CN102634154A - Blue translucent crystal adhesive material and preparation method thereof - Google Patents
Blue translucent crystal adhesive material and preparation method thereof Download PDFInfo
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- CN102634154A CN102634154A CN2012101344591A CN201210134459A CN102634154A CN 102634154 A CN102634154 A CN 102634154A CN 2012101344591 A CN2012101344591 A CN 2012101344591A CN 201210134459 A CN201210134459 A CN 201210134459A CN 102634154 A CN102634154 A CN 102634154A
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- acrylamide
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- blue
- borax
- translucent crystal
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Abstract
The invention relates to a crystal adhesive material and a preparation method thereof. The blue translucent crystal adhesive material is prepared through the following steps: mixing, emulsifying and stirring PVA (polyvinyl acetate) powder, water, borax, Carbomer resins, propylene glycol or glycerin, vanillin, clove oil, amyl acetate, gardenia blue, propionic acid, benzoic acid, sodium dodecyl benzene sulfonate and an acrylamide-acrylate copoly-crosslink; and finally adding borax water and solidifying. The translucent crystal adhesive material has the following advantages: the translucent crystal adhesive material has a good moisturizing effect, is not easy to crack in the air, has bright color, is not easy to discolor and has stable hue, good transparency above 50% and service life longer than 18 months.
Description
Technical field
The present invention relates to a kind of polyester resin material and this polyester resin preparation methods.
Background technology
The polyester resin material is mainly used in preparation room interior trim spare, ornaments part, and some style apparatus and soft elasticity toy.Mainly be divided into two kinds of colored translucent and water white transparencies; Existing colored translucent polyester resin material mainly is made up of PVA, water, borax and pigment, and this colored translucent polyester resin material moisture is volatile, and humidity-holding effect is poor; Easy of crack; Bad and the easy oxidation discoloration of transparency, work-ing life is short, and work-ing life is only at 7～11 months.Especially add the blue translucent crystal glue material of blue industrial pigment, not only color is not bright-coloured, decolouring, and pigment state labile easily, and oxidation stain easily also influences transparency, and transparency is between 35～45%.
Summary of the invention
It is good that goal of the invention of the present invention provides a kind of humidity-holding effect, be placed in the air not easy to crack, colour stable, the blue translucent crystal glue material of the good and long service life of transparency.
Another object of the present invention provides a kind of preparation method of above-mentioned blue translucent crystal glue material.
A kind of blue translucent crystal glue material, process by following component according to weight percent:
PVA powder: 20～35%;
Water: 50～60%;
Borax: 0.5～0.9%;
Carbomer: 5～8%;
Ucar 35: 6～9%;
Vanillin food grade,1000.000000ine mesh: 0.01～0.03%;
Syzygium aromaticum stem oil: 0.01～0.03%;
Pentyl acetate: 0.01～0.02%;
Gardenia blue: 0.05～0.1%;
Propionic acid: 0.01～0.04%;
Phenylformic acid: 0.01～0.05%;
X 2073: 0.3～0.5%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 2～4%;
The summation of said above-mentioned all components percentage composition is 100%.
As preferably; Said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the acrylic amide that accounts for its gross weight 55%～56%, 33%～34% potassium acrylate, 9.5～11% water and 0.5%～1% linking agent; Said linking agent is any one or its arbitrary combination that is selected from Vinylstyrene, vulcabond and the N,N methylene bis acrylamide.
As preferably, process by following component according to weight percent:
PVA powder: 25%;
Water: 57.6%;
Borax: 0.7%;
Carbomer: 5%;
Ucar 35: 8%;
Vanillin food grade,1000.000000ine mesh: 0.01%;
Syzygium aromaticum stem oil: 0.02%;
Pentyl acetate: 0.02%;
Gardenia blue: 0.06%;
Propionic acid: 0.04%;
Phenylformic acid: 0.05%;
X 2073: 0.5%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 3%;
Said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the acrylic amide that accounts for its gross weight 55%, 34% potassium acrylate, 10% water and 1% N,N methylene bis acrylamide.
A kind of preparation method of blue translucent crystal glue material, this preparation method may further comprise the steps:
(1) water and PVA powder poured into to dissolve in the device stirred 5～10 minutes, pour into again emulsification pot internal heating to temperature between 90～100 ℃, and stir and make its dissolving;
(2) carbomer is joined in the PVC solution of step (1), maintain the temperature between 90～100 ℃ and after stirring 2～3 hours, add phenylformic acid, X 2073 and acrylamide-acrylicacid salt crosslinking copolymerization thing again and mix and obtain mixed solution;
(3) mixed solution in the emulsification pot is poured in the stirrer, is added Ucar 35 again, stir 20～30 minutes even until transparent glue solution;
(4) with borax and water join stir in the warming pan heat to 90～100 ℃ until dissolving fully, obtain borax solution;
(5) borax solution that vanillin food grade,1000.000000ine mesh, Syzygium aromaticum stem oil, pentyl acetate, propionic acid, gardenia blue and step (4) is prepared joins in the agitator kettle in the 3rd step, stirs and obtains finished product in 10～30 minutes;
Above-mentioned blue translucent crystal glue material provided by the invention is compared existing blue translucent crystal glue material, on major ingredient, has increased carbomer, acrylamide-acrylicacid salt crosslinking copolymerization thing, the Ucar 35 of above-mentioned percentage composition; Vanillin food grade,1000.000000ine mesh, Syzygium aromaticum stem oil and pentyl acetate on auxiliary agent, have also been added, as the X 2073 of tensio-active agent, as the gardenia blue of blue pigment, as the propionic acid and the phenylformic acid of sanitas as food flavour.Carbomer has very strong water-absorbent, and suction is prone to swelling, is water-soluble thickener, and the still emulsifying agent in preparing method's process as residuite, is enhanced the transparency in above-mentioned blue translucent crystal glue material compsn simultaneously.In addition, carbomer is an acidulous material, can destroy alkaline sanitas, so sanitas is selected phenylformic acid for use; On the contrary, under alkaline condition, a little less than the carbomer water absorption and swelling ability, select for use alkaline sanitas can suppress the performance of carbomer swelling behavior.With carbomer similarly, the acrylamide-acrylicacid salt crosslinking copolymerization thing easy swelling that also absorbs water, acrylamide-acrylicacid salt crosslinking copolymerization thing is a kind of water-holding agent, water absorbent rate is very high, can effectively suppress moisture evaporation, prevents that blue translucent crystal glue material is dry and cracked.Ucar 35 is a kind of wetting Agent for Printing Inks; Keep the moisture in the compsn not volatile; Prevent dry and crackedly, especially the acrylamide-acrylicacid salt crosslinking copolymerization thing in component can slow trace be released water, and the water that disengages is absorbed by wetting Agent for Printing Inks again just; Form dynamic water conservation balance, it is very good with the anti-chap effect to preserve moisture.Have wetting very by force, increase-volume and dissemination as the X 2073 of tensio-active agent, let the material in above-mentioned steps (2) and (3) be more prone to uniform mixing.Aspect color, gardenia blue is a kind of natural blue pigment, English name Gardenia Blue; The water-soluble blueness that is, temperature capacity is strong, but can only under acid and neutrallty condition, be blue; Especially under acidic conditions, gardenia blue water-soluble with propylene glycol solvent in be distinct blueness.And above-mentioned phenylformic acid and propionic acid are sanitass, and mould, yeast and aerobic bacteria are all had restraining effect, and wherein phenylformic acid of selecting for use and propionic acid all are acid sanitass, are intended to rot-resistant simultaneously, keep the bright-coloured nondiscoloration of blue pigment.In a word, this blueness translucent crystal glue material humidity-holding effect is good, is placed in the air not easy to crackly, bright-colored, and not easy to change and tone is stable, the good and long service life of transparency, and transparency reaches more than 50%, and work-ing life is more than 18 months.
Embodiment
Be the present invention to be done further to describe for example below through embodiment.
Embodiment 1
A kind of blue translucent crystal glue material, process by following component according to weight percent meter:
PVA powder: 25%;
Water: 57.6%;
Borax: 0.7%;
Carbomer: 5%;
Ucar 35: 8%;
Vanillin food grade,1000.000000ine mesh: 0.01%;
Syzygium aromaticum stem oil: 0.02%;
Pentyl acetate: 0.02%;
Gardenia blue: 0.06%;
Propionic acid: 0.04%;
Phenylformic acid: 0.05%;
X 2073: 0.5%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 3%;
Said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the acrylic amide that accounts for its gross weight 55%, 34% potassium acrylate, 10% water and 1% N,N methylene bis acrylamide.
Acrylamide-acrylicacid salt crosslinking copolymerization thing is a kind of water-holding agent, and its preparation method is: in acrylic acid aqueous solution, add acrylic amide, stirring at room is even; Add N,N methylene bis acrylamide (NNMBA) again, heat to 35 ℃ and keep 35 ℃ of temperature constant; Add ammonium persulphate-potassium sulfite redox initiator; Stirring reaction 10～30 minutes is put into baking oven again and is dried, and being crushed into powder obtains this water-holding agent.
The preparation method of above-mentioned blue translucent crystal glue material may further comprise the steps:
(1) water and PVA powder poured into to dissolve in the device stirred 5～10 minutes, pour into again emulsification pot internal heating to temperature between 90～100 ℃, and stir and make its dissolving;
(2) carbomer is joined in the PVC solution of step (1), maintain the temperature between 90～100 ℃ and after stirring 2～3 hours, add phenylformic acid, X 2073 and acrylamide-acrylicacid salt crosslinking copolymerization thing again and mix and obtain mixed solution;
(3) mixed solution in the emulsification pot is poured in the stirrer, is added Ucar 35 again, stir 20～30 minutes even until transparent glue solution;
(4) with borax and water join stir in the warming pan heat to 90～100 ℃ until dissolving fully, obtain borax solution;
(5) borax solution that vanillin food grade,1000.000000ine mesh, Syzygium aromaticum stem oil, pentyl acetate, propionic acid, gardenia blue and step (4) is prepared joins in the agitator kettle in the 3rd step, covers the stirring cover, stirs and obtains finished product in 10～30 minutes;
Above-mentioned each step is all carried out under normal pressure.
Embodiment 2
A kind of blue translucent crystal glue material, process by following component according to weight percent:
PVA powder: 28%;
Water: 54.54%;
Borax: 0.9%;
Carbomer: 8%;
Ucar 35: 6%;
Vanillin food grade,1000.000000ine mesh: 0.02%;
Syzygium aromaticum stem oil: 0.01%;
Pentyl acetate: 0.02%;
Gardenia blue: 0.05%;
Propionic acid: 0.02%;
Phenylformic acid: 0.04%;
X 2073: 0.4%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 2%;
Said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the water of the acrylic amide that accounts for its gross weight 56%, 34% potassium acrylate 9.5% and 0.5% N,N methylene bis acrylamide.
The preparation method of this acrylamide-acrylicacid salt crosslinking copolymerization thing is all identical with embodiment 1 with the preparation method of above-mentioned blue translucent crystal glue material.
Embodiment 3
A kind of blue translucent crystal glue material, process by following component according to weight percent:
PVA powder: 20%;
Water: 58.85%;
Borax: 0.6%;
Carbomer: 7%;
Ucar 35: 9%;
Vanillin food grade,1000.000000ine mesh: 0.01%;
Syzygium aromaticum stem oil: 0.03%;
Pentyl acetate: 0.01%;
Gardenia blue: 0.05%;
Propionic acid: 0.04%;
Phenylformic acid: 0.01%;
X 2073: 0.4%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 4%;
Said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the acrylic amide that accounts for its gross weight 56%, 33% potassium acrylate, 10% water and 1% N,N methylene bis acrylamide.
The preparation method of this acrylamide-acrylicacid salt crosslinking copolymerization thing is all identical with embodiment 1 with the preparation method of above-mentioned blue translucent crystal glue material.
Be the partial properties contrast table of existing blue translucent crystal glue material and the foregoing description 1,2,3 below.
The time in work-ing life begins in material appearance cracking or oxidation stain time in the table.
Claims (4)
1. blue translucent crystal glue material is characterized in that being processed by following component according to weight percent:
PVA powder: 20～35%;
Water: 50～60%;
Borax: 0.5～0.9%;
Carbomer: 5～8%;
Ucar 35: 6～9%;
Vanillin food grade,1000.000000ine mesh: 0.01～0.03%;
Syzygium aromaticum stem oil: 0.01～0.03%;
Pentyl acetate: 0.01～0.02%;
Gardenia blue: 0.05～0.1%;
Propionic acid: 0.01～0.04%;
Phenylformic acid: 0.01～0.05%;
X 2073: 0.3～0.5%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 2～4%.
2. according to the said a kind of blue translucent crystal glue material of claim 1; It is characterized in that said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the acrylic amide that accounts for its gross weight 55%～56%, 33%～34% potassium acrylate, 9.5～11% water and 0.5%～1% linking agent; Said linking agent is any one or its arbitrary combination that is selected from Vinylstyrene, vulcabond and the N,N methylene bis acrylamide.
3. according to the said a kind of blue translucent crystal glue material of claim 1, it is characterized in that processing by following component according to weight percent:
PVA powder: 25%;
Water: 57.6%;
Borax: 0.7%;
Carbomer: 5%;
Ucar 35: 8%;
Vanillin food grade,1000.000000ine mesh: 0.01%;
Syzygium aromaticum stem oil: 0.02%;
Pentyl acetate: 0.02%;
Gardenia blue: 0.06%;
Propionic acid: 0.04%;
Phenylformic acid: 0.05%;
X 2073: 0.5%;
Acrylamide-acrylicacid salt crosslinking copolymerization thing: 3%;
Said acrylamide-acrylicacid salt crosslinking copolymerization thing is made up of the acrylic amide that accounts for its gross weight 55%, 34% potassium acrylate, 10% water and 1% N,N methylene bis acrylamide.
4. the preparation method of an a kind of according to claim 1 blue translucent crystal glue material is characterized in that this preparation method may further comprise the steps:
(1) water and PVA powder poured into to dissolve in the device stirred 5～10 minutes, pour into again emulsification pot internal heating to temperature between 90～100 ℃, and stir and make its dissolving;
(2) carbomer is joined in the PVC solution of step (1), maintain the temperature between 90～100 ℃ and after stirring 2-3 hour, add phenylformic acid, X 2073 and acrylamide-acrylicacid salt crosslinking copolymerization thing again and mix and obtain mixed solution;
(3) mixed solution in the emulsification pot is poured in the stirrer, is added Ucar 35 again, stir 20～30 minutes even until transparent glue solution;
(4) with borax and water join stir in the warming pan heat to 90～100 ℃ until dissolving fully, obtain borax solution;
(5) borax solution that vanillin food grade,1000.000000ine mesh, Syzygium aromaticum stem oil, pentyl acetate, propionic acid, gardenia blue and step (4) is prepared joins in the agitator kettle in the 3rd step, stirs and obtains finished product in 10～30 minutes.
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| CN 201210134459 CN102634154B (en) | 2012-05-04 | 2012-05-04 | Blue translucent crystal adhesive material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201210134459 CN102634154B (en) | 2012-05-04 | 2012-05-04 | Blue translucent crystal adhesive material and preparation method thereof |
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| CN102634154A true CN102634154A (en) | 2012-08-15 |
| CN102634154B CN102634154B (en) | 2013-06-12 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974017A (en) * | 2018-01-17 | 2018-05-01 | 厦门卡拉风娱乐有限公司 | A kind of color water curing materials for toy for children and preparation method thereof |
| CN109988481A (en) * | 2019-02-25 | 2019-07-09 | 孙建忠 | A kind of low viscous rapid-hardening polyester resin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772776A (en) * | 2004-11-10 | 2006-05-17 | 仲恺农业技术学院 | Crystal mud and its prepn and use |
| CN101525458A (en) * | 2008-11-17 | 2009-09-09 | 稂武忠 | Lava |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
-
2012
- 2012-05-04 CN CN 201210134459 patent/CN102634154B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772776A (en) * | 2004-11-10 | 2006-05-17 | 仲恺农业技术学院 | Crystal mud and its prepn and use |
| CN101525458A (en) * | 2008-11-17 | 2009-09-09 | 稂武忠 | Lava |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974017A (en) * | 2018-01-17 | 2018-05-01 | 厦门卡拉风娱乐有限公司 | A kind of color water curing materials for toy for children and preparation method thereof |
| CN109988481A (en) * | 2019-02-25 | 2019-07-09 | 孙建忠 | A kind of low viscous rapid-hardening polyester resin |
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| CN102634154B (en) | 2013-06-12 |
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Address after: 322204 Zhejiang city of Jinhua Province Huang Town Pujiang County Parkway Park No. 30 Patentee after: Zhejiang Silver Dragon animation culture Limited by Share Ltd Address before: 322200 Zhejiang city of Jinhua Province Huang Town Pujiang County Parkway Park No. 30 Patentee before: Pujiang County Kintaro Toys Co., Ltd. |
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Granted publication date: 20130612 Termination date: 20190504 |