CN1995107A - Transparent heat-insulated resin sheet - Google Patents
Transparent heat-insulated resin sheet Download PDFInfo
- Publication number
- CN1995107A CN1995107A CN 200610098364 CN200610098364A CN1995107A CN 1995107 A CN1995107 A CN 1995107A CN 200610098364 CN200610098364 CN 200610098364 CN 200610098364 A CN200610098364 A CN 200610098364A CN 1995107 A CN1995107 A CN 1995107A
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- resin
- transparent heat
- insulated
- heat
- resin sheet
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Abstract
The invention discloses a transparent insulating resin board, which comprises the following parts: 30-65% macromolecular resin, 5-20% nanometer powder, 1-10% coating adjuvant and 29-58% diluent. The invention makes the penetrating rate of coating layer over 75% in the visible area, which reaches over 60% for screening rate in the near infrared region and 98% in the ultraviolet region.
Description
Technical field
The present invention relates to a kind of sheet material, especially a kind of transparent heat-insulated resin sheet.
Background technology
Public building, top, station, station, passage ceiling and modernized agricultural greenhouse construction at present can adopt glass, bilayer film etc. as the covering material of building.The problem that the building that adopts these materials to build mainly exists is the energy consumption height, the ability of withstanding natural calamities, film with after also will cause white pollution.Therefore, extensively adopt some resin plate now.
These transparent resin sheet materials are mainly the engineering plastics plate of polycarbonate (PC), synthetic glass (PMMA), polyvinyl chloride (PVC) and polystyrene materials such as (PS).
The heat-insulating problem of resin plate mainly can adopt the method for various heat reflection pad pastings, in order to the energy in the sunlight of reflecting part, thereby reaches the purpose of heat insulation and heat control.But the effect of heat insulation that these products have is not good, does not reach expected effect; The transmittance that has is lower, though can sunshade, also stopped penetrating of visible light, need transparent occasion bring inconvenience to some; The equipment that then needs costliness that has, control of process condition is also very complicated, and required cost is higher.
Having data to show that Chinese patent CN96102662.6 (heat-insulating plate with vacuum interlayer) relates to a kind of hollow sandwich thermal baffle, is to be made of header board, back plate, support bar and edge strip.Cover thermal reflecting coating at the interlayer internal surface, with the interlayer formation thermofin that is evacuated.
Chinese patent CN90211162.0 (plastics plated film warming plate) invents a kind of plastics plated film warming plate, it is the structural part of heat insulating under the normal temperature, constitute by the gas cloud that seals between transparent panel, the transparent lamina membranacea that is coated with heat reflection coating, the floor that prevents thermal convection, frame, panel and the lamina membranacea, can prevent the radiation of heat loss effectively.
Chinese patent CN91230043.4 (reflective insulation matrix material liner plate) invents a kind of new type reflection heat-insulation composite material liner plate, it is characterized in that being coated with binding agent by aluminium foil, dipping polyvinyl non-woven fabrics, polyvinyl acupuncture suede, PEP foam material interlayer, in mould, heat, it is compound to exert pressure, and spraying resol layer.Have good heat reflection, heat insulation, sound absorption qualities.
Chinese patent CN97245126.9 (radioprotective adiabatic composite material) has invented the adiabatic section bar of a kind of radioprotective, is layered composite structure, successively by protection transition layer, thermal resistent material layer, heat-reflecting layer is compound is one.Between thermal resistent material layer, heat-reflecting layer, can also be compounded with the protection transition layer.
The method technology that above-mentioned patent adopts is relatively complicated, and required cost is higher.
Summary of the invention
The present invention proposes a kind of preparation method of transparent heat-insulated resin sheet, the method that promptly adopts coating to apply, nano transparent insulating coating is coated on the ordinary resin plate surface, constitute resin plate with heat-proof quality, neither influence the transparency of resin plate, played good effect of heat insulation again.Technology is simple and easy to do, and production cost is low.
The technical solution adopted in the present invention is: at first prepare nano transparent insulating coating, the nano transparent insulating coating of making is coated on the resin plate surface, can apply by multiple modes such as spraying or roller coat.Behind completion of cure, can obtain having the transparent heat-insulated resin sheet of transparent heat-insulated performance.
In the present invention on the basis of patent CN200410014672.4 " nano transparent heat-insulation composite coating ", improve formulation for coating material, with spraying or the method for roller coat in the transparent heat-insulated coating of resin surface coated with nano, invention has also prepared several different insulation resin sheet materials that are coated with transparent heat-insulated coating, the application scenario is very extensive, as making transparent thermal baffle on the item of bus station etc.
The correlation detection data presentation, the visible light transmissivity of these several transparent heat-insulated resin sheets all can reach more than 75%, the infrared shielding rate reaches more than 60%, UV-light then almost can be shielded fully, can be applicable to occasions such as top, bus station, can well play the purpose of heat insulation and heat control, and this kind transparent heat-insulated resin sheet can prevent ultraviolet, play anti-aging effect.
Concrete technical scheme of the present invention is:
A kind of transparent heat-insulated resin sheet is characterized in that being made up of resin plate and transparent heat-insulated coating; The component and the parts by weight of wherein said heat insulating coat are as follows:
Macromolecule resin 30～65
Nano-powder 5～20
Coatings additive(s) 1～10
Thinner 29～58
Macromolecule resin is pure dissolubility or solvent type resin such as acrylic resin or polyvinyl butyral resin etc. in the wherein said coating; Nano-powder is for containing ZnSb at least
2O
6(zinc antimonates), AZO (Al-Doped ZnO), SnO
2(stannic oxide), Cd
2SnO
4(stannic acid cadmium), Cu
2Among S (cupric sulfide), the ZnS (zinc sulphide) any one or any two kinds of combinations, particle size range is 20～80nm; Coatings additive(s) comprises a kind of of dispersion agent, flow agent, defoamer, auxiliary rheological agents, film coalescence aid and thickening material at least.Described dispersion agent is a kind of PU type macromolecule dispersing agent; Flow agent is silicone based or the fluorocarbon class; Defoamer is polyacrylic ester and polyolefins; Auxiliary rheological agents is a polyacrylate solution; Film coalescence aid is propylene glycol monomethyl ether or alcohol ester-12; Thickening material is a kind of non-ionic type associative thickener; Thinner is an organic solvent.Described resin plate is polycarbonate (PC), synthetic glass (PMMA), polyvinyl chloride (PVC) or polystyrene transparent resin sheet materials such as (PS).
The preparation method of nano transparent heat-insulating coating of the present invention is: at first by prescription the method for above-mentioned raw materials by mechanical blending is prepared into coating, adopt the transparent heat-insulated coating that the method for spraying or roller coat will contain nanoparticle to be coated on the resin then, under 60～180 ℃ temperature, solidified 1～2 hour, the resin that applies of nano transparent heat-insulating coating.
Insulation resin of the present invention can be made up of layer of transparent resin plate and layer of transparent heat insulating coat.Wherein the thickness of resin plate surface heat insulating coat is 20～50 μ m; The specific function effect of nanoparticle makes coating reach more than 75% in the transmitance of visible region, and the near-infrared region shielding rate reaches more than 60%, and the ultravioletlight screening rate reaches more than 98%.
Description of drawings
The present invention is further described below in conjunction with drawings and Examples.
Fig. 1 is a structural representation of the present invention.
1. transparent heat-insulated coating 2. resin plates among the figure.
Embodiment
Describe the present invention with relevant chart below in conjunction with example.But the invention is not restricted to given example.
As shown in Figure 1, transparent heat-insulated resin sheet is made up of resin plate 2 and transparent heat-insulated coating 1, and described transparent heat-insulated coating 1 thickness is 20～50 μ m, and described resin plate 2 is the engineering plastics plate.
Now enumerate following four embodiment, respectively the composition and the optics/heat-proof quality of the structure of transparent heat-insulated resin, transparent heat-insulated coating are tabulated.
The transparent heat-insulated resin board of example 1:PC is made up of one deck nano transparent heat-insulating coating and PC resin board.
The structure of the transparent heat-insulated resin of table 1
| Component | Form | Thickness | Remarks |
| Resin plate nano transparent heat-insulating coating | PC contains nanometer AZO, SnO 2 | 3mm 30μm | Film-forming temperature is 60 ℃, and film formation time is 2 hours |
The composition of the transparent heat-insulated coating of table 2
| Component | Material name | Specification | Consumption (wt%) |
| Film forming matter nano-powder nano-powder | Acrylic resin AZO SnO 2 | The A-1 particle diameter is that 40 ~ 80nm particle diameter is 20 ~ 60nm | 60 11 5 |
| Flow agent thinner thickening material | Silicone based acetone non-ionic type associative thickener | Commercially available product commercially available product commercially available product | 1 22 1 |
Method by roller coat is coated in transparent heat insulating dope on the PC sunlight board, drying and forming-film under certain filming condition, constitute and be coated with transparent heat-insulated PC resin plate of filming, this heat insulation glass resin plate has excellent heat insulation property and visible light transmissivity, through dependence test and calculating, concrete data see Table 3:
Table 3 is coated with the optics/heat-proof quality of the PC sunlight board of transparent heat-insulated coating
| Optical property | Heat-proof quality | |||
| Ultravioletlight screening rate 99.9% | Visible light transmissivity 76.1% | Infrared shielding rate 63.8% | 11 ℃ of the base plate temperature difference | Heat insulation index 58% |
The transparent heat-insulated poly (methyl methacrylate) plate of example 2:PMMA is made up of one deck nano transparent insulating coating and poly (methyl methacrylate) plate.
The structure of the transparent heat-insulated resin of table 4
| Component | Form | Thickness | Remarks |
| Resin plate nano transparent heat-insulating coating | PMMA contains nano-znic antimonite | 5mm 25μm | Film-forming temperature is 60 ℃, and film formation time is 2 hours |
The composition of the transparent heat-insulated coating of table 5
| Component | Material name | Specification | Consumption (wt%) |
| Film forming matter nano-powder diluent dispersant defoamer auxiliary rheological agents | Acrylic resin zinc antimonates acetone PU type macromolecule dispersing agent polyolefins polyacrylate solution | The A-2 particle diameter is 40 ~ 80nm commercially available product macromolecule dispersing agent commercially available product commercially available product | 31 3 62 2 1 1 |
Method by spraying is coated in transparent heat insulating dope on the synthetic glass PMMA plate, drying and forming-film under certain filming condition, constitute and be coated with transparent heat-insulated poly (methyl methacrylate) plate of filming, this heat insulation methacrylate sheet has excellent heat insulation property and visible light transmissivity, through dependence test and calculating, concrete data see Table 6:
Table 6 is coated with the optics/heat-proof quality of the synthetic glass glass (PMMA) of transparent heat-insulated coating
| Optical property | Heat-proof quality | |||
| Ultravioletlight screening rate 98.6% | Visible light transmissivity 82.8% | Infrared shielding rate 73.9% | 12 ℃ of the base plate temperature difference | Heat insulation index 60.7% |
The transparent heat-insulated resin board of example 3:PVC is made up of one deck nano transparent insulating coating and polyvinyl chloride resin plate.
The structure of the transparent heat-insulated resin of table 7
| Component | Form | Thickness | Remarks |
| Resin plate nano transparent heat-insulating coating | PVC contains nanometer Cd 2SnO 4、ZnS | 5mm 45μm | Film-forming temperature is 30 ℃, and film formation time is 24 hours |
The composition of the transparent heat-insulated coating of table 8
| Component | Material name | Specification | Consumption |
| Film forming matter nano-powder nano-powder auxiliary rheological agents thinner dispersion agent | Polyvinyl butyral resin Cd 2SnO 4ZnS polyacrylate solution Virahol PU type macromolecule dispersing agent | The PVB-1 particle diameter is that 40 ~ 80nm particle diameter is 20 ~ 60nm commercially available product commercially available product macromolecule dispersing agent | 42 20 5 1 27 5 |
Method by roller coat is coated in transparent heat insulating dope on the polyvinyl chloride resin sheet material, drying and forming-film under certain filming condition, constitute and be coated with transparent heat-insulated PVC sheet material of filming, this heat insulation glass resin plate has excellent heat insulation property and visible light transmissivity, through dependence test and calculating, concrete data see Table 9:
Table 9 is coated with the optics/heat-proof quality of the high saturating PVC plate of transparent heat-insulated coating
| Optical property | Heat-proof quality | |||
| Ultravioletlight screening rate 98.3% | Visible light transmissivity 80.5% | Infrared shielding rate 66.1% | 11 ℃ of the base plate temperature difference | Heat insulation index 59.2% |
The transparent heat-insulated resin of example 4:PS is made up of one deck nano transparent insulating coating and PS resin board.
The structure of the transparent heat-insulated resin of table 7
| Component | Form | Thickness | Remarks |
| Resin plate nano transparent heat-insulating coating | PS contains nanometer AZO, Cu 2S | 5mm 30μm | Film-forming temperature is 35 ℃, and film formation time is 24 hours |
The composition of the transparent heat-insulated coating of table 8
| Component | Material name | Specification | Consumption |
| Film forming matter nano-powder nano-powder levelling agent diluent dispersant coalescents | Polyvinyl butyral resin AZO Cu 2The silicone based Virahol PU of S type macromolecule dispersing agent propylene glycol monomethyl ether | The PVB-2 particle diameter is that 40 ~ 80nm particle diameter is 20 ~ 60nm commercially available product commercially available product macromolecule dispersing agent commercially available product | 40 15 5 1 31 5 3 |
Method by spraying is coated in transparent heat insulating dope on glass, drying and forming-film under certain filming condition, constitute and be coated with transparent heat-insulated PS sheet material of filming, this heat insulation glass resin plate has excellent heat insulation property and visible light transmissivity, through dependence test and calculating, concrete data see Table 9:
Table 9 is coated with the optics/heat-proof quality of the PS plate of transparent heat-insulated coating
| Optical property | Heat-proof quality | |||
| Ultravioletlight screening rate 99.1% | Visible light transmissivity 75.3% | Infrared shielding rate 65.4.% | 12 ℃ of the base plate temperature difference | Heat insulation index 58.8% |
Claims (6)
1, a kind of transparent heat-insulated resin sheet is characterized in that being made up of resin plate and transparent heat-insulated coating; The component and the parts by weight of wherein said heat insulating coat are as follows:
Macromolecule resin 30～65
Nano-powder 5～20
Coatings additive(s) 1～10
Thinner 29～58
Macromolecule resin is pure dissolubility or solvent type resin in the described coating; Nano-powder is for containing ZnSb at least
2O
6(zinc antimonates), AZO (Al-Doped ZnO), SnO
2(stannic oxide), Cd
2SnO
4(stannic acid cadmium), Cu
2Among S (cupric sulfide), the ZnS (zinc sulphide) any one or any two kinds of combinations, particle size range is 20～80nm; Coatings additive(s) comprises a kind of of dispersion agent, flow agent, defoamer, auxiliary rheological agents, film coalescence aid and thickening material at least.
2, transparent heat-insulated resin sheet according to claim 1 is characterized in that described pure dissolubility or solvent type resin are acrylic resin or polyvinyl butyral resin.
3, transparent heat-insulated resin sheet according to claim 1 is characterized in that described dispersion agent is a PU type macromolecule dispersing agent; Flow agent is silicone based or the fluorocarbon class; Defoamer is polyacrylic ester and polyolefins; Auxiliary rheological agents is a polyacrylate solution; Film coalescence aid is propylene glycol monomethyl ether or alcohol ester-12; Thickening material is the non-ionic type associative thickener; Thinner is an organic solvent.
4, transparent heat-insulated resin sheet according to claim 1 is characterized in that the transparent heat-insulated coating that will contain nanoparticle with the spraying or the method for roller coat is coated on the resin plate.
5, transparent heat-insulated resin sheet according to claim 1 is characterized in that described transparent heat-insulated coat-thickness is 20～50 μ m.
6, transparent heat-insulated resin sheet according to claim 1 is characterized in that described resin plate is the engineering plastics plate, and material is polycarbonate (PC), synthetic glass (PMMA), polyvinyl chloride (PVC) or polystyrene (PS).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100983643A CN100480306C (en) | 2006-12-08 | 2006-12-08 | Transparent heat-insulated resin sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100983643A CN100480306C (en) | 2006-12-08 | 2006-12-08 | Transparent heat-insulated resin sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1995107A true CN1995107A (en) | 2007-07-11 |
| CN100480306C CN100480306C (en) | 2009-04-22 |
Family
ID=38250320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100983643A Expired - Fee Related CN100480306C (en) | 2006-12-08 | 2006-12-08 | Transparent heat-insulated resin sheet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100480306C (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787238B (en) * | 2009-12-31 | 2012-01-25 | 江南大学 | Preparation method for high stain-resistant and thermal-insulating type UV curing fluorine coating |
| CN102559020A (en) * | 2011-12-11 | 2012-07-11 | 江苏荣昌化工有限公司 | High-decorative heat-insulating coating material for vehicles |
| CN102582136A (en) * | 2012-02-21 | 2012-07-18 | 南京工业大学 | Transparent heat insulating material with multilayer composite structure and preparation method thereof |
| CN102653654A (en) * | 2012-04-28 | 2012-09-05 | 安徽工程大学 | ATO (antimony doped tin oxides) coating material for laminated glass and application method thereof |
| CN103118984A (en) * | 2010-08-27 | 2013-05-22 | 日产化学工业株式会社 | Dispersion in hydrophobic organic solvent of surface-modified colloidal particles of anhydrous zinc antimonate, coating composition containing same, and coated member |
| CN103283532A (en) * | 2013-06-17 | 2013-09-11 | 湖北天瑞博能科技有限公司 | Nanometer self-assembly thermal insulation agricultural film |
| CN103483719A (en) * | 2013-08-28 | 2014-01-01 | 杭州正奥科技有限公司 | Repeatedly-adhered heat-insulating film and manufacturing method thereof |
| CN104292721A (en) * | 2014-09-22 | 2015-01-21 | 常州大学 | Ultraviolet-shielding polyvinyl butyral transparent heat-insulating material and preparation method thereof |
| CN104292720A (en) * | 2014-09-23 | 2015-01-21 | 常州大学 | Polyvinyl butyral composite heat-insulating film for safety glass and preparation method of film |
| CN104327558A (en) * | 2013-11-26 | 2015-02-04 | 阳泉市澳丽丝科技涂料有限公司 | Heat insulation coating |
| CN104448756A (en) * | 2014-11-26 | 2015-03-25 | 宁波小康塑料有限公司 | PC sheet material with coating and preparation method of PC sheet material |
| CN106496836A (en) * | 2016-11-22 | 2017-03-15 | 袁洁 | A kind of transparent lamina heat-barrier material |
| CN107383573A (en) * | 2017-07-13 | 2017-11-24 | 北京华腾新材料股份有限公司 | One kind contains near infrared absorption and reflection composite pigment multifunctional transparent heat insulating coat and polyolefin coextruded film and preparation |
| CN107619493A (en) * | 2017-10-04 | 2018-01-23 | 镇江市星耀智能装备有限公司 | A kind of preparation method of the sheet material of high water resistance |
| CN107964112A (en) * | 2017-12-13 | 2018-04-27 | 安徽新胜塑料科技有限公司 | A kind of preparation method of organic glass plate surface coating for woolen surface |
| CN108336167A (en) * | 2018-04-20 | 2018-07-27 | 深圳瑞凌新能源科技有限公司 | A kind of solar photovoltaic assembly with radiation cooling function |
| CN108517047A (en) * | 2018-05-04 | 2018-09-11 | 苏州奥美材料科技有限公司 | A kind of polycarbonate membrane and its preparation process that resistance is infrared |
| CN115260847A (en) * | 2022-07-21 | 2022-11-01 | 南京工业大学 | Transparent sound-proof heat-insulation coating and preparation method thereof |
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2006
- 2006-12-08 CN CNB2006100983643A patent/CN100480306C/en not_active Expired - Fee Related
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787238B (en) * | 2009-12-31 | 2012-01-25 | 江南大学 | Preparation method for high stain-resistant and thermal-insulating type UV curing fluorine coating |
| CN103118984A (en) * | 2010-08-27 | 2013-05-22 | 日产化学工业株式会社 | Dispersion in hydrophobic organic solvent of surface-modified colloidal particles of anhydrous zinc antimonate, coating composition containing same, and coated member |
| CN102559020A (en) * | 2011-12-11 | 2012-07-11 | 江苏荣昌化工有限公司 | High-decorative heat-insulating coating material for vehicles |
| CN102582136A (en) * | 2012-02-21 | 2012-07-18 | 南京工业大学 | Transparent heat insulating material with multilayer composite structure and preparation method thereof |
| CN102582136B (en) * | 2012-02-21 | 2014-12-10 | 南京工业大学 | Transparent heat insulating material with multilayer composite structure and preparation method thereof |
| CN102653654A (en) * | 2012-04-28 | 2012-09-05 | 安徽工程大学 | ATO (antimony doped tin oxides) coating material for laminated glass and application method thereof |
| CN103283532A (en) * | 2013-06-17 | 2013-09-11 | 湖北天瑞博能科技有限公司 | Nanometer self-assembly thermal insulation agricultural film |
| CN103283532B (en) * | 2013-06-17 | 2014-11-19 | 湖北天瑞博能科技有限公司 | Nanometer self-assembly thermal insulation agricultural film |
| CN103483719B (en) * | 2013-08-28 | 2016-04-13 | 杭州正奥科技有限公司 | A kind of thermal isolation film that can repeatedly paste and manufacture method |
| CN103483719A (en) * | 2013-08-28 | 2014-01-01 | 杭州正奥科技有限公司 | Repeatedly-adhered heat-insulating film and manufacturing method thereof |
| CN104327558A (en) * | 2013-11-26 | 2015-02-04 | 阳泉市澳丽丝科技涂料有限公司 | Heat insulation coating |
| CN104292721A (en) * | 2014-09-22 | 2015-01-21 | 常州大学 | Ultraviolet-shielding polyvinyl butyral transparent heat-insulating material and preparation method thereof |
| CN104292720A (en) * | 2014-09-23 | 2015-01-21 | 常州大学 | Polyvinyl butyral composite heat-insulating film for safety glass and preparation method of film |
| CN104448756A (en) * | 2014-11-26 | 2015-03-25 | 宁波小康塑料有限公司 | PC sheet material with coating and preparation method of PC sheet material |
| CN104448756B (en) * | 2014-11-26 | 2017-02-22 | 宁波小康塑料有限公司 | PC sheet material with coating and preparation method of PC sheet material |
| CN106496836A (en) * | 2016-11-22 | 2017-03-15 | 袁洁 | A kind of transparent lamina heat-barrier material |
| CN107383573A (en) * | 2017-07-13 | 2017-11-24 | 北京华腾新材料股份有限公司 | One kind contains near infrared absorption and reflection composite pigment multifunctional transparent heat insulating coat and polyolefin coextruded film and preparation |
| CN107383573B (en) * | 2017-07-13 | 2020-01-24 | 北京华腾新材料股份有限公司 | Multifunctional transparent heat-insulating coating containing near-infrared absorption and reflection composite pigment, polyolefin co-extruded film and preparation |
| CN107619493A (en) * | 2017-10-04 | 2018-01-23 | 镇江市星耀智能装备有限公司 | A kind of preparation method of the sheet material of high water resistance |
| CN107964112A (en) * | 2017-12-13 | 2018-04-27 | 安徽新胜塑料科技有限公司 | A kind of preparation method of organic glass plate surface coating for woolen surface |
| CN108336167A (en) * | 2018-04-20 | 2018-07-27 | 深圳瑞凌新能源科技有限公司 | A kind of solar photovoltaic assembly with radiation cooling function |
| CN108517047A (en) * | 2018-05-04 | 2018-09-11 | 苏州奥美材料科技有限公司 | A kind of polycarbonate membrane and its preparation process that resistance is infrared |
| CN115260847A (en) * | 2022-07-21 | 2022-11-01 | 南京工业大学 | Transparent sound-proof heat-insulation coating and preparation method thereof |
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Granted publication date: 20090422 Termination date: 20100108 |