Η 6 — 五、發明説明（1) 經濟部十央標半杓β工消价合作杜印似Η 6 — V. Description of the invention (1) The ten central standard, half-bundle, β-price-loss cooperation of the Ministry of Economic Affairs
Jfjf^ 本發明係關於一毺粉體彩色可塑性組成物。 本公司已獲發明專利第533 55號之導利申請第80100 60 6號彩色可塑性組成物，係採用水溶性聚合物水溶液， 加人食用色素、凝聚劑及添加劑形成透明彩色凝膠，具有 粘土的質感’可供捏塑或塗佈，其水晶般透明和柔軟的視 覺和觸覺舒適感’再加上彈性、v延展性的特點，爲非常有 趣味性、敎育性的材料。惟此種可塑性組成物儲存、運輸 等方面較爲不便。 本發明之主要固的，在於就前案發明専利進一步改進， 提供粉體彩色可塑性組成物，便利儲Μ，血使用前可用水 立卽溶化，使用方便。 本發明上述及其他目的、特點和優點，山F述詳細説 明卽可更爲明白。 本發明粉體彩色可塑性組成物，爲本申請人前案Γ彩 色可塑性組成物」之延伸應用，將水溶性聚合物、色索、 凝聚劑及添加劑等原料以粉體狀態混合、硏磨均勻。應用 時祇需將此粉體彩色可塑性組成物倒入特定之模具中，浸 入水中，或是通人尚來水卽可。本狻明之粉體原料中的水 溶性聚合物，遇水則表面'開始呈現溶解現象，此溶化之水 溶性聚合物接觸到粉體原料中之凝聚劑，立刻形成凝聚视 象而變成含有水份但不溶於水之水晶般凝膠，就如前案彩 色可塑性組成物之粘土般彩色透明膠體。山於本骏明之水 性彩色可朗性組成物味以粉體敁料，使川畤毗人水十 成加人自米水，即讨達到預期之足型彩膠，選擇小Μ模 (請先閲讀背而之注意麥項"填寫本汀) 本紙5S·尺度边用中®國家榇準(CNS)ΗΜ规格(210X297公址）_ A(i _______H (i__ 五、發明説明（2) ' 具塑造各種不同形狀，塑模簡單，方Μ，脫模迅速容易* 富趣味性的粉體原料。再由於本發明可塑性組成物*原料 係以粉體形態組成，携帶方便，保存容易，本鉍明粉體原 料可使彩色可塑性組成物之趣味性及敎育性增加° 本發明粉體彩色可塑性組成物包括水溶性聚合物、凝 聚劑、色素、添加劑和塡充劑。其中的水溶性聚合物係選 1¾態粉體之聚乙烯酵，或部分鹼化之聚醋酸乙烯酯、聚 丙烯酸醯胺、.聚丙烯酸酯等親水性聚合物，或其混合體爲 主體，其比例佔總組成物的60 — 90%重滅。凝聚劑足選自 包含碳酸納、硼酸納、氫氧化納、焦磷酸納、硫酸納、硫 酸鋁或其混合物，其含量爲1 一10%。色素则選自各種食 用色素，水分散性或水溶性色素粉末，旨在使粉體原料經 灌模浸水後*形成彩色塑型體。添加劑則使用具有滲透潤 濕功能之陰離子型或非離子型界面活性劑，如十二烷基苯 磺酸納，或山梨糖脂肪酸酯等，其用量爲（).5 —10 %重量。 另可摻人無機塡充物，如二氧化鈦、氧化鐵、氧化鎂、矽 膠、氧化鋁等除調整浸水凝膠的速度之外，還町調節脫模 後塑型之硬度。此無機填充物之用迨在1 —20%重徵。 茲以如下貿施例進一步具體說明。Jfjf ^ The present invention relates to a powdery color plastic composition. Our company has obtained the invention patent No. 533 55 and the guide application No. 80100 60 6 color plastic composition, which is a water-soluble polymer aqueous solution, added with human food coloring, coagulant and additives to form a transparent color gel, with clay The texture 'can be kneaded or coated, and its crystal-clear and soft visual and tactile comfort', combined with the characteristics of elasticity and v extensibility, is a very interesting and educational material. However, the storage and transportation of such plastic components are more inconvenient. The main solidity of the present invention is to further improve the invention of the previous case, to provide a powder color plastic composition, which is convenient for storing M, and blood can be dissolved in water before use, which is convenient to use. The above and other objects, features and advantages of the present invention can be more clearly explained in detail. The powder color plastic composition of the present invention is an extended application of the applicant's previous case Γ color plastic composition. The raw materials such as water-soluble polymers, color cords, coagulants and additives are mixed in a powder state and evenly ground. In application, it is only necessary to pour this powder color plasticity composition into a specific mold, immerse it in water, or pass it through water. The water-soluble polymer in the powder raw material of this 狻 明, the surface 'began to show dissolution in case of water, this melted water-soluble polymer contacted the coagulant in the powder raw material, and immediately formed a condensed image and became water-containing But the crystal-like gel that is insoluble in water is like a colored transparent colloid like the clay of the colored plastic composition in the previous case. The color composition of the water-based color composition of Yamamoto Benming is powdered, so that the 10% of the water is added to the rice and the water is used to meet the expected foot color glue. Choose the small M model (please first Read the note on the back of the page " Fill in Bing Ting. ”This paper is 5S · Standard Use ® National Standard (CNS) HM Specification (210X297 Public Address) _ A (i _______H (i__ V. Description of Invention (2) ' Molding various shapes, simple molding, square M, quick and easy demoulding * Interesting powder raw materials. Since the plastic composition of the present invention * raw materials are composed of powder, it is convenient to carry and easy to store. The powder raw material can increase the fun and education of the color plastic composition. The powder color plastic composition of the present invention includes a water-soluble polymer, a coagulant, a pigment, an additive and a filler. The water-soluble polymer is Select 12.8-state powdered yeast, or partially alkalized polyvinyl acetate, polyacrylamide, polyacrylate and other hydrophilic polymers, or their mixture as the main body, the proportion of which accounts for 60% of the total composition — 90% annihilation. The coagulant is selected from Sodium carbonate, sodium borate, sodium hydroxide, sodium pyrophosphate, sodium sulfate, aluminum sulfate or their mixtures, the content of which is 1 to 10%. The colorants are selected from various food colors, water-dispersible or water-soluble color powders. After the powder material is immersed in water by pouring mold * to form a colored plastic body. The additive uses anionic or nonionic surfactant with penetration and wetting function, such as sodium dodecylbenzenesulfonate or sorbose fatty acid Ester, etc., its dosage is (). 5-10% by weight. It can also be mixed with inorganic fillers, such as titanium dioxide, iron oxide, magnesium oxide, silica gel, aluminum oxide, etc. In addition to adjusting the speed of the immersion gel, it is also Adjust the hardness of the mold after demoulding. The use of this inorganic filler is repeated at 1-20%. The following trade examples are used to further explain.
實施例I ：選川邰份鹼化之聚醋酸乙烯酷1公斤，依F列紺成， 桫浞介、乾燥、即丨(1粉丨似"!吶Μ成物0 紺成物 迢W % 聚醋酸乙祕酷 70 本紙張尺度迈用中《國家榣半（CNS)T4规怙（21〇x2lJ7公址）—-4 — 經濟部屮央梂準局只工消赀合作社印製 五、發明説明（3) 氫氧化納 7 1 硫酸鋁 1 食用色素（黃） 0.5 山梨糖脂防酸酯 1.5 氧化鋁 20 使用時，將粉體原料注人模具 ，再浸泡於水中1〜5分鐘 脫模，即可得富彈性之模型。 實施例2 ‘選川聚乙烯醇和聚内烯酸醯胺各500公兑，色尜先以 酒精溶解，經混合、乾燥、硏磨卽得粉體可塑性組成物。 使用時，粉體丨泉料注人模具， 再浸泡於水中1〜5分鐘， 脫模，卽得具彈性之彩色模型 〇 組成物 重 聚乙烯醇 40 聚丙烯酸醯胺 40 氫氧化納 5 碳酸納 k 直接染料（藍色） 1 十二烷基苯磺酸納 2 矽膠 8 賞施例3 依照實施例1之組成比例 ，以聚乙烯醇代替聚醋酸乙 烯酯，以硼酸納取代硫酸鋁，其餘依實施例1之操作，卽 得速乾型粉體可塑性組成物。 各紙5&尺度逍用中《»家標準((：[^}'?4規格(2丨(丨><297公.!1：>——5—— ( 21 i. 0 ^Example I: Select 1 kg of alkalinized polyvinyl acetate to be made in Sichuan, according to column F, 桫 浞 介, dry, that is, 丨 (1 粉 丨 似 "! Μ 成 物 0 绀 成 物 迢 W % Polyvinyl Acetate Secret Cool 70 This paper is used in the "National Mid-and-Side (CNS) T4 Regulations (21〇x2lJ7 public address)-4-Printed by the Cooperative Society of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs. Description of the invention (3) sodium hydroxide 7 1 aluminum sulfate 1 food coloring (yellow) 0.5 sorbitan acid-proof ester 1.5 alumina 20 When in use, the powder raw material is injected into the mold, and then soaked in water for 1 to 5 minutes to demold , You can get a model with rich elasticity. Example 2 'Select 500 vol. Each of polyvinyl alcohol and polylactene amide, the color is first dissolved in alcohol, and then mixed, dried, and ground to obtain a powder plastic composition. When in use, the powder is poured into a mold, and then immersed in water for 1 to 5 minutes, demolded, and a flexible color model is obtained. The composition is heavy polyvinyl alcohol 40 polyacrylamide 40 sodium hydroxide 5 carbonic acid Nanok Direct Dyes (Blue) 1 Sodium dodecylbenzenesulfonate 2 Silicone 8 Example 3 According to the composition ratio of Example 1, polyvinyl alcohol was used to replace polyvinyl acetate, sodium borate was used to replace aluminum sulfate, and the rest was operated as in Example 1. A quick-drying powder plastic composition was obtained. Each paper 5 & In the "» home standard ((: [^} '? 4 specifications (2 丨 (丨 > < 297 public.! 1: > —— 5—— (21 i. 0 ^
Λ (i H (J 五、發明説明（4 ) 貨施例4 . 依照實施例1之組成比例，以聚内烯酸醯胺代替聚酸 乙烯酯，用碳酸納収代硫酸鋁，其餘依貨施例1之操作， 卽得粉體可塑性組成物。 賨施例5 依照實施例2之組成比例，以聚内烯酸醯胺和聚内烯 酸鹽代替聚乙烯醇和聚内烯酸醯胺，以硫酸納代替碳酸納、 以氧化鎂代替矽膠，K餘依貨施例2之操作，可得粉體可 塑性組成物。 貨施例6 依照賣施例2之組成比例，以聚醋酸乙烯酯和聚内烯 酸鹽代替聚乙烯醇和聚丙烯酸醯胺，以酸性染料（紅色） 代替食用色素，其餘依實施例2之操作，卽得粉體可塑性 組成物。 (•;,?;L間4计-命之注、 經濟部屮央榡準局兵工消赀合作社印52 表紙張尺度中BB家標準（CNSVP4規格（210x^7公放）一 6——Λ (i H (J V. Description of the invention (4)) Cargo Example 4. According to the composition ratio of Example 1, the polylactamide is used instead of polyvinyl acetate, and the sodium sulfate is used to replace aluminum sulfate, and the rest depends on the goods. According to the operation of Example 1, a powdery plastic composition was obtained. Example 5 According to the composition ratio of Example 2, polylactenylamide and polylactenate were used instead of polyvinyl alcohol and polylactoneamide, Using sodium sulfate instead of sodium carbonate and magnesium oxide instead of silicone rubber, K Yu can follow the operation of Example 2 to obtain a powdery plastic composition. Example 6 According to the composition ratio of Example 2, use polyvinyl acetate and Polylactenate is used instead of polyvinyl alcohol and polyacrylamide, acid dye (red) is used to replace food coloring, and the rest is operated as in Example 2 to obtain a powdery plastic composition. (•;,?; L 间 4 计-Future Note, printed by the BBIA Standards of the Ministry of Economic Affairs of the Ministry of Economic Affairs, the 52nd paper standard (CNSVP4 specification (210x ^ 7 public)) 1 6——