CN108047542A - A kind of Environment protection mulch film formula - Google Patents

A kind of Environment protection mulch film formula Download PDF

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Publication number
CN108047542A
CN108047542A CN201711382341.XA CN201711382341A CN108047542A CN 108047542 A CN108047542 A CN 108047542A CN 201711382341 A CN201711382341 A CN 201711382341A CN 108047542 A CN108047542 A CN 108047542A
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CN
China
Prior art keywords
parts
microwax
environment protection
ethylene
mulch film
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Pending
Application number
CN201711382341.XA
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Chinese (zh)
Inventor
仲伟嫱
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Jiangsu Tianheng Nano Science And Technology Co Ltd
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Jiangsu Tianheng Nano Science And Technology Co Ltd
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Priority to CN201711382341.XA priority Critical patent/CN108047542A/en
Publication of CN108047542A publication Critical patent/CN108047542A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2403/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2403/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2479/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
    • C08J2479/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2479/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/132Phenols containing keto groups, e.g. benzophenones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/20Carboxylic acid amides

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of Environment protection mulch film formulas, it is characterised in that:Including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, 23 parts of polypropylene, 7 parts of Arabic gum, 2, 43 parts of dihydroxy benaophenonels, 2, 2, 6, 3 parts of 6 tetramethyl, 4 piperidyl, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amides, 1 part of microwax poly butylene succinate, 2 parts of microwax, N, 3 parts of N ethylene bis stearamides, 1 part of talcum powder, 25 35 parts of pulullan polysaccharide, 10 30 parts of ethylene-vinyl alcohol copolymer, 13 parts of tartaric acid, 15 parts of calcium stearate, 10 20 parts of polyimides, 46 parts of cedar wood oil, 0.5 2 parts of ultra-violet absorber;The ground film quality that this formula makes is good, and production cost is low, and mulch has stronger anti-ultraviolet property, resistance to low temperature, high mechanical performance and antistatic property, and degradation speed is fast, environmentally safe.

Description

A kind of Environment protection mulch film formula
Technical field
The present invention relates to Environment protection mulch film formulation art more particularly to a kind of Environment protection mulch film formulas.
Background technology
China's plastic industry generally uses existing plastic film national standard at present.The standard is at the beginning of formulation due to China All many factors limitations such as agricultural economy condition are, it is specified that " mulch " minimum thickness calibration is 0.008mm;Covering is recommended to use Time is -120 days 50 days.Traditional plastic film there are it is one very big the shortcomings that --- difficult degradation.And since this is lacked Point so that traditional plastic film also can continue development to agricultural and bring serious harm while large-scale application. In addition partly plastic manufacturing enterprise reduces modeling again and again in order to cater to the psychology that peasant household blindly reduces overlay film cost and pursues economic benefit Expect mulch inherent quality and thickness, many plastic films is caused to occur as soon as season cracking phenomenon using less than two months.Degradable Environment-friendly type plastic mulch by be from now on Farm mulch research Main way.Plastic film is early when treating one batch of crop maturity Incoherent, unrestrained Tian Tian all over the fields, can not accomplish effectively to recycle at all.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of Environment protection mulch films.
In order to solve the above technical problems, the technical scheme is that:A kind of Environment protection mulch film formula, innovative point are: Including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, 23 parts of polypropylene, 7 parts of Arabic gum, 2, 3 parts of 4- dihydroxy benaophenonels, 2,2,6,6- 3 parts of tetramethyl -4- piperidyls, 4 parts of polyvinyl alcohol, organic carboxyl acid acyl 5 parts of amine, microwax poly-succinic -1 part of butanediol ester, 2 parts, N of microwax, 3 parts of N- ethylene bis stearamides, talcum powder 1 part, 25-35 parts of pulullan polysaccharide, 10-30 parts of ethylene-vinyl alcohol copolymer, 1-3 parts of tartaric acid, 1-5 parts of calcium stearate, gather 10-20 parts of acid imide, 4-6 parts of cedar wood oil, 0.5-2 parts of ultra-violet absorber.
The advantage of the invention is that:
1)The initial mechanical intensity of Environment protection mulch film of the present invention is high, and durability is good, and degradation speed is fast, each functional, is not easy to soil Earth damages, and the ground film quality that this formula makes is good, and production cost is low, and mulch has stronger anti-ultraviolet property, resistance to low Warm nature energy, high mechanical performance and antistatic property, and degradation speed is fast, it is environmentally safe.
Specific embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among the embodiment described scope.
Embodiment 1:
A kind of Environment protection mulch film formula, including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, polypropylene 23 parts, 7 parts of Arabic gum, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- 3 parts of tetramethyl -4- piperidyls, gather 4 parts of vinyl alcohol, 5 parts of organic carboxyl acid amides, microwax poly-succinic -1 part of butanediol ester, 2 parts, N, N- ethylenes of microwax are double 3 parts of stearmide, 1 part of talcum powder, 25 parts of pulullan polysaccharide, 10 parts of ethylene-vinyl alcohol copolymer, 1 part of tartaric acid are stearic Sour 1 part of calcium, 10 parts of polyimides, 4 parts of cedar wood oil, 0.5 part of ultra-violet absorber.
Embodiment 2:
A kind of Environment protection mulch film formula, including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, polypropylene 23 parts, 7 parts of Arabic gum, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- 3 parts of tetramethyl -4- piperidyls, gather 4 parts of vinyl alcohol, 5 parts of organic carboxyl acid amides, microwax poly-succinic -1 part of butanediol ester, 2 parts, N, N- ethylenes of microwax are double 3 parts of stearmide, 1 part of talcum powder, 30 parts of pulullan polysaccharide, 20 parts of ethylene-vinyl alcohol copolymer, 2 parts of tartaric acid are stearic Sour 3 parts of calcium, 15 parts of polyimides, 5 parts of cedar wood oil, 1.8 parts of ultra-violet absorber.
Embodiment 3:
A kind of Environment protection mulch film formula, including following component, 50 parts of linear low density polyethylene, 10 parts of cornstarch, polypropylene 23 parts, 7 parts of Arabic gum, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- 3 parts of tetramethyl -4- piperidyls, gather 4 parts of vinyl alcohol, 5 parts of organic carboxyl acid amides, microwax poly-succinic -1 part of butanediol ester, 2 parts, N, N- ethylenes of microwax are double 3 parts of stearmide, 1 part of talcum powder, 35 parts of pulullan polysaccharide, 30 parts of ethylene-vinyl alcohol copolymer, 3 parts of tartaric acid are stearic Sour 5 parts of calcium, 20 parts of polyimides, 6 parts of cedar wood oil, 2 parts of ultra-violet absorber.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention It is defined by the appending claims and its equivalent thereof.

Claims (1)

1. a kind of Environment protection mulch film formula, it is characterised in that:Including following component, 50 parts of linear low density polyethylene, corn forms sediment 10 parts of powder, 23 parts of polypropylene, 7 parts of Arabic gum, 2,4- 3 parts of dihydroxy benaophenonels, 2,2,6,6- tetramethyl -4- 3 parts of piperidyl, 4 parts of polyvinyl alcohol, 5 parts of organic carboxyl acid amides, microwax poly-succinic -1 part of butanediol ester, microwax 2 Part, N, 3 parts of N- ethylene bis stearamides, 1 part of talcum powder, 25-35 parts of pulullan polysaccharide, ethylene-vinyl alcohol copolymer 10-30 parts, 1-3 parts of tartaric acid, 1-5 parts of calcium stearate, 10-20 parts of polyimides, 4-6 parts of cedar wood oil, ultra-violet absorber 0.5-2 parts.
CN201711382341.XA 2017-12-20 2017-12-20 A kind of Environment protection mulch film formula Pending CN108047542A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711382341.XA CN108047542A (en) 2017-12-20 2017-12-20 A kind of Environment protection mulch film formula

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711382341.XA CN108047542A (en) 2017-12-20 2017-12-20 A kind of Environment protection mulch film formula

Publications (1)

Publication Number Publication Date
CN108047542A true CN108047542A (en) 2018-05-18

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Application Number Title Priority Date Filing Date
CN201711382341.XA Pending CN108047542A (en) 2017-12-20 2017-12-20 A kind of Environment protection mulch film formula

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108727680A (en) * 2018-06-14 2018-11-02 江苏天成生化制品有限公司 A kind of Fast-degradation mulch film formula

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108727680A (en) * 2018-06-14 2018-11-02 江苏天成生化制品有限公司 A kind of Fast-degradation mulch film formula

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Application publication date: 20180518