CN107417984A - A kind of Degradable environment-friendlyplastic plastic - Google Patents
A kind of Degradable environment-friendlyplastic plastic Download PDFInfo
- Publication number
- CN107417984A CN107417984A CN201710497156.9A CN201710497156A CN107417984A CN 107417984 A CN107417984 A CN 107417984A CN 201710497156 A CN201710497156 A CN 201710497156A CN 107417984 A CN107417984 A CN 107417984A
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- CN
- China
- Prior art keywords
- degradable environment
- friendlyplastic plastic
- synthetic resin
- modified starch
- solubilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Degradable environment-friendlyplastic plastic, and it is comprised the following raw materials by weight percent:Including:Modified starch, cellulose, sensitising agent, PHA polymer, PE synthetic resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30 45, cellulose 3.5 8, sensitising agent 15, PHA polymer 2 10, PE synthetic resin 5 10, solubilizer 0.5 3, coupling agent 25, the sensitising agent are the organic compound or salt of transition metal.By the above-mentioned means, a kind of a kind of plastics of the Degradable environment-friendlyplastic plastic of the present invention for light degradation and microbial combination, it has the characteristics of light and micro-biological degradable plastic simultaneously, is easier to degrade in natural environment, and the influence to environment is reduced to minimum.
Description
Technical field
The present invention relates to molecular material field, more particularly to a kind of Degradable environment-friendlyplastic plastic.
Background technology
It is reported that the degraded of common plasticses needs 200-300, white pollution be present, ecological environment, which is destroyed, etc. asks
Topic, and be to solve this problem, degradation plastic arises at the historic moment, and on long terms, Environmental Protection in China consciousness enhancing is domestic degradable
The production technology of plastics is reached its maturity, and cost, which is gradually decrease to downstream, can receive scope, and the maturation with each side condition is matched somebody with somebody
Close, degradation plastic has more vast potential for future development.
The content of the invention
A kind of Degradable environment-friendlyplastic plastic of the present invention is a kind of plastics of light degradation and microbial combination, and it has light simultaneously
And the characteristics of micro-biological degradable plastic, it is easier to degrade in natural environment, can be degraded under natural environmental condition after use
The material of environmental sound.
In order to solve the above technical problems, one aspect of the present invention is:Modified starch, cellulose, sensitising agent,
PHA polymer, PE synthetic resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30-45, cellulose
3.5-8, sensitising agent 1-5, PHA polymer 2-10, PE synthetic resin 5-10, solubilizer 0.5-3, coupling agent 2-5, the sensitising agent
For the organic compound or salt of transition metal.
In a preferred embodiments of the invention, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch
30th, cellulose 3.5, sensitising agent 1, PHA polymer 5, PE synthetic resin 8, solubilizer 0.5, coupling agent 2.
In a preferred embodiments of the invention, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch
35th, cellulose 5, sensitising agent 2, PHA polymer 7, PE synthetic resin 6, solubilizer 1, coupling agent 3.
In a preferred embodiments of the invention, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch
40th, cellulose 6, sensitising agent 4, PHA polymer 9, PE synthetic resin 6, solubilizer 3, coupling agent 5.
In a preferred embodiments of the invention, the PE synthetic resin is ethylene/acrylic acid copolymer, ethylene/vinyl alcohol
Copolymer or polyvinyl alcohol.
In a preferred embodiments of the invention, the modified starch is green pea starch.
The beneficial effects of the invention are as follows:Can be with light degradation and microbial combination degradative plastics, it has light and micro- simultaneously
The characteristics of biodegradable plastic, it is easier to degrade in natural environment, the influence to environment is reduced to minimum.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only the part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
All other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
The embodiment of the present invention includes:
A kind of Degradable environment-friendlyplastic plastic, it is characterised in that including:Modified starch, cellulose, sensitising agent, PHA polymer, PE are closed
Resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30-45, cellulose 3.5-8, sensitising agent 1-5,
PHA polymer 2-10, PE synthetic resin 5-10, solubilizer 0.5-3, coupling agent 2-5, the sensitising agent are organic for transition metal
Compound or salt.
Further, the mass fraction of the Degradable environment-friendlyplastic plastic each component is:Modified starch 30, cellulose 3.5, light
Quick dose 1, PHA polymer 5, PE synthetic resin 8, solubilizer 0.5, coupling agent 2.
Further, the mass fraction of the Degradable environment-friendlyplastic plastic each component is the Degradable environment-friendlyplastic plastic each group
Point mass fraction be:Modified starch 35, cellulose 5, sensitising agent 2, PHA polymer 7, PE synthetic resin 6, solubilizer 1, coupling
Agent 3.
Further, the mass fraction of the Degradable environment-friendlyplastic plastic each component is the Degradable environment-friendlyplastic plastic each group
Point mass fraction be:Modified starch 40, cellulose 6, sensitising agent 4, PHA polymer 9, PE synthetic resin 6, solubilizer 3, coupling
Agent 5.
Further, the PE synthetic resin is ethylene/acrylic acid copolymer, ethylene/vinyl alcohol copolymer or polyethylene
Alcohol.
Further, the modified starch is green pea starch.
The beneficial effects of the invention are as follows:A kind of Degradable environment-friendlyplastic plastic, it has light and micro-biological degradable plastic simultaneously
Feature, is easier to degrade in natural environment, and the influence to environment is reduced to minimum.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
The equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, similarly it is included in the scope of patent protection of the present invention.
Claims (6)
- A kind of 1. Degradable environment-friendlyplastic plastic, it is characterised in that including:Modified starch, cellulose, sensitising agent, PHA polymer, PE Synthetic resin, solubilizer, coupling agent, the mass fraction of each component are:Modified starch 30-45, cellulose 3.5-8, sensitising agent 1- 5th, PHA polymer 2-10, PE synthetic resin 5-10, solubilizer 0.5-3, coupling agent 2-5, the sensitising agent have for transition metal Machine compound or salt.
- A kind of 2. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 30, cellulose 3.5, sensitising agent 1, PHA polymer 5, PE synthetic resin 8, solubilizer 0.5, Coupling agent 2.
- A kind of 3. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 35, cellulose 5, sensitising agent 2, PHA polymer 7, PE synthetic resin 6, solubilizer 1, coupling Agent 3.
- A kind of 4. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the Degradable environment-friendlyplastic plastic each group Point mass fraction be:Modified starch 40, cellulose 6, sensitising agent 4, PHA polymer 9, PE synthetic resin 6, solubilizer 3, coupling Agent 5.
- A kind of 5. Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the PE synthetic resin be ethene/ Acrylic copolymer, ethylene/vinyl alcohol copolymer or polyvinyl alcohol.
- 6. a kind of Degradable environment-friendlyplastic plastic according to claim 1, it is characterised in that the modified starch forms sediment for green pea Powder.
Priority Applications (1)
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CN201710497156.9A CN107417984A (en) | 2017-06-27 | 2017-06-27 | A kind of Degradable environment-friendlyplastic plastic |
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CN201710497156.9A CN107417984A (en) | 2017-06-27 | 2017-06-27 | A kind of Degradable environment-friendlyplastic plastic |
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Publication Number | Publication Date |
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CN107417984A true CN107417984A (en) | 2017-12-01 |
Family
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CN201710497156.9A Pending CN107417984A (en) | 2017-06-27 | 2017-06-27 | A kind of Degradable environment-friendlyplastic plastic |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109233233A (en) * | 2018-08-23 | 2019-01-18 | 惠州市顺利包装制品有限公司 | A kind of easy breakdown type foamed plastics and production technology |
WO2021163778A1 (en) | 2020-02-18 | 2021-08-26 | Biopolix Materiais Tecnológicos Ltda - Me | Biodegradable, thermoplastic, nanostructured bioresin composition, bioresin obtained and article |
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CN1097775A (en) * | 1993-07-19 | 1995-01-25 | 成都市柯力化工研究所 | Biology and light degradation plastic film |
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CN1289792A (en) * | 2000-09-30 | 2001-04-04 | 王集忠 | Optically and biologically degradable plastics and its preparing process |
CN1631958A (en) * | 2004-11-04 | 2005-06-29 | 沈阳化工学院 | Nano antibacterial and controllable photodegradation and biodegradation polyethylene plastic film and method for preparing same |
CN1702110A (en) * | 2005-06-15 | 2005-11-30 | 沈阳化工学院 | Light-degradable and biodegradable nano antibacterial plastics prepared by using waste plastics and process for preparing same |
CN103587187A (en) * | 2013-05-22 | 2014-02-19 | 上海优珀斯材料科技有限公司 | Controllable degradation antiadherent film and preparation method |
CN104311951A (en) * | 2014-10-11 | 2015-01-28 | 铜陵市新泰电容电器有限责任公司 | Easily degradable environment-friendly metallized film for capacitor |
CN105778200A (en) * | 2014-12-16 | 2016-07-20 | 青岛蓝农谷农产品研究开发有限公司 | Heat-insulating, photosensitive and degradable film |
CN106750566A (en) * | 2016-11-15 | 2017-05-31 | 上海大觉包装制品有限公司 | Degradation plastic and its packaging bag being made |
CN106810838A (en) * | 2015-11-27 | 2017-06-09 | 青岛城轨交通装备科技有限公司 | A kind of degradable preservative film |
-
2017
- 2017-06-27 CN CN201710497156.9A patent/CN107417984A/en active Pending
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1097775A (en) * | 1993-07-19 | 1995-01-25 | 成都市柯力化工研究所 | Biology and light degradation plastic film |
CN1122815A (en) * | 1995-08-28 | 1996-05-22 | 叶永成 | Mother raw material degradable by light or organisms |
CN1242390A (en) * | 1998-07-16 | 2000-01-26 | 吉林省金鹰实业有限责任公司 | PE raw material with photo degradable and biodegradable properties |
CN1289792A (en) * | 2000-09-30 | 2001-04-04 | 王集忠 | Optically and biologically degradable plastics and its preparing process |
CN1631958A (en) * | 2004-11-04 | 2005-06-29 | 沈阳化工学院 | Nano antibacterial and controllable photodegradation and biodegradation polyethylene plastic film and method for preparing same |
CN1702110A (en) * | 2005-06-15 | 2005-11-30 | 沈阳化工学院 | Light-degradable and biodegradable nano antibacterial plastics prepared by using waste plastics and process for preparing same |
CN103587187A (en) * | 2013-05-22 | 2014-02-19 | 上海优珀斯材料科技有限公司 | Controllable degradation antiadherent film and preparation method |
CN104311951A (en) * | 2014-10-11 | 2015-01-28 | 铜陵市新泰电容电器有限责任公司 | Easily degradable environment-friendly metallized film for capacitor |
CN105778200A (en) * | 2014-12-16 | 2016-07-20 | 青岛蓝农谷农产品研究开发有限公司 | Heat-insulating, photosensitive and degradable film |
CN106810838A (en) * | 2015-11-27 | 2017-06-09 | 青岛城轨交通装备科技有限公司 | A kind of degradable preservative film |
CN106750566A (en) * | 2016-11-15 | 2017-05-31 | 上海大觉包装制品有限公司 | Degradation plastic and its packaging bag being made |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109233233A (en) * | 2018-08-23 | 2019-01-18 | 惠州市顺利包装制品有限公司 | A kind of easy breakdown type foamed plastics and production technology |
WO2021163778A1 (en) | 2020-02-18 | 2021-08-26 | Biopolix Materiais Tecnológicos Ltda - Me | Biodegradable, thermoplastic, nanostructured bioresin composition, bioresin obtained and article |
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Application publication date: 20171201 |
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