CN107974832A - 一种聚酯帘子线的浸胶液配方 - Google Patents

一种聚酯帘子线的浸胶液配方 Download PDF

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CN107974832A
CN107974832A CN201711338102.4A CN201711338102A CN107974832A CN 107974832 A CN107974832 A CN 107974832A CN 201711338102 A CN201711338102 A CN 201711338102A CN 107974832 A CN107974832 A CN 107974832A
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石杰
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Shz Advanced Belting Fabric Group
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

一种聚酯帘子线的浸胶液配方，其特征是，包括第一浴配方、第二浴配方，所述第一浴配方为：己内酰胺封闭异氰酸酯40‑80重量份、RF树脂45‑65重量份、软水300‑600重量份；所述RF树脂的配方为：软水60‑90重量份、氢氧化钠0.3‑4.5重量份、间苯二酚固体1.8‑6.6重量份、甲醛6‑12重量份；所述第二浴配方为：RF树脂湿重为100‑180重量份、乙烯基吡啶胶乳湿重为200‑280重量份、氨水为11‑18重量份、软水60‑100重量份。本发明具有抗高温、抗酸碱、高耐磨的优点，提升了浸胶液的性能。

Description

一种聚酯帘子线的浸胶液配方
技术领域
本发明涉及一种浸胶液的配方，尤其是一种聚酯帘子线的浸胶液配方，属于工业用布技术领域。
背景技术
聚酯产业用纺织品采用聚酯工业丝作为主要原料，聚酯工业丝以其高强度、高模量、耐高温等优异性能已成为产业用纺织品的主要原材料，机械橡胶制品—橡胶输送带、传动带、橡胶胶管所必须的骨架材料，目前已经基本聚酯化。聚酯材料的熔点在264℃，具有良好的耐热性能，因此聚酯浸胶帆布已经普遍替代早先的棉帆布，各类耐高温输送带的应用领域里显示了其强大的优势。
浸胶是织物通过胶液浸槽，使织物纤维浸上胶浆，以提高织物与胶料的熟结力。浸胶可使人造丝、合成纤维及玻璃纤维帘线表面光滑，浸胶浆后可显著提高胶料与纤维的勃着力。常用的浸液为天然乳胶与间苯二酚甲醛树脂相配合的水乳液。役胶设备包括役渍槽、干燥室、热仲张及卷取装置，也可与压延机连接，组成帝布浸胶、贴胶、擦胶联动生产线。浸胶液可提高橡胶与玻璃纤维的私着力，棉帘布经浸酚醛胶乳，也能显著提高轮胎的耐用性能。但是，现有的浸胶液在提高织布纤维的耐热、耐腐、耐压性能方面亟待改善。
发明内容
本发明的目的是针对上述现有技术的不足，提高一种聚酯帘子线的浸胶液配方，以改善工业用布的耐热、耐腐、耐压以及耐疲劳性能。
本发明的技术方案如下：一种聚酯帘子线的浸胶液配方，其特征是，包括第一浴配方、第二浴配方，所述第一浴配方为：己内酰胺封闭异氰酸酯40-80重量份、RF树脂45-65重量份、软水300-600重量份；所述RF树脂的配方为：软水60-90重量份、氢氧化钠0.3-4.5重量份、间苯二酚固体1.8-6.6重量份、甲醛6-12重量份；所述第二浴配方为：RF树脂湿重为100-180重量份、乙烯基吡啶胶乳湿重为200-280重量份、氨水为11-18重量份、软水60-100重量份。
所述氨水的质量分数为0.28。
所述乙烯基吡啶胶乳的质量分数为0.41。
所述甲醛的浓度为37%。
乙烯基吡啶胶乳无色至黄色液体，遇光、受热发生聚合，贮存时常加0.1%-0.2%的对苯二酚作为阻聚剂。主要用作有机合成中间体和聚合物的单体。应用于功能性高分子、表面活性剂、抗静电剂、感光性树脂、涂料、医药、农药等许多方面。由乙基吡啶脱氢而制得。
间苯二酚主要用于橡胶粘合剂、合成树脂、染料、防腐剂、医药和分析试剂等主面，间苯二酚具有杀菌作用，可用作防腐剂，添中于化妆品和皮肤病药物糊剂及软膏等。与甲醛生成缩聚物，可用于制粘胶丝及尼龙用的轮胎帘子线粘结剂，制备木材胶合剂，用于乙烯基材料与金属的粘合，间苯二酚是许多偶氮染料、毛皮染料的中间体，也是医药中间体对氮基水杨酸的原料。甲醛分子中有醛基生缩聚反应，可以得到酚醛树脂。
本发明中的胶乳可在纤维表面形成胶膜，靠分子间力和化学键合起粘合作用。与现有技术相比，采用本发明的浸胶配方生产的浸胶工业用布，具有浸胶层的高温老化性能好、使用寿命长等特点，本发明通过在原料中加入乳胶，使浸渍在工业布上的浸胶液表面快速形成一层薄膜，该层薄膜可以起到耐热、耐腐、耐磨作用，保证浸胶液与工业布表面的粘合性能。本发明具有抗高温、抗酸碱、高耐磨的优点，提升了浸胶液的性能。
具体实施方式
实施例1
一种聚酯帘子线的浸胶液配方，包括第一浴配方、第二浴配方，所述第一浴配方为：己内酰胺封闭异氰酸酯40-80重量份、RF树脂45-65重量份、软水300-600重量份；所述RF树脂的配方为：软水60-90重量份、氢氧化钠0.3-4.5重量份、间苯二酚固体1.8-6.6重量份、甲醛6-12重量份；所述第二浴配方为：RF树脂湿重为100-180重量份、乙烯基吡啶胶乳湿重为200-280重量份、氨水为11-18重量份、软水60-100重量份。
氨水的质量分数为0.28,乙烯基吡啶胶乳的质量分数为0.41,甲醛的浓度为37%。
实施例2
一种聚酯帘子线的浸胶液配方，包括第一浴配方、第二浴配方，所述第一浴配方为：己内酰胺封闭异氰酸酯80重量份、RF树脂65重量份、软水600重量份；所述RF树脂的配方为：软水90重量份、氢氧化钠4.5重量份、间苯二酚固体6.6重量份、甲醛12重量份；所述第二浴配方为：RF树脂湿重为180重量份、乙烯基吡啶胶乳湿重为280重量份、氨水为18重量份、软水100重量份。
氨水的质量分数为0.28,乙烯基吡啶胶乳的质量分数为0.41,甲醛的浓度为37%。
实施例3
一种聚酯帘子线的浸胶液配方，包括第一浴配方、第二浴配方，所述第一浴配方为：己内酰胺封闭异氰酸酯40重量份、RF树脂45重量份、软水300重量份；所述RF树脂的配方为：软水60重量份、氢氧化钠0.3重量份、间苯二酚固体1.8重量份、甲醛6重量份；所述第二浴配方为：RF树脂湿重为100重量份、乙烯基吡啶胶乳湿重为200重量份、氨水为11重量份、软水60重量份。
氨水的质量分数为0.28,乙烯基吡啶胶乳的质量分数为0.41,甲醛的浓度为37%。

Claims (4)

1.一种聚酯帘子线的浸胶液配方，其特征是，包括第一浴配方、第二浴配方，所述第一浴配方为：己内酰胺封闭异氰酸酯40-80重量份、RF树脂45-65重量份、软水300-600重量份；所述RF树脂的配方为：软水60-90重量份、氢氧化钠0.3-4.5重量份、间苯二酚固体1.8-6.6重量份、甲醛6-12重量份；所述第二浴配方为：RF树脂湿重为100-180重量份、乙烯基吡啶胶乳湿重为200-280重量份、氨水为11-18重量份、软水60-100重量份。
2.根据权利要求1所述的一种聚酯帘子线的浸胶液配方，其特征是，所述氨水的质量分数为0.28。
3.根据权利要求1所述的一种聚酯帘子线的浸胶液配方，其特征是，所述乙烯基吡啶胶乳的质量分数为0.41。
4.根据权利要求1所述的一种聚酯帘子线的浸胶液配方，其特征是，所述甲醛的浓度为37%。
CN201711338102.4A 2017-12-14 2017-12-14 一种聚酯帘子线的浸胶液配方 Pending CN107974832A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109056330A (zh) * 2018-07-30 2018-12-21 江苏百利达股份有限公司 一种高流动性rf液及其制备方法
CN110804873A (zh) * 2019-10-22 2020-02-18 芜湖华烨新材料有限公司 一种石墨烯改性涤纶浸胶帆布的生产方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199878A (zh) * 2011-04-12 2011-09-28 可隆（南京）特种纺织品有限公司 一种聚酯帘子布1次浸胶液及其浸胶处理方法
CN102220699A (zh) * 2011-05-30 2011-10-19 浙江尤夫科技工业有限公司 用于耐高温输送带的浸胶配方、浸胶生产方法及浸胶工艺
JP2013082923A (ja) * 2011-09-30 2013-05-09 Bridgestone Corp 接着剤組成物およびそれを用いたタイヤ用コード
CN106087430A (zh) * 2016-06-20 2016-11-09 南通三荣实业有限公司 一种浸胶配方

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199878A (zh) * 2011-04-12 2011-09-28 可隆（南京）特种纺织品有限公司 一种聚酯帘子布1次浸胶液及其浸胶处理方法
CN102220699A (zh) * 2011-05-30 2011-10-19 浙江尤夫科技工业有限公司 用于耐高温输送带的浸胶配方、浸胶生产方法及浸胶工艺
JP2013082923A (ja) * 2011-09-30 2013-05-09 Bridgestone Corp 接着剤組成物およびそれを用いたタイヤ用コード
CN106087430A (zh) * 2016-06-20 2016-11-09 南通三荣实业有限公司 一种浸胶配方

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109056330A (zh) * 2018-07-30 2018-12-21 江苏百利达股份有限公司 一种高流动性rf液及其制备方法
CN110804873A (zh) * 2019-10-22 2020-02-18 芜湖华烨新材料有限公司 一种石墨烯改性涤纶浸胶帆布的生产方法

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