensitising agent 4, PHA polymer 9, PE synthetic resin 6, solubilizer 3, coupling agent 5.
In a preferred embodiments of the invention, the PE synthetic resin is ethylene/acrylic acid copolymer, ethylene/vinyl alcohol Copolymer or polyvinyl alcohol.
In a preferred embodiments of the invention, the modified starch is green pea starch.
The beneficial effects of the invention are as follows:Can be with light degradation and microbial combination degradative plastics, it has light and micro- simultaneously The characteristics of biodegradable plastic, it is easier to degrade in natural environment, the influence to environment is reduced to minimum.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation Example is only the part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area All other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
The embodiment of the present invention includes:
A kind of Degradable environment-friendlyplastic plastic, it is characterised in that including:Modified starch, cellulose, sensitising agent, PHA polymer, PE are closed Resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30-45, cellulose 3.5-8, sensitising agent 1-5, PHA polymer 2-10, PE synthetic resin 5-10, solubilizer 0.5-3, coupling agent 2-5, the sensitising agent are organic for transition metal Compound or salt.
Further, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch 30, cellulose 3.5, light Quick dose 1, PHA polymer 5, PE synthetic resin 8, solubilizer 0.5, coupling agent 2.
Further, the mass fraction of the Degradable environment-friendlyplastic plastic each component is the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 35, cellulose 5, sensitising agent 2, PHA polymer 7, PE synthetic resin 6, solubilizer 1, coupling Agent 3.
Further, the mass fraction of the Degradable environment-friendlyplastic plastic each component is the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 40, cellulose 6, sensitising agent 4, PHA polymer 9, PE synthetic resin 6, solubilizer 3, coupling Agent 5.
Further, the PE synthetic resin is ethylene/acrylic acid copolymer, ethylene/vinyl alcohol copolymer or polyethylene Alcohol.
Further, the modified starch is green pea starch.
The beneficial effects of the invention are as follows:A kind of Degradable environment-friendlyplastic plastic, it has light and micro-biological degradable plastic simultaneously Feature, is easier to degrade in natural environment, and the influence to environment is reduced to minimum.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair The equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, similarly it is included in the scope of patent protection of the present invention.

Claims (6)

  1. A kind of 1. Degradable environment-friendlyplastic plastic, it is characterised in that including:Modified starch, cellulose, sensitising agent, PHA polymer, PE Synthetic resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30-45, cellulose 3.5-8, sensitising agent 1- 5th, PHA polymer 2-10, PE synthetic resin 5-10, solubilizer 0.5-3, coupling agent 2-5, the sensitising agent have for transition metal Machine compound or salt.
  2. A kind of 2. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 30, cellulose 3.5, sensitising agent 1, PHA polymer 5, PE synthetic resin 8, solubilizer 0.5, Coupling agent 2.
  3. A kind of 3. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 35, cellulose 5, sensitising agent 2, PHA polymer 7, PE synthetic resin 6, solubilizer 1, coupling Agent 3.
  4. A kind of 4. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 40, cellulose 6, sensitising agent 4, PHA polymer 9, PE synthetic resin 6, solubilizer 3, coupling Agent 5.
  5. A kind of 5. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the PE synthetic resin be ethene/ Acrylic copolymer, ethylene/vinyl alcohol copolymer or polyvinyl alcohol.
  6. 6. a kind of Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the modified starch forms sediment for green pea Powder.
CN201710497156.9A 2017-06-27 2017-06-27 A kind of Degradable environment-friendlyplastic plastic Pending CN107417984A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710497156.9A CN107417984A (en) 2017-06-27 2017-06-27 A kind of Degradable environment-friendlyplastic plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710497156.9A CN107417984A (en) 2017-06-27 2017-06-27 A kind of Degradable environment-friendlyplastic plastic

Publications (1)

Publication Number Publication Date
CN107417984A true CN107417984A (en) 2017-12-01

Family

ID=60426691

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710497156.9A Pending CN107417984A (en) 2017-06-27 2017-06-27 A kind of Degradable environment-friendlyplastic plastic

Country Status (1)

Country Link
CN (1) CN107417984A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109233233A (en) * 2018-08-23 2019-01-18 惠州市顺利包装制品有限公司 A kind of easy breakdown type foamed plastics and production technology
WO2021163778A1 (en) 2020-02-18 2021-08-26 Biopolix Materiais Tecnológicos Ltda - Me Biodegradable, thermoplastic, nanostructured bioresin composition, bioresin obtained and article

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1097775A (en) * 1993-07-19 1995-01-25 成都市柯力化工研究所 Biology and light degradation plastic film
CN1122815A (en) * 1995-08-28 1996-05-22 叶永成 Mother raw material degradable by light or organisms
CN1242390A (en) * 1998-07-16 2000-01-26 吉林省金鹰实业有限责任公司 PE raw material with photo degradable and biodegradable properties
CN1289792A (en) * 2000-09-30 2001-04-04 王集忠 Optically and biologically degradable plastics and its preparing process
CN1631958A (en) * 2004-11-04 2005-06-29 沈阳化工学院 Nano antibacterial and controllable photodegradation and biodegradation polyethylene plastic film and method for preparing same
CN1702110A (en) * 2005-06-15 2005-11-30 沈阳化工学院 Light-degradable and biodegradable nano antibacterial plastics prepared by using waste plastics and process for preparing same
CN103587187A (en) * 2013-05-22 2014-02-19 上海优珀斯材料科技有限公司 Controllable degradation antiadherent film and preparation method
CN104311951A (en) * 2014-10-11 2015-01-28 铜陵市新泰电容电器有限责任公司 Easily degradable environment-friendly metallized film for capacitor
CN105778200A (en) * 2014-12-16 2016-07-20 青岛蓝农谷农产品研究开发有限公司 Heat-insulating, photosensitive and degradable film
CN106750566A (en) * 2016-11-15 2017-05-31 上海大觉包装制品有限公司 Degradation plastic and its packaging bag being made
CN106810838A (en) * 2015-11-27 2017-06-09 青岛城轨交通装备科技有限公司 A kind of degradable preservative film

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1097775A (en) * 1993-07-19 1995-01-25 成都市柯力化工研究所 Biology and light degradation plastic film
CN1122815A (en) * 1995-08-28 1996-05-22 叶永成 Mother raw material degradable by light or organisms
CN1242390A (en) * 1998-07-16 2000-01-26 吉林省金鹰实业有限责任公司 PE raw material with photo degradable and biodegradable properties
CN1289792A (en) * 2000-09-30 2001-04-04 王集忠 Optically and biologically degradable plastics and its preparing process
CN1631958A (en) * 2004-11-04 2005-06-29 沈阳化工学院 Nano antibacterial and controllable photodegradation and biodegradation polyethylene plastic film and method for preparing same
CN1702110A (en) * 2005-06-15 2005-11-30 沈阳化工学院 Light-degradable and biodegradable nano antibacterial plastics prepared by using waste plastics and process for preparing same
CN103587187A (en) * 2013-05-22 2014-02-19 上海优珀斯材料科技有限公司 Controllable degradation antiadherent film and preparation method
CN104311951A (en) * 2014-10-11 2015-01-28 铜陵市新泰电容电器有限责任公司 Easily degradable environment-friendly metallized film for capacitor
CN105778200A (en) * 2014-12-16 2016-07-20 青岛蓝农谷农产品研究开发有限公司 Heat-insulating, photosensitive and degradable film
CN106810838A (en) * 2015-11-27 2017-06-09 青岛城轨交通装备科技有限公司 A kind of degradable preservative film
CN106750566A (en) * 2016-11-15 2017-05-31 上海大觉包装制品有限公司 Degradation plastic and its packaging bag being made

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109233233A (en) * 2018-08-23 2019-01-18 惠州市顺利包装制品有限公司 A kind of easy breakdown type foamed plastics and production technology
WO2021163778A1 (en) 2020-02-18 2021-08-26 Biopolix Materiais Tecnológicos Ltda - Me Biodegradable, thermoplastic, nanostructured bioresin composition, bioresin obtained and article

Similar Documents

Publication Publication Date Title
CN104559087A (en) Controllable bio-based full-degradable mulching film
MX2011011366A (en) Algae-blended compositions for thermoplastic articles.
CN103601961A (en) High strength anti-microbial packaging bag
CN102407644B (en) Biodegradable multilayer composite polyethylene film and preparation method thereof
US11548269B2 (en) Degradable EVOH high-barrier composite film
CN103113659B (en) Environment-friendly type water-saving agricultural mulching film and preparation method for same
CN102002179A (en) Double wall corrugated pipe
CN107417984A (en) A kind of Degradable environment-friendlyplastic plastic
CN103694646A (en) Polyester/thermoplastic starch biodegradable composition and preparation method thereof
CN105295107B (en) A kind of degradable refuse bag and preparation method thereof
CN103044718B (en) A kind of starch-based degradable plastics and preparation method thereof
CN104910499A (en) Environmentally digestible plastic preparation method taking calcium carbonate as filler
CN105906932A (en) Degradable plastic packaging bag
CN103589182A (en) Environment-friendly plastic bag
CN106700359A (en) Water-soluble environment-friendly special material for mulching film
CN1978512A (en) Nano material modified weather-resistance film much
CN101717527A (en) Potato starch degradation plastic product
CN108102203A (en) A kind of Novel mulching film formula
CN105968739A (en) Biomass degradable plastic
CN112980155A (en) High impact plastic film
CN104163944A (en) Composite with good ductility
CN113442533A (en) Degradable polymer composite material, preparation method and food packaging film
Eker et al. Developing flat drip irrigation pipes using bioplastic materials
CN104497400A (en) Agricultural environment-friendly oxygen-insulating degradable thin film
CN104231329A (en) Degradable composite material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171201

RJ01 Rejection of invention patent application after publication