CN107964112A - A kind of preparation method of organic glass plate surface coating for woolen surface - Google Patents
A kind of preparation method of organic glass plate surface coating for woolen surface Download PDFInfo
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- CN107964112A CN107964112A CN201711324432.8A CN201711324432A CN107964112A CN 107964112 A CN107964112 A CN 107964112A CN 201711324432 A CN201711324432 A CN 201711324432A CN 107964112 A CN107964112 A CN 107964112A
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- coating
- organic glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/101—Pretreatment of polymeric substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
- B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
- C09D169/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
Abstract
The present invention discloses a kind of preparation method of organic glass plate surface coating for woolen surface, including following operating procedure：（1）To prepare molding organic glass plate surface wash with water it is clean after, then spray ethanol solution and cleaned；（2）Step will be passed through（1）The poly (methyl methacrylate) plate external coating coating for woolen surface of processing, is then put into flocking machine electrostatic field by poly (methyl methacrylate) plate, after 120 150min of curing process, finished product.A kind of preparation method of organic glass plate surface coating for woolen surface provided by the invention, it is environmentally protective, poly (methyl methacrylate) plate after processing, surface will not volatilize poisonous gas, the resistance to bubble of matte of organic glass, will not have excellent wear-resisting property and resistance to oxidation, corrosion resistance there is a phenomenon where depilation and aliquation.
Description
Technical field
The invention belongs to poly (methyl methacrylate) plate technical field of surface, and in particular to a kind of organic glass plate surface matte applies
The preparation method of material.
Background technology
Organic glass is a kind of popular title, is abbreviated as PMMA.The chemical name of this macromolecule transparent material is poly- first
Base methyl acrylate, is the high-molecular compound formed by methyl methacrylate polymerization.It is a kind of exploitation important heat earlier
Thermoplastic plastic, organic glass have the preferable transparency, chemical stability, mechanical property and a weatherability, easy dyeing, easy processing,
The advantages that attractive appearance.It is known as poly (methyl methacrylate) plate using plate made of organic glass.Coating for woolen surface refers in vision and sense of touch
On give soft, the warm feel of similar contact velveting, there is noble, magnificent, warm decorative paint.The prior art
In, organic glass external coating coating for woolen surface is low there is adhesive force the defects of.
The content of the invention
In order to solve the above technical problem, the present invention provides a kind of preparation method of organic glass plate surface coating for woolen surface.
The present invention is achieved by the following technical solutions.
A kind of preparation method of organic glass plate surface coating for woolen surface, including following operating procedure：
（1）To prepare molding organic glass plate surface wash with water it is clean after, then spray ethanol solution and cleaned；
（2）Step will be passed through（1）The poly (methyl methacrylate) plate external coating coating for woolen surface of processing, is then put into flocking by poly (methyl methacrylate) plate
Machine electrostatic field, after curing process 120-150min, finished product, wherein coating for woolen surface are made of following methods：By weight
Meter, by 36-44 parts of adipic acids, 24-30 parts of butanediols, 1-2 parts of 2- nonenyl succinic acids acid anhydrides, 3-5 parts of 4- trifluoromethy carbonic acid
Vinyl acetate, 0.2-0.4 part initiator after mixing, are heated to 180-200 DEG C, when isothermal holding 4-5 is small after, be made copolymerization breast
Liquid, then adds 2-4 parts of kojic dipalmitates, 1-2 parts of aluminium oxide thereto, after mixing, coating for woolen surface is made.
Specifically, above-mentioned steps（1）In, the volume fraction of ethanol solution is 75%.
Specifically, above-mentioned steps（2）In, initiator is peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester
In any one.
Specifically, above-mentioned steps（2）In, the temperature setting in flocking machine electrostatic field is 65-70 DEG C.
Specifically, above-mentioned steps（2）In, the Average Particle Diameters of aluminium oxide are 550-600 mesh.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows：
A kind of preparation method of organic glass plate surface coating for woolen surface provided by the invention, environmentally protective, organic glass after processing
Glass plate, surface will not volatilize poisonous gas, the resistance to bubble of matte of organic glass, will not there is a phenomenon where depilation and aliquation,
With excellent wear-resisting property and resistance to oxidation, corrosion resistance.Nonenyl succinic acid acid anhydride, 4- trifluoromethy ethylene carbonates
Addition, it can strengthen the surface energy of poly (methyl methacrylate) plate, and then significantly enhance attachment of the coating for woolen surface on organic glass surface
Power, solves in the prior art, the technical problem that coating for woolen surface is difficult to adhere on organic surface；Kojic dipalmitate and oxidation
The addition of aluminium, can greatly lift the villous sense of touch of coating for woolen surface, and then the effective decoration for improving organic glass
Effect.
Embodiment
Following embodiments are used to illustrate the present invention, but cannot be used for limiting the scope of the invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of preparation method of organic glass plate surface coating for woolen surface, including following operating procedure：
（1）To prepare molding organic glass plate surface wash with water it is clean after, then spray ethanol solution and cleaned；
（2）Step will be passed through（1）The poly (methyl methacrylate) plate external coating coating for woolen surface of processing, is then put into flocking by poly (methyl methacrylate) plate
Machine electrostatic field, after curing process 120min, finished product, wherein coating for woolen surface are made of following methods：By weight, will
36 parts of adipic acids, 24 parts of butanediols, 1 part of 2- nonenyl succinic acids acid anhydride, 3 parts of 4- trifluoromethies ethylene carbonates, 0.2 part of initiation
Agent after mixing, is heated to 180 DEG C, when isothermal holding 4 is small after, be made copolymer emulsion, then thereto add 2 parts of kojic acids two
Palmitate, 1 part of aluminium oxide, after mixing, are made coating for woolen surface.
Specifically, above-mentioned steps（1）In, the volume fraction of ethanol solution is 75%.
Specifically, above-mentioned steps（2）In, initiator is peroxidized t-butyl perbenzoate.
Specifically, above-mentioned steps（2）In, the temperature setting in flocking machine electrostatic field is 65 DEG C.
Specifically, above-mentioned steps（2）In, the Average Particle Diameters of aluminium oxide are 550 mesh.
Embodiment 2
A kind of preparation method of organic glass plate surface coating for woolen surface, including following operating procedure：
（1）To prepare molding organic glass plate surface wash with water it is clean after, then spray ethanol solution and cleaned；
（2）Step will be passed through（1）The poly (methyl methacrylate) plate external coating coating for woolen surface of processing, is then put into flocking by poly (methyl methacrylate) plate
Machine electrostatic field, after curing process 130min, finished product, wherein coating for woolen surface are made of following methods：By weight, will
40 parts of adipic acids, 28 parts of butanediols, 1 part of 2- nonenyl succinic acids acid anhydride, 4 parts of 4- trifluoromethies ethylene carbonates, 0.3 part of initiation
Agent after mixing, is heated to 190 DEG C, when isothermal holding 4.5 is small after, be made copolymer emulsion, then thereto add 3 parts of kojic acids
Dipalmitate, 2 parts of aluminium oxide, after mixing, are made coating for woolen surface.
Specifically, above-mentioned steps（1）In, the volume fraction of ethanol solution is 75%.
Specifically, above-mentioned steps（2）In, initiator is peroxidating trimethylacetic acid tertiary butyl ester.
Specifically, above-mentioned steps（2）In, the temperature setting in flocking machine electrostatic field is 68 DEG C.
Specifically, above-mentioned steps（2）In, the Average Particle Diameters of aluminium oxide are 580 mesh.
Embodiment 3
A kind of preparation method of organic glass plate surface coating for woolen surface, including following operating procedure：
（1）To prepare molding organic glass plate surface wash with water it is clean after, then spray ethanol solution and cleaned；
（2）Step will be passed through（1）The poly (methyl methacrylate) plate external coating coating for woolen surface of processing, is then put into flocking by poly (methyl methacrylate) plate
Machine electrostatic field, after curing process 150min, finished product, wherein coating for woolen surface are made of following methods：By weight, will
44 parts of adipic acids, 30 parts of butanediols, 2 parts of 2- nonenyl succinic acids acid anhydrides, 5 parts of 4- trifluoromethies ethylene carbonates, 0.4 part of initiation
Agent after mixing, is heated to 200 DEG C, when isothermal holding 5 is small after, be made copolymer emulsion, then thereto add 4 parts of kojic acids two
Palmitate, 2 parts of aluminium oxide, after mixing, are made coating for woolen surface.
Specifically, above-mentioned steps（1）In, the volume fraction of ethanol solution is 75%.
Specifically, above-mentioned steps（2）In, initiator is peroxidating trimethylacetic acid tertiary butyl ester.
Specifically, above-mentioned steps（2）In, the temperature setting in flocking machine electrostatic field is 70 DEG C.
Specifically, above-mentioned steps（2）In, the Average Particle Diameters of aluminium oxide are 600 mesh.
Coating for woolen surface is made on the surface of organic glass with the method for each embodiment respectively, then test its water resistance and
Wear-resisting property, water resistance test：When by finished product organic glass, immersion treatment 24 is small in 40 DEG C of warm water, it is not allow for losing hair or feathers
With aliquation phenomenon；Wear-resisting property is tested：Carried out on abrasiometer it is reciprocating abrasion 30000 times, check whether and expose base
Material, test result is as shown in table 1, is the organic glass for being brushed on commercially available common coating for woolen surface wherein in control group：
The test result of 1 coating for woolen surface of table
| Project | Water resistance is tested | Wear-resisting property is tested |
| Embodiment 1 | Pass through | Do not reveal base material |
| Embodiment 2 | Pass through | Do not reveal base material |
| Embodiment 3 | Pass through | Do not reveal base material |
| Control group | Do not pass through, depilation, aliquation are serious | Expose base material |
As shown in Table 1, there is excellent wearability in matte coating made from poly (methyl methacrylate) plate using method provided by the invention
Energy and water resistance.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, can be to the technology of invention
Scheme technical scheme is modified or replaced equivalently, without departing from the scope of technical solution of the present invention, it should all cover the power in the present invention
In sharp claimed range.
Claims (5)
1. a kind of preparation method of organic glass plate surface coating for woolen surface, it is characterised in that including following operating procedure：
（1）To prepare molding organic glass plate surface wash with water it is clean after, then spray ethanol solution and cleaned；
（2）Step will be passed through（1）The poly (methyl methacrylate) plate external coating coating for woolen surface of processing, is then put into flocking by poly (methyl methacrylate) plate
Machine electrostatic field, after curing process 120-150min, finished product, wherein coating for woolen surface are made of following methods：By weight
Meter, by 36-44 parts of adipic acids, 24-30 parts of butanediols, 1-2 parts of 2- nonenyl succinic acids acid anhydrides, 3-5 parts of 4- trifluoromethy carbonic acid
Vinyl acetate, 0.2-0.4 part initiator after mixing, are heated to 180-200 DEG C, when isothermal holding 4-5 is small after, be made copolymerization breast
Liquid, then adds 2-4 parts of kojic dipalmitates, 1-2 parts of aluminium oxide thereto, after mixing, coating for woolen surface is made.
2. the preparation method of a kind of organic glass plate surface coating for woolen surface according to claim 1, it is characterised in that above-mentioned
Step（1）In, the volume fraction of ethanol solution is 75%.
3. the preparation method of a kind of organic glass plate surface coating for woolen surface according to claim 1, it is characterised in that above-mentioned
Step（2）In, initiator is any one in peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester.
4. the preparation method of a kind of organic glass plate surface coating for woolen surface according to claim 1, it is characterised in that above-mentioned
Step（2）In, the temperature setting in flocking machine electrostatic field is 65-70 DEG C.
5. the preparation method of a kind of organic glass plate surface coating for woolen surface according to claim 1, it is characterised in that above-mentioned
Step（2）In, the Average Particle Diameters of aluminium oxide are 550-600 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711324432.8A CN107964112A (en) | 2017-12-13 | 2017-12-13 | A kind of preparation method of organic glass plate surface coating for woolen surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711324432.8A CN107964112A (en) | 2017-12-13 | 2017-12-13 | A kind of preparation method of organic glass plate surface coating for woolen surface |
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| CN107964112A true CN107964112A (en) | 2018-04-27 |
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| CN201711324432.8A Pending CN107964112A (en) | 2017-12-13 | 2017-12-13 | A kind of preparation method of organic glass plate surface coating for woolen surface |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995107A (en) * | 2006-12-08 | 2007-07-11 | 江苏晨光涂料有限公司 | Transparent heat-insulated resin sheet |
| CN103906798A (en) * | 2011-10-31 | 2014-07-02 | 巴斯夫涂料有限公司 | Method for coating plastic substrates |
| CN104559577A (en) * | 2013-10-12 | 2015-04-29 | 成都飞机工业（集团）有限责任公司 | Aviation organic glass protective coating and preparation method thereof |
| CN104629609A (en) * | 2015-02-06 | 2015-05-20 | 安庆昊业树脂材料科技有限公司 | Waterborne polyurethane suede coating and preparation method thereof |
-
2017
- 2017-12-13 CN CN201711324432.8A patent/CN107964112A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995107A (en) * | 2006-12-08 | 2007-07-11 | 江苏晨光涂料有限公司 | Transparent heat-insulated resin sheet |
| CN103906798A (en) * | 2011-10-31 | 2014-07-02 | 巴斯夫涂料有限公司 | Method for coating plastic substrates |
| CN104559577A (en) * | 2013-10-12 | 2015-04-29 | 成都飞机工业（集团）有限责任公司 | Aviation organic glass protective coating and preparation method thereof |
| CN104629609A (en) * | 2015-02-06 | 2015-05-20 | 安庆昊业树脂材料科技有限公司 | Waterborne polyurethane suede coating and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 孔人英编著: "《化学建筑材料》", 31 August 1999 * |
| 张丹枫编著: "《烯烃聚合》", 31 December 2014 * |
| 韩哲文主编: "《高分子科学教程》", 31 December 2001 * |
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Application publication date: 20180427 |
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