CN107974017A - A kind of color water curing materials for toy for children and preparation method thereof - Google Patents
A kind of color water curing materials for toy for children and preparation method thereof Download PDFInfo
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- CN107974017A CN107974017A CN201810042849.3A CN201810042849A CN107974017A CN 107974017 A CN107974017 A CN 107974017A CN 201810042849 A CN201810042849 A CN 201810042849A CN 107974017 A CN107974017 A CN 107974017A
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- curing materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/24—Homopolymers or copolymers of amides or imides
- C08J2333/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/02—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2403/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2431/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
- C08J2431/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
- C08J2431/04—Homopolymers or copolymers of vinyl acetate
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toys (AREA)
Abstract
It is disclosed by the invention to belong to toy for children technical field, it is specially a kind of color water curing materials for toy for children and preparation method thereof, according to weight percentage, the color water curing materials for being used for toy for children are made of following components：Water；30 40 mesh water-absorbing resins；Water soluble solid agent；Redispersible rubber powder；Water soluble solid glue；Water-soluble toner, the preparation method for being used for the color water curing materials of toy for children include the following steps：S1：It is first that water soluble solid agent is soluble in water；S2：Re-dispersible glue powder is soluble in water；S3：Water soluble solid glue and water-soluble toner is soluble in water, the deionized water of 30 40 tens times of mesh water-absorbing resin energy absorptance itself weights, it is gelled after water suction, even if pressurization also is difficult to expressed water, serve not only as the carrier and skeleton of other materials, the unnecessary water for not participating in curing reaction, and intumescent filler void among particles can more be absorbed.
Description
Technical field
The present invention relates to toy for children technical field, be specially a kind of color water curing materials for toy for children and its
Preparation method.
Background technology
Water cure toy is a kind of novel toy, and it is fast curing-formed can to meet water.By the water cure material of different colours
Inject in the cavity mould of various moulding, several seconds submerged in water, allow it to fully absorb moisture, take out, it is quickly solid in 1 minute
Chemical conversion type, opens mould and takes out, you can obtain colorful doll.The material of existing water cure toy can not allow water completely into material
Material is internal, and curing rate is slow, it is also possible to the village hollowing of material internal is caused, for this reason, it is proposed that a kind of be used for children's object for appreciation
Color water curing materials of tool and preparation method thereof.
The content of the invention
It is an object of the invention to provide a kind of color water curing materials for toy for children and preparation method thereof, with solution
The material of existing water cure toy certainly proposed in the above background technology can not allow water completely into material internal, and cure
Speed is slow, it is also possible to the problem of causing the village hollowing of material internal.
To achieve the above object, the present invention provides following technical solution：A kind of colored water cure material for toy for children
Material, according to weight percentage, the color water curing materials for being used for toy for children are made of following components：
Water：5%-15%；30-40 mesh water-absorbing resins：29%-88.4%；Water soluble solid agent：0.5%-5%；It can divide again
Dissipate property rubber powder：5%-30%；Water soluble solid glue：1%-20%；Water-soluble toner：0.1%-1%.
The sum of above-mentioned each component percentage composition is 100%.
Preferably, according to weight percentage, the color water curing materials for being used for toy for children are made of following components：
Water：8%-12%；30-40 mesh water-absorbing resins：54.4%-78.7%；Water soluble solid agent：1%-3%；It can divide again
Dissipate property rubber powder：10%-20%；Water soluble solid glue：2%-10%；Water-soluble toner：0.3%-0.6%.
Preferably, the water-soluble toner is nontoxic colouring agent soluble in water, and the colouring agent includes canthaxanthin, rouge
Fat is red, amaranth, lemon yellow and light green.
Preferably, the redispersible rubber powder is vinylacetate and tertiary ethylene carbonate or ethene or acrylate two
The copolymer of member or ternary, the copolymer include watt gram 328N, watt gram 4115N, watt gram 5010N and Wa Ke 5044N.
Preferably, the water soluble solid glue and water soluble solid agent are that one kind can be quickly dissolved in water, and are sent out in water
The cross-linking system of raw associated reaction, particle effectively is bonded, the water soluble solid glue and water soluble solid agent are
Nontoxic solid powder, the nontoxic solid powder are Polyvinyl alcohol-borax or sodium alginate-calcium chloride.
Preferably, the 30-40 mesh water-absorbing resin is the anionic polymer containing carboxylic acid group, it is described containing carboxylic acid group it is cloudy from
Sub- macromolecule include starch conversion Sodium Polyacrylate, starch conversion polyacrylamide, carboxymethyl cellulose graft acrylamide and
Hydroxyethyl cellulose graft acrylamide.
A kind of preparation method of color water curing materials for toy for children, this is used for the colored water cure of toy for children
The preparation method of material includes the following steps：
S1：It is first that water soluble solid agent is soluble in water, sprayed into through atomizer in the 30-40 mesh water-absorbing resins of high-speed stirred,
Obtain semi-finished product；
S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain
Semi-finished product；
S3：Water soluble solid glue and water-soluble toner is soluble in water, spray into the step S2's of high-speed stirred through atomizer
In semi-finished product, finished product is obtained.
Compared with prior art, the beneficial effects of the invention are as follows：A kind of colour for toy for children that the invention proposes
Water cure material and preparation method thereof, by water, 30-40 mesh water-absorbing resin, water soluble solid agent, redispersible rubber powder, water-soluble
Property solidification glue and water-soluble 6 kinds of components of toner be made, this 6 kinds of materials are all that nontoxic material is suitable for toy for children, 30-40
Mesh water-absorbing resin is also referred to as super absorbent resin, is a kind of new functional macromolecule material, it can tens times of absorptance itself weight
Deionized water, after water suction be gelled, even if pressurization also be difficult to expressed water, it serves not only as other materials in the present invention
The carrier and skeleton of material, can more absorb the unnecessary water for not participating in curing reaction, and intumescent filler void among particles, can
Redispersibility rubber powder is wrapped between solidification glue and curing agent, can temporary their reaction of barrier, extend hardening time, allow water
Can each position of penetration material, and elasticity, water soluble solid glue and water soluble solid agent are provided to the material after curing completely
Effectively particle can be bonded.
Embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this area is common
Technical staff's all other embodiments obtained without making creative work, belong to the model that the present invention protects
Enclose.The present invention provides a kind of color water curing materials for toy for children, and according to weight percentage, this is used for toy for children
Color water curing materials be made of following components：
Water：5%-15%；30-40 mesh water-absorbing resins：29%-88.4%；Water soluble solid agent：0.5%-5%；It can divide again
Dissipate property rubber powder：5%-30%；Water soluble solid glue：1%-20%；Water-soluble toner：0.1%-1%.
The sum of above-mentioned each component percentage composition is 100%.
Wherein, according to weight percentage, the color water curing materials for being used for toy for children are made of following components：
Water：8%-12%；30-40 mesh water-absorbing resins：54.4%-78.7%；Water soluble solid agent：1%-3%；It can divide again
Dissipate property rubber powder：10%-20%；Water soluble solid glue：2%-10%；Water-soluble toner：0.3%-0.6%, the water solubility color
Powder is nontoxic colouring agent soluble in water, and the colouring agent includes canthaxanthin, famille rose, amaranth, lemon yellow and light green, institute
Redispersible rubber powder is stated as vinylacetate and tertiary ethylene carbonate or ethene or the copolymer of acrylate binary or ternary,
The copolymer includes watt gram 328N, watt gram 4115N, watt gram 5010N and Wa Ke 5044N, the water soluble solid glue and water-soluble
Property curing agent be that one kind can be quickly dissolved in water, and the cross-linking system of associated reaction occurs in water, effectively bonds particle
Get up, the water soluble solid glue and water soluble solid agent are nontoxic solid powder, and the nontoxic solid powder is poly-
Vinyl alcohol-borax or sodium alginate-calcium chloride, the 30-40 mesh water-absorbing resin is the anionic polymer containing carboxylic acid group, described
Anionic polymer containing carboxylic acid group includes starch conversion Sodium Polyacrylate, starch conversion polyacrylamide, carboxymethyl cellulose
Graft acrylamide and hydroxyethyl cellulose graft acrylamide.
A kind of preparation method of color water curing materials for toy for children：
Embodiment 1
The preparation method for being used for the color water curing materials of toy for children includes the following steps：
S1：It is first that water soluble solid agent is soluble in water, sprayed into through atomizer in the 30-40 mesh water-absorbing resins of high-speed stirred,
Obtain semi-finished product；
S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain
Semi-finished product；
S3：Water soluble solid glue and water-soluble toner is soluble in water, spray into the step S2's of high-speed stirred through atomizer
In semi-finished product, finished product is obtained.
In the present embodiment, 30-40 mesh water-absorbing resin is 30-40 mesh starch conversion Sodium Polyacrylates；Water soluble solid agent
For borax；Redispersible rubber powder is watt gram 328N；Water soluble solid glue is polyvinyl alcohol；Water-soluble toner is canthaxanthin, is pressed
According to weight, the percentage composition of each component is：30-40 mesh starch conversion Sodium Polyacrylates：77.6%；Borax：
2%；Watt gram 328N：10%；Polyvinyl alcohol：10%；Canthaxanthin：0.4%.
Embodiment 2
The preparation method for being used for the color water curing materials of toy for children includes the following steps：
S1：It is first that water soluble solid agent is soluble in water, sprayed into through atomizer in the 30-40 mesh water-absorbing resins of high-speed stirred,
Obtain semi-finished product；
S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain
Semi-finished product；
S3：Water soluble solid glue and water-soluble toner is soluble in water, spray into the step S2's of high-speed stirred through atomizer
In semi-finished product, finished product is obtained.
In the present embodiment, 30-40 mesh water-absorbing resin is 30-40 starch conversion polyacrylamides；Water soluble solid agent is
Calcium chloride；Redispersible rubber powder is watt gram 4115N；Water soluble solid glue is sodium alginate；Water-soluble toner is famille rose, is pressed
According to weight, the percentage composition of each component is：30-40 starch conversion polyacrylamides：76.5%；Calcium chloride：
3%；Watt gram 4115N：12%；Sodium alginate：8%；It is carmine：0.5%.
Embodiment 3
The preparation method for being used for the color water curing materials of toy for children includes the following steps：
S1：It is first that water soluble solid agent is soluble in water, sprayed into through atomizer in the 30-40 mesh water-absorbing resins of high-speed stirred,
Obtain semi-finished product；
S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain
Semi-finished product；
S3：Water soluble solid glue and water-soluble toner is soluble in water, spray into the step S2's of high-speed stirred through atomizer
In semi-finished product, finished product is obtained.
In the present embodiment, 30-40 mesh water-absorbing resin is 30-40 mesh carboxymethyl cellulose graft acrylamides；It is water-soluble
Curing agent is borax；Redispersible rubber powder is watt gram 5010N；Water soluble solid glue is polyvinyl alcohol；Water-soluble toner is amaranth
Dish is red, and according to weight, the percentage composition of each component is：30-40 mesh carboxymethyl cellulose graft acrylamides：
78.1%；Borax：1.5%；Watt gram 5010N：14%；Polyvinyl alcohol：6%；Amaranth：0.4%.
Embodiment 4
The preparation method for being used for the color water curing materials of toy for children includes the following steps：
S1：It is first that water soluble solid agent is soluble in water, sprayed into through atomizer in the 30-40 mesh water-absorbing resins of high-speed stirred,
Obtain semi-finished product；
S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain
Semi-finished product；
S3：Water soluble solid glue and water-soluble toner is soluble in water, spray into the step S2's of high-speed stirred through atomizer
In semi-finished product, finished product is obtained.
In the present embodiment, 30-40 mesh water-absorbing resin is 30-40 mesh hydroxyethyl cellulose graft acrylamides；It is water-soluble
Curing agent is calcium chloride；Redispersible rubber powder is watt gram 5044N；Water soluble solid glue is sodium alginate；Water-soluble toner is
Lemon yellow, according to weight, the percentage composition of each component is：30-40 mesh hydroxyethyl cellulose graft acrylamides：
78.4%；Calcium chloride：1%；Watt gram 5044N：16%；Sodium alginate：4%；Lemon yellow：0.6%.
Embodiment 5
The preparation method for being used for the color water curing materials of toy for children includes the following steps：
S1：It is first that water soluble solid agent is soluble in water, sprayed into through atomizer in the 30-40 mesh water-absorbing resins of high-speed stirred,
Obtain semi-finished product；
S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain
Semi-finished product；
S3：Water soluble solid glue and water-soluble toner is soluble in water, spray into the step S2's of high-speed stirred through atomizer
In semi-finished product, finished product is obtained.
In the present embodiment, 30-40 mesh water-absorbing resin is 30-40 mesh starch conversion polyacrylamides；Water soluble solid agent
For calcium chloride；Redispersible rubber powder is watt gram 5044N；Water soluble solid glue is sodium alginate；Water-soluble toner is light green, is pressed
According to weight, the percentage composition of each component is：30-40 mesh starch conversion polyacrylamides：76.7%；Calcium chloride：
1%；Watt gram 5044N：20%；Sodium alginate：2%；It is light green：0.3%.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of changes, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (7)
- A kind of 1. color water curing materials for toy for children, it is characterised in that：According to weight percentage, this is used for children The color water curing materials of toy are made of following components：Water：5%-15%；30-40 mesh water-absorbing resins：29%-88.4%；Water soluble solid agent：0.5%-5%；Redispersible Rubber powder：5%-30%；Water soluble solid glue：1%-20%；Water-soluble toner：0.1%-1%.The sum of above-mentioned each component percentage composition is 100%.
- A kind of 2. color water curing materials for toy for children according to claim 1, it is characterised in that：According to weight The percentage composition color water curing materials for being used for toy for children are made of following components：Water：8%-12%；30-40 mesh water-absorbing resins：54.4%-78.7%；Water soluble solid agent：1%-3%；Redispersible Rubber powder：10%-20%；Water soluble solid glue：2%-10%；Water-soluble toner：0.3%-0.6%.
- A kind of 3. color water curing materials for toy for children according to claim 1, it is characterised in that：It is described water-soluble Property toner is nontoxic colouring agent soluble in water, and the colouring agent includes canthaxanthin, famille rose, amaranth, lemon yellow and fruit It is green.
- A kind of 4. color water curing materials for toy for children according to claim 1, it is characterised in that：It is described can be again Dispersed rubber powder is vinylacetate and tertiary ethylene carbonate or ethene or the copolymer of acrylate binary or ternary, described common Polymers includes watt gram 328N, watt gram 4115N, watt gram 5010N and Wa Ke 5044N.
- A kind of 5. color water curing materials for toy for children according to claim 1, it is characterised in that：It is described water-soluble Property solidification glue and water soluble solid agent be that one kind can be quickly dissolved in water, and the cross-linking system of associated reaction occurs in water, has Particle is bonded by effect ground, and the water soluble solid glue and water soluble solid agent are nontoxic solid powder, described nontoxic Solid powder be Polyvinyl alcohol-borax or sodium alginate-calcium chloride.
- A kind of 6. color water curing materials for toy for children according to claim 1, it is characterised in that：The 30- 40 mesh water-absorbing resins are the anionic polymer containing carboxylic acid group, and the anionic polymer containing carboxylic acid group gathers including starch conversion Sodium acrylate, starch conversion polyacrylamide, carboxymethyl cellulose graft acrylamide and hydroxyethyl cellulose grafted propylene acyl Amine.
- A kind of 7. preparation method of color water curing materials for toy for children, it is characterised in that：This is used for toy for children The preparation method of color water curing materials includes the following steps：S1：It is first that water soluble solid agent is soluble in water, spray into the 30-40 mesh water-absorbing resins of high-speed stirred, obtain through atomizer Semi-finished product；S2：Re-dispersible glue powder is soluble in water, in the semi-finished product for the step S1 that high-speed stirred is sprayed into through atomizer, obtain half into Product；S3：Water soluble solid glue and water-soluble toner is soluble in water, sprayed into through atomizer high-speed stirred step S2 half into In product, finished product is obtained.
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| CN201810042849.3A CN107974017A (en) | 2018-01-17 | 2018-01-17 | A kind of color water curing materials for toy for children and preparation method thereof |
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| CN201810042849.3A CN107974017A (en) | 2018-01-17 | 2018-01-17 | A kind of color water curing materials for toy for children and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109847672A (en) * | 2019-01-10 | 2019-06-07 | 北美发明有限公司 | A kind of mixture and the method using its production different shape solid |
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| CN109847672A (en) * | 2019-01-10 | 2019-06-07 | 北美发明有限公司 | A kind of mixture and the method using its production different shape solid |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 361000 07, unit 13, Po Ye tower, 66 East Taiwan Road, Guanyin Mountain, Xiamen, Fujian. Applicant after: Xiamen Cara wind Education Technology Co., Ltd. Address before: 361000 07, unit 13, Po Ye tower, 66 East Taiwan Road, Guanyin Mountain, Xiamen, Fujian. Applicant before: Xiamen Cara wind Entertainment Co., Ltd. |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180501 |