CN107955692A - A kind of engineering machinery special lube and its production technology - Google Patents
A kind of engineering machinery special lube and its production technology Download PDFInfo
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- CN107955692A CN107955692A CN201711356252.8A CN201711356252A CN107955692A CN 107955692 A CN107955692 A CN 107955692A CN 201711356252 A CN201711356252 A CN 201711356252A CN 107955692 A CN107955692 A CN 107955692A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/105—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/08—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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Abstract
The invention discloses a kind of engineering machinery special lube and its production technology, it is made of the raw material of following weight：88 100 parts of biological basis oil, 2, 634 parts of di-tert-butyl p-cresol, iso-octyl 3 (3, 5 di-t-butyl hydroxy phenyls) 13 parts of propionic ester, 13 parts of triphenyl phosphate, 12 parts of alkyl phosphate, 57 parts of polyphosphoric acid, 34 parts of fatty acid methyl ester, 68 parts of organic zinc, 14 parts of sulfide aliphatic acid ester, vulcanize 35 parts of triglycerides, 25 parts of triethanol ammonium, 12 parts of silicone oil, vulcanize poly- 12 parts of isobutyl, 79 parts of glycerin mono-fatty acid ester, 13 parts of diolein, 36 parts of lanolin fatty acid, 12 parts of oxidized polyethylene wax, 13 parts of nanoporous silica particle, metal based 12 parts of sodium.Environment-friendly degradable of the present invention and there is good antioxidant, wear resistence, lubricity and cleaning effect.
Description
Technical field
The invention belongs to technical field of lubricating oil, and in particular to a kind of engineering machinery special lube and its production technology.
Background technology
Engineering machinery lubricating oil refers to that specialty is used for large excavator tool, loading machine, lifting machine, soil-shifting and road machine
The special lube of the heavy mechanical equipments such as tool.Engineering machinery lubricating oil mainly includes the special diesel supercharging engine of engineering machinery
Oil, engineering machinery is antiwear hydraulic oil specially used, totally four major class such as heavy load gear oil, hydraulic transmission oil, more than ten kinds.It is existing
Engineering machinery lubricating oil is mostly mineral base oil, and not environmentally, and the existing biological basis oiliness as replacement can not possess generally
Cleaning effect.
The content of the invention
In view of this, it is an object of the present invention to provide a kind of engineering machinery special lube and its production technology.
In order to solve the above-mentioned technical problem, the technical scheme is that：A kind of engineering machinery special lube, by following
The raw material of weight is made：88-100 parts of biological basis oil, 3-4 parts of DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5
Di-t-butyl-hydroxy phenyl) 1-3 parts of propionic ester, 1-3 parts of triphenyl phosphate, 1-2 parts of alkyl phosphate, 5-7 parts of polyphosphoric acid, fat
3-4 parts of fat acid methyl ester, 6-8 parts of organic zinc, 1-4 parts of sulfide aliphatic acid ester, 3-5 parts of triglycerides of vulcanization, triethanol ammonium 2-5
Part, 1-2 parts of silicone oil, vulcanization it is poly- isobutyl 1-2 parts, 7-9 parts of glycerin mono-fatty acid ester, 1-3 parts of diolein, lanolin fatty acid 3-6
It is part, 1-2 parts of oxidized polyethylene wax, 1-3 parts of nanoporous silica particle, sodium 1-2 parts metal based.
A kind of production technology of engineering machinery special lube, it is characterised in that：Comprise the following steps：
1）By DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, triphenyl phosphate,
Alkyl phosphate, polyphosphoric acid, fatty acid methyl ester, sulfide aliphatic acid ester, vulcanization triglycerides, triethanol ammonium, the poly- isobutyl of vulcanization,
Glycerin mono-fatty acid ester and lanolin fatty acid are mixed by portion rate, 10~20min are stirred under the rotating speed of 20~26rps, and be heated to 70
~80 DEG C, sodium hydroxide solution is added dropwise, adjusts pH value to 7~8 stoppings, being cooled to 50~60 DEG C, obtain reaction solution；
2）Above-mentioned reaction solution is mixed with nanoporous silica particle, metal based sodium and organic zinc by portion rate, maintains temperature
50~60 DEG C of degree, stirs 30min under the rotating speed of 15~20rps, when reaction 1~3 is small after, it is spare；The metal based sodium, its
Working mechanism is same greasy filth chemical reaction neutralization reaction occurs so that greasy filth is solvable, avoids greasy filth accumulated plugging.
3）By step 2）Gained mixed solution through filtering, wash by alcohol, washes, and drying is spare；
4）Step 3 is added after biological basis oil is heated to 55~65 DEG C）Gained mixed solution, silicon is added dropwise by portion rate
Oil, stirs 10~20min under the rotating speed of 35~40rps；Glycerin mono-fatty acid ester and oxidized polyethylene wax are added by portion rate again,
20~30min is stirred under the rotating speed of 30~35rps, to obtain the final product.
Further, the optional castor oil of the biological basis oil.
Further, the step 1）Need to carry out under the protection of nitrogen.
Further, the step 2）Described in sodium hydroxide solution pass through pipe for 32% sodium hydroxide solution and desalted water
Road is conveyed through 10% sodium hydroxide solution that static mixer is mixed into.
Further, nanoporous silica particle jelly type titanium dioxide made of glass or quartz are with ethanol
Silicon is made as raw material.This type silica gel has the colloid system that wherein solid particle is interconnected and can not crushed in room temperature and normal pressure
System.Since the nano-pore particle with nanosized oil-soluble hole of the present invention reduces friction coefficient, and long-term gradually release
Active ingredient, the antifriction liniment that the lubricant oil composite comprising nano-pore particle of the invention can rub as long-term reduction, from
And show splendid lubricating action.
Further, it is made of the raw material of following weight：Biological basis oil 92 parts, DBPC 2,6 ditertiary butyl p cresol
3.5 parts, 2 parts of iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, 2 parts of triphenyl phosphate, 1.5 parts of alkyl phosphate,
6 parts of polyphosphoric acid, 3.5 parts of fatty acid methyl ester, 7 parts of organic zinc, 2 parts of sulfide aliphatic acid ester, 4 parts of triglycerides of vulcanization, three ethanol
3 parts of ammonium, 1.5 parts of silicone oil, poly- 1.5 parts of the isobutyl of vulcanization, 8 parts of glycerin mono-fatty acid ester, 2 parts of diolein, 5 parts of lanolin fatty acid, oxygen
Change 1.5 parts of Tissuemat E, 2 parts of nanoporous silica particle, 1.5 parts of metal based sodium.
（Antioxidant）DBPC 2,6 ditertiary butyl p cresol.
（Antiwear additive）For triphenyl phosphate, alkyl phosphate.
（Extreme pressure agent）For sulfide aliphatic acid ester, vulcanization triglycerides.
（Antirust agent）Triethanol ammonium.
（Defoamer）Silicone oil.
（Detersive）Vulcanize poly- isobutyl.
（Lubricating additive）Glycerin mono-fatty acid ester, diolein.
（Viscosity additive）Oxidized polyethylene wax.
Beneficial effects of the present invention are：By biological basis oil alternative ore base oil, can be biodegradable and rapidly reduce
Environmental pollution.And added by the cooperation of each analog assistant, and the reasonable process that step is simple and environmentally-friendly, easy to implement so that the work
Journey machinery special lube has good antioxidant, wear resistence, lubricity, sulfide aliphatic acid ester, the vulcanization glycerine three of addition
Ester make it that product stability is more preferable as defoamer, coordinates antirust agent triethanol ammonium so that preventing as extreme pressure agent, the silicone oil of addition
Rust is more preferable；The poly- isobutyl of vulcanization of addition is more preferable as detersive complexed metal base sodium cleaning effect.
Embodiment
Embodiment 1
A kind of engineering machinery special lube, is made of the raw material of following weight：Biological basis oil 88 parts, bis- uncles of 2,6-
3 parts of butyl paracresol, 1 part of iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, 1 part of triphenyl phosphate, alkyl phosphoric acid
1 part of ester, 5 parts of polyphosphoric acid, 3 parts of fatty acid methyl ester, 6 parts of organic zinc, 1 part of sulfide aliphatic acid ester, 3 parts of triglycerides of vulcanization, three
2 parts of ethanol ammonium, 1 part of silicone oil, poly- 1 part of the isobutyl of vulcanization, 7 parts of glycerin mono-fatty acid ester, 1 part of diolein, 3 parts of lanolin fatty acid, oxygen
Change 1 part of Tissuemat E, 1 part of nanoporous silica particle, 1 part of metal based sodium.
A kind of production technology of engineering machinery special lube, it is characterised in that：Comprise the following steps：
1）By DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, triphenyl phosphate,
Alkyl phosphate, polyphosphoric acid, fatty acid methyl ester, sulfide aliphatic acid ester, vulcanization triglycerides, triethanol ammonium, the poly- isobutyl of vulcanization,
Glycerin mono-fatty acid ester and lanolin fatty acid are mixed by portion rate, and 10min is stirred under the rotating speed of 20rps, and are heated to 70 DEG C, dropwise
Sodium hydroxide solution is added, pH value is adjusted to 7 stoppings, being cooled to 50 DEG C, obtain reaction solution；
2）Above-mentioned reaction solution is mixed with nanoporous silica particle, metal based sodium and organic zinc by portion rate, maintains temperature
50 DEG C of degree, stirs 30min under the rotating speed of 15rps, when reaction 1 is small after, it is spare；The metal based sodium, its working mechanism are
Neutralization reaction occurs with greasy filth chemical reaction so that greasy filth is solvable, avoids greasy filth accumulated plugging.
3）By step 2）Gained mixed solution through filtering, wash by alcohol, washes, and drying is spare；
4）Step 3 is added after biological basis oil is heated to 55 DEG C）Gained mixed solution, silicone oil is added dropwise by portion rate,
10min is stirred under the rotating speed of 35rps；Glycerin mono-fatty acid ester and oxidized polyethylene wax are added by portion rate again, in the rotating speed of 30rps
Lower stirring 20min, to obtain the final product.
Further, the optional castor oil of the biological basis oil.
Further, the step 1）Need to carry out under the protection of nitrogen.
Further, the step 2）Described in sodium hydroxide solution pass through pipe for 32% sodium hydroxide solution and desalted water
Road is conveyed through 10% sodium hydroxide solution that static mixer is mixed into.
Further, nanoporous silica particle jelly type titanium dioxide made of glass or quartz are with ethanol
Silicon is made as raw material.This type silica gel has the colloid system that wherein solid particle is interconnected and can not crushed in room temperature and normal pressure
System.Since the nano-pore particle with nanosized oil-soluble hole of the present invention reduces friction coefficient, and long-term gradually release
Active ingredient, the antifriction liniment that the lubricant oil composite comprising nano-pore particle of the invention can rub as long-term reduction, from
And show splendid lubricating action.
Embodiment 2
A kind of engineering machinery special lube, is made of the raw material of following weight：Biological basis oil 100 parts, 2,6- bis-
4 parts of Butylated Hydroxytoluene, 3 parts of iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, 3 parts of triphenyl phosphate, alkyl phosphorus
2 parts of acid esters, 7 parts of polyphosphoric acid, 4 parts of fatty acid methyl ester, 8 parts of organic zinc, 4 parts of sulfide aliphatic acid ester, vulcanization 5 parts of triglycerides,
5 parts of triethanol ammonium, 2 parts of silicone oil, poly- 2 parts of the isobutyl of vulcanization, 9 parts of glycerin mono-fatty acid ester, 3 parts of diolein, 6 parts of lanolin fatty acid,
2 parts of oxidized polyethylene wax, 3 parts of nanoporous silica particle, 2 parts of metal based sodium.
A kind of production technology of engineering machinery special lube, it is characterised in that：Comprise the following steps：
1）By DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, triphenyl phosphate,
Alkyl phosphate, polyphosphoric acid, fatty acid methyl ester, sulfide aliphatic acid ester, vulcanization triglycerides, triethanol ammonium, the poly- isobutyl of vulcanization,
Glycerin mono-fatty acid ester and lanolin fatty acid are mixed by portion rate, and 20min is stirred under the rotating speed of 26rps, and are heated to 80 DEG C, are added dropwise
Enter sodium hydroxide solution, adjust pH value to 8 stoppings, being cooled to 60 DEG C, obtain reaction solution；
2）Above-mentioned reaction solution is mixed with nanoporous silica particle, metal based sodium and organic zinc by portion rate, maintains temperature
60 DEG C of degree, stirs 30min under the rotating speed of 20rps, when reaction 3 is small after, it is spare；The metal based sodium, its working mechanism are
Neutralization reaction occurs with greasy filth chemical reaction so that greasy filth is solvable, avoids greasy filth accumulated plugging.
3）By step 2）Gained mixed solution through filtering, wash by alcohol, washes, and drying is spare；
4）Step 3 is added after biological basis oil is heated to 65 DEG C）Gained mixed solution, silicone oil is added dropwise by portion rate,
20min is stirred under the rotating speed of 40rps；Glycerin mono-fatty acid ester and oxidized polyethylene wax are added by portion rate again, in the rotating speed of 35rps
Lower stirring 30min, to obtain the final product.
Further, the optional castor oil of the biological basis oil.
Further, the step 1）Need to carry out under the protection of nitrogen.
Further, the step 2）Described in sodium hydroxide solution pass through pipe for 32% sodium hydroxide solution and desalted water
Road is conveyed through 10% sodium hydroxide solution that static mixer is mixed into.
Further, nanoporous silica particle jelly type titanium dioxide made of glass or quartz are with ethanol
Silicon is made as raw material.This type silica gel has the colloid system that wherein solid particle is interconnected and can not crushed in room temperature and normal pressure
System.Since the nano-pore particle with nanosized oil-soluble hole of the present invention reduces friction coefficient, and long-term gradually release
Active ingredient, the antifriction liniment that the lubricant oil composite comprising nano-pore particle of the invention can rub as long-term reduction, from
And show splendid lubricating action.
Embodiment 3
A kind of engineering machinery special lube, is made of the raw material of following weight：Biological basis oil 92 parts, bis- uncles of 2,6-
3.5 parts of butyl paracresol, 2 parts of iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, 2 parts of triphenyl phosphate, alkyl phosphorus
1.5 parts of acid esters, 6 parts of polyphosphoric acid, 3.5 parts of fatty acid methyl ester, 7 parts of organic zinc, 2 parts of sulfide aliphatic acid ester, vulcanization triglycerides 4
Part, 3 parts of triethanol ammonium, 1.5 parts of silicone oil, poly- 1.5 parts of the isobutyl of vulcanization, 8 parts of glycerin mono-fatty acid ester, 2 parts of diolein, wool
5 parts of acid, 1.5 parts of oxidized polyethylene wax, 2 parts of nanoporous silica particle, 1.5 parts of metal based sodium.
A kind of production technology of engineering machinery special lube, it is characterised in that：Comprise the following steps：
1）By DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, triphenyl phosphate,
Alkyl phosphate, polyphosphoric acid, fatty acid methyl ester, sulfide aliphatic acid ester, vulcanization triglycerides, triethanol ammonium, the poly- isobutyl of vulcanization,
Glycerin mono-fatty acid ester and lanolin fatty acid are mixed by portion rate, and 15min is stirred under the rotating speed of 23rps, and are heated to 75 DEG C, are added dropwise
Enter sodium hydroxide solution, adjust pH value to 7.2 stoppings, being cooled to 55 DEG C, obtain reaction solution；
2）Above-mentioned reaction solution is mixed with nanoporous silica particle, metal based sodium and organic zinc by portion rate, maintains temperature
55 DEG C of degree, stirs 30min under the rotating speed of 18rps, when reaction 2 is small after, it is spare；The metal based sodium, its working mechanism are
Neutralization reaction occurs with greasy filth chemical reaction so that greasy filth is solvable, avoids greasy filth accumulated plugging.
3）By step 2）Gained mixed solution through filtering, wash by alcohol, washes, and drying is spare；
4）Step 3 is added after biological basis oil is heated to 60 DEG C）Gained mixed solution, silicone oil is added dropwise by portion rate,
15min is stirred under the rotating speed of 37rps；Glycerin mono-fatty acid ester and oxidized polyethylene wax are added by portion rate again, in the rotating speed of 33rps
Lower stirring 25min, to obtain the final product.
Further, the optional castor oil of the biological basis oil.
Further, the step 1）Need to carry out under the protection of nitrogen.
Further, the step 2）Described in sodium hydroxide solution pass through pipe for 32% sodium hydroxide solution and desalted water
Road is conveyed through 10% sodium hydroxide solution that static mixer is mixed into.
Further, nanoporous silica particle jelly type titanium dioxide made of glass or quartz are with ethanol
Silicon is made as raw material.This type silica gel has the colloid system that wherein solid particle is interconnected and can not crushed in room temperature and normal pressure
System.Since the nano-pore particle with nanosized oil-soluble hole of the present invention reduces friction coefficient, and long-term gradually release
Active ingredient, the antifriction liniment that the lubricant oil composite comprising nano-pore particle of the invention can rub as long-term reduction, from
And show splendid lubricating action.
Experimental example
Experimental subjects：Using engineering machinery special lube made from the embodiment of the present invention 1 and 3 as experimental group one, in fact
Group two is tested, chooses ordinary skill machinery special lube group as a comparison in city, four groups of engineering machinery used in experimentation
Special lube engineering machinery special lube its weight, number all same.
Experimental method：Experimental method：Engineering machinery special lube in the present embodiment is used into GB/T 8030-1987
Standard assay carries out each performance detection.
Experiment purpose：Test antioxidant, wear resistence, the lubrication of above-mentioned experimental group and contrast groups engineering machinery special lube
Property and cleaning effect, according to the numerical ordering of GB/T 8030-1987 standard tests, general, preferable, poor three class of remarks.
And by result record in the following table.
By being contrasted to the experimental data of upper table, so as to draw the engineering machine by being prepared in the present invention
Antioxidant, wear resistence, lubricity and the cleaning effect of tool special lube are optimal.
Beneficial effects of the present invention are：Beneficial effects of the present invention are：, can by biological basis oil alternative ore base oil
Environmental pollution is rapidly reduced with biodegradable.And added by the cooperation of each analog assistant, and step is simple and environmentally-friendly, is easy to real
The reasonable process applied so that the engineering machinery special lube has good antioxidant, wear resistence, lubricity, the sulphur of addition
Change fatty acid ester, vulcanization triglycerides make it that product stability is more preferable, coordinates as extreme pressure agent, the silicone oil of addition as defoamer
Antirust agent triethanol ammonium make it that antirust is more preferable；The poly- isobutyl of vulcanization of addition as detersive complexed metal base sodium cleaning effect more
It is good.
Certainly, the above is the representative instance of the present invention, and in addition, the present invention can also have other a variety of specific implementations
Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.
Claims (7)
1. a kind of engineering machinery special lube, it is characterised in that be made of the raw material of following weight：Biological basis oil
88-100 parts, 3-4 parts of DBPC 2,6 ditertiary butyl p cresol, 1-3 parts of iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester,
1-3 parts of triphenyl phosphate, 1-2 parts of alkyl phosphate, 5-7 parts of polyphosphoric acid, 3-4 parts of fatty acid methyl ester, 6-8 parts of organic zinc, sulphur
1-4 parts of fatty acid ester of change, 3-5 parts of triglycerides of vulcanization, 2-5 parts of triethanol ammonium, 1-2 parts of silicone oil, vulcanization are isobutyl 1-2 parts poly-, sweet
Oily monoleate 7-9 parts, 1-3 parts of diolein, 3-6 parts of lanolin fatty acid, 1-2 parts of oxidized polyethylene wax, nano-pore titanium dioxide
It is 1-3 parts of silicon grain, sodium 1-2 parts metal based.
A kind of 2. production technology of engineering machinery special lube, it is characterised in that：Comprise the following steps：
1）By DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl) propionic ester, triphenyl phosphate,
Alkyl phosphate, polyphosphoric acid, fatty acid methyl ester, sulfide aliphatic acid ester, vulcanization triglycerides, triethanol ammonium, the poly- isobutyl of vulcanization,
Glycerin mono-fatty acid ester and lanolin fatty acid are mixed by portion rate, 10~20min are stirred under the rotating speed of 20~26rps, and be heated to 70
~80 DEG C, sodium hydroxide solution is added dropwise, adjusts pH value to 7~8 stoppings, being cooled to 50~60 DEG C, obtain reaction solution；
2）Above-mentioned reaction solution is mixed with nanoporous silica particle, metal based sodium and organic zinc by portion rate, maintains temperature
50~60 DEG C of degree, stirs 30min under the rotating speed of 15~20rps, when reaction 1~3 is small after, it is spare；
3）By step 2）Gained mixed solution through filtering, wash by alcohol, washes, and drying is spare；
4）Step 3 is added after biological basis oil is heated to 55~65 DEG C）Gained mixed solution, silicon is added dropwise by portion rate
Oil, stirs 10~20min under the rotating speed of 35~40rps；Glycerin mono-fatty acid ester and oxidized polyethylene wax are added by portion rate again,
20~30min is stirred under the rotating speed of 30~35rps, to obtain the final product.
A kind of 3. engineering machinery special lube as claimed in claim 1, it is characterised in that：The optional castor of the biological basis oil
Sesame oil.
A kind of 4. engineering machinery special lube as claimed in claim 2, it is characterised in that：The step 1）Need in nitrogen
Protection under carry out.
A kind of 5. engineering machinery special lube as claimed in claim 2, it is characterised in that：The step 2）Described in hydrogen-oxygen
Change 10% hydroxide that sodium solution is mixed into desalted water for 32% sodium hydroxide solution by pipeline by static mixer
Sodium solution.
A kind of 6. engineering machinery special lube as claimed in claim 1, it is characterised in that：The nanoporous silica
Grain jelly type silica made of glass or quartz are with ethanol is made as raw material.
A kind of 7. engineering machinery special lube as claimed in claim 1, it is characterised in that：By the original of following weight
Material is made：92 parts of biological basis oil, 3.5 parts of DBPC 2,6 ditertiary butyl p cresol, iso-octyl -3- (3,5 di-t-butyls-hydroxy phenyl)
2 parts of propionic ester, 2 parts of triphenyl phosphate, 1.5 parts of alkyl phosphate, 6 parts of polyphosphoric acid, 3.5 parts of fatty acid methyl ester, organic zinc 7
Part, 2 parts of sulfide aliphatic acid ester, 4 parts of triglycerides of vulcanization, 3 parts of triethanol ammonium, 1.5 parts of silicone oil, poly- 1.5 parts of the isobutyl of vulcanization, glycerine
8 parts of monoleate, 2 parts of diolein, 5 parts of lanolin fatty acid, 1.5 parts of oxidized polyethylene wax, nanoporous silica particle 2
Part, 1.5 parts of metal based sodium.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109097174A (en) * | 2018-08-18 | 2018-12-28 | 孟祥冰 | A kind of water glycol nonflammable hydraulic fluid and preparation method thereof |
| CN109679706A (en) * | 2018-12-29 | 2019-04-26 | 南京派诺金属表面处理技术有限公司 | The preparation method of reactive drawing oil |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1511931A (en) * | 2000-12-08 | 2004-07-14 | 申保安 | Full loss mechanical lubricating oil |
| CN102212411A (en) * | 2011-04-25 | 2011-10-12 | 广西大学 | Universal machinery lubricating oil in pharmaceutical industry |
| CN102947429A (en) * | 2010-03-26 | 2013-02-27 | 爱思开润滑油株式会社 | Lubricating oil composition for reducing friction comprising nanoporous particles |
| JP2014047403A (en) * | 2012-08-31 | 2014-03-17 | Nsk Ltd | Rolling bearing |
| CN104031729A (en) * | 2014-07-02 | 2014-09-10 | 宝捷润滑油镇江有限公司 | Lubricating oil special for motorcycle engine and preparing method thereof |
| CN104419510A (en) * | 2013-08-22 | 2015-03-18 | 韦尔斯润滑油(天津)有限公司 | Material preparing method for lubricating oil production |
| CN105524682A (en) * | 2015-12-11 | 2016-04-27 | 东莞太平洋博高润滑油有限公司 | Wear-self-repairing gear oil |
| CN107090335A (en) * | 2017-05-05 | 2017-08-25 | 山东沾化莱斯特石油化工有限公司 | A kind of thermostable heat-conductive oil |
-
2017
- 2017-12-16 CN CN201711356252.8A patent/CN107955692A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1511931A (en) * | 2000-12-08 | 2004-07-14 | 申保安 | Full loss mechanical lubricating oil |
| CN102947429A (en) * | 2010-03-26 | 2013-02-27 | 爱思开润滑油株式会社 | Lubricating oil composition for reducing friction comprising nanoporous particles |
| CN102212411A (en) * | 2011-04-25 | 2011-10-12 | 广西大学 | Universal machinery lubricating oil in pharmaceutical industry |
| JP2014047403A (en) * | 2012-08-31 | 2014-03-17 | Nsk Ltd | Rolling bearing |
| CN104419510A (en) * | 2013-08-22 | 2015-03-18 | 韦尔斯润滑油(天津)有限公司 | Material preparing method for lubricating oil production |
| CN104031729A (en) * | 2014-07-02 | 2014-09-10 | 宝捷润滑油镇江有限公司 | Lubricating oil special for motorcycle engine and preparing method thereof |
| CN105524682A (en) * | 2015-12-11 | 2016-04-27 | 东莞太平洋博高润滑油有限公司 | Wear-self-repairing gear oil |
| CN107090335A (en) * | 2017-05-05 | 2017-08-25 | 山东沾化莱斯特石油化工有限公司 | A kind of thermostable heat-conductive oil |
Non-Patent Citations (2)
| Title |
|---|
| 张康夫 编著: "《防锈油脂与乳化切削油》", 31 May 1983, 国防工业出版社 * |
| 汪多仁 编著: "《绿色油脂深加工产品》", 28 February 2007, 科学技术文献出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109097174A (en) * | 2018-08-18 | 2018-12-28 | 孟祥冰 | A kind of water glycol nonflammable hydraulic fluid and preparation method thereof |
| CN109679706A (en) * | 2018-12-29 | 2019-04-26 | 南京派诺金属表面处理技术有限公司 | The preparation method of reactive drawing oil |
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