CN107978656A - A kind of thin-film solar cells film-removing technology and thin-film solar cells - Google Patents

A kind of thin-film solar cells film-removing technology and thin-film solar cells Download PDF

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Publication number
CN107978656A
CN107978656A CN201711238320.0A CN201711238320A CN107978656A CN 107978656 A CN107978656 A CN 107978656A CN 201711238320 A CN201711238320 A CN 201711238320A CN 107978656 A CN107978656 A CN 107978656A
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CN
China
Prior art keywords
film
thin
solar cells
film solar
layer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711238320.0A
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Chinese (zh)
Inventor
苏育家
张学良
林健
林俊荣
施栓林
席峰
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Beijing Apollo Ding Rong Solar Technology Co Ltd
Original Assignee
Beijing Apollo Ding Rong Solar Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Beijing Apollo Ding Rong Solar Technology Co Ltd filed Critical Beijing Apollo Ding Rong Solar Technology Co Ltd
Priority to CN201711238320.0A priority Critical patent/CN107978656A/en
Priority to PCT/CN2017/117926 priority patent/WO2019104791A1/en
Publication of CN107978656A publication Critical patent/CN107978656A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B27/00Other grinding machines or devices
    • B24B27/0076Other grinding machines or devices grinding machines comprising two or more grinding tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B9/00Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor
    • B24B9/02Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground
    • B24B9/06Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground of non-metallic inorganic material, e.g. stone, ceramics, porcelain
    • B24B9/08Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground of non-metallic inorganic material, e.g. stone, ceramics, porcelain of glass
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/02002Arrangements for conducting electric current to or from the device in operations
    • H01L31/02005Arrangements for conducting electric current to or from the device in operations for device characterised by at least one potential jump barrier or surface barrier
    • H01L31/02008Arrangements for conducting electric current to or from the device in operations for device characterised by at least one potential jump barrier or surface barrier for solar cells or solar cell modules
    • H01L31/02013Arrangements for conducting electric current to or from the device in operations for device characterised by at least one potential jump barrier or surface barrier for solar cells or solar cell modules comprising output lead wires elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a kind of thin-film solar cells film-removing technology and thin-film solar cells, by being removed and the relevant position of molybdenum layer, cigs layer, tco layer to base plate glass progress edging processing at same station, so that there are leakage Mo regions in base plate glass edge, so as to facilitate welding electrode lead-out wire.The film-removing technology process of the present invention is simple so that the thin-film solar cells cost of making is relatively low.

Description

A kind of thin-film solar cells film-removing technology and thin-film solar cells
Technical field
The present invention relates to thin-film solar cells manufacture field, more particularly to a kind of thin-film solar cells film-removing technology and Thin-film solar cells.
Background technology
Thin-film solar cells is the future trend of photovoltaic generation, is particularly lifted with the further of component efficiency, Flexibility, filming will be increasingly becoming the emerging developing direction of photovoltaic market.The advantage of thin-film solar cells is:Without dirt Dye, low energy consumption, have wide range of applications.Thin-film solar cells material has a clear superiority in terms of temperature coefficient, dim light power generation, Thin film solar cell technologies also have very big room for promotion and development potentiality.Great promising thin film solar cell technologies Based on semiconductor Cu (In, Ga) Se2, CIGS is abbreviated as, it has the high efficiency confirmed and work persistence.Typical CIGS is too Positive energy battery includes the glass substrate 1, the Mo back electrode layers 2 that thickness is 0.5-1 μm, 1.5-2 μm of cigs layer that thickness is 2-3mm 3rd, thickness is the CdS cushions and 0.5-1 μm of ZnO Window layers 5 of 50nm.Optional second buffer layer 6 can be located at CdS cushions Between Window layer, and the thickness with 50nm.
Cigs layer is p- conductions Cu (In, Ga) (Se, S) 2 compound.CdS cushions are used as the protection of cigs layer.Window layer For n-type conductiving doping zinc oxide film.It and cigs layer form pn- and tie and be used as transparent front contact.Optional second buffer layer bag Include undoped ZnO.Statistically observe, compared with the battery with single ZnO layer, there is the solar energy of this second buffer layer Battery shows better performance.
In order to be reliably achieved the electric insulation of solar cell module and sealing, the glass of Thinfilm solar cell assembly All film layers of the glass substrate top in outer region will be usually completely removed in so-called " edge removal " operation. Laser ablation, blasting treatment and grinding are the edge minimizing technologies used at present.Edge is removed so that being obtained in outer edge area To the possibility that is sealed to of glass, the film layer of corrosion solar cell module can be so prevented.Electric insulation is also anti-leak-stopping Necessary to electricity and short circuit.
Moreover, edge goes to be typically to contact after division operation, that is, using such as conducting resinl and copper bar, can be by cable Stacking, cooperation and the installation for the terminal box being connected thereto carry out the so-called of solar cell the top conductive layer (front contact) " overlapping edges ".So-called " wiring " for example can be directed to wiring by the hole that is drilled out in substrate or by substrate edges Box.
Complicated edge removes and overlapping edges operation is very for making reliable thin-film solar cells equipment Important factor.The development need of current thin film solar cell device has high yield to obtain low cost, the high-performance sun Effective technique of energy battery apparatus.Means for reducing cost include the surface area of increase solar cell module.Therefore, exist Keep or also require edge to remove the high removal rate in division operation while preferably improving precision and cleannes.If until connecing The residue from edge removal step is still left on solar cell module, then final solar cell when touching and being laminated The durability and performance of equipment will may be decreased obviously.Therefore usually it is required for extending process time and limits output clear Clean operation.In addition, the dust from process operation is probably to have harm, it is therefore desirable to safely collects and is pocessed.
Each film layer is handled therefore, it is necessary to a kind of technique so that the appearance leakage Mo regions at base plate glass edge, weldering Receiving electrode lead-out wire.The side of present process generally point three steps in existing technology, first step laser or sandblasting Method removes all film layers at edge;Second step, the film layers such as CIGS and TCO are removed, leave Mo layers with the mode of scraper;3rd Step, round edge is worn into edge polisher by base plate glass edge.
But the treatment process of the prior art is complex, inconvenient, largely effects on work efficiency.
The content of the invention
It is existing to solve the object of the present invention is to provide a kind of thin-film solar cells film-removing technology and thin-film solar cells There is the problem of in technology so that leakage Mo regions occurs in base plate glass edge.
On the one hand, the present invention provides a kind of thin-film solar cells film-removing technology, comprise the following steps:
Using the first film removing device remove molybdenum layer above the base plate glass of thin-film solar cells in the first outer edge area, Cigs layer, tco layer;
Cigs layer, tco layer in the second outer edge area above the molybdenum layer are removed using the second film removing device.
Preferably, the thin-film solar cells film-removing technology further includes:
Using edging device, fillet is worn into at the edge of the base plate glass.
Preferably, first film removing device and edging device include emery wheel group, second film removing device includes Scraper group.
Preferably, the first outer edge area width is 12mm, the second outer edge area width is 4mm.
Preferably, the roughness of the emery wheel of first film removing device is less than the roughness of the emery wheel of edging device.
Preferably, the emery wheel rotating speed is 4000-6000 revs/min.
Preferably, the length direction of second outer edge area is parallel with the long axis direction of thin-film solar cells.
Preferably, the thin-film solar cells film-removing technology, further includes refine/pre-shaping step.
On the other hand, the present invention also provides a kind of thin-film solar cells, the thin-film solar cells to include substrate glass Glass, molybdenum layer, cigs layer, the tco layer being arranged on base plate glass, and be arranged on the electrode of the second outer edge area above molybdenum layer and draw Outlet, the molybdenum layer, cigs layer, tco layer are handled by the thin-film solar cells film-removing technology.
Preferably, the edge of the base plate glass carries out rounding side processing.
Preferably, rounding side processing is carried out to the edge of base plate glass by edging device.
Preferably, the edging device includes emery wheel group, and emery wheel has arc-shaped surface, and the arc-shaped surface can be with base The corner angle of the opposite sides at the edge of glass sheet contact at the same time.
Thin-film solar cells film-removing technology provided by the invention and thin-film solar cells, by molybdenum layer, cigs layer, The relevant position of tco layer is removed so that leakage Mo regions occurs in base plate glass edge, so as to facilitate welding electrode lead-out wire; The film-removing technology process of the present invention is simple, easy to operate so that the thin-film solar cells cost of making is relatively low, and can improve work Make efficiency.
Brief description of the drawings
Fig. 1 is the structure diagram of thin-film solar cells provided in an embodiment of the present invention;
Fig. 2 is the membrane removal state diagram for the thin-film solar cells that further embodiment of this invention provides;
Fig. 3 is the edging state diagram for the thin-film solar cells that further embodiment of this invention provides.
Description of reference numerals:
1- base plate glass, 2- molybdenum layers, 3-CIGS layers, 4-TCO layers, the first film removing devices of 5-, 6- edging devices, 7- electrodes draw Outlet.
Embodiment
The embodiment of the present invention is described below in detail, the example of the embodiment is shown in the drawings, wherein from beginning to end Same or similar label represents same or similar element or has the function of same or like element.Below with reference to attached The embodiment of figure description is exemplary, and is only used for explaining the present invention, and is not construed as limiting the claims.
Embodiment one
An embodiment of the present invention provides a kind of thin-film solar cells film-removing technology, comprise the following steps:
Removed using the first film removing device 5 in first outer edge area of the top of base plate glass 1 of the thin-film solar cells Molybdenum layer 2, cigs layer 3, tco layer 4;
Cigs layer 3, tco layer 4 in second outer edge area of the top of molybdenum layer 2 are removed using the second film removing device.
Wherein, as shown in Figure 1, also can be found in Fig. 2, cigs layer 3 refers to by Cu (copper), In (indium), Ga (gallium), Se (selenium) four Kind element forms the chalcopyrite crystalline film of optimal proportion, and tco layer 4 refers to transparent conductive oxide film (Transparent Conductive Oxide), first outer edge area of the top of base plate glass 1, refers specifically to base plate glass 1 and scribbles The edge region of film layer side, and second outer edge area of the top of molybdenum layer 2, refer specifically to the upper area of 2 end of molybdenum layer, It is used for the leakage Mo regions for placing electrode outlet line 7.
Thin-film solar cells film-removing technology provided by the invention and thin-film solar cells, by molybdenum layer 2, cigs layer 3rd, the relevant position of tco layer 4 is removed so that leakage Mo regions occurs in 1 edges at two ends of base plate glass, so as to facilitate welding electrode Lead-out wire 7;The film-removing technology process of the present invention is simple, easy to operate so that and the thin-film solar cells cost of making is relatively low, and Work efficiency can be improved.
Preferably, the first outer edge area width is 12mm, the second outer edge area width is 4mm.As excellent Choosing, the length direction of second outer edge area are parallel with the long axis direction of thin-film solar cells.
Wherein, as shown in Figure 1, the length direction of the second outer edge area and the long axis direction of thin-film solar cells are each meant Perpendicular to the direction of paper in the longitudinal direction of thin-film solar cells, i.e. Fig. 1, the second outer edge area is used to place electrode outlet line 7.
As shown in figure 3, preferably, the thin-film solar cells film-removing technology further includes:Using edging device 6, Fillet is worn into at the edge of the base plate glass 1.Preferably, as shown in Fig. 2, first film removing device 5 and edging device 6 Include emery wheel group, and the first film removing device and edging device be at same station, while or successively carry out membrane removal and edging step Suddenly.Second film removing device includes scraper group.Preferably, the roughness of the emery wheel of first film removing device 5 is less than mill The roughness of the emery wheel of side device 6.Preferably, the emery wheel rotating speed is 4000-6000 revs/min.
Wherein, the emery wheel in the first film removing device 5 is used to remove molybdenum layer, cigs layer, tco layer, and edging device 6 In emery wheel be used to wear into fillet to the edge of base plate glass 1, emery wheel has arc-shaped surface, and arc-shaped surface can be with base plate glass 1 The corner angle of opposite sides at edge contact at the same time, enabling while edging is carried out to two opposite edges of base plate glass 1, greatly It is big to improve work efficiency;According to the difference of actual process requirement, the roughness that can set the emery wheel of the first film removing device 5 is less than mill The roughness of the emery wheel of side device 6, but skilled person will appreciate that, the roughness and rotating speed of emery wheel are not specifically limited, Flexibly set according to actual conditions;In addition, the cigs layer 3, tco layer 4 above 2 both ends of molybdenum layer generally by scraper at Reason, scraper sheet is easy to operate for membrane removal as the prior art, and is not easy to produce additional injury to molybdenum layer 2.
Preferably, the thin-film solar cells film-removing technology, further includes refine/pre-shaping step.Wherein, to battery After carrying out process above processing, refine/pre-shaping step can be also carried out, such as base plate glass 1 and each film layer are polished and beaten The processing such as mill.
Embodiment two
Another embodiment of the present invention provides a kind of thin-film solar cells, and the thin-film solar cells includes substrate glass Glass 1, molybdenum layer 2, cigs layer 3, the tco layer 4 being arranged on base plate glass 1, and it is arranged on second outer edge area of the top of molybdenum layer 2 Electrode outlet line, the molybdenum layer 2, cigs layer 3, tco layer 4 by above-described thin-film solar cells film-removing technology at Reason.
Preferably, as shown in figure 3, the edge of the base plate glass 1 carries out rounding side processing.Preferably, pass through mill The processing when device 6 carries out rounding to the edge of base plate glass 1.Preferably, the edging device 6 includes emery wheel group, and grind Wheel has arc-shaped surface, and the arc-shaped surface can contact at the same time with the corner angle of the opposite sides at the edge of base plate glass 1.
Wherein, the edges at two ends of base plate glass 1 is generally angular, easily produces damage, does not also meet production requirement, because This needs is processed to, and in the embodiment of the present invention, rounding is carried out by edging device 6, and edging device 6 has arc-shaped surface, Arc-shaped surface can contact at the same time with the corner angle of the opposite sides at the edge of base plate glass 1, you can realize at the same time to the corner angle of both sides Realize rounding, improve efficiency;Certainly, skilled person will appreciate that, edging device 6 does not limit its shape, as long as can be to corner angle Contact simultaneously rounding.
Embodiment three
In the thin-film solar cells of the embodiment of the present invention, base plate glass 1 need to only be handled two corner angle of one side edge Into round edge;In practical operation, by the emery wheel group of the first film removing device 5 by first outer edge area of the top of base plate glass 1 Molybdenum layer 2, cigs layer 3, tco layer 4 remove, and two corner angle of the emery wheel group mill one side edge with edging device 6, two above Process can be carried out at the same time.
Example IV
Thin-film solar cells in the embodiment of the present invention, be big panel battery, four of 1 both sides of the edge of base plate glass Corner angle are both needed to be processed into round edge, and membrane removal processing is first carried out in the first step, afterwards at same station, reuse edging dress Put 6 carry out edging processing.
The present invention by realizing membrane removal to each film layer, meanwhile, realize and base plate glass 1 is realized at same station grind Side, simplifies processing step, and reduces process costs.
The structure, feature and effect of the present invention, above institute are described in detail based on the embodiments shown in the drawings Only presently preferred embodiments of the present invention is stated, but the present invention is not to limit practical range shown in drawing, it is every according to structure of the invention Want made change, or be revised as the equivalent embodiment of equivalent variations, when not going beyond the spirit of the description and the drawings, Should all be within the scope of the present invention.

Claims (12)

1. a kind of thin-film solar cells film-removing technology, it is characterised in that comprise the following steps:
Molybdenum layer, the CIGS above the base plate glass of thin-film solar cells in the first outer edge area are removed using the first film removing device Layer, tco layer;
Cigs layer, tco layer in the second outer edge area above the molybdenum layer are removed using the second film removing device.
2. thin-film solar cells film-removing technology according to claim 1, it is characterised in that the thin-film solar cells Film-removing technology further includes:
Using edging device, fillet is worn into at the edge of the base plate glass.
3. thin-film solar cells film-removing technology according to claim 2, it is characterised in that first film removing device and Edging device includes emery wheel group, and second film removing device includes scraper group.
4. thin-film solar cells film-removing technology according to claim 1, it is characterised in that first rim area field width It is 4mm to spend for 12mm, the second outer edge area width.
5. thin-film solar cells film-removing technology according to claim 3, it is characterised in that first film removing device The roughness of emery wheel is less than the roughness of the emery wheel of edging device.
6. thin-film solar cells film-removing technology according to claim 5, it is characterised in that the emery wheel rotating speed is 4000-6000 revs/min.
7. thin-film solar cells film-removing technology according to claim 1, it is characterised in that second outer edge area Length direction is parallel with the long axis direction of thin-film solar cells.
8. thin-film solar cells film-removing technology according to claim 1, it is characterised in that the thin-film solar cells Film-removing technology, further includes refine/pre-shaping step.
9. a kind of thin-film solar cells, the thin-film solar cells includes base plate glass, the molybdenum being arranged on base plate glass Layer, cigs layer, tco layer, and it is arranged on the electrode outlet line of the second outer edge area above molybdenum layer, it is characterised in that the molybdenum Layer, cigs layer, tco layer are handled by claim 1-8 any one of them thin-film solar cells film-removing technologies.
10. thin-film solar cells according to claim 9, it is characterised in that ground at the edge of the base plate glass Round edge processing.
11. thin-film solar cells according to claim 10, it is characterised in that by edging device to base plate glass Edge carries out rounding side processing.
12. thin-film solar cells according to claim 11, it is characterised in that the edging device includes emery wheel group, And emery wheel has arc-shaped surface, the arc-shaped surface can contact at the same time with the corner angle of the opposite sides at the edge of base plate glass.
CN201711238320.0A 2017-11-30 2017-11-30 A kind of thin-film solar cells film-removing technology and thin-film solar cells Pending CN107978656A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201711238320.0A CN107978656A (en) 2017-11-30 2017-11-30 A kind of thin-film solar cells film-removing technology and thin-film solar cells
PCT/CN2017/117926 WO2019104791A1 (en) 2017-11-30 2017-12-22 Film solar cell film removal process and film solar cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711238320.0A CN107978656A (en) 2017-11-30 2017-11-30 A kind of thin-film solar cells film-removing technology and thin-film solar cells

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Application publication date: 20180501