CN106701284A - Open gear oil composition and preparation method thereof - Google Patents
Open gear oil composition and preparation method thereof Download PDFInfo
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- CN106701284A CN106701284A CN201611207316.3A CN201611207316A CN106701284A CN 106701284 A CN106701284 A CN 106701284A CN 201611207316 A CN201611207316 A CN 201611207316A CN 106701284 A CN106701284 A CN 106701284A
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- type gear
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/0806—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/14—Metal deactivation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention provides an open gear oil composition and a preparation method thereof. The open gear oil composition is prepared from 85.5-99.56%, preferably 90.9-98.37%, more preferably 92-96% of ester synthetic oil, 0.1-8%, preferably 1-6% of anti-wear reagent at extreme pressure, 0.03-3.0%, preferably 0.1-1.5% of oil-based antiabrasive agent, 0.01-0.5%, preferably 0.03-0.1% of metal deactivator and 0.3-3.0%, preferably 0.5-1.5% of antioxygen according to the total weight of the open gear oil composition being 100%. The open gear oil composition has good antiabrasive and abrasion-resistant performance, extremely high bearing capacity and high anti-rust and water-resistant performance, further has excellent low-temperature fluidity and high-temperature adhesion and excellent shear stability, and has the wide application range, and no oil is shed when the open gear oil composition is used for a long time.
Description
Technical field
The invention belongs to lubricating oil field, and in particular to a kind of open type gear oil composition and preparation method thereof.
Background technology
Exposed gear oil is mainly used in lubricating the operating tooth of open type, semi-open type gear-box and low speed heavy load geared system
Wheel, on the Work machine of the industries such as cement, metallurgy, mining industry, particularly has extensively on some oversized slewings
Using.Because open type (or semi-open type) transmission exposes, it is easy to during work by dust or other extraneous various factors shadows
Ring and cause abrasion and oil deterioration, therefore exposed gear oil requires possess good adhesiveness, viscosity-temperature characteristics, extreme pressure anti-wear
Deng to ensure exposed gear during low-speed running, gear surface has enough oil films to protect.
Exposed gear oil product is generally divided into asphaltic base exposed gear oil, graphite-based exposed gear grease, full oil type open type tooth
Wheel oil etc..Asphaltic base exposed gear oil is poor because of viscosity temperature characteristic and contamination resistance, and solvent flashing exists at present containing strong carcinogen etc.
America and Europe has been prohibited from using；Graphite-based exposed gear grease is the widest product of current range of application, such as patent application document
CN104164277A provides a kind of heavy load open-type gear grease and preparation method thereof, is lubricated by base oil, composite aluminum base
Fat, graphite, MoS2Etc. being prepared from, with good adhesiveness and extreme pressure and antiwear behavior, frictional resistance can be reduced, save power
Consumption, but due to graphite and MoS2Belong to black solid lubricant, inconvenience is brought to maintenance and cleaned in situ, its is low in addition
Warm mobility is poor, also limit its application.
The agent of synthesis type exposed gear lubricating is generally formulated using high viscosity synthetic base oil and additive, viscous with height
Spend index synthetic base oil and additive with the use of making it have excellent thermal oxidation stability, high temperature performance and pole
Pressure wear resistence.Patent application document CN104962360A provides a kind of synthesis type open type gear oil composition, using three kinds not
With synthesizing ester base oil reconciled and with appropriate additive compatibility, with preferable thermal oxidation stability, high/low temperature
Performance and extreme pressure anti-wear, and viscosity adjustable extent is wide, substantially meets the duty requirements of various open gears, but because of it
Comprising various synthesizing esters oil complex structure, prepare cumbersome, corresponding commercial product is lacked in the market, so cannot
Carry out industrial amplification production.
The content of the invention
Problems to be solved by the invention
Present invention aim at a kind of open type gear oil composition of offer and preparation method thereof.The open type gear oil composition
Preparation method it is simple, excellent combination property can be flexibly applied to splash, be added dropwise, infiltrating and various lubrication sides such as oil foglubrication
Formula, while problem will not be polluted to equipment, environment etc..
The scheme for solving problem
The present invention provides a kind of open type gear oil composition, and the gross weight with the open type gear oil composition is 100%
Meter, comprising following components：
Synthetic ester lubricant：85.5-99.56%, preferably 90.9-98.37%, more preferably 92-96%；
Extreme pressure anti-wear additives：0.1-8%, preferably 1-6%；
Oiliness anti-friction composition：0.03-3.0%, preferably 0.1%-1.5%；
Matal deactivator：0.01-0.5%, preferably 0.03%-0.1%；
Antioxidant：0.3-3.0%, preferably 0.5%-1.5%.
Open type gear oil composition of the invention, the synthetic ester lubricant contains being total to for alkyl and ester group including main chain
Polymers, preferably includes the copolymer of alhpa olefin and unsaturated Esters oil, wherein, the carbon number of the alhpa olefin is between 1-22
Integer between integer, preferably 5-17；Preferably, the unsaturated Esters oil includes that unsaturated acid anhydride and alcohol reaction are prepared not
Saturation dibasic acid esters.
Preferably, the average weight-average molecular weight of the synthetic ester lubricant is 1000-10000Da, preferably 3000-10000Da.
Open type gear oil composition of the invention, the extreme pressure anti-wear additives include：Sulfur-bearing extreme pressure anti-wear additives, phosphorous pole
Pressure antiwear additive in one or two；Preferably, the sulfur-bearing extreme pressure anti-wear additives include：Sulfide aliphatic acid ester, olefine sulfide, sulphur
Change isobutene, benzyl polysulfide, phenyl polysulfide, dialkyl dithiocarbamate, dialkyl dithio amino first
One or more in acid esters；The phosphorous extreme pressure anti-wear additives include：Triphenyl phosphate, tricresyl phosphate, acid phosphoric acid ester,
One or more in alkyl phosphate, alkyl phosphoric acid amine, aryl phosphoric acids amine, phosphorodithioate, ashless organic phospho acid amine salt.
Open type gear oil composition of the invention, the extreme pressure anti-wear additives include：Sulfur-bearing extreme pressure anti-wear additives and phosphorous
Extreme pressure anti-wear additives；Preferably, the sulfur-bearing extreme pressure anti-wear additives and the mass ratio of phosphorous extreme pressure anti-wear additives are 1:4~4:1, preferably
1:2~2:1.
Open type gear oil composition of the invention, the oiliness anti-friction composition includes：Aliphatic acid, fatty acid ester, fat
One or more in alcohol, amine salt, organosulfur compound；Preferably, the oiliness anti-friction composition includes：Ten dihydroxystearic acids,
One or more in stearic acid, oleic acid, butyl oleate, glyceryl monooleate, oleic acid epoxy ester.
Open type gear oil composition of the invention, the matal deactivator includes：Benzotriazole or derivatives thereof, benzo
One kind or many in thiazole or derivatives thereof, thiadiazoles or derivatives thereof, benzimidazole or derivatives thereof, indazole or derivatives thereof
Kind.
Open type gear oil composition of the invention, the antioxidant includes：In amine antioxidants, phenolic antioxidant
One or two；Preferably, the amine antioxidants include：It is right, in p- dioctyl diphenylamine, octyl group butyl diphenylamines, naphthylamines
One or more；The phenolic antioxidant includes DBPC 2,6 ditertiary butyl p cresol, double (3,5- di-tert-butyl-4-hydroxyl benzyls)
One or two in thioether.
Open type gear oil composition of the invention, the open type gear oil composition also includes antirust agent, anticorrosion
One or more in agent, demulsifier.
Open type gear oil composition of the invention, according to the method for testing of GB/T265, the synthetic ester lubricant exists
Kinematic viscosity at 100 DEG C is 15~3000mm2/s。
The present invention also provides a kind of preparation method of open type gear oil composition of the invention, including by the open type
The step of each component of gear oil composition mixes.
The effect of invention
Open type gear oil composition of the present invention possesses preferable anti-attrition abrasion resistance and high bearing capacity, antirust water resistant
Property it is strong, also with excellent low temperature flow and high temperature adhesion, shear stability is excellent, and long-term use does not get rid of oil, with wide
The general scope of application.
Specific embodiment
The present invention provides a kind of open type gear oil composition, and the gross weight with the open type gear oil composition is 100%
Meter, comprising following components：
Synthetic ester lubricant：85.5-99.56%, preferably 90.9-98.37%, more preferably 92-96%；
Extreme pressure anti-wear additives：0.1-8%, preferably 1-6%；
Oiliness anti-friction composition：0.03-3.0%, preferably 0.1%-1.5%；
Matal deactivator：0.01-0.5%, preferably 0.03%-0.1%；
Antioxidant：0.3-3.0%, preferably 0.5%-1.5%.
Open type gear oil composition of the invention, the present invention in synthetic ester lubricant have excellent lubricating ability,
Oxidation stability, hydrolytic stability and adhesion.In the present invention, the addition of the synthetic ester lubricant is 85.5-99.56%,
It is preferred that 90.9-98.37%, more preferably 92-96%.
Open type gear oil composition of the invention, the synthetic ester lubricant contains the copolymerization of alkyl and ester group for main chain
Thing.Included in synthetic ester lubricant with more highly polar ester group so that synthetic ester lubricant be easier absorption in metal surface；From
And enable that open type gear oil composition forms thick oil film in friction surface, the lubrication state of friction surface is improved,
Enhancing anti-attrition, greasy property；This extremely strong absorption affinity also improves the water resistant erosion of open type gear oil composition simultaneously.Ester
The poly- hydrocarbyl molecular chain included in class artificial oil so that the hydrolytic stability and oxidation stability of open type gear oil composition are excellent
It is different.
Specifically, the synthetic ester lubricant includes the copolymer of alhpa olefin and unsaturated Esters oil；Wherein, the price of alhpa olefin
Cheap, cost is relatively low.Unsaturated Esters oil enables to the synthetic ester lubricant to have high viscosity index (HVI) and shear stability, in the summer in winter
Ji Jun has good adhesion property, while will not the thinning loss because the lasting shearing under top load runs.
More specifically, in the synthetic ester lubricant, the carbon number of alhpa olefin is the integer between 1-22, preferably 5-17
Between integer, specifically, the unsaturated Esters oil include unsaturated acid anhydride and alcohol reaction prepare unsaturated dibasic acid esters.
Preferably, the average weight-average molecular weight of the synthetic ester lubricant is 1000-10000Da, preferably 3000-10000Da.
Synthetic ester lubricant is applied in open type gear oil composition of the invention, the synthetic ester lubricant possesses excellent
Seal compatibility, is shown as neutral to slight swelling feature to conventional seals material；And additive is molten in synthetic ester lubricant
Xie Du and excellent performance, and synthetic ester lubricant is more preferable with the compatibility of other components.The high/low temperature performance of synthetic ester lubricant is good
It is good, during synthetic ester lubricant answered into open type gear oil composition used in this invention, the startup and spray of pump under high/low temperature can be met
The use penetrated.In addition, synthetic ester lubricant does not exist absorption competition with extreme pressure anti-wear additives in metal surface, therefore, ester of the invention
Class artificial oil nor affects on the performance of its extreme pressure and antiwear behavior.
Specifically, the degree of polymerization of the synthetic ester lubricant is 1-100, more preferably 5-20.By changing synthetic ester lubricant
The degree of polymerization, the open type gear oil composition of various range of viscosities can be prepared；By changing alkyl and ester group in main chain
Comonomer ratio, can prepare the open type gear oil composition of opposed polarity size.Therefore, it can be flown according to exposed gear
Splash, be added dropwise, infiltrating and various lubricating system requirements such as oil foglubrication, so as to flexibly select suitable product.
In the present invention, according to the method for testing of GB/T265, kinematic viscosity of the synthetic ester lubricant at 100 DEG C is 15
~3000mm2/s。
Open type gear oil composition of the invention, wherein, the addition of the extreme pressure anti-wear additives is 0.1-8%, excellent
Elect 1-6% as.When the addition of extreme pressure anti-wear additives is less than 0.1%, it is impossible to provide sufficient pole to open type gear oil composition
Pressure abrasion resistance, when the addition of extreme pressure anti-wear additives is more than 8%, the extreme pressure anti-wear of open type gear oil composition can enter
One step is improved, the utilization rate reduction of extreme pressure anti-wear additives, cost of material increase, while can also influence the anti-of open type gear oil composition
Oxidation and metal erosion performance.
The extreme pressure anti-wear additives include：One or two in sulfur-bearing extreme pressure anti-wear additives, phosphorous extreme pressure anti-wear additives.It is preferred that
Ground, the sulfur-bearing extreme pressure anti-wear additives include：Sulfide aliphatic acid ester, olefine sulfide, sulfide isobutene, benzyl polysulfide are (for example：
Benzyl disulfide etc.), phenyl polysulfide, dialkyl dithiocarbamate (for example：Dibutyl dithiocaarbamate
Salt, the trade mark：T351 etc.), dialkyl dithio amino formate (for example：Di-2-ethylhexylphosphine oxide (Keywords dibutyl dithiocarbamate),
The trade mark：Vanlube7723 etc.) in one or more；The phosphorous extreme pressure anti-wear additives include：Triphenyl phosphate, tripotassium phosphate
Phenolic ester, acid phosphoric acid ester, alkyl phosphate, alkyl phosphoric acid amine are (for example：The trade mark：Vanlube672 etc.), aryl phosphoric acids amine, two sulphur
One or more in substituted phosphate, ashless organic phospho acid amine salt.
Open type gear oil composition of the invention, wherein, the extreme pressure anti-wear additives include：Sulfur-bearing extreme pressure anti-wear additives and
Phosphorous extreme pressure anti-wear additives.Extreme pressure anti-wear additives of the invention have synergy well with synthetic ester lubricant.Further, this hair
Bright synthetic ester lubricant can help reduce frictional force in the oil film that metal surface is formed, and reduce metal surface friction temperature, prolong
The time that slow element sulphur and/or P elements react with frictional contact surface.
Specifically, the sulfur-bearing extreme pressure anti-wear additives and the mass ratio of phosphorous extreme pressure anti-wear additives are 1:4~4:1, preferably 1:2
~2:1.The mass ratio of sulfur-bearing extreme pressure anti-wear additives and phosphorous extreme pressure anti-wear additives is 1:4~4:When in the range of 1, can be according to metal
Skin-friction temperature and bear the height of load pressure and targetedly reacted with the ferro element of frictional contact surface, and then altogether
Acted on extreme-pressure anti-wear is played.Therefore, in open type gear oil composition of the invention, sulfur-bearing extreme pressure anti-wear additives and phosphorous extreme pressure are anti-
Grinding agent is added according to suitable ratio, can further improve the combination property of open type gear oil composition of the present invention.
Open type gear oil composition of the invention, wherein, the addition of oiliness anti-friction composition is 0.03-3.0%, preferably
It is 0.1-1.5%.When the addition of oiliness anti-friction composition is less than 0.03%, it is impossible to provide sufficient to open type gear oil composition
Lubricity and anti-attrition, when the addition of oiliness anti-friction composition is more than 3.0%, except under the utilization rate that can make oiliness anti-friction composition
Drop, outside influence cost performance, can also influence point aqueous energy of open type gear oil composition.
Specifically, the oiliness anti-friction composition includes：In aliphatic acid, fatty acid ester, fatty alcohol, amine salt, organosulfur compound
One or more；Preferably, the oiliness anti-friction composition includes：Ten dihydroxystearic acids, stearic acid, oleic acid, butyl oleate, list
One or more in olein, oleic acid epoxy ester.
Open type gear oil composition of the invention, wherein, the addition of the matal deactivator is 0.01-0.5%,
Preferably 0.03-0.1%.When the addition of matal deactivator is less than 0.01%, it is impossible to provided to open type gear oil composition
Sufficient metal passivation, and when the addition of matal deactivator is more than 0.5%, the metal passivation for being played is not yet
Can be further continued for improving, utilization rate and the cost performance reduction of matal deactivator.
Specifically, the matal deactivator includes：Benzotriazole or derivatives thereof, benzothiazole or derivatives thereof, thiadiazoles
Or derivatives thereof, one or more in benzimidazole or derivatives thereof, indazole or derivatives thereof.
Open type gear oil composition of the invention, wherein, the addition of the antioxidant is 0.3-3.0%, preferably
It is 0.5-1.5%.Specifically, the antioxidant includes：One or two in amine antioxidants, phenolic antioxidant；Preferably,
The amine antioxidants include：It is right, one or more in p- dioctyl diphenylamine, octyl group butyl diphenylamines, naphthylamines；It is described
Phenolic antioxidant includes the one kind or two in DBPC 2,6 ditertiary butyl p cresol, double (3,5- di-tert-butyl-4-hydroxyl benzyls) thioethers
Kind.
In addition, in open type gear oil composition of the invention, can also be containing in antirust agent, anticorrosive, demulsifier etc.
One or more, it is also possible to do not contain graphite and pitch.
The raw material of open type gear oil composition of the invention is simple and easy to get, and cost performance is high, and safe when using, not dirty
Dye environment, the scope of application widely, is very beneficial to industrialized production popularization.
The present invention also provides a kind of preparation method of open type gear oil composition of the invention, and it includes：Will be described
The step of each component of open type gear oil composition mixes.
Specifically, the method according to the invention, comprises the following steps：
Synthetic ester lubricant is added in reactor, maintains temperature at 75-90 DEG C, be subsequently adding oiliness anti-friction composition, stirred
To homogeneous transparent, stopping is heated and cools the temperature to 40-60 DEG C, then extreme pressure anti-wear additives, antioxidant, matal deactivator are added to
In reactor, it is stirred until homogeneous transparent, obtains open type gear oil composition.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is unreceipted specific in embodiment
Condition person, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or the unreceipted production firm person of instrument, are
Can by city available from conventional products.
Embodiment 1
By 94.4 weight portion synthetic ester lubricant (manufacturers：Italmatch Chemicals, the trade mark：
Ketjenlube2700, the synthetic ester lubricant by 14 alhpa olefins, 16 alhpa olefins and maleic anhydride and ethanol reaction
Product copolymerization is formed, and its average weight-average molecular weight is 7000Da, No. CAS：173521-40-9) it is added in reactor, maintains kettle
Temperature is at 80 DEG C；Ten dihydroxystearic acids of 1 weight portion are added, is stirred until homogeneous transparent, stop heating and with cooling water by kettle temperature
It is down to 50 DEG C；Again successively by the sulfide isobutene (manufacturer of 2 weight portions：Bo great Chemical Co., Ltd.s, the trade mark：T321, under
Together), the tricresyl phosphate (manufacturer of 1.5 weight portions：Bo great Chemical Co., Ltd.s, the trade mark：T306, similarly hereinafter), 1 weight portion
Octyl group butyl diphenylamines, the benzotriazole derivative (manufacturer of 0.1 weight portion：Jinzhou limited public affairs of safe lube oil additive
Department, the trade mark：T551, similarly hereinafter) be added in mediation kettle, stirring to mixture is all dissolved, homogeneous transparent, obtains exposed gear oil
Composition I.
Embodiment 2
Except the tricresyl phosphate of 1.5 weight portions in embodiment 1 is changed into the sulfide isobutene of 1.5 weight portions with
Outward, according to method same as Example 1, open type gear oil composition II is prepared.
Comparative example 1
Polyisobutene (production except the synthetic ester lubricant of 94.4 weight portions in embodiment 1 to be changed into 69.4 weight portions
Producer：Great Lin Co., Ltds of South Korea, the trade mark：PB950) and 25 weight portions polyisobutene (manufacturer：The limited public affairs of South Korea great Lin
Department, the trade mark：PB1300 beyond), according to method same as Example 1, open type gear oil composition III is prepared.
Comparative example 2
Polyalphaolefin PAO300 except the synthetic ester lubricant of 94.4 weight portions in embodiment 1 to be changed into 54.4 weight portions
(manufacturer：Exxon Mobil Chemical, the trade mark：SpectraSyn Elite 300) and 40 weight portions high-viscosity compound
Close ester (manufacturer：Croda Company, Inc, the trade mark：Priolube3986, similarly hereinafter) beyond, according to same as Example 1
Method, prepare open type gear oil composition IV.
Comparative example 3
Except changing the tricresyl phosphate of the sulfide isobutene of 2 weight portions in embodiment 1 and 1.5 weight portions into 3.5
Three potassium borate neutral oil dispersion liquid (manufacturers of weight portion：Tiarco Chemical, the trade mark：OCTOPOL PTB) beyond,
According to method same as Example 1, open type gear oil composition V is prepared.
Above-mentioned open type gear oil composition I, II, III, IV and V carry out performance test respectively, and testing result is as shown in table 1：
Table 1
As can be seen from Table 1, there is the open type gear oil composition I prepared by the present invention viscosity and viscosity higher to refer to
Number；Open type gear oil composition I pour points can arrive -12 DEG C, of the invention in addition with good low temperature flow and pump startup
Open type gear oil composition also has oxidation stability and extreme pressure and antiwear behavior higher, and viscosity build rate is low, and combination property is excellent
It is different.
By embodiment 2 as can be seen that only with the addition of sulfur-bearing extreme pressure anti-wear additives when open type gear oil composition II is prepared, and
Without the phosphorous extreme pressure anti-wear additives of addition, its PB value remains to reach 1186N, excellent abrasion resistance is shown, due to ester used
Contain more polar ester functional groups in class artificial oil, diaphragm can be formed in friction surface, increase exposed gear oil combination
The lubrication abrasion resistance of thing.
Relative to open type gear oil composition I, due in comparative example 1 using oil based on polyisobutene, it is prepared
The viscosity index (VI) of open type gear oil composition III is relatively low, and viscosity temperature characteristic is poor, and pour point is higher, high temperature, the bad adaptability of low temperature,
Be not suitable for the operation in the operating mode of wide temperature range change.And because polyisobutene is free of polar ester functional groups, it is not easy to
Friction surface forms thick oil film, thus itself PB and PD value is relatively low, and wear scar diameter is also bigger than normal, extreme-pressure anti-wear Wear vesistance
Equal deviation.In addition, the viscosity build rate of the oxidation stability of open type gear oil composition III is than open type gear oil composition I's
Higher, its oxidation stability is poor.
In comparative example 2, because polyalphaolefin PAO300 and high viscosity complex ester are incompatible, obtained exposed gear oil group
Compound IV muddinesses are opaque, and this also indicates that the composition that only cannot obtain having concurrently polyalphaolefin and Esters oil advantage by blending, uses
Synthetic ester lubricant can avoid above inconsistent problem.
By comparative example 3 as can be seen that relative to open type gear oil composition I and II, the PB values of open type gear oil composition V
Relatively low with PD values, wear scar diameter is bigger than normal, and this shows that the present invention uses synthetic ester lubricant and sulfur-bearing and/or phosphorous extreme-pressure anti-wear
The compatibility of agent is good, and the synergy with extreme-pressure anti-wear can obtain the more excellent exposed gear of extreme pressure and antiwear behavior
Fluid composition.
Embodiment 3
By the synthetic ester lubricant (manufacturer of 93.4 weight portions：Italmatch Chemicals, the trade mark：
Ketjenlube23000, the synthetic ester lubricant is anti-by 14 alhpa olefins, 16 alhpa olefins and maleic anhydride and ethanol
Product copolymerization is answered to form, its average weight-average molecular weight is 10000Da, No. CAS：173521-40-9) it is added in reactor, ties up
Kettle temperature is held at 80 DEG C；Add the oleic acid of 1.5 weight portions, be stirred until homogeneous it is transparent, stop heating simultaneously kettle temperature is down to cooling water
40℃；Again successively by di-2-ethylhexylphosphine oxide (Keywords dibutyl dithiocarbamate) (manufacturer of 2.5 weight portions：The U.S.
Vanderbilt Company, the trade mark：Vanlube7723), the ashless organic phospho acid amine salt (manufacturer of 2 weight portions：Bohai Sea is big
Chemical Co., Ltd., the trade mark：KT139), the octyl group butyl diphenylamines of 0.5 weight portion, the benzotriazole derivative of 0.1 weight portion, plus
Enter in mediation kettle, stirring to mixture is all dissolved, homogeneous transparent, obtains finished product open type gear oil composition VI.
Comparative example 4
In addition to changing the synthetic ester lubricant in embodiment 3 into high viscosity complex ester, according to side same as Example 3
Method, prepares open type gear oil composition VII.
Above-mentioned open type gear oil composition VI and VII carries out performance test respectively, and testing result is as shown in table 2：
Table 2
Be can see by table 2, the open type gear oil composition VI as prepared by synthetic ester lubricant equally glues with higher
Degree index, oxidation stability and extreme pressure and antiwear behavior.Its viscosity index (VI) is up to more than 300, and viscosity temperature characteristic is very excellent, maximum nothing
Seizing load PB values are up to more than 1700N, excellent combination property.
In addition, the oxidation stability and pour point of open type gear oil composition VII as prepared by high viscosity complex ester are all poor
In open type gear oil composition VI, extreme pressure and antiwear behavior is also slightly less than open type gear oil composition VI, further illustrates the present invention
Synthetic ester lubricant and sulfur-bearing and/or phosphorous extreme pressure anti-wear additives there is preferable compatibility.
In sum, the present invention uses synthetic ester lubricant, while adding suitable additive, it is ensured that exposed gear oil group
Compound has viscosity and viscosity temperature characteristic higher, it is to avoid the situation that summer is easy to run off, winter hardly possible flows occur, and beneficial to open type tooth
The formation and holding of lubricating oil film during wheel fluid composition use；Secondly, open type gear oil composition of the invention has excellent
Different low temperature flowability, expands its temperature in use scope；Furthermore, open type gear oil composition of the invention in use can
Bring gear pair in the low fluid friction of load area, reduce operation temperature, the raising gear of little gear and gear drive
Efficiency.
In addition, from embodiment 1 and embodiment 3 as can be seen that open type gear oil composition of the invention can be prepared
The exposed gear oil of different viscosities rank, the wider model of range of application.
Claims (10)
1. a kind of open type gear oil composition, it is characterised in that the gross weight with the open type gear oil composition is 100%
Meter, comprising following components：
Synthetic ester lubricant：85.5-99.56%, preferably 90.9-98.37%, more preferably 92-96%；
Extreme pressure anti-wear additives：0.1-8%, preferably 1-6%；
Oiliness anti-friction composition：0.03-3.0%, preferably 0.1%-1.5%；
Matal deactivator：0.01-0.5%, preferably 0.03%-0.1%；
Antioxidant：0.3-3.0%, preferably 0.5%-1.5%.
2. open type gear oil composition according to claim 1, it is characterised in that the synthetic ester lubricant contains including main chain
There is the copolymer of alkyl and ester group, preferably include the copolymer of alhpa olefin and unsaturated Esters oil, wherein, the carbon of the alhpa olefin is former
Subnumber is the integer between 1-22, the integer between preferably 5-17；Preferably, the unsaturated Esters oil includes unsaturated acids
Unsaturated dibasic acid esters prepared by acid anhydride and alcohol reaction；
Preferably, the average weight-average molecular weight of the synthetic ester lubricant is 1000-10000Da, preferably 3000-10000Da.
3. open type gear oil composition according to claim 1 and 2, it is characterised in that the extreme pressure anti-wear additives include：Contain
One or two in sulphur extreme pressure anti-wear additives, phosphorous extreme pressure anti-wear additives；Preferably, the sulfur-bearing extreme pressure anti-wear additives include：Vulcanization
Fatty acid ester, olefine sulfide, sulfide isobutene, benzyl polysulfide, phenyl polysulfide, dialkyldithiocarbamacompositions
One or more in salt, dialkyl dithio amino formate；The phosphorous extreme pressure anti-wear additives include：Triphenyl phosphate, phosphorus
It is sour front three phenolic ester, acid phosphoric acid ester, alkyl phosphate, alkyl phosphoric acid amine, aryl phosphoric acids amine, phosphorodithioate, ashless organic
One or more in phosphonic amine salt.
4. open type gear oil composition according to claim 3, it is characterised in that the extreme pressure anti-wear additives include：Sulfur-bearing
Extreme pressure anti-wear additives and phosphorous extreme pressure anti-wear additives；Preferably, the mass ratio of the sulfur-bearing extreme pressure anti-wear additives and phosphorous extreme pressure anti-wear additives
It is 1:4~4:1, preferably 1:2~2:1.
5. the open type gear oil composition according to any one of Claims 1 to 4, it is characterised in that the oiliness anti-friction composition
Including：One or more in aliphatic acid, fatty acid ester, fatty alcohol, amine salt, organosulfur compound；Preferably, the oiliness subtracts
Grinding agent includes：One kind in ten dihydroxystearic acids, stearic acid, oleic acid, butyl oleate, glyceryl monooleate, oleic acid epoxy ester
Or it is various.
6. the open type gear oil composition according to any one of Claims 1 to 5, it is characterised in that the matal deactivator
Including：Benzotriazole or derivatives thereof, benzothiazole or derivatives thereof, thiadiazoles or derivatives thereof, benzimidazole or derivatives thereof,
One or more in indazole or derivatives thereof.
7. the open type gear oil composition according to any one of claim 1~6, it is characterised in that the antioxidant includes：
One or two in amine antioxidants, phenolic antioxidant；Preferably, the amine antioxidants include：It is right, p- dioctyl two
One or more in aniline, octyl group butyl diphenylamines, naphthylamines；The phenolic antioxidant include DBPC 2,6 ditertiary butyl p cresol,
One or two in double (3,5- di-tert-butyl-4-hydroxyl benzyls) thioethers.
8. the open type gear oil composition according to any one of claim 1~7, it is characterised in that the exposed gear oil
Composition also includes one or more in antirust agent, anticorrosive, demulsifier.
9. the open type gear oil composition according to any one of claim 1~8, it is characterised in that according to the survey of GB/T265
Method for testing, kinematic viscosity of the synthetic ester lubricant at 100 DEG C is 15~3000mm2/s。
10. the preparation method of a kind of open type gear oil composition according to any one of claim 1~9, it is characterised in that
The step of including each component of the open type gear oil composition is mixed.
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| CN107474914A (en) * | 2017-07-19 | 2017-12-15 | 沈阳迈腾石化有限公司 | A kind of fully synthetic extreme pressure exposed gear oil and its synthetic method |
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| CN107502416A (en) * | 2017-09-30 | 2017-12-22 | 徐州翔凯重工科技有限公司 | A kind of engineering machinery fire-resistant lubricants composition and preparation method thereof |
| CN108410561A (en) * | 2018-05-10 | 2018-08-17 | 广州雷斯曼新材料科技有限公司 | A kind of gear oil and preparation method thereof |
| CN109370721A (en) * | 2018-11-01 | 2019-02-22 | 江苏龙蟠科技股份有限公司 | The excellent heavy duty automobile gear oil composition and preparation method thereof of shear stability |
| CN109370721B (en) * | 2018-11-01 | 2021-11-23 | 江苏龙蟠科技股份有限公司 | Heavy-duty vehicle gear oil composition with excellent shear stability and preparation method thereof |
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